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Adamanzane

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20: 28: 68:(1996) these can be described according to the number of chains of specified length: thus, for example, adamanzane is 1,3,6,8-tetraazatricyclododecane, a compound which contains four one-carbon chains and two two-carbon chains linking the nitrogen atoms. 64:, with potentially four faces and six edges, with the carbon chains running approximately along the edges. They can have a "bowl" or "cage" structure, with varying lengths or omission of the carbon chains. In the nomenclature of Springborg 92: 93:"Structure of Gas Phase Radical Cation of 1,3,6,8-Tetraazatricyclo[4.4.1.13,8] Dodecane Determined from Zero Kinetic Energy Photoelectron Spectroscopy" 75:", a compound in which Na and H ions coexist, due to the ability of the adamanzane to encapsulate the H and render it kinetically inert to react with the Na. 198: 193: 188: 19: 131: 148:
Mikhail Y. Redko; et al. (2002). ""Inverse Sodium Hydride": A Crystalline Salt that Contains H and Na".
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Often coordinated to a central ligand, the nitrogens occupy the vertices of a
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Adamanzane has found a special use in the preparation of "
8: 57:with nitrogen at the branched position). 83: 7: 199:Heterocyclic compounds with 3 rings 14: 91:Yonggang He; et al. (2005). 45:) are compounds containing four 1: 16:Class of chemical compounds 215: 194:Adamantane-like molecules 23:Structure of adamanzane 73:inverse sodium hydride 35: 33:hexamethylenetetramine 24: 189:Nitrogen heterocycles 30: 22: 112:2005JPCA..109..959H 36: 25: 162:10.1021/ja025655+ 156:(21): 5928–5929. 120:10.1021/jp0444619 206: 174: 173: 150:J. Am. Chem. Soc 145: 139: 138: 136: 130:. Archived from 100:J. Phys. Chem. A 97: 88: 49:atoms linked by 214: 213: 209: 208: 207: 205: 204: 203: 179: 178: 177: 147: 146: 142: 134: 95: 90: 89: 85: 81: 17: 12: 11: 5: 212: 210: 202: 201: 196: 191: 181: 180: 176: 175: 140: 137:on 2012-01-03. 106:(6): 959–961. 82: 80: 77: 53:(analogous to 15: 13: 10: 9: 6: 4: 3: 2: 211: 200: 197: 195: 192: 190: 187: 186: 184: 171: 167: 163: 159: 155: 151: 144: 141: 133: 129: 125: 121: 117: 113: 109: 105: 101: 94: 87: 84: 78: 76: 74: 69: 67: 63: 58: 56: 52: 48: 44: 41:(abbreviated 40: 34: 31:Structure of 29: 21: 153: 149: 143: 132:the original 103: 99: 86: 70: 65: 59: 42: 38: 37: 62:tetrahedron 39:Adamanzanes 183:Categories 79:References 55:adamantane 170:12022811 128:16833400 47:nitrogen 108:Bibcode 51:carbons 168:  126:  66:et al. 135:(PDF) 96:(PDF) 166:PMID 124:PMID 158:doi 154:124 116:doi 104:109 43:Adz 185:: 164:. 152:. 122:. 114:. 102:. 98:. 172:. 160:: 118:: 110::

Index



hexamethylenetetramine
nitrogen
carbons
adamantane
tetrahedron
inverse sodium hydride
"Structure of Gas Phase Radical Cation of 1,3,6,8-Tetraazatricyclo[4.4.1.13,8] Dodecane Determined from Zero Kinetic Energy Photoelectron Spectroscopy"
Bibcode
2005JPCA..109..959H
doi
10.1021/jp0444619
PMID
16833400
the original
doi
10.1021/ja025655+
PMID
12022811
Categories
Nitrogen heterocycles
Adamantane-like molecules
Heterocyclic compounds with 3 rings

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