Knowledge (XXG)

Oxygenate

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the use of oxygenated gasoline in certain areas during winter to regulate carbon monoxide emissions; however, the programs to fulfill its conditions are implemented by the states. In addition to this North American automakers from 2006 onwards promoted a blend of 85% ethanol and 15% gasoline,
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it is not capable of producing as much energy per gallon as gasoline. Much gasoline sold in the United States is blended with up to 10% of an oxygenating agent. This is known as oxygenated fuel and often (but not entirely correctly, as there are reformulated gasolines without oxygenate) as
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can be grouped with oxygenates in the simple definition that they contain at least one oxygen atom. However, they are usually unwanted in oils, and therefore likely fuels, due to their environmental toxicity and tendency to cause
230:(EPA) had authority to mandate that minimum proportions of oxygenates be added to automotive gasoline on regional and seasonal basis from 1992 until 2006 in an attempt to reduce air pollution, in particular 262:
bonus to vehicles capable of running on 85% alcohol blends over vehicles not adapted to run on 85% alcohol blends. There is also alcohols' intrinsically cleaner combustion, however due to its lower
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Inal, Fikret; Senkan, Selim M. (2002). "Effects of oxygenate additives on polycyclic aromatic hydrocarbons(pahs) and soot formation".
275:. Typically, gasoline with added MTBE is called reformulated gasoline, while gasoline with ethanol is called oxygenated gasoline. 62: 255: 126: 20: 537: 397:"Versatile One-Pot Tandem Conversion of Biomass-Derived Light Oxygenates into High-Yield Jet Fuel Range Aromatics" 271:-butyl ether (MTBE) was the most common fuel additive in the United States, prior to government mandated use of 180: 161: 356: 189: 171: 199: 70: 361: 322: 239: 547: 77: 374: 231: 102: 457: 418: 208: 131: 58: 449: 408: 366: 519: 437: 259: 93: 50: 490: 436:
Ni, Wei; Zhu, Gangtian; Liu, Fei; Li, Zhiyong; Xie, Can; Han, Yuanjia (19 August 2021).
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in fuel mixtures. Oxygenates can also be employed to reduce air pollution by reducing
531: 223: 42: 453: 396: 378: 438:"Carboxylic Acids in Petroleum: Separation, Analysis, and Geochemical Significance" 147: 35: 370: 46: 461: 422: 413: 137: 106: 66: 116: 89: 514: 395:
Yeboah, Isaac; Feng, Xiang; Rout, Kumar R.; Chen, De (27 October 2021).
272: 122: 476:"Code of Federal Regulations, title 40, part 600, section 600.510-93" 85: 30:
means to impregnate, combine, or supply something with oxygen, while
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Chemical compounds containing oxygen often used as fuel additives
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polyaromatic hydrocarbons that are side-products caused by
478:. United States Government Printing Office. 1 August 2005. 38:
containing at least one oxygen atom that are used as
401:Industrial & Engineering Chemistry Research 8: 412: 360: 258:(CAFE) standards give an artificial 54% 284: 254:'s Live Green, Go Yellow campaign. US 92:are also included in this distinction. 491:"MTBE, Oxygenates, and Motor Gasoline" 76:The most common oxygenates are either 7: 489:Lidderdale, Tancred (6 March 2000). 390: 388: 290: 288: 109:during oil production and refining. 57:particle size and compounds such as 14: 498:Energy Information Administration 349:Combustion Science and Technology 247:, and their flex-fuel vehicles, 454:10.1021/acs.energyfuels.1c01518 228:Environmental Protection Agency 267:reformulated gasoline. Methyl 256:Corporate Average Fuel Economy 1: 520:USGS Definition of Oxygenates 321:US EPA, OAR (7 August 2015). 515:EPA Definition of Oxygenates 323:"Gasoline Winter Oxygenates" 127:Common ethanol fuel mixtures 564: 18: 371:10.1080/00102200290021353 296:"Definition of OXYGENATE" 63:polyaromatic hydrocarbons 414:10.1021/acs.iecr.1c02994 300:www.merriam-webster.com 238:. As of 2023, the EPA 71:incomplete combustion 59:aromatic hydrocarbons 240:continues to require 218:In the United States 45:to promote complete 19:For other uses, see 448:(16): 12828–12844. 407:(42): 15095–15105. 184:-Hexyl methyl ether 538:Petroleum products 442:Energy & Fuels 232:ground-level ozone 175:-Amyl methyl ether 103:catalyst poisoning 209:Diisopropyl ether 203:-Amyl ethyl ether 132:Isopropyl alcohol 125:(EtOH); see also 555: 502: 501: 495: 486: 480: 479: 472: 466: 465: 433: 427: 426: 416: 392: 383: 382: 364: 344: 338: 337: 335: 333: 318: 312: 311: 309: 307: 292: 94:Carboxylic acids 563: 562: 558: 557: 556: 554: 553: 552: 528: 527: 525: 511: 506: 505: 493: 488: 487: 483: 474: 473: 469: 435: 434: 430: 394: 393: 386: 362:10.1.1.524.1105 346: 345: 341: 331: 329: 320: 319: 315: 305: 303: 294: 293: 286: 281: 260:fuel efficiency 220: 146:Gasoline grade 53:production and 51:carbon monoxide 24: 17: 12: 11: 5: 561: 559: 551: 550: 545: 540: 530: 529: 523: 522: 517: 510: 509:External links 507: 504: 503: 481: 467: 428: 384: 339: 313: 302:. 2 March 2024 283: 282: 280: 277: 264:energy density 219: 216: 215: 214: 213: 212: 206: 197: 187: 178: 169: 156: 155: 154: 144: 135: 129: 120: 15: 13: 10: 9: 6: 4: 3: 2: 560: 549: 546: 544: 541: 539: 536: 535: 533: 526: 521: 518: 516: 513: 512: 508: 499: 492: 485: 482: 477: 471: 468: 463: 459: 455: 451: 447: 443: 439: 432: 429: 424: 420: 415: 410: 406: 402: 398: 391: 389: 385: 380: 376: 372: 368: 363: 358: 354: 350: 343: 340: 328: 324: 317: 314: 301: 297: 291: 289: 285: 278: 276: 274: 270: 265: 261: 257: 253: 250: 246: 241: 237: 233: 229: 225: 224:United States 217: 210: 207: 204: 202: 198: 195: 193: 188: 185: 183: 179: 176: 174: 170: 167: 165: 160: 159: 157: 152: 150: 145: 142: 140: 136: 133: 130: 128: 124: 121: 118: 115: 114: 112: 111: 110: 108: 104: 99: 95: 91: 87: 83: 79: 74: 72: 68: 64: 60: 56: 52: 48: 44: 41: 37: 33: 29: 22: 524: 497: 484: 470: 445: 441: 431: 404: 400: 352: 348: 342: 330:. Retrieved 326: 316: 304:. Retrieved 299: 268: 248: 243:marketed as 221: 200: 194:-butyl ether 191: 181: 172: 166:-butyl ether 163: 148: 138: 75: 36:hydrocarbons 31: 27: 25: 355:(9): 1–19. 327:www.epa.gov 21:Oxygenation 548:Oxygenates 532:Categories 279:References 113:Alcohols: 47:combustion 32:oxygenates 462:0887-0624 423:0888-5885 357:CiteSeerX 107:corrosion 90:aldehydes 43:additives 28:oxygenate 379:56015797 332:17 March 306:17 March 158:Ethers: 151:-butanol 141:-Butanol 117:Methanol 78:alcohols 67:nitrated 273:ethanol 222:In the 186:(THEME) 162:Methyl 123:Ethanol 86:ketones 460:  421:  377:  359:  226:, the 211:(DIPE) 205:(TAEE) 196:(ETBE) 190:Ethyl 177:(TAME) 168:(MTBE) 153:(GTBA) 143:(BuOH) 119:(MeOH) 98:esters 84:, but 82:ethers 65:, and 543:Fuels 494:(PDF) 375:S2CID 134:(IPA) 458:ISSN 419:ISSN 334:2024 308:2024 269:tert 249:e.g. 236:smog 234:and 201:tert 192:tert 182:tert 173:tert 164:tert 149:tert 105:and 96:and 88:and 55:soot 40:fuel 34:are 450:doi 409:doi 367:doi 353:174 245:E85 80:or 26:To 534:: 496:. 456:. 446:35 444:. 440:. 417:. 405:60 403:. 399:. 387:^ 373:. 365:. 351:. 325:. 298:. 287:^ 252:GM 73:. 61:, 500:. 464:. 452:: 425:. 411:: 381:. 369:: 336:. 310:. 139:n 23:.

Index

Oxygenation
hydrocarbons
fuel
additives
combustion
carbon monoxide
soot
aromatic hydrocarbons
polyaromatic hydrocarbons
nitrated
incomplete combustion
alcohols
ethers
ketones
aldehydes
Carboxylic acids
esters
catalyst poisoning
corrosion
Methanol
Ethanol
Common ethanol fuel mixtures
Isopropyl alcohol
n-Butanol
tert-butanol
Methyl tert-butyl ether
tert-Amyl methyl ether
tert-Hexyl methyl ether
Ethyl tert-butyl ether
tert-Amyl ethyl ether

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