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Absolute zero

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934:. However, some systems have a maximum amount of energy that they can hold, and as they approach that maximum energy their entropy actually begins to decrease. Because temperature is defined by the relationship between energy and entropy, such a system's temperature becomes negative, even though energy is being added. As a result, the Boltzmann factor for states of systems at negative temperature increases rather than decreases with increasing state energy. Therefore, no complete system, i.e. including the electromagnetic modes, can have negative temperatures, since there is no highest energy state, so that the sum of the probabilities of the states would diverge for negative temperatures. However, for quasi-equilibrium systems (e.g. spins out of equilibrium with the electromagnetic field) this argument does not apply, and negative effective temperatures are attainable. 2974: 1396: 1104: 2927: 685: 2986: 1085:. It followed from the principles on which this scale was constructed that its zero was placed at −273 °C, at almost precisely the same point as the zero of the air thermometer, where the air volume would reach "nothing". This value was not immediately accepted; values ranging from −271.1 °C (−455.98 °F) to −274.5 °C (−462.10 °F), derived from laboratory measurements and observations of 992:. His instrument indicated temperatures by the height at which a certain mass of air sustained a column of mercury—the pressure, or "spring" of the air varying with temperature. Amontons therefore argued that the zero of his thermometer would be that temperature at which the spring of the air was reduced to nothing. He used a scale that marked the boiling point of water at +73 and the melting point of ice at + 946: 34: 1188: 131: 2025:( whence it appears that the extreme cold of this thermometer would be that which would reduce the air to supporting no load by its spring, ) In other words, the lowest temperature which can be measured by a thermometer which is based on the expansion and contraction of air is that temperature at which the air's pressure ("spring") has decreased to zero. 666:. The Fermi temperature is defined as this maximum energy divided by the Boltzmann constant, and is on the order of 80,000 K for typical electron densities found in metals. For temperatures significantly below the Fermi temperature, the electrons behave in almost the same way as at absolute zero. This explains the failure of the classical 1330:") in gases. The gas is artificially forced out of equilibrium into a high potential energy state, which is, however, cold. When it then emits radiation it approaches the equilibrium, and can continue emitting despite reaching formal absolute zero; thus, the temperature is formally negative. 1159:. In 1898, after 20 years of effort, Dewar was the first to liquefy hydrogen, reaching a new low-temperature record of −252 °C (−421.6 °F; 21.1 K). However, Kamerlingh Onnes, his rival, was the first to liquefy helium, in 1908, using several precooling stages and the 1006:, so that the zero was equivalent to about −240 on the Celsius scale. Amontons held that the absolute zero cannot be reached, so never attempted to compute it explicitly. The value of −240 °C, or "431 divisions below the cold of freezing water" was published by 692:
atoms at a temperature within a few billionths of a degree above absolute zero. Left: just before the appearance of a Bose–Einstein condensate. Center: just after the appearance of the condensate. Right: after further evaporation, leaving a sample of nearly pure
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was observed to have been releasing gases at a speed of 500,000 km/h (310,000 mph) for the last 1,500 years. This has cooled it down to approximately 1 K, as deduced by astronomical observation, which is the lowest natural temperature ever
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in Italy cooled a copper vessel with a volume of one cubic meter to 0.006 kelvins (−273.144 °C; −459.659 °F) for 15 days, setting a record for the lowest temperature in the known universe over such a large contiguous
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had managed to liquefy most gases then known to exist, and reached a new record for lowest temperatures by reaching −130 °C (−202 °F; 143 K). Faraday believed that certain gases, such as oxygen, nitrogen, and
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The implication is that the entropy of a perfect crystal approaches a constant value. An adiabat is a state with constant entropy, typically represented on a graph as a curve in a manner similar to isotherms and isobars.
1163:. He lowered the temperature to the boiling point of helium −269 °C (−452.20 °F; 4.15 K). By reducing the pressure of the liquid helium, he achieved an even lower temperature, near 1.5 K. These were the 1837:
Deppner, Christian; Herr, Waldemar; Cornelius, Merle; Stromberger, Peter; Sternke, Tammo; Grzeschik, Christoph; Grote, Alexander; Rudolph, Jan; Herrmann, Sven; Krutzik, Markus; Wenzlawski, André (30 August 2021).
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system with a positive temperature, in the sense that if a negative-temperature system and a positive-temperature system come in contact, heat flows from the negative to the positive-temperature system.
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Perfect crystals never occur in practice; imperfections, and even entire amorphous material inclusions, can and do get "frozen in" at low temperatures, so transitions to more stable states do not occur.
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approached the question from an entirely different point of view, and in 1848 devised a scale of absolute temperature that was independent of the properties of any particular substance and was based on
1060:) by about 1/273 parts per degree Celsius of temperature's change up or down, between 0° and 100° C. This suggested that the volume of a gas cooled at about −273 °C would reach zero. 1207:
predict that the average temperature of the universe is decreasing over time. This temperature is calculated as the mean density of energy in space; it should not be confused with the mean
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Donley, Elizabeth A.; Claussen, Neil R.; Cornish, Simon L.; Roberts, Jacob L.; Cornell, Eric A.; Wieman, Carl E. (2001). "Dynamics of collapsing and exploding Bose–Einstein condensates".
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cooled molecules in a gas of sodium potassium to a temperature of 500 nanokelvin, and it is expected to exhibit an exotic state of matter by cooling these molecules somewhat further.
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On 3 January 2013, physicists announced that for the first time they had created a quantum gas made up of potassium atoms with a negative temperature in motional degrees of freedom.
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indicate that absolute zero cannot be reached using only thermodynamic means, because the temperature of the substance being cooled approaches the temperature of the cooling agent
976:. But all of them seemed to agree that, "There is some body or other that is of its own nature supremely cold and by participation of which all other bodies obtain that quality." 239:. Even a system at absolute zero, if it could somehow be achieved, would still possess quantum mechanical zero-point energy, the energy of its ground state at absolute zero; the 208:
state possible, because all real substances begin to depart from the ideal gas when cooled as they approach the change of state to liquid, and then to solid; and the sum of the
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at −195 °C (−319.0 °F; 78.1 K). This was followed in 1883 by the production of liquid oxygen −218 °C (−360.4 °F; 55.1 K) by the Polish professors
1028:, in their 1780 treatise on heat, arrived at values ranging from 1,500 to 3,000 below the freezing point of water, and thought that in any case it must be at least 600 below. 1234:
has produced temperatures of less than a billionth of a kelvin. At very low temperatures in the vicinity of absolute zero, matter exhibits many unusual properties, including
2142:"Essay II. On the force of steam or vapour from water and various other liquids, both in vacuum and in air" and Essay IV. "On the expansion of elastic fluids by heat," 1297:
was discovered and is one of the coldest known objects in the Solar System. With an average surface temperature of -400°F (-240°C), due to its extremely far orbit of 903
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The question of whether there is a limit to the degree of coldness possible, and, if so, where the zero must be placed, was first addressed by the French physicist
1368:. In this space-based laboratory, temperatures as low as 1 picokelvin (10 K) are projected to be achievable, and it could further the exploration of unknown 910:
Temperatures that are expressed as negative numbers on the familiar Celsius or Fahrenheit scales are simply colder than the zero points of those scales. Certain
834:-scaled increments) with increasing rarity. Absolute temperature measurement is uniquely determined by a multiplicative constant which specifies the size of the 387:
the T = 0 isotherm. Consequently no adiabatic process initiated at nonzero temperature can lead to zero temperature. (≈ Callen, pp. 189–190)
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confined in an external potential and cooled to temperatures very near absolute zero. Under such conditions, a large fraction of the bosons occupy the lowest
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slopes. For the specific heats at least, the limiting value itself is definitely zero, as borne out by experiments to below 10 K. Even the less detailed
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shows this curious drop in specific heats. In fact, all specific heats vanish at absolute zero, not just those of crystals. Likewise for the coefficient of
2049: 1271: 2442: 968:. The concept was well known among naturalists of the time. Some contended an absolute minimum temperature occurred within earth (as one of the four 1548: 2011:[The thermometer reduced to a fixed & certain measurement, & the means of relating to it observations made with old thermometers]. 922:
quantity. A system with a truly negative temperature is not colder than absolute zero. Rather, a system with a negative temperature is hotter than
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The average temperature of the universe today is approximately 2.73 kelvins (−454.76 °F), or about −270.42 °C, based on measurements of
1195:, a bi-polar, filamentary, likely proto-planetary nebula in Centaurus, has a temperature of 1 K, the lowest observed outside of a laboratory. 1098: 2973: 1395: 2891: 2872: 2845: 2471: 1531: 788: 2009:"Le thermomètre rèduit à une mesure fixe & certaine, & le moyen d'y rapporter les observations faites avec les anciens Thermométres" 2654: 1215: 1164: 2461: 1504:, it remains common practice to express a thermodynamic temperature, symbol T, in terms of its difference from the reference temperature T 1491: 1013:
This close approximation to the modern value of −273.15 °C for the zero of the air thermometer was further improved upon in 1779 by
2023:" d'où il paroît que l'extrême froid de ce Thermométre seroit celui qui réduiroit l'air à ne soutenir aucune charge par son ressort, " 1338: 2188:"On an Absolute Thermometric Scale founded on Carnot's Theory of the Motive Power of Heat, and calculated from Regnault's observations" 857: 806:
In 2021, University of Bremen physicists achieved a BEC with a temperature of only 38 pK, the current coldest temperature record.
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demonstrated that these gases could be liquefied, but only under conditions of very high pressure and very low temperatures. In 1877,
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reach their minimum value. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical,
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The current world record for effective temperatures was set in 2021 at 38 picokelvin (pK) through matter-wave lensing of rubidium
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Scientists and technologists routinely achieve temperatures close to absolute zero, where matter exhibits quantum effects such as
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With a better theoretical understanding of absolute zero, scientists were eager to reach this temperature in the lab. By 1845,
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in 1913. Kamerlingh Onnes would continue to study the properties of materials at temperatures near absolute zero, describing
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Amontons described the relation between his new thermometer (which was based on the expansion and contraction of alcohol (
407:. Every lattice element of the structure is in its proper place, whether it is a single atom or a molecular grouping. For 186: 174: 70: 2964: 2234: 1913: 1380: 1365: 1243: 869: 746: 698: 679: 383:
S = 0, although other isotherms and adiabats are distinct. As no two adiabats intersect, no other adiabat can
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Leanhardt, A. E.; Pasquini, TA; Saba, M; Schirotzek, A; Shin, Y; Kielpinski, D; Pritchard, DE; Ketterle, W (2003).
1007: 499: 44: 2944: 1436: 1279: 915: 872:(for particles of integer spin). All of these define the relative numbers of particles in a system as decreasing 815: 742:, which published it. Einstein then extended Bose's ideas to material particles (or matter) in two other papers. 738: 569: 146: 2276: 2321: 2013:
Histoire de l'Académie Royale des Sciences, avec les Mémoires de Mathématique et de Physique pour la même Année
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Absolute zero cannot be achieved, although it is possible to reach temperatures close to it through the use of
209: 84: 2385:"History of temperature changes in the Universe revealed—First measurement using the Sunyaev-Zeldovich effect" 1160: 321: 2157: 1972: 1053: 1036:
gave ten calculations of this value, and finally adopted −3,000 °C as the natural zero of temperature.
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At temperatures near 0 K (−273.15 °C; −459.67 °F), nearly all molecular motion ceases and Δ
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structure extends uninterrupted in all directions. The perfect order can be represented by translational
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Most familiar systems cannot achieve negative temperatures because adding energy always increases their
736:). Einstein was impressed, translated the paper from English to German and submitted it for Bose to the 667: 1137: 1120:, were permanent gases and could not be liquefied. Decades later, in 1873 Dutch theoretical scientist 1020:
Values of this order for the absolute zero were not, however, universally accepted about this period.
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Talbot, G.R.; Pacey, A.C. (1972). "Antecedents of thermodynamics in the work of Guillaume Amontons".
1851: 1785: 1659: 1597: 1465: 1353: 1327: 1323: 1208: 1125: 1069: 1021: 911: 905: 873: 1017:, who observed that −270 °C (−454.00 °F; 3.15 K) might be regarded as absolute cold. 637:
the equilibrium state to which a system proceeds is the one that evolves the greatest amount of heat
3011: 2008: 721: 662:, even at absolute zero. The maximum energy that electrons can have at absolute zero is called the 303: 2187: 2643: 2564: 2423: 2366: 1954: 1883: 1809: 1683: 1649: 1587: 1575: 1461: 985: 885: 750: 729: 451: 408: 376: 308: 213: 2398:
Zu, H.; Dai, W.; de Waele, A.T.A.M. (2022). "Development of Dilution refrigerators – A review".
2299: 1578:(14 March 2017), "A general derivation and quantification of the third law of thermodynamics", 2916: 2897: 2887: 2868: 2851: 2841: 2477: 2467: 2415: 2217: 2141: 2123: 2100: 1976: 1875: 1867: 1801: 1735: 1701: 1675: 1623: 1527: 1369: 1298: 1235: 1172: 1025: 969: 856:, are the same in all scales. The most transparent definition of this standard comes from the 714: 561: 482: 475: 471: 271: 247: 217: 162: 1521: 2990: 2556: 2546: 2407: 2356: 2081: 1944: 1859: 1793: 1667: 1613: 1605: 1416: 1286: 1192: 1057: 631:
are nearly the same over a considerable range of temperatures and justifies the approximate
2719: 2608:"Scientific Perspectives for ESA's Future Programme in Life and Physical sciences in Space" 91: 1839: 1770: 1373: 1141: 1112: 1045: 989: 919: 725: 702: 684: 658:, must be in different quantum states, which leads the electrons to get very high typical 392: 283: 225: 2242: 165:-induced particle motion. The theoretical temperature is determined by extrapolating the 2542: 2384: 2263: 2077: 1855: 1789: 1747: 1663: 1601: 2978: 2910: 2834: 2502:(Press release). Low Temperature Laboratory, Teknillinen Korkeakoulu. 8 December 2000. 2085: 1618: 1451: 1446: 1401: 865: 467: 299: 240: 236: 204:
It is commonly thought of as the lowest temperature possible, but it is not the lowest
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that, at constant pressure, ideal gases expanded or contracted their volume linearly (
216:(liquid to solid) exceeds the ideal gas's change in enthalpy to absolute zero. In the 3006: 3000: 2828: 2568: 2427: 2411: 2370: 2209: 2038: 1958: 1887: 1508:= 273.15 K, close to the ice point. This difference is called the Celsius temperature 1492:"SI Brochure: The International System of Units (SI) – 9th edition (updated in 2022)" 1239: 1231: 827: 773: 710: 400: 251: 198: 166: 2387:. Kavli Institute for the Physics and Mathematics of the Universe. 10 November 2020. 2043: 1813: 478:
show that various other quantities also vanish. These phenomena were unanticipated.
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One of the first to discuss the possibility of an absolute minimal temperature was
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is bounded). Experimentally, it is found that all spontaneous processes (including
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in Germany reported to have achieved temperatures formally below absolute zero ("
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states the entropy of a perfect crystal vanishes at absolute zero. The original
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of the external potential, at which point quantum effects become apparent on a
1949: 1936: 1391: 1219: 1133: 831: 803:(peak emittance) wavelength of 6.4 megameters is roughly the radius of Earth. 800: 659: 632: 608: 589: 307:
makes the weaker and less controversial claim that the entropy change for any
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Clark, Ronald W. "Einstein: The Life and Times" (Avon Books, 1971) pp. 408–9
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gave details of technologies and benefits of femtokelvin research in space.
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that exist in two (or more) stable crystalline forms, such as diamond and
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temperature scales set their zero points at absolute zero by definition.
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This article is about the minimum temperature limit. For other uses, see
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temperatures below 100 pK were reported for an experiment at the
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for metals that eluded classical physicists in the late 19th century.
1671: 1410: 1309: 1156: 819: 733: 416: 194: 170: 135: 791:(MIT) achieved a temperature of 450 ± 80 picokelvin (pK) ( 2551: 2526: 2021:)) and the old thermometer (which was based on air). From p. 52: 1155:
took on the challenge to liquefy the remaining gases, hydrogen and
1592: 1468:, hypothetical upper limits to the thermodynamic temperature scale 1356:(CAL), an experimental instrument was developed for launch to the 1334: 1263: 1186: 1102: 973: 972:), others within water, others air, and some more recently within 944: 706: 683: 129: 2884:
Thermodynamics: An Advanced Treatment for Chemists and Physicists
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Massachusetts Institute of Technology, Massachusetts, Cambridge
2160:(1802), "Recherches sur la dilatation des gaz et des vapeurs", 2145:
Memoirs of the Literary and Philosophical Society of Manchester
458:. (Guggenheim, p. 111) These quantities drop toward their 1346: 27: 423:. The question remains whether both can have zero entropy at 282:. In such a circumstance, pure substances can (ideally) form 1250:, scientists have worked to obtain even lower temperatures. 1132:
in Switzerland succeeded in producing the first droplets of
1081:'s theory of the Motive Power of Heat and data published by 2672:"Atoms Reach Record Temperature, Colder than Absolute Zero" 2527:"The Boomerang Nebula: The Coldest Region of the Universe?" 2042: 1906:"Below Absolute Zero -What Does Negative Temperature Mean?" 169:; by international agreement, absolute zero is taken as 0 2928:
BIPM Mise en pratique - Kelvin - Appendix 2 - SI Brochure
2277:"The Nobel Prize in Physics 1913: Heike Kamerlingh Onnes" 1771:"Cooling Bose–Einstein Condensates Below 500 Picokelvin" 914:
can achieve truly negative temperatures; that is, their
2886:(Fifth ed.). Amsterdam: North Holland Publishing. 1978:
The Stanford Dictionary of Anglicised Words and Phrases
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in 1924–25. Bose first sent a paper to Einstein on the
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Thermodynamics and an Introduction to Thermostatistics
1270:. However, this was the temperature of one particular 635:
Principle of Thomsen and Berthelot, which states that
427: = 0 even though each is perfectly ordered. 2962: 2466:. Espoo, Finland: Helsinki University of Technology. 1278:
property called nuclear spin—not the overall average
502: 324: 2867:(Second ed.). New York: John Wiley & Sons. 2235:"ABSOLUTE ZERO – PBS NOVA DOCUMENTARY (full length)" 1315:
In May 2006, the Institute of Quantum Optics at the
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in 1703, in connection with his improvements in the
1364:environment of the ISS leading to the formation of 1322:In January 2013, physicist Ulrich Schneider of the 58:. Unsourced material may be challenged and removed. 2833: 2827: 2742:"Coolest science ever headed to the space station" 2463:Nuclear Magnetism and Superconductivity in Rhodium 2266:. Scienceclarified.com. Retrieved on 22 July 2012. 2192:Proceedings of the Cambridge Philosophical Society 1072:had determined the mechanical equivalent of heat, 533: 442:and entropy of a pure crystal are proportional to 355: 2101:"Essay VI: The various degrees of heat in bodies" 462: = 0 limiting values and approach with 2690:"CUORE: The Coldest Heart in the Known Universe" 2583:"Mysterious Sedna | Science Mission Directorate" 2216:, New York: The Macmillan Company, p. 175, 1372:phenomena and test some of the most fundamental 745:Seventy years later, in 1995, the first gaseous 326: 1167:at the time and his achievement earned him the 391:A perfect crystal is one in which the internal 220:description, matter at absolute zero is in its 2107:. London, England, UK: A. Millar. p. 291. 1994:New Experiments and Observations touching Cold 962:New Experiments and Observations touching Cold 646:One model that estimates the properties of an 138:(−273.15 °C) is defined as absolute zero. 1840:"Collective-Mode Enhanced Matter-Wave Optics" 1718:"New State of Matter Seen Near Absolute Zero" 1089:, remained in use in the early 20th century. 892:representing the temperature observed at the 534:{\displaystyle \Delta G=\Delta H-T\Delta S\,} 8: 2053:(11th ed.). Cambridge University Press. 818:, temperature is conventionally measured in 720:This state of matter was first predicted by 2798:"Cold Atom Laboratory Creates Atomic Dance" 2525:Sahai, Raghvendra; Nyman, Lars-Åke (1997). 2298:Kruszelnicki, Karl S. (25 September 2003). 799:) in a BEC of sodium atoms. The associated 596:reactions can proceed spontaneously if the 588: < 0, which would indicate an 2443:"Cosmos Online – Verging on absolute zero" 2349:HTS Teologiese Studies/Theological Studies 2550: 2360: 2033: 2031: 1948: 1653: 1617: 1591: 1551:. Smithsonian Institution. Archived from 1486: 1484: 1482: 1345:In June 2015, experimental physicists at 1191:The rapid expansion of gases leaving the 592:reaction. However, this is not required; 530: 501: 329: 323: 181:scale, and equals −459.67 degrees on the 118:Learn how and when to remove this message 1899: 1897: 1044:From 1787 to 1802, it was determined by 356:{\displaystyle \lim _{T\to 0}\Delta S=0} 243:of the ground state cannot be removed. 2969: 2441:Catchpole, Heather (4 September 2008). 1526:. Tata McGraw-Hill. Table 2.4 page 43. 1478: 1427:International Temperature Scale of 1990 964:, articulated the dispute known as the 952:pioneered the idea of an absolute zero. 876:of energy (at the particle level) over 688:Velocity-distribution data of a gas of 379:T = 0 as coincident with the 2712:"MIT team creates ultracold molecules" 1937:"Quantum gas goes below absolute zero" 1746:. Physics Today online. Archived from 1308:proposed research in space to achieve 1165:coldest temperatures achieved on Earth 1099:Timeline of low-temperature technology 705:of a dilute gas of weakly interacting 674:Relation with Bose–Einstein condensate 650:gas at absolute zero in metals is the 481:Since the relation between changes in 2912:Introduction to Statistical Mechanics 2651:University of California, Los Angeles 2506:from the original on 18 February 2008 2345:"The building blocks of the universe" 2302:. Australian Broadcasting Corporation 2147:, vol. 8, pt. 2, pp. 550–74, 595–602. 1832: 1830: 1333:In September 2014, scientists in the 789:Massachusetts Institute of Technology 7: 2660:from the original on 9 October 2022. 1823:from the original on 9 October 2022. 1282:for all possible degrees in freedom. 286:with no structural imperfections as 56:adding citations to reliable sources 2840:. New York: John Wiley & Sons. 2214:A Compendium of Spherical Astronomy 1547:Zielinski, Sarah (1 January 2008). 1339:Laboratori Nazionali del Gran Sasso 918:(expressed in kelvins) can be of a 623: = 0. This ensures that Δ 177:), which is −273.15 degrees on the 2909:George Stanley Rushbrooke (1949). 2343:John, Anslyn J. (25 August 2021). 2324:. The Straight Dope. 3 August 2004 2322:"What's the temperature of space?" 2086:10.1111/j.1600-0498.1972.tb00163.x 1203:radiation. Standard models of the 619:converge and are equal to zero at 584: < 0 may imply that Δ 524: 512: 503: 341: 14: 2644:"Atomic Quantum Sensors in Space" 2300:"Coldest Place in the Universe 1" 2118:Lambert, Johann Heinrich (1779). 1432:Orders of magnitude (temperature) 1260:Helsinki University of Technology 1228:nuclear adiabatic demagnetization 759:University of Colorado at Boulder 639:, i.e., an actual process is the 556:approach each other (so long as Δ 262:Thermodynamics near absolute zero 2984: 2972: 2412:10.1016/j.cryogenics.2021.103390 2105:Essays Medical and Philosophical 1394: 1205:future expansion of the universe 32: 1147:Scottish chemist and physicist 864:(for particles of half-integer 826:-scaled increments) and in the 43:needs additional citations for 2768:"Cold Atom Laboratory Mission" 2500:"Low Temperature World Record" 2172:English translation (extract). 1910:The Physics and Relativity FAQ 1864:10.1103/PhysRevLett.127.100401 1122:Johannes Diderik van der Waals 1107:Commemorative plaque in Leiden 858:Maxwell–Boltzmann distribution 842:of two absolute temperatures, 333: 21:Absolute Zero (disambiguation) 16:Lowest theoretical temperature 1: 2950:originally aired January 2008 980:Limit to the "degree of cold" 643:. (Callen, pp. 186–187) 187:United States customary units 175:International System of Units 2774:. NASA. 2017. Archived from 787:In 2003, researchers at the 732:of light quanta (now called 607:Moreover, the slopes of the 149:scale; a state at which the 2915:. Oxford: Clarendon Press. 1358:International Space Station 1201:cosmic microwave background 810:Absolute temperature scales 296:third law of thermodynamics 145:is the lowest limit of the 3035: 2863:Herbert B. Callen (1985). 2826:Herbert B. Callen (1960). 2007:Amontons (18 April 1703). 1262:'s Low Temperature Lab in 1244:Bose–Einstein condensation 1096: 903: 860:. It can also be found in 677: 580:are small, the condition Δ 564:) result in a decrease in 256:Bose–Einstein condensation 18: 2772:Jet Propulsion Laboratory 2531:The Astrophysical Journal 2460:Knuuttila, Tauno (2000). 1950:10.1038/nature.2013.12146 1437:Thermodynamic temperature 1381:Bose–Einstein condensates 1366:Bose–Einstein condensates 1280:thermodynamic temperature 1093:The race to absolute zero 916:thermodynamic temperature 772:atoms cooled to 170  399:along three (not usually 147:thermodynamic temperature 2955:"What is absolute zero?" 2882:E.A. Guggenheim (1967). 2099:Martine, George (1740). 1973:Stanford, John Frederick 870:Bose–Einstein statistics 699:Bose–Einstein condensate 680:Bose–Einstein condensate 210:enthalpy of vaporization 2050:Encyclopædia Britannica 1844:Physical Review Letters 1798:10.1126/science.1088827 1087:astronomical refraction 1054:Joseph Louis Gay-Lussac 1015:Johann Heinrich Lambert 654:. The electrons, being 568:as they proceed toward 270: = 0 for any 2362:10.4102/hts.v77i3.6831 1992:Boyle, Robert (1665). 1935:Merali, Zeeya (2013). 1744:Search & Discovery 1720:. NIST. Archived from 1317:University of Hannover 1285:In February 2003, the 1224:dilution refrigerators 1196: 1153:Heike Kamerlingh Onnes 1108: 953: 862:Fermi–Dirac statistics 739:Zeitschrift für Physik 694: 604:term is large enough. 535: 389: 357: 294:'s strong form of the 233:laws of thermodynamics 224:, the point of lowest 139: 2958:Lansing State Journal 1580:Nature Communications 1520:Arora, C. P. (2001). 1413:(unit of temperature) 1337:collaboration at the 1306:European Space Agency 1190: 1183:Very low temperatures 1106: 1083:Henri Victor Regnault 948: 900:Negative temperatures 874:exponential functions 687: 668:equipartition theorem 536: 493:) and the entropy is 419:, there is a kind of 369: 358: 133: 2692:. INFN Press Release 2449:on 22 November 2008. 1466:Hagedorn temperature 1354:Cold Atom Laboratory 1328:negative temperature 1324:University of Munich 1209:electron temperature 1179:for the first time. 1151:and Dutch physicist 1126:Louis Paul Cailletet 1070:James Prescott Joule 1063: 1022:Pierre-Simon Laplace 906:Negative temperature 768:lab, using a gas of 500: 454:are proportional to 322: 212:(gas to liquid) and 52:improve this article 2804:. 26 September 2014 2543:1997ApJ...487L.155S 2078:1972Cent...16...20T 2015:(in French): 50–56. 1856:2021PhRvL.127j0401D 1790:2003Sci...301.1513L 1784:(5639): 1513–1515. 1664:2001Natur.412..295D 1610:10.1038/ncomms14538 1602:2017NatCo...814538M 1576:Oppenheim, Jonathan 1494:. BIPM. p. 133 1216:evaporative cooling 1161:Hampson–Linde cycle 1039: 1034:Chemical Philosophy 722:Satyendra Nath Bose 641:most exothermic one 476:Maxwell's relations 421:chemical degeneracy 311:approaches zero as 2748:. 5 September 2017 2140:J. Dalton (1802), 1750:on 24 October 2007 1736:Levi, Barbara Goss 1462:Planck temperature 1370:quantum mechanical 1299:astronomical units 1293:In November 2003, 1254:In November 2000, 1197: 1138:Zygmunt Wróblewski 1109: 1064:Lord Kelvin's work 986:Guillaume Amontons 970:classical elements 954: 886:Boltzmann constant 730:quantum statistics 695: 562:chemical reactions 531: 452:chemical potential 353: 340: 309:isothermal process 218:quantum-mechanical 214:enthalpy of fusion 140: 2893:978-0-444-86951-7 2874:978-0-471-86256-7 2847:978-0-471-13035-2 2722:on 18 August 2015 2678:. 3 January 2013. 2624:on 6 October 2014 2473:978-951-22-5208-4 2162:Annales de Chimie 2158:Gay-Lussac, J. L. 1916:on 15 August 2011 1648:(6844): 295–299. 1533:978-0-07-462014-4 1304:In May 2005, the 1272:degree of freedom 1236:superconductivity 1173:superconductivity 1026:Antoine Lavoisier 884:representing the 715:macroscopic scale 489:), the enthalpy ( 483:Gibbs free energy 472:thermal expansion 325: 272:adiabatic process 248:superconductivity 163:zero-point energy 128: 127: 120: 102: 3024: 2989: 2988: 2987: 2977: 2976: 2968: 2924: 2905: 2878: 2859: 2839: 2831: 2814: 2813: 2811: 2809: 2794: 2788: 2787: 2785: 2783: 2778:on 29 March 2013 2764: 2758: 2757: 2755: 2753: 2738: 2732: 2731: 2729: 2727: 2718:. Archived from 2708: 2702: 2701: 2699: 2697: 2686: 2680: 2679: 2668: 2662: 2661: 2659: 2648: 2640: 2634: 2633: 2631: 2629: 2623: 2617:. Archived from 2612: 2604: 2598: 2597: 2595: 2593: 2587:science.nasa.gov 2579: 2573: 2572: 2554: 2537:(2): L155–L159. 2522: 2516: 2515: 2513: 2511: 2496: 2490: 2489: 2487: 2485: 2480:on 28 April 2001 2476:. Archived from 2457: 2451: 2450: 2445:. Archived from 2438: 2432: 2431: 2395: 2389: 2388: 2381: 2375: 2374: 2364: 2340: 2334: 2333: 2331: 2329: 2318: 2312: 2311: 2309: 2307: 2295: 2289: 2288: 2286: 2284: 2279:. Nobel Media AB 2273: 2267: 2261: 2255: 2254: 2252: 2250: 2241:. Archived from 2231: 2225: 2224: 2206: 2200: 2199: 2184:Thomson, William 2180: 2174: 2169: 2154: 2148: 2138: 2132: 2131: 2115: 2109: 2108: 2096: 2090: 2089: 2061: 2055: 2054: 2046: 2035: 2026: 2016: 2004: 1998: 1997: 1989: 1983: 1982: 1969: 1963: 1962: 1952: 1932: 1926: 1925: 1923: 1921: 1912:. Archived from 1901: 1892: 1891: 1834: 1825: 1824: 1822: 1775: 1766: 1760: 1759: 1757: 1755: 1732: 1726: 1725: 1714: 1708: 1698: 1692: 1691: 1672:10.1038/35085500 1657: 1655:cond-mat/0105019 1637: 1631: 1630: 1621: 1595: 1586:(14538): 14538, 1574:Masanes, Lluís; 1571: 1565: 1564: 1562: 1560: 1544: 1538: 1537: 1517: 1511: 1510: 1501: 1499: 1488: 1404: 1399: 1398: 1287:Boomerang Nebula 1246:. To study such 1193:Boomerang Nebula 1005: 1004: 1000: 997: 798: 796: 783: 781: 749:was produced by 540: 538: 537: 532: 373:Nernst postulate 362: 360: 359: 354: 339: 284:perfect crystals 123: 116: 112: 109: 103: 101: 60: 36: 28: 3034: 3033: 3027: 3026: 3025: 3023: 3022: 3021: 2997: 2996: 2995: 2985: 2983: 2971: 2963: 2940:"Absolute zero" 2936: 2908: 2894: 2881: 2875: 2862: 2848: 2825: 2822: 2820:Further reading 2817: 2807: 2805: 2796: 2795: 2791: 2781: 2779: 2766: 2765: 2761: 2751: 2749: 2740: 2739: 2735: 2725: 2723: 2710: 2709: 2705: 2695: 2693: 2688: 2687: 2683: 2676:livescience.com 2670: 2669: 2665: 2657: 2646: 2642: 2641: 2637: 2627: 2625: 2621: 2610: 2606: 2605: 2601: 2591: 2589: 2581: 2580: 2576: 2524: 2523: 2519: 2509: 2507: 2498: 2497: 2493: 2483: 2481: 2474: 2459: 2458: 2454: 2440: 2439: 2435: 2397: 2396: 2392: 2383: 2382: 2378: 2342: 2341: 2337: 2327: 2325: 2320: 2319: 2315: 2305: 2303: 2297: 2296: 2292: 2282: 2280: 2275: 2274: 2270: 2262: 2258: 2248: 2246: 2245:on 6 April 2017 2233: 2232: 2228: 2208: 2207: 2203: 2182: 2181: 2177: 2156: 2155: 2151: 2139: 2135: 2117: 2116: 2112: 2098: 2097: 2093: 2063: 2062: 2058: 2037: 2036: 2029: 2006: 2005: 2001: 1991: 1990: 1986: 1971: 1970: 1966: 1934: 1933: 1929: 1919: 1917: 1903: 1902: 1895: 1836: 1835: 1828: 1820: 1773: 1768: 1767: 1763: 1753: 1751: 1734: 1733: 1729: 1724:on 1 June 2010. 1716: 1715: 1711: 1699: 1695: 1639: 1638: 1634: 1573: 1572: 1568: 1558: 1556: 1555:on 1 April 2013 1549:"Absolute Zero" 1546: 1545: 1541: 1534: 1519: 1518: 1514: 1507: 1497: 1495: 1490: 1489: 1480: 1476: 1471: 1400: 1393: 1390: 1374:laws of physics 1185: 1142:Karol Olszewski 1113:Michael Faraday 1101: 1095: 1066: 1048:(unpublished), 1046:Jacques Charles 1042: 1002: 998: 995: 993: 990:air thermometer 982: 966:primum frigidum 943: 908: 902: 855: 848: 812: 794: 792: 779: 777: 726:Albert Einstein 703:state of matter 682: 676: 498: 497: 375:identifies the 320: 319: 264: 226:internal energy 124: 113: 107: 104: 67:"Absolute zero" 61: 59: 49: 37: 24: 17: 12: 11: 5: 3032: 3031: 3028: 3020: 3019: 3014: 3009: 2999: 2998: 2994: 2993: 2981: 2961: 2960: 2952: 2935: 2934:External links 2932: 2931: 2930: 2925: 2906: 2892: 2879: 2873: 2860: 2846: 2836:Thermodynamics 2821: 2818: 2816: 2815: 2789: 2759: 2746:Science | AAAS 2733: 2703: 2681: 2663: 2635: 2599: 2574: 2552:10.1086/310897 2517: 2491: 2472: 2452: 2433: 2390: 2376: 2335: 2313: 2290: 2268: 2256: 2226: 2210:Newcomb, Simon 2201: 2175: 2149: 2133: 2110: 2091: 2056: 2041:, ed. (1911). 2039:Chisholm, Hugh 2027: 1999: 1984: 1964: 1927: 1904:Chase, Scott. 1893: 1850:(10): 100401. 1826: 1761: 1727: 1709: 1693: 1632: 1566: 1539: 1532: 1523:Thermodynamics 1512: 1505: 1477: 1475: 1472: 1470: 1469: 1459: 1454: 1452:Kinetic energy 1449: 1447:Ultracold atom 1444: 1439: 1434: 1429: 1424: 1419: 1414: 1407: 1406: 1405: 1402:Physics portal 1389: 1386: 1385: 1384: 1377: 1350: 1343: 1331: 1320: 1313: 1302: 1291: 1283: 1184: 1181: 1128:in France and 1094: 1091: 1065: 1062: 1041: 1038: 1008:George Martine 981: 978: 942: 939: 904:Main article: 901: 898: 853: 846: 811: 808: 678:Main article: 675: 672: 542: 541: 529: 526: 523: 520: 517: 514: 511: 508: 505: 468:Einstein model 364: 363: 352: 349: 346: 343: 338: 335: 332: 328: 263: 260: 241:kinetic energy 237:asymptotically 191:imperial units 126: 125: 40: 38: 31: 15: 13: 10: 9: 6: 4: 3: 2: 3030: 3029: 3018: 3015: 3013: 3010: 3008: 3005: 3004: 3002: 2992: 2982: 2980: 2975: 2970: 2966: 2959: 2956: 2953: 2951: 2947: 2946: 2942:: a two part 2941: 2938: 2937: 2933: 2929: 2926: 2922: 2918: 2914: 2913: 2907: 2903: 2899: 2895: 2889: 2885: 2880: 2876: 2870: 2866: 2861: 2857: 2853: 2849: 2843: 2838: 2837: 2830: 2824: 2823: 2819: 2803: 2799: 2793: 2790: 2777: 2773: 2769: 2763: 2760: 2747: 2743: 2737: 2734: 2721: 2717: 2713: 2707: 2704: 2691: 2685: 2682: 2677: 2673: 2667: 2664: 2656: 2652: 2645: 2639: 2636: 2620: 2616: 2609: 2603: 2600: 2588: 2584: 2578: 2575: 2570: 2566: 2562: 2558: 2553: 2548: 2544: 2540: 2536: 2532: 2528: 2521: 2518: 2505: 2501: 2495: 2492: 2479: 2475: 2469: 2465: 2464: 2456: 2453: 2448: 2444: 2437: 2434: 2429: 2425: 2421: 2417: 2413: 2409: 2405: 2401: 2394: 2391: 2386: 2380: 2377: 2372: 2368: 2363: 2358: 2354: 2350: 2346: 2339: 2336: 2323: 2317: 2314: 2301: 2294: 2291: 2278: 2272: 2269: 2265: 2260: 2257: 2244: 2240: 2236: 2230: 2227: 2223: 2219: 2215: 2211: 2205: 2202: 2197: 2193: 2189: 2185: 2179: 2176: 2173: 2167: 2163: 2159: 2153: 2150: 2146: 2143: 2137: 2134: 2129: 2125: 2121: 2114: 2111: 2106: 2102: 2095: 2092: 2087: 2083: 2079: 2075: 2071: 2067: 2060: 2057: 2052: 2051: 2045: 2040: 2034: 2032: 2028: 2024: 2020: 2019:esprit de vin 2014: 2010: 2003: 2000: 1995: 1988: 1985: 1980: 1979: 1974: 1968: 1965: 1960: 1956: 1951: 1946: 1942: 1938: 1931: 1928: 1915: 1911: 1907: 1900: 1898: 1894: 1889: 1885: 1881: 1877: 1873: 1869: 1865: 1861: 1857: 1853: 1849: 1845: 1841: 1833: 1831: 1827: 1819: 1815: 1811: 1807: 1803: 1799: 1795: 1791: 1787: 1783: 1779: 1772: 1765: 1762: 1749: 1745: 1741: 1737: 1731: 1728: 1723: 1719: 1713: 1710: 1707: 1706:0-380-01159-X 1703: 1697: 1694: 1689: 1685: 1681: 1677: 1673: 1669: 1665: 1661: 1656: 1651: 1647: 1643: 1636: 1633: 1629: 1625: 1620: 1615: 1611: 1607: 1603: 1599: 1594: 1589: 1585: 1581: 1577: 1570: 1567: 1554: 1550: 1543: 1540: 1535: 1529: 1525: 1524: 1516: 1513: 1509: 1493: 1487: 1485: 1483: 1479: 1473: 1467: 1463: 1460: 1458: 1455: 1453: 1450: 1448: 1445: 1443: 1440: 1438: 1435: 1433: 1430: 1428: 1425: 1423: 1420: 1418: 1417:Charles's law 1415: 1412: 1409: 1408: 1403: 1397: 1392: 1387: 1382: 1378: 1375: 1371: 1367: 1363: 1359: 1355: 1351: 1348: 1344: 1340: 1336: 1332: 1329: 1325: 1321: 1318: 1314: 1312:temperatures. 1311: 1307: 1303: 1300: 1296: 1292: 1288: 1284: 1281: 1277: 1273: 1269: 1265: 1261: 1257: 1253: 1252: 1251: 1249: 1245: 1241: 1240:superfluidity 1237: 1233: 1232:laser cooling 1230:. The use of 1229: 1225: 1221: 1217: 1212: 1210: 1206: 1202: 1194: 1189: 1182: 1180: 1178: 1174: 1170: 1166: 1162: 1158: 1154: 1150: 1145: 1143: 1139: 1135: 1131: 1127: 1123: 1119: 1114: 1105: 1100: 1092: 1090: 1088: 1084: 1080: 1075: 1071: 1061: 1059: 1058:Charles's law 1055: 1051: 1047: 1040:Charles's law 1037: 1035: 1031: 1027: 1023: 1018: 1016: 1011: 1009: 991: 987: 979: 977: 975: 971: 967: 963: 959: 951: 947: 940: 938: 935: 933: 928: 925: 921: 917: 913: 907: 899: 897: 895: 891: 887: 883: 879: 875: 871: 867: 863: 859: 852: 845: 841: 837: 833: 829: 828:Rankine scale 825: 821: 817: 816:thermodynamic 814:Absolute, or 809: 807: 804: 802: 790: 785: 775: 771: 767: 763: 760: 756: 752: 748: 743: 741: 740: 735: 731: 727: 723: 718: 716: 712: 711:quantum state 708: 704: 700: 691: 686: 681: 673: 671: 669: 665: 661: 657: 653: 649: 644: 642: 638: 634: 630: 626: 622: 618: 614: 610: 605: 603: 599: 595: 591: 587: 583: 579: 575: 571: 567: 563: 559: 555: 551: 547: 527: 521: 518: 515: 509: 506: 496: 495: 494: 492: 488: 484: 479: 477: 473: 469: 465: 461: 457: 453: 449: 445: 441: 440:specific heat 437: 432: 428: 426: 422: 418: 414: 410: 406: 402: 398: 394: 388: 386: 382: 378: 374: 368: 350: 347: 344: 336: 330: 318: 317: 316: 314: 310: 306: 305: 301: 297: 293: 289: 285: 281: 277: 273: 269: 261: 259: 257: 253: 252:superfluidity 249: 244: 242: 238: 234: 229: 227: 223: 219: 215: 211: 207: 202: 200: 196: 192: 188: 184: 180: 176: 172: 168: 167:ideal gas law 164: 160: 156: 152: 148: 144: 143:Absolute zero 137: 132: 122: 119: 111: 108:December 2022 100: 97: 93: 90: 86: 83: 79: 76: 72: 69: –  68: 64: 63:Find sources: 57: 53: 47: 46: 41:This article 39: 35: 30: 29: 26: 22: 2957: 2943: 2911: 2883: 2864: 2835: 2829:"Chapter 10" 2806:. 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Retrieved 1442:Triple point 1362:microgravity 1256:nuclear spin 1213: 1198: 1146: 1130:Raoul Pictet 1110: 1067: 1043: 1033: 1019: 1012: 983: 965: 961: 958:Robert Boyle 955: 950:Robert Boyle 936: 929: 923: 909: 889: 881: 877: 850: 843: 839: 835: 813: 805: 786: 751:Eric Cornell 744: 737: 719: 696: 664:Fermi energy 645: 640: 636: 628: 624: 620: 616: 612: 606: 601: 597: 585: 581: 577: 573: 565: 557: 553: 549: 548:decreases, Δ 545: 543: 490: 486: 480: 463: 459: 455: 446:, while the 443: 433: 429: 424: 420: 390: 370: 365: 312: 304:heat theorem 302: 287: 275: 267: 265: 245: 230: 222:ground state 205: 203: 157:of a cooled 142: 141: 114: 105: 95: 88: 81: 74: 62: 50:Please help 45:verification 42: 25: 3017:Temperature 2782:22 December 2592:25 November 2510:11 February 2484:11 February 2249:23 November 1498:7 September 1310:femtokelvin 1295:90377 Sedna 1220:cryocoolers 1177:superfluids 1169:Nobel Prize 1149:James Dewar 1074:Lord Kelvin 1050:John Dalton 1030:John Dalton 960:. His 1665 894:macroscopic 755:Carl Wieman 701:(BEC) is a 693:condensate. 609:derivatives 594:endothermic 570:equilibrium 436:Debye model 3012:Cryogenics 3001:Categories 2696:21 October 2561:2014/22450 2400:Cryogenics 2264:Cryogenics 2122:. 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kelvin
thermodynamic temperature
enthalpy
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