Knowledge (XXG)

Oxazines

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are a class of polymers formed by the reaction of phenols, formaldehyde, and primary amines which on heating to ~200 °C (~400 °F) polymerise to produce polybenzoxazine networks. The resulting high molecular weight
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Tietze R, Chaudhari M (2011). "Advanced benzoxazine chemistries provide improved performance in a broad range of applications". In Ishida H, Agag T (eds.).
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composites are used where enhanced mechanical performance, flame and fire resistance compared to epoxy and phenolic resins is required.
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Tappe H, Helmling W, Mischke P, Rebsamen K, Reiher U, Russ W, Schläfer L, Vermehren P (2000). "Reactive Dyes".
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are pentacyclic compounds consisting of two oxazine subunits. A commercially important example is the pigment
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are bicyclic compounds formed by the ring fusion of a benzene ring with an oxazine.
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The Chemistry of Heterocycles: Structures, Reactions, Synthesis, and Applications
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By extension, the derivatives are also referred to as oxazines; examples include
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E heterocyclic organic compounds containing one oxygen and one nitrogen atom
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Chamberlain T (2002). "Dioxazine violet pigments". In Smith HM (ed.).
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Benzoxazine resin synthetic pathway, structure and cure mechanism
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Development of polymeric materials as a class of benzoxazines
256:Stone TW, Stoy N, Darlington LG (February 2013). 221:Eicher T, Hauptmann S, Speicher A (March 2013). 53:exist depending on the relative position of the 429:"Predicting the UV-vis spectra of oxazine dyes" 49:ring (a doubly unsaturated six-membered ring). 333:Ullmann's Encyclopedia of Industrial Chemistry 8: 427:Fleming S, Mills A, Tuttle T (2011-04-15). 302:. John Wiley & Sons. pp. 185–194. 364:Tsotra P, Setiabudi F, Weidmann U (2008). 481:at the U.S. National Library of Medicine 452: 227:(3rd ed.). Wiley Inc. p. 442. 18: 213: 162: 76:of aldehydes. Fluorescent dyes such as 433:Beilstein Journal of Organic Chemistry 7: 84:are based on the aromatic compound 404:10.1016/B978-0-444-53790-4.00079-5 398:. Elsevier B.V. pp. 595–604. 265:Trends in Pharmacological Sciences 114:Synthetic route to dioxazine dyes. 14: 203:is a commercially useful pigment. 193: 179: 165: 396:Handbook of Benzoxazine Resins 1: 57:and relative position of the 520: 277:10.1016/j.tips.2012.09.006 300:High Performance Pigments 483:Medical Subject Headings 341:10.1002/14356007.a22_651 141:thermoset polymer matrix 23:The 8 isomers of oxazine 335:. Weinheim: Wiley-VCH. 308:10.1002/3527600493.ch12 128: 115: 24: 151:Oxazine dyes exhibit 126: 113: 22: 147:Physical properties 47:cyclohexa-1,4-diene 129: 116: 25: 445:10.3762/bjoc.7.56 413:978-0-444-53790-4 317:978-3-527-30204-8 234:978-3-527-66987-5 201:Pigment violet 23 105:pigment violet 23 35:organic compounds 511: 467: 466: 456: 424: 418: 417: 391: 385: 384: 370: 361: 355: 354: 328: 322: 321: 295: 289: 288: 262: 253: 247: 246: 218: 197: 183: 169: 136:Polybenzoxazines 86:benzophenoxazine 74:Meyers synthesis 519: 518: 514: 513: 512: 510: 509: 508: 494: 493: 475: 470: 426: 425: 421: 414: 393: 392: 388: 368: 363: 362: 358: 351: 330: 329: 325: 318: 297: 296: 292: 260: 255: 254: 250: 235: 220: 219: 215: 211: 204: 198: 189: 184: 175: 170: 161: 153:solvatochromism 149: 121: 98: 37:containing one 17: 12: 11: 5: 517: 515: 507: 506: 496: 495: 492: 491: 486: 474: 473:External links 471: 469: 468: 419: 412: 386: 356: 349: 323: 316: 290: 248: 233: 212: 210: 207: 206: 205: 199: 192: 190: 185: 178: 176: 171: 164: 160: 157: 148: 145: 120: 117: 97: 94: 15: 13: 10: 9: 6: 4: 3: 2: 516: 505: 502: 501: 499: 490: 487: 484: 480: 477: 476: 472: 464: 460: 455: 450: 446: 442: 438: 434: 430: 423: 420: 415: 409: 405: 401: 397: 390: 387: 382: 378: 374: 367: 360: 357: 352: 346: 342: 338: 334: 327: 324: 319: 313: 309: 305: 301: 294: 291: 286: 282: 278: 274: 271:(2): 136–43. 270: 266: 259: 252: 249: 244: 240: 236: 230: 226: 225: 217: 214: 208: 202: 196: 191: 188: 182: 177: 174: 168: 163: 158: 156: 154: 146: 144: 142: 137: 133: 125: 118: 112: 108: 106: 102: 95: 93: 91: 87: 83: 79: 75: 71: 67: 62: 60: 56: 52: 48: 44: 40: 36: 33: 29: 21: 436: 432: 422: 395: 389: 372: 359: 332: 326: 299: 293: 268: 264: 251: 223: 216: 150: 132:Benzoxazines 130: 119:Benzoxazines 100: 99: 63: 59:double bonds 32:heterocyclic 27: 26: 439:: 432–441. 373:Engineering 187:Phenoxazine 55:heteroatoms 350:3527306730 209:References 173:Morpholine 101:Dioxazines 96:Dioxazines 90:tryptophan 70:morpholine 66:ifosfamide 45:atom in a 243:836864122 82:Nile blue 504:Oxazines 498:Category 479:Oxazines 463:21647257 381:18422389 285:23123095 78:Nile red 43:nitrogen 41:and one 28:Oxazines 454:3107493 51:Isomers 485:(MeSH) 461:  451:  410:  379:  347:  314:  283:  241:  231:  159:Images 39:oxygen 377:S2CID 369:(PDF) 261:(PDF) 459:PMID 408:ISBN 345:ISBN 312:ISBN 281:PMID 239:OCLC 229:ISBN 80:and 68:and 30:are 449:PMC 441:doi 400:doi 337:doi 304:doi 273:doi 500:: 457:. 447:. 435:. 431:. 406:. 375:. 371:. 343:. 310:. 279:. 269:34 267:. 263:. 237:. 155:. 107:. 92:. 61:. 465:. 443:: 437:7 416:. 402:: 383:. 353:. 339:: 320:. 306:: 287:. 275:: 245:.

Index


heterocyclic
organic compounds
oxygen
nitrogen
cyclohexa-1,4-diene
Isomers
heteroatoms
double bonds
ifosfamide
morpholine
Meyers synthesis
Nile red
Nile blue
benzophenoxazine
tryptophan
pigment violet 23


Benzoxazines
Polybenzoxazines
thermoset polymer matrix
solvatochromism
Morpholine
Morpholine
Phenoxazine
Phenoxazine
Pigment violet 23 is a commercially useful pigment.
Pigment violet 23
The Chemistry of Heterocycles: Structures, Reactions, Synthesis, and Applications

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