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AD-mix

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154: 125: 40:. The two letters AD, stand for asymmetric dihydroxylation. The mix is available in two variations, "AD-mix α" and "AD-mix β" following ingredient lists published by 240: 33: 72: 93: 29: 181: 153: 124: 84: 17: 201: 143: 67: 51: 88: 41: 110: 225: 234: 189: 139: 106: 205: 37: 25: 222:Catalytic Asymmetric Dihydroxylation of Alkenes 32:for various chemical reactions, including the 8: 170: 24:is a commercially available mixture of 7: 34:Sharpless asymmetric dihydroxylation 14: 152: 123: 241:Reagents for organic chemistry 1: 224:at Imperial College London 257: 134:AD-mix β contains (DHQD) 101:AD-mix α contains (DHQ) 73:Potassium ferricyanide 206:10.1021/jo00036a003 94:Potassium carbonate 47:The mixes contain: 30:asymmetric catalyst 98:A chiral ligand: 66:as the source of 18:organic chemistry 248: 209: 182:Sharpless, K. B. 180: 175: 156: 144:dihydroquinidine 127: 68:Osmium tetroxide 52:Potassium osmate 28:that acts as an 256: 255: 251: 250: 249: 247: 246: 245: 231: 230: 218: 213: 212: 177: 176: 172: 167: 137: 104: 89:catalytic cycle 83:, which is the 82: 78: 65: 61: 57: 42:Barry Sharpless 12: 11: 5: 254: 252: 244: 243: 233: 232: 229: 228: 217: 216:External links 214: 211: 210: 200:, 2768-2771. ( 169: 168: 166: 163: 162: 161: 160: 159: 158: 157: 147: 146: 135: 131: 130: 129: 128: 116: 115: 114: 113: 111:dihydroquinine 102: 96: 91: 80: 76: 70: 63: 59: 55: 13: 10: 9: 6: 4: 3: 2: 253: 242: 239: 238: 236: 227: 223: 220: 219: 215: 207: 203: 199: 195: 192: 191: 190:J. Org. Chem. 187: 183: 179: 174: 171: 164: 155: 151: 150: 149: 148: 145: 141: 133: 132: 126: 122: 121: 120: 119: 118: 117: 112: 108: 100: 99: 97: 95: 92: 90: 86: 74: 71: 69: 53: 50: 49: 48: 45: 43: 39: 35: 31: 27: 23: 19: 221: 197: 193: 188: 185: 178: 173: 142:adduct with 109:adduct with 46: 21: 15: 140:phthalazine 107:phthalazine 165:References 138:PHAL, the 105:PHAL, the 85:re-oxidant 235:Category 26:reagents 87:in the 38:alkenes 186:et al. 79:Fe(CN) 22:AD-mix 226:Link 194:1992 62:(OH) 202:doi 58:OsO 36:of 16:In 237:: 198:57 196:, 184:, 44:. 20:, 208:) 204:: 136:2 103:2 81:6 77:3 75:K 64:4 60:2 56:2 54:K

Index

organic chemistry
reagents
asymmetric catalyst
Sharpless asymmetric dihydroxylation
alkenes
Barry Sharpless
Potassium osmate
Osmium tetroxide
Potassium ferricyanide
re-oxidant
catalytic cycle
Potassium carbonate
phthalazine
dihydroquinine
DHQ2PHAL AD-mix
phthalazine
dihydroquinidine
DHQD2PHAL AD-mix
Sharpless, K. B.
J. Org. Chem.
doi
10.1021/jo00036a003
Link
Category
Reagents for organic chemistry

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