Knowledge (XXG)

Anthony J. Arduengo

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31: 1264: 621: 1232: 1248: 1178: 1194: 1217: 1162: 1074:, 1,3,4,5-tetraphenylimidazol-2-ylidene, remained as an example of a carbene that could (should) have been isolable. The re-examination of Wanzlick's original procedure identified some key experimental features that would have hindered the original researchers. With these problems corrected, the DuPont scientists were able to isolate the target carbene and fully characterize it including an X-ray structure determination. In a tribute to Hans-Werner Wanzlick, these results were published under the title "1,3,4,5-Tetraphenylimidazol-2-ylidene: The Realization of Wanzlick's Dream." 1122: 467: 1142: 451: 653: 637: 1106: 1082: 6114: 669: 2086: 7474: 5035: 4372: 2124: 689: 7498: 2143: 7510: 4457: 3938: 7486: 5045: 3819: 2250: 2105: 2269: 2231: 1308:
In June 2020 Arduengo returned to his alma mater as Professor of the Practice. His research in carbene chemistry continues there along efforts in support of the Medicines for All Institute sustainable chemistry, and a partnership to address repatriation of critical chemical manufacturing technology
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chemistry and hypervalency. Many of the technical discussions between Martin and Arduengo would take place over lunch (the choice of restaurants often influenced by the quality of the napkins for writing chemical structures). To facilitate discussions about unusual molecular structures and bonding
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that could not be isolated as stable entities. However, Arduengo (already well-aware of the history) had the starting materials on hand for the chemistry and decided to proceed with the experiments. "Arduengo's gamble paid off. In 1991, more than 150 years after the first attempt ..." a stable
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and instilled his son with an interest and skill for all things mechanical and scientific. By the age of 16, he and his father had built his first car from miscellaneous parts. The car was registered as street-legal and road-worthy. With some re-engineering, the car was later fitted to run on
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In 1998, Arduengo and coworkers carefully re-examined the earlier attempts to produce stable carbenes in Wanzlick's laboratory in light of the knowledge and experience gained from the recent successful experiments at DuPont. Although the majority of Wanzlick's work on the saturated
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fused imidazol-2-ylidene. Research into the unusual valency in diphosphacyclobutane-2,4-diyls has been reported from the Arduengo group in collaboration with Professors Masaaki Yoshifuji and Shigekazu Ito. Arduengo also directs research programs into Chemical Hydrogen Storage and
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thirty years earlier (without isolation) were now also shown to be stable enough to isolate with appropriate substituents at nitrogen. An air-stable carbene was produced. The chemistry was extended to include thiazol-2-ylidenes (conjectured to exist in 1957 as a
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K. Akiba; Y. Yamamoto (1988). "Chemistry of hypervalent organic compounds. Fundamental aspects of hypervalent organic compounds. Characteristic features of structure and reactivity of hypervalent organic compounds of main group elements".
2084:, A. J. Arduengo, Y. C. Ray, "Process for Preparing a Strengthened Polyimide Film Containing Organometallic Compounds for Improving Adhesion", issued 1993-12-21, assigned to E. I. du Pont de Nemours and Company, Inc. 7586: 5979: 1247: 2122:, A. J. Arduengo, P. H. Corcoran, "Epoxy/Isocyanate Crosslinked Coatings Containing 1,3-Disubstituted Imidazole-2-thione Catalysts", issued 1991-01-28, assigned to E. I. du Pont de Nemours and Company, Inc. 1231: 620: 6093: 4168: 1177: 2141:, A. J. Arduengo, R. J. Barsotti, P. H. Corcoran, "Curable compositions containing 1,3-dialkylimidazole-2-thione catalysts", issued 1993-02-25, assigned to E. I. du Pont de Nemours and Company, Inc. 1925:
A. J. Arduengo; C. A. Stewart; F. Davidson; D. A. Dixon; J. Y. Becker; S. A. Culley; M. B. Mizen (1987). "The synthesis, structure, and chemistry of 10-Pn-3 systems: tricoordinate hypervalent pnictogen compounds".
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C. W. Perkins; J. C. Martin; A. J. Arduengo; W. Lau; A. Alegria; J. K. Kochi (1980). "An electrically neutral σ-sulfuranyl radical from the homolysis of a perester with neighboring sulfenyl sulfur: 9-S-3 species".
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S. Ito; J. Miura; N. Morita; M. Yoshifuji; A. J. Arduengo (2009). "Catenation of 1,3-Diphosphacyclobutane-2,4-diyl Units Having 2,4,6-Tri-tert-butylphenyl Protecting Groups and a P-sec-Butyl Group in the Ring".
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At the University of Alabama research from Arduengo's laboratory has focused on enhancements to the basic structure of the imidazol-2-ylidenes through substituent effects leading to novel compounds like a
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A. J. Arduengo; H. Bock; H. Chen; M. Denk; D. A. Dixon; J. C. Green; W. A. Herrmann; N. L. Jones; M. Wagner; R. West (1994). "Photoelectron Spectroscopy of a Carbene/Silylene/Germylene Series".
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S. Ito; J. Miura; N. Morita; M. Yoshifuji; A. J. Arduengo (2010). "Synthesis and properties of oligo(biradicals) composed of 1,3-diphosphacyclobutane-2,4-diyl units and benzyl-type linkers".
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A. J. Arduengo; F. Davidson; R. Krafczyk; W. J. Marshall; R. Schmutzler (1999). "A Tris(trifluoromethyl)antimony Adduct of a Nucleophilic Carbene: Geometric Distortions in Carbene Adducts".
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A. J. Arduengo; J. C. Calabrese; F. Davidson; H. V. R. Dias; J. R. Goerlich; R. Krafczyk; W. J. Marshall; M. Tamm; R. Schmutzler (1999). "C-H Insertion Reactions of Nucleophilic Carbenes".
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and study their chemistry. The proposal was soundly declined with the admonition that he should have certainly known better than to make such a suggestion in light of the long history of
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molecule and related structures. This line of research proved to be extremely fruitful and resulted in a steady string of publications on new and unusual bonding arrangements. The
5903: 5695: 5224: 5206: 5191: 5074: 3571: 3041: 2248:, A. J. Arduengo, "1,3-Dialkylimidazole-2-thione Catalyst and Method for Making Same", issued 1992-04-14, assigned to E. I. du Pont de Nemours and Company, Inc. 5789: 3902: 466: 5269: 3962: 3917: 2022:
A. J. Arduengo; D. A. Dixon; D. C. Roe (1986). "Direct determination of the barrier to edge inversion at trivalent phosphorus: verification of the edge inversion mechanism".
1322: 1081: 85: 2103:, A. J. Arduengo,, "Amine-Borane Adduct Curing Agents for Epoxy/Anhydride Resins", issued 1991-07-23, assigned to E. I. du Pont de Nemours and Company, Inc. 1263: 5579: 4254: 4213: 450: 4336: 4228: 4034: 3907: 2450:
A. J. Arduengo; R. Krafczyk; R. Schmutzler; H. A. Craig; J. R. Goerlich; W. J. Marshall; M. Unverzagt (1992). "Imidazolylidenes, imidazolinylidenes and imidazolidines".
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A. J. Arduengo; F. Davidson; H. V. R. Dias; J. R. Goerlich; D. Khasnis; W. J. Marshall; T. K. Prakasha (1997). "An Air Stable Carbene and Mixed Carbene "Dimers"".
2267:, A. J. Arduengo, "Preparation of 1,3- Disubstituted Imidazolium Salts", issued 1993-01-26, assigned to E. I. du Pont de Nemours and Company, Inc. 1216: 1105: 526: 6233: 5385: 5380: 4331: 4321: 1326: 7591: 5239: 5146: 1983:
D. A. Dixon; A. J. Arduengo; T. Fukunaga (1986). "A new inversion process at Group VA (Group 15) elements. Edge inversion through a planar T-shaped structure".
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S. Ito; J. Miura; N. Morita; M. Yoshifuji; A. J. Arduengo (2010). "Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride".
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C. A. Stewart; J. C. Calabrese; A. J. Arduengo (1985). "Synthesis and structure of the first 20-Bi-9 system: a discrete nine-coordinate 20-electron bismuth".
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A. J. Arduengo; S. F. Gamper; M. Tamm; J. C. Calabrese; F. Davidson; H. A. Craig (1995). "A Bis(carbene)-Proton Complex: Structure of a C-H-C Hydrogen Bond".
7601: 6670: 5837: 5416: 5401: 5365: 5355: 5294: 5201: 2229:, A. J. Arduengo, "Preparation of Tertiary Amine-Borane Adducts", issued 1992-09-01, assigned to E. I. du Pont de Nemours and Company, Inc. 6675: 5229: 5156: 6010: 5503: 5299: 5289: 6310: 6305: 6290: 2975:
A. J. Arduengo; F. Davidson; R. Krafczyk; W. J. Marshall; R. Schmutzler (1997). "Carbene Complexes of Pnictogen Pentafluorides and Boron Trifluoride".
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A. J. Arduengo; H. V. R. Dias; J. C. Calabrese; F. Davidson (1993). "A : model of the non-least-motion pathway for dimerization of singlet carbenes".
6400: 6275: 6103: 6015: 5659: 5370: 4375: 4144: 821:. The observation that the catalyst syntheses were well tolerant of varied reaction conditions and substituents led Arduengo to postulate that the 652: 636: 7596: 7546: 6653: 6167: 5827: 5432: 5196: 5090: 5005: 4173: 3426: 3255: 3242: 3240:
A. J. Arduengo; J. R. Goerlich; R. Krafczyk; W. J. Marshall (1998). "1,3,4,5-Tetraphenylimidazol-2-ylidene: The Realization of Wanzlick's Dream".
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A. J. Arduengo; H. V. Rasika Dias; D. A. Dixon; R. L. Harlow; W. T. Klooster; T. F. Koetzle (1994). "Electron Distribution in a Stable Carbene".
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from 1977 to 1984. He retired from teaching in 2018 and is now Professor of the Practice in the School of Chemistry and Biochemistry at the
7556: 6709: 6371: 6122: 5964: 5832: 5534: 4024: 4019: 3823: 253:. In 1969 he left high school with enrollment in Georgia Tech's Joint Enrollment Program for High School Students (JEPHS). He obtained his 4621: 6562: 6500: 6098: 6046: 5589: 4162: 2793: 6383: 3849: 7551: 5779: 5151: 3922: 3802: 234: 7514: 2759:
A. J. Arduengo; H. V. R. Dias; J. C. Calabrese; F. Davidson (1993). "Homoleptic carbene-silver(I)] and carbene-copper(I) complexes".
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A. J. Arduengo; F. Davidson; R. Krafczyk; W. J. Marshall; M. Tamm (1999). "Adducts of Carbenes with Group II and XII Metallocenes".
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A. J. Arduengo; S. F. Gamper; J. C. Calabrese; F. Davidson (1994). "Low-Coordinate Carbene Complexes of Nickel(0) and Platinum(0)".
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A. J. Arduengo; D. A. Dixon; K. K. Kumashiro; C. Lee; W. P. Power; K. W. Zilm (1994). "Chemical Shielding Tensor of a Carbene".
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A. J. Arduengo; D. A. Dixon; D. C. Roe; M. Kline (1988). "Edge inversion barrier at a four-coordinate main group IV center".
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A. J. Arduengo; M. Kline; J. C. Calabrese; F. Davidson (1991). "Synthesis of a reverse ylide from a nucleophilic carbene".
758:-ZT, that is widely used in electronics for flexible printed circuits, connections, and insulation. Arduengo's research at 7566: 6836: 6590: 6395: 6300: 6280: 6270: 6020: 5893: 5769: 3993: 3723: 3607: 3171: 2822: 2370: 1370: 832:
As Arduengo's involvement in the automotive coatings program came to an end, he submitted a proposal to the management in
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Gold Medal for "Excellence in Main Group Chemistry Research" from The International Council on Main Group Chemistry, 1996
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H.-J. SchĂśnherr; H.-W. Wanzlick (1970). "Chemie nucleophiler Carbene, XVIII 1.3.4.5-Tetraphenyl-imidazoliumperchlorat".
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occurred during this period. This work with electron deficient carbenes led to the first structure determinations on a
355:, Arduengo began his career in the Chemical Sciences Section (1977 & on return in 1984). In 1988, he was appointed 229:
alternate fuels including alcohol and hydrogen (which would foretell Arduengo's professional research involvement with
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S. Ito; J. Miura; N. Morita; M. Yoshifuji; A. J. Arduengo (2009). "Modeling the Direct Activation of Dihydrogen by a P
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and served as Executive Officer and Captain for that organization. In 1971 he was inducted into the Iota chapter of
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A. J. Arduengo; H. V. R. Dias; R. L. Harlow; M. Kline (1992). "Electronic stabilization of nucleophilic carbenes".
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E. P. Janulis; S. R. Wilson; A. J. Arduengo (1984). "The synthesis and structure of a stabilized nitrilium ylide".
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would have been expected to yield dimers in the absence of bulky substituents on nitrogen, a single (unsaturated)
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Arduengo's research interests focus largely on the chemistry of new or unusual bonding arrangements, and unusual
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A. J. Arduengo; J. C. Calabrese; A. H. Cowley; H. V. R. Dias; J. R. Goerlich; W. J. Marshall; B. Riegel (1997).
7383: 7299: 6938: 5933: 5764: 5597: 5340: 5323: 5166: 5019: 4129: 3724:"Synthesis and physicochemical properties of stable 1,3-diphosphacyclobutane-2,4-diyls bearing sulfanyl groups" 3109:
A. J. Arduengo; M. Tamm; J. C. Calabrese; F. Davidson; W. J. Marshall (1999). "Carbene-Lithium Interactions".
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A. J. Arduengo; E. M. Burgess (1976). "Syntheses and reactions of substituent stabilized thione methylides".
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C. A. Stewart; R. L. Harlow; A. J. Arduengo (1985). "Chemistry and structure of the first 10-Sb-3 species".
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A. J. Arduengo; H. V. R. Dias; J. C. Calabrese (1997). "A Carbene•Phosphinidene Adduct: "Phosphaalkene"".
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A. J. Arduengo; H. V. R. Dias; F. Davidson; R. L. Harlow (1993). "Carbene adducts of magnesium and zinc".
1292:. In 2015, together with Professor Till Opatz (Johannes Gutenberg Universität-Mainz) Arduengo founded the 325: 143: 731:, which was fully characterized and modelled by the collaborative work of Arduengo and David A. Dixon at 7388: 7285: 7270: 7200: 7123: 6955: 6905: 6814: 6739: 6638: 6228: 6062: 6005: 5739: 5642: 4786: 4233: 4111: 4049: 3863: 2452: 2364: 897: 875: 845: 826: 582: 437: 400: 333: 285:, Arduengo's research activities began in the laboratory of Professor Charles L. Liotta. He was awarded 179: 128: 7490: 2264: 2245: 2226: 2138: 2119: 2100: 2081: 7541: 7378: 7333: 7108: 6928: 6858: 6615: 6595: 6431: 6425: 6253: 5923: 5437: 4851: 4402: 4134: 4118: 3998: 3533:
M. Yoshifuji; A. J. Arduengo; S. Ito (2008). "Studies on Stable 1,3-Diphosphacyclobutane-2,4-diyls".
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A. J. Arduengo; R. Krafczyk; W. J. Marshall; R. Schmutzler (1997). "A Carbene−Phosphorus(V) Adduct".
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A. J. Arduengo; E. M. Burgess (1976). "The structure of a substituent stabilized thione methylide".
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A. J. Arduengo; J. R. Goerlich; W. J. Marshall (1997). "A Stable Thiazol-2-ylidene and Its Dimer".
1687: 901: 561: 534: 421: 404: 321: 305: 195: 113: 105: 7497: 888:, but not isolated for 40 years). The imidazol-2-ylidenes were extensively characterized by their 7478: 7444: 7306: 7275: 7156: 7098: 6796: 6779: 6774: 6729: 6692: 6682: 6643: 5538: 5048: 4836: 4831: 4811: 4731: 4716: 4711: 4661: 4428: 4294: 4287: 4223: 4039: 3841: 3704: 3550: 3091: 2992: 2738: 2720:
A. J. Arduengo; M. Kline; J. C. Calabrese; F. Davidson (1992). "A stable carbene-alane adduct]".
1831: 1387: 1071: 1028: 988: 908: 858: 854: 850: 822: 787: 779: 759: 747: 736: 732: 712: 594: 593:, was also accomplished by the Arduengo group at Illinois and paved the way for a range of novel 570: 565: 538: 530: 487: 429: 5493: 3501: 379:
in 1996 began Arduengo's transition back into academe. The one year Humboldt award was spent in
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was complemented by a wide-ranging exploration of their chemistry. This new chemistry included
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S. A. Culley; A. J. Arduengo (1985). "Synthesis and Structure of the First 10-As-3 Species".
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often coalesced with his other hobbies outside the laboratory; for example with sports cars (
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A. J. Arduengo; M. Tamm; S. J. McLain; J. C. Calabrese; F. Davidson; W. J. Marshall (1994).
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S. A. Culley; A. J. Arduengo (1984). "Synthesis and structure of the first 10-P-3 species".
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M. Yoshifuji; A. J. Arduengo; T. A. Konovalova; L. D. Kispert; M. Kikuchi; S. Ito (2006).
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in the syntheses had to be far more stable than the then conventional wisdom would allow.
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A. J. Arduengo; M. Tamm; J. C. Calabrese (1994). "A Bis(carbene) Adduct of Iodine(1+)]".
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Anthony J. Arduengo III, Krafczyk Roland (1998). "Auf der Suche nach Stabilen Carbenen".
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Wanzlick's original tetraphenylimidazol-2-ylidene isolated and characterized at DuPont.
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A. J. Arduengo (1976). "Looking for Stable Carbenes: The Difficulty in Starting Anew".
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First fully characterized imidazolin-2-ylidene (saturated) carbene isolated at DuPont.
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bearing a variety of substituent groups were prepared and characterized. The saturated
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team provided experimental verification on the new inversion pathway at 3-coordinate
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Cars to Carbenes: A Personal Account of Georgia Tech – Molding Futures One at a Time
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A. J. Arduengo; E. M. Burgess (1977). "Tricoordinate hypervalent sulfur compounds".
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Stable small perdeuterocarbene used for exact electron density mapping experiments.
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were also reported from Arduengo's laboratory in addition to insertion reactions of
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10.1002/(SICI)1521-3773(19980803)37:13/14<1963::AID-ANIE1963>3.0.CO;2-M
3095: 815: 560:). During the Illinois years Arduengo had a close collaboration with his colleague 556:
chemistry would become his most recognized contribution to the field of chemistry (
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undergraduate fellowships in 1972 & 1973 when he had moved to research in the
3463:"A Bimetallic Complex Containing a Cyclopentadienyl-Annulated Imidazol-2-ylidene" 3406: 1819: 727:
related chemistry provided a basis for the discovery of a new inversion process,
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10.1002/(SICI)1522-2675(19991215)82:12<2348::AID-HLCA2348>3.0.CO;2-M
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10.1002/(SICI)1521-3749(199911)625:11<1813::AID-ZAAC1813>3.0.CO;2-C
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A. J. Arduengo; C. A. Stewart (1994). "Low coordinate hypervalent phosphorus".
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for the paints on which he worked would launch his re-entry into the area of
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Diazotetrakis(trifluoro methyl)cyclopentadiene from Arduengo and Janulis.
7434: 4996: 4975: 4511: 3519: 3373: 3122: 1036: 972: 962: 922: 862: 818: 803: 771: 578: 6547: 4456: 3340: 3312: 3151: 2926: 2898: 2866: 2835: 2774: 2734: 2706: 2678: 2650: 2619: 2591: 2500: 2436: 2405: 2067: 2036: 1997: 1969: 1940: 1911: 1883: 1778: 1732: 1671: 1639: 1611: 1583: 7454: 6459: 6454: 4486: 4095: 3692: 1552: 1051: 1047: 1043: 1024: 984: 912: 841: 807: 553: 541: 510: 384: 345: 215: 3620: 3478: 3184: 3025: 2954: 2531: 1383: 849:
crystalline carbene was isolated and characterized in laboratories at
766:
photo in the summary box above). He contributed to development of low
249:
Arduengo attended Bouldercrest and Meadowview Elementary Schools, and
4972:(incl. The Playhouse on Rodney Square, formerly the DuPont Playhouse) 4942: 4541: 4526: 4501: 4496: 4471: 4418: 3655: 1792:
J. C. Martin (1983). ""Frozen" transition states: pentavalent carbon
987:
chemistry conducted from Braunschweig included reactivity studies of
956: 932: 928: 916: 755: 602: 440: 433: 392: 368: 317: 3067:
A. J. Arduengo; J. R. Goerlich; F. Davidson; W. J. Marshall (1999).
2351:(November 30, 2009). Archived from the original on December 13, 2009 1297: 191: 5260:
Institute for Computing in the Humanities, Arts, and Social Science
1505: 802:
models. Arduengo's effort on the industrial-scale syntheses of the
7587:
Fellows of the American Association for the Advancement of Science
4577: 4554: 4546: 4536: 4521: 4516: 4506: 4481: 3722:
S. Ito; J. Miura; N. Morita; M. Yoshifuji; A. J. Arduengo (2010).
3387:
A. J. Arduengo; T. P. Bannenberg; D. Tapu; W. J. Marshall (2005).
3356:"Heteroferrocene: The Synthesis of Bisimidazo-2-thionoyl]iron(II)" 3354:
A. J. Arduengo; T. P. Bannenberg; D. Tapu; W. J. Marshall (2005).
1111:
Nine coordinate bismuth complex prepared by Arduengo and Stewart.
750:
also involved a number of applied projects including the flexible
549: 502: 3605:
Cyclic Biradical: Formation of a Cyclic Bis(P−H λ-phosphorane)".
1404:
Talon (Walker High School paper), Vol. V, No. 1. September, 1968.
490:, Arduengo became a member of the exploratory chemistry group of 308:; later serving as Secretary and President for the local Circle. 194:). He is notable for his work on chemical compounds with unusual 7429: 5635: 4491: 4100: 1478:
The synthesis, structure and chemistry of substituent-perturbed
1464:- Georgia Tech's Joint Enrollment Program. Retrieved 2010-10-04. 1269: 944: 182:, adjunct professor at the Institute for Inorganic Chemistry of 6551: 6035: 5063: 4391: 3859: 1532:- Georgia Tech's Alpha Eta Circle of ΟΔΚ. Retrieved 2013-02-08. 1318:
Charles M. Knight Lectureship, University of Akron, April 2013.
90:
ICMGC Gold Medal for Excellence in Main-Group Element Chemistry
7439: 1147:
Germanium compound used by Arduengo, Dixon, and Roe to verify
991:
with fluorinated inorganic compounds. New structures included
3389:"A zwitterionic cyclopentadienyl annulated imidazolium salt" 1296:
coalition for sustainable chemistry based on woody biomass (
605:. The final Illinois research extended the newly discovered 472:
Hypervalent sulfuranide from Arduengo's Ph.D. dissertation.
190:
coalition for sustainable chemistry based on woody biomass (
564:
who was a physical-organic chemist also working on organo-
6378:
Board of Trustees of the University of Alabama v. Garrett
4387: 1529: 1520:
Georgia Tech's Iota Chapter of ΚΚΨ. Retrieved 2017-10-07.
1442: 5235:
Center for International Business Education and Research
3835: 3535:
Phosphorus, Sulfur, and Silicon and the Related Elements
719:
and continued the research into the recently discovered
5310:
Universal Parallel Computing Research Center - Illinois
2482:
A. J. Arduengo; J. R. Goerlich; W. J. Marshall (1995).
456:
Thiocarbonyl ylide from Arduengo's Ph.D. dissertation.
395:, Arduengo maintained a guest Professor appointment in 222:
area. His father was a pressman and mechanic with the
5225:
Beckman Institute for Advanced Science and Technology
3830:
Saxon Professor of Chemistry, Anthony J. Arduengo III
1167:
First stable crystalline carbene prepared at DuPont.
896:, and exact experimental electron density mapping by 3845:
interview with Anthony J. Arduengo III, October 2012
537:. His first publications involving the chemistry of 353:
DuPont's Central Research and Development Department
233:'s 2003 National Hydrogen Fuel Initiative (HFI) and 7371: 7132: 7048: 6969: 6919: 6795: 6738: 6614: 6468: 6418: 6364: 6319: 6263: 6252: 6176: 6121: 6086: 5993: 5952: 5916: 5851: 5798: 5705: 5694: 5651: 5611: 5572: 5565: 5522: 5486: 5425: 5394: 5333: 5322: 5270:
Mortenson Center for International Library Programs
5215: 5127: 5120: 4984: 4865: 4614: 4586: 4563: 4464: 4425: 4304: 4267: 4242: 4206: 4199: 4073: 4007: 3971: 3945: 3895: 2161:
Sports Rainbow of Waterborne Finish Paints from DPC
1323:
American Association for the Advancement of Science
1031:
included synthesis and characterization of carbene¡
853:. After the first successful reaction to produce a 529:
Arduengo examined more broadly the areas of organo-
336:, and holds a position as adjunct professor at the 304:. In 1972 he was tapped by the Alpha Eta Circle of 149: 119: 101: 86:
American Association for the Advancement of Science
74: 66: 56: 37: 21: 5137:Agricultural, Consumer, and Environmental Sciences 1131:analog used by Arduengo, Dixon, and Roe to verify 915:reactions with numerous element centers including 296:As an undergraduate, Arduengo was a member of the 6094:College of Communication and Information Sciences 1747:From Hypervalent Compounds to Hypovalent Carbenes 1416:- Hydrogen Fuel Initiative. Retrieved 2010-10-04. 1095:) synthesized at DuPont by Arduengo and Stewart. 790:waterborne performance coatings would be used by 861:management and research in this area continued. 7577:University of Illinois Urbana-Champaign faculty 5275:National Center for Supercomputing Applications 3461:A. J. Arduengo; D.Tapu; W. J. Marshall (2005). 3420:A. J. Arduengo; D.Tapu; W. J. Marshall (2005). 2387:A. J. Arduengo; R. L. Harlow; M. Kline (1991). 2327:Georgia Tech's 100 Years of Chemistry Symposium 1504:Ph.D. Thesis, Georgia Institute of Technology. 743:centers and a 4-coordinate germanium molecule. 320:from 1976 to 1977, and from 1984 to 1998, and 6563: 6047: 5240:Center for the Simulation of Advanced Rockets 5075: 4403: 3871: 3235: 3233: 3231: 359:. A move into the Polymer Science section of 8: 5295:Sousa Archives and Center for American Music 2970: 2968: 2966: 2964: 2847: 2845: 2786: 2784: 2754: 2752: 1338:Alexander von Humboldt Senior Research Prize 782:Performance Coatings in next-generation low- 533:chemistry, and molecules containing unusual 377:Alexander von Humboldt Senior Research Prize 5230:Carl R. Woese Institute for Genomic Biology 3852:, chemistry.ua.edu. Accessed April 4, 2024. 3832:, chemistry.ua.edu. Accessed April 4, 2024. 2631: 2629: 2543: 2541: 2512: 2510: 2477: 2475: 2417: 2415: 2382: 2380: 1445:– personal home page. Retrieved 2021-01-02. 642:Nitrilium ylide from Arduengo and Janulis. 375:which he attained in 1995. The award of an 332:, Saxon Chair Emeritus of Chemistry at the 6570: 6556: 6548: 6260: 6054: 6040: 6032: 5702: 5569: 5330: 5300:State Farm Research and Development Center 5290:Regional Economics Applications Laboratory 5124: 5082: 5068: 5060: 4410: 4396: 4388: 4203: 3878: 3864: 3856: 3838:, ajarduengo.net. Accessed April 4, 2024. 2317: 2315: 2313: 2311: 1438: 1436: 1434: 1432: 1430: 1428: 1426: 1424: 1422: 1363: 1361: 1359: 844:chemistry that firmly established them as 658:Carbonyl ylide from Arduengo and Janulis. 210:Anthony "Bo" Arduengo was born in 1952 in 18: 907:The Arduengo group's characterization of 573:centers, Martin and Arduengo devised the 5660:Comparative Labor Law and Policy Journal 3467:Journal of the American Chemical Society 2283: 2281: 2279: 1472: 1470: 715:in 1984, Arduengo resumed a position in 363:in 1991 was accompanied by promotion to 5828:Krannert Center for the Performing Arts 5092:University of Illinois Urbana-Champaign 5006:NASCAR Cup Series career of Jeff Gordon 4174:Omega Chapter of the Chi Phi Fraternity 3427:Angewandte Chemie International Edition 3243:Angewandte Chemie International Edition 2048: 2046: 2017: 2015: 1355: 1077: 616: 446: 5285:The Rare Book & Manuscript Library 2362: 1714:E. P. Janulis; A. J. Arduengo (1983). 1653:E. P. Janulis; A. J. Arduengo (1983). 1331:Walter J. Chute Lectureship 1999–2000. 869:that were extensively investigated by 810:chemistry, but this time it was to be 597:chemistry (including the discovery of 498:. His first research project involved 432:chemistry, specifically, thiocarbonyl 5265:Institute for Condensed Matter Theory 4938:Winterthur Museum, Garden and Library 3757:– Researchgate. Retrieved 2021-01-02. 983:, Professor Reinhard Schmutzler. His 981:Alexander von Humboldt Research Prize 316:Arduengo was a research scientist at 184:Braunschweig University of Technology 134:Technische Universität - Braunschweig 7: 7592:Scientists from Georgia (U.S. state) 7485: 6104:College of Community Health Sciences 5833:Newmark Civil Engineering Laboratory 5044: 3769:– affiliates. Retrieved 2021-01-02. 3069:"Carbene Adducts of Dimethylcadmium" 1546: 1544: 1542: 1540: 1538: 1346:Undergraduate Fellowship, 1972, 1973 993:carbene•phenyltetrafluorophosphorane 488:E. I. du Pont de Nemours and Company 428:group, his research involved organo- 170:is Professor of the Practice at the 7602:Academics from Georgia (U.S. state) 7509: 3805:Web Page - Retrieved Oct. 20, 2016. 3793:Web Page - Retrieved Oct. 20, 2016. 3781:– affiliates. Retrieved 2020-01-02. 2794:Journal of Organometallic Chemistry 2329:(Atlanta, Georgia, April 19, 2007). 2196:Developing the Lotus Elise Series 2 5838:Siebel Center for Computer Science 3958:Industrial and Systems Engineering 2202:Automotive Design & Production 1753:(Vanderbilt University, May, 1992) 1551:Arduengo, Anthony J (2021-01-02). 1023:adducts. Arduengo's final work on 235:United States Department of Energy 186:in Germany, and co-founder of the 70:Unusual Valency, Carbene Chemistry 14: 6481:Center for Advanced Public Safety 5884:Conservatory and Plant Collection 5681:University of Illinois Law Review 5013:The DuPont Show with June Allyson 1751:From σ-Constants to σ-Aromaticity 609:chemistry to the arsenic analog ( 416:Graduate research at Georgia Tech 7508: 7496: 7484: 7473: 7472: 6112: 5590:Graduate Employees' Organization 5433:Activities and Recreation Center 5043: 5034: 5033: 4455: 4371: 4370: 4163:Ramblin' Wreck from Georgia Tech 3936: 3817: 3791:Charles M. Knight Lecture series 1476:Anthony Joseph Arduengo (1976), 1262: 1246: 1230: 1215: 1192: 1176: 1160: 1140: 1120: 1104: 1080: 770:automotive coatings by devising 687: 667: 651: 635: 619: 521:University of Illinois 1978–1984 465: 449: 241:Program by more than 30 years). 29: 5808:Business Instructional Facility 5667:Illinois Journal of Mathematics 5468:Kenney Gym and Kenney Gym Annex 5443:Campus Recreation Center – East 5002:Hendrick Motorsports Car No. 24 3888:Georgia Institute of Technology 3843:Chemical & Engineering News 1278:University of Alabama 1999–2020 424:. As a graduate student in the 330:Georgia Institute of Technology 172:Georgia Institute of Technology 124:Georgia Institute of Technology 61:Georgia Institute of Technology 7597:Scientists from Tampa, Florida 7547:21st-century American chemists 5970:Unofficial Saint Patrick's Day 5619:Fighting Illini Sports Network 5245:Coordinated Science Laboratory 5177:Labor and Employment Relations 3803:Walter J. Chute Lecture Series 3167:"Carbene−Pnictinidene Adducts" 2882:"Carbene-Lanthanide Complexes" 2389:"A stable crystalline carbene" 1553:"AJ Arduengo Curriculum Vitae" 857:, Arduengo won the support of 174:, Saxon Professor Emeritus of 1: 7582:University of Alabama faculty 6837:Interface and colloid science 6591:Glossary of chemical formulae 6396:Stand in the Schoolhouse Door 6021:University of Illinois System 5894:McFarland Memorial Bell Tower 5770:Noyes Laboratory of Chemistry 3850:Alabama's Arduengo Lecturship 2466:10.1016/S0040-4020(99)00927-8 1701:10.1016/S0040-4039(00)99896-4 1371:Accounts of Chemical Research 198:, especially in the field of 6511:University of Alabama System 5813:Grainger Engineering Library 5594:Illinois Business Consulting 3407:10.1016/j.tetlet.2005.08.018 2807:10.1016/0022-328X(93)83336-T 1820:10.1126/science.221.4610.509 836:to isolate these apparently 225:Atlanta Journal-Constitution 7557:American inorganic chemists 7114:Bioorganometallic chemistry 6601:List of inorganic compounds 6450:University of Alabama Press 6438:Crimson Tide Sports Network 5725:Busey–Evans Residence Halls 5580:Fraternities and sororities 5255:Information Trust Institute 4672:Anthony Joseph Arduengo III 4601:DuPont Experimental Station 4276:Continuing the Conversation 3836:The Arduengo Research Group 3824:Anthony Joseph Arduengo III 1290:nonlinear optical materials 1135:at 3-coordinate phosphorus. 977:bis(carbene)-proton complex 894:photo-electron spectroscopy 168:Anthony Joseph Arduengo III 42:Anthony Joseph Arduengo III 7618: 7040:Dynamic covalent chemistry 7011:Enantioselective synthesis 6991:Physical organic chemistry 6944:Organolanthanide chemistry 5980:COVID-19 pandemic response 5280:Prairie Research Institute 5250:Illinois Newspaper Project 4959:DuPont v. Kolon Industries 4948:Consolidation Coal Company 4156:Up with the White and Gold 4106:Georgia Tech Cable Network 3742:10.1016/j.crci.2010.04.007 1749:", J.C. Martin Symposium: 1460:September 5, 2010, at the 1199:Stable thiazol-2-ylidene ( 697:from Arduengo and Culley. 678:from Arduengo and Culley. 367:. His final position with 7552:American organic chemists 7468: 6629:Electroanalytical methods 6586: 6519: 6214:Museum of Natural History 6110: 6071: 6064:The University of Alabama 5187:Liberal Arts and Sciences 5099: 5029: 4903:Hagley Museum and Library 4883:Atlas Chemical Industries 4822:Howard Ensign Simmons Jr. 4677:Jacques Antoine Bidermann 4453: 4365: 3934: 3547:10.1080/10426500701734588 2564:10.1002/jlac.199719970213 2369:: CS1 maint: unfit URL ( 2343:Taming Carbon's Wild Side 1304:Georgia Tech 2020–present 1151:at 4-coordinate centers. 575:N-X-L nomenclature system 281:. As an undergraduate at 161: 94: 28: 7384:Nobel Prize in Chemistry 7300:Supramolecular chemistry 6939:Organometallic chemistry 5960:1960s slush fund scandal 5934:Mount Laguna Observatory 5765:Natural History Building 5598:Illinois Solar Decathlon 5341:Illinois Fighting Illini 5020:DuPont Show of the Month 4622:Éleuthère IrĂŠnĂŠe du Pont 4060:Campus Recreation Center 3285:10.1002/jlac.19707310121 2339:Cristina Luiggi (2009). 2302:10.1002/ciuz.19980320103 7322:Combinatorial chemistry 7233:Food physical chemistry 7196:Environmental chemistry 7080:Bioorthogonal chemistry 7006:Retrosynthetic analysis 6827:Chemical thermodynamics 6810:Spectroelectrochemistry 6753:Computational chemistry 5142:Applied Health Sciences 4908:Hercules Powder Company 4596:DuPont Central Research 4357:Georgia Tech Foundation 3994:Nuclear Research Center 3989:Nanotechnology Building 3755:Anthony J. Arduengo III 2484:"stable diaminocarbene" 1508:. Retrieved 2009-12-04. 1443:Anthony J. Arduengo III 1272:, a popular NHC ligand. 486:In 1977 when he joined 139:DuPont Central Research 7394:of element discoveries 7240:Agricultural chemistry 7228:Carbohydrate chemistry 7119:Bioinorganic chemistry 6984:Alkane stereochemistry 6929:Coordination chemistry 6758:Mathematical chemistry 6624:Instrumental chemistry 6327:Alabama Soccer Stadium 6204:Insurance Hall of Fame 5172:Grainger (Engineering) 4667:Jeffery Stanford Agate 4642:Francis IrĂŠnĂŠe du Pont 4637:Francis Gurney du Pont 4045:Hank McCamish Pavilion 3963:Mechanical Engineering 3953:Biomedical Engineering 3584:10.1002/zaac.200801265 3541:(2 & 3): 335–339. 3440:10.1002/anie.200502814 3209:Helvetica Chimica Acta 2977:Monatshefte fĂźr Chemie 2290:Chemie in unserer Zeit 2167:DuPont Refinisher News 2157:R. W. Yearich (2004). 1050:adducts. Reactions of 846:reactive intermediates 552:. His later work with 338:Technische Universität 326:University of Illinois 144:University of Illinois 7389:Timeline of chemistry 7286:Post-mortem chemistry 7271:Clandestine chemistry 7201:Atmospheric chemistry 7124:Biophysical chemistry 6956:Solid-state chemistry 6906:Equilibrium chemistry 6815:Photoelectrochemistry 6352:Sewell–Thomas Stadium 6229:Paul W. Bryant Museum 5740:Foellinger Auditorium 5643:Illinois Public Media 5417:Wheelchair basketball 5162:Fine and Applied Arts 4787:William Dale Phillips 4050:Russ Chandler Stadium 3729:Comptes Rendus Chimie 3572:Z. Anorg. Allg. Chem. 3088:10.1515/znb-1999-1102 3042:Z. Anorg. Allg. Chem. 2989:10.1007/s007060070101 2265:US patent 5182405 2246:US patent 5104993 2227:US patent 5144032 2192:C. A. Sawyer (2004). 2139:US patent 5091498 2120:US patent 5084542 2101:US patent 5034464 2082:US patent 5272194 1068:imidazolin-2-ylidenes 1060:imidazolin-2-ylidenes 876:reactive intermediate 867:imidazolin-2-ylidenes 746:Arduengo's work with 436:, and low-coordinate 401:University of Alabama 334:University of Alabama 180:University of Alabama 129:University of Alabama 7567:Georgia Tech faculty 7379:History of chemistry 7334:Chemical engineering 7109:Bioorganic chemistry 6859:Structural chemistry 6596:List of biomolecules 6432:The Bear Bryant Show 6426:Alabama Public Radio 6332:Bryant–Denny Stadium 5438:Atkins Tennis Center 5192:Information Sciences 4852:Edgar S. Woolard Jr. 4135:Brittain Dining Hall 4065:Athletic Association 3984:Research Corporation 3826:at Wikimedia Commons 3644:Heteroatom Chemistry 3520:10.1246/cl.2006.1136 3374:10.1246/cl.2005.1010 3250:(13–14): 1963–1965. 3123:10.1246/cl.1999.1021 1852:Kikan Kagaku Sosetsu 1506:Online catalog entry 1222:Air-stable carbene. 1033:alkaline earth metal 871:Hans-Werner Wanzlick 786:paints. Eventually, 735:. Additionally, the 674:The original 10-P-3 389:Technical University 214:. He grew up in the 7562:Georgia Tech alumni 7402:The central science 7356:Ceramic engineering 7281:Forensic toxicology 7254:Chemistry education 7152:Radiation chemistry 7134:Interdisciplinarity 7087:Medicinal chemistry 7025:Fullerene chemistry 6901:Microwave chemistry 6770:Molecular mechanics 6765:Molecular modelling 6501:Million Dollar Band 6234:President's Mansion 6189:Archaeological Park 6143:Amelia Gayle Gorgas 6079:Tuscaloosa, Alabama 5975:Chancellors of UIUC 5965:2000s clout scandal 5823:Krannert Art Museum 5785:Smith Memorial Hall 5509:Ohio State football 5207:Veterinary Medicine 5113:Champaign, Illinois 4928:Savannah River Site 4782:Charles J. Pedersen 4752:Edward G. Jefferson 4742:Charles O. Holliday 4578:Antec International 4442:Alexander M. Cutler 3680:Dalton Transactions 3608:Inorganic Chemistry 3473:(47): 16400–16401. 3394:Tetrahedron Letters 3341:10.1021/ja00297a084 3313:10.1021/ja00305a046 3172:Inorganic Chemistry 3152:10.1246/cl.1997.143 2927:10.1021/ja00106a082 2899:10.1021/ja00096a072 2867:10.1021/ja00089a029 2836:10.1021/ic00061a004 2823:Inorganic Chemistry 2775:10.1021/om00033a009 2735:10.1021/ja00050a098 2707:10.1021/ja00087a069 2679:10.1021/ja00025a063 2651:10.1021/ja00094a040 2620:10.1021/ja00094a020 2592:10.1021/ja00093a041 2526:(52): 12742–12749. 2501:10.1021/ja00149a034 2495:(44): 11027–11028. 2460:(51): 14523–14534. 2437:10.1021/ja00040a007 2406:10.1021/ja00001a054 2068:10.1021/ja00221a067 2037:10.1021/ja00281a070 1998:10.1021/ja00269a063 1970:10.1021/cr00029a003 1941:10.1021/ja00237a001 1912:10.1021/ja00290a072 1884:10.1021/ja00316a084 1812:1983Sci...221..509M 1779:10.1021/ja00546a019 1733:10.1021/ja00356a044 1688:Tetrahedron Letters 1672:10.1021/ja00349a032 1640:10.1021/ja00449a078 1612:10.1021/ja00432a057 1584:10.1021/ja00432a056 1087:Antimony analog of 989:imidazol-2-ylidenes 902:neutron diffraction 823:imidazol-2-ylidenes 601:) on his return to 322:assistant professor 275:academic descendant 273:. That made him an 106:Inorganic chemistry 23:Anthony J. Arduengo 7445:Chemical substance 7307:Chemical synthesis 7276:Forensic chemistry 7157:Actinide chemistry 7099:Clinical chemistry 6780:Molecular geometry 6775:Molecular dynamics 6730:Elemental analysis 6683:Separation process 6526:: $ 631.95 million 6311:Women's basketball 5953:History and people 5889:Engineering Campus 5539:Hail to the Orange 5386:Women's volleyball 5381:Women's basketball 5305:University Library 4873:DuPont (1802–2017) 4857:Nathaniel C. Wyeth 4837:Chadwick A. Tolman 4832:Frederick N. Tebbe 4812:Richard R. Schrock 4732:Richard Goodmanson 4717:Curtis J. Crawford 4712:Thomas M. Connelly 4662:T. Coleman du Pont 4352:Alumni Association 4305:People and history 4295:The First Graduate 4288:The Three Pioneers 4040:Bobby Dodd Stadium 4035:Women's basketball 3979:Research Institute 3736:(8–9): 1180–1184. 3693:10.1039/c0dt00532k 1072:imidazol-2-ylidene 778:chemistry used by 595:main-group element 583:coordinate bonding 571:main-group element 566:main group element 539:electron-deficient 531:main group element 430:main group element 251:Walker High School 7524: 7523: 7460:Quantum mechanics 7425:Chemical compound 7408:Chemical reaction 7346:Materials science 7264:General chemistry 7259:Amateur chemistry 7187:Photogeochemistry 7172:Stellar chemistry 7142:Nuclear chemistry 7063:Molecular biology 7030:Polymer chemistry 7001:Organic synthesis 6996:Organic reactions 6961:Ceramic chemistry 6951:Cluster chemistry 6881:Chemical kinetics 6869:Molecular physics 6748:Quantum chemistry 6661:Mass spectrometry 6545: 6544: 6444:The Crimson White 6384:Historic District 6360: 6359: 6342:Foster Auditorium 6029: 6028: 6016:Stoesser Lecturer 5912: 5911: 5690: 5689: 5561: 5560: 5478:State Farm Center 5318: 5317: 5057: 5056: 4913:Kinetic Chemicals 4898:Eleutherian Mills 4892:Manhattan Project 4807:Irving S. Shapiro 4802:William K. Reilly 4702:Wallace Carothers 4657:Pierre S. du Pont 4627:Alfred I. du Pont 4385: 4384: 4342:George P. Burdell 4282:Kessler Campanile 4263: 4262: 4229:Historic district 3822:Media related to 3687:(35): 8281–8287. 3621:10.1021/ic901072z 3615:(17): 8063–8065. 3514:(10): 1136–1137. 3507:Chemistry Letters 3479:10.1021/ja055565f 3434:(44): 7240–7244. 3401:(40): 6847–6850. 3361:Chemistry Letters 3335:(11): 3397–3398. 3329:J. Am. Chem. Soc. 3307:(19): 5543–5544. 3301:J. Am. Chem. Soc. 3216:(12): 2348–2364. 3185:10.1021/ic970174q 3179:(10): 2151–2158. 3139:Chemistry Letters 3117:(10): 1021–1022. 3111:Chemistry Letters 3082:(11): 1350–1356. 3076:Z. Naturforsch. B 3048:(11): 1813–1817. 3026:10.1021/om980438w 3020:(15): 3375–3382. 2955:10.1021/ja964094h 2949:(14): 3381–3382. 2943:J. Am. Chem. Soc. 2915:J. Am. Chem. Soc. 2893:(17): 7927–7928. 2887:J. Am. Chem. Soc. 2861:(10): 4391–4394. 2855:J. Am. Chem. Soc. 2729:(24): 9724–9725. 2723:J. Am. Chem. Soc. 2695:J. Am. Chem. Soc. 2673:(25): 3625–3626. 2667:J. Am. Chem. Soc. 2645:(15): 6812–6822. 2639:J. Am. Chem. Soc. 2614:(15): 6641–6649. 2608:J. Am. Chem. Soc. 2586:(14): 6361–6367. 2580:J. Am. Chem. Soc. 2532:10.1021/ja973241o 2520:J. Am. Chem. Soc. 2489:J. Am. Chem. Soc. 2431:(14): 5530–5534. 2425:J. Am. Chem. Soc. 2394:J. Am. Chem. Soc. 2062:(13): 4437–4438. 2056:J. Am. Chem. Soc. 2025:J. Am. Chem. Soc. 1986:J. Am. Chem. Soc. 1929:J. Am. Chem. Soc. 1900:J. Am. Chem. Soc. 1872:J. Am. Chem. Soc. 1806:(4610): 509–514. 1773:(26): 7753–7759. 1767:J. Am. Chem. Soc. 1727:(18): 5929–5930. 1721:J. Am. Chem. Soc. 1666:(11): 3563–3567. 1660:J. Am. Chem. Soc. 1628:J. Am. Chem. Soc. 1606:(16): 1521–1523. 1600:J. Am. Chem. Soc. 1578:(16): 1520–1521. 1572:J. Am. Chem. Soc. 1384:10.1021/ar980126p 585:arrangement at a 515:organic synthesis 298:Georgia Tech Band 279:Justus von Liebig 271:Edward M. Burgess 165: 164: 110:Organic chemistry 96:Scientific career 7609: 7512: 7511: 7500: 7488: 7487: 7476: 7475: 7420:Chemical element 7075:Chemical biology 6934:Magnetochemistry 6911:Mechanochemistry 6864:Chemical physics 6805:Electrochemistry 6710:Characterization 6572: 6565: 6558: 6549: 6409:Bishop v. Aronov 6401:1963 documentary 6337:Coleman Coliseum 6276:Men's basketball 6261: 6256: 6125: 6116: 6080: 6065: 6056: 6049: 6042: 6033: 5735:English Building 5730:Engineering Hall 5703: 5698: 5630:The Daily Illini 5570: 5543:Illinois Loyalty 5473:Memorial Stadium 5407:Men's volleyball 5402:Men's ice hockey 5366:Men's gymnastics 5356:Men's basketball 5331: 5326: 5152:Carle (Medicine) 5125: 5114: 5108: 5093: 5084: 5077: 5070: 5061: 5047: 5046: 5037: 5036: 4933:Wilmington Trust 4762:Stephanie Kwolek 4757:Ellen J. Kullman 4697:Richard H. Brown 4459: 4412: 4405: 4398: 4389: 4374: 4373: 4204: 4030:Men's basketball 3946:Dept and Schools 3940: 3889: 3880: 3873: 3866: 3857: 3821: 3806: 3800: 3794: 3788: 3782: 3776: 3770: 3764: 3758: 3752: 3746: 3745: 3719: 3713: 3712: 3674: 3668: 3667: 3656:10.1002/hc.20625 3639: 3633: 3632: 3594: 3588: 3587: 3565: 3559: 3558: 3530: 3524: 3523: 3497: 3491: 3490: 3458: 3452: 3451: 3417: 3411: 3410: 3384: 3378: 3377: 3368:(7): 1010–1011. 3351: 3345: 3344: 3323: 3317: 3316: 3295: 3289: 3288: 3266: 3260: 3259: 3237: 3226: 3225: 3203: 3197: 3196: 3162: 3156: 3155: 3133: 3127: 3126: 3106: 3100: 3099: 3073: 3064: 3058: 3057: 3036: 3030: 3029: 3007: 3001: 3000: 2972: 2959: 2958: 2937: 2931: 2930: 2909: 2903: 2902: 2877: 2871: 2870: 2849: 2840: 2839: 2830:(9): 1541–1542. 2817: 2811: 2810: 2788: 2779: 2778: 2769:(9): 3405–3409. 2756: 2747: 2746: 2717: 2711: 2710: 2701:(8): 3625–3626. 2689: 2683: 2682: 2661: 2655: 2654: 2633: 2624: 2623: 2602: 2596: 2595: 2574: 2568: 2567: 2545: 2536: 2535: 2514: 2505: 2504: 2479: 2470: 2469: 2447: 2441: 2440: 2419: 2410: 2409: 2384: 2375: 2374: 2368: 2360: 2358: 2356: 2336: 2330: 2319: 2306: 2305: 2285: 2274: 2273: 2272: 2268: 2261: 2255: 2254: 2253: 2249: 2242: 2236: 2235: 2234: 2230: 2223: 2217: 2216: 2214: 2212: 2189: 2183: 2182: 2180: 2178: 2154: 2148: 2147: 2146: 2142: 2135: 2129: 2128: 2127: 2123: 2116: 2110: 2109: 2108: 2104: 2097: 2091: 2090: 2089: 2085: 2078: 2072: 2071: 2050: 2041: 2040: 2031:(9): 6821–6823. 2019: 2010: 2009: 1992:(9): 2461–2462. 1980: 1974: 1973: 1964:(5): 1215–1237. 1957:Chemical Reviews 1951: 1945: 1944: 1922: 1916: 1915: 1906:(4): 1089–1090. 1894: 1888: 1887: 1878:(4): 1164–1165. 1866: 1860: 1859: 1846: 1840: 1839: 1789: 1783: 1782: 1760: 1754: 1743: 1737: 1736: 1716:"carbonyl ylide" 1711: 1705: 1704: 1682: 1676: 1675: 1650: 1644: 1643: 1634:(2): 2376–2377. 1622: 1616: 1615: 1594: 1588: 1587: 1566: 1560: 1559: 1557: 1548: 1533: 1530:Alpha Eta Circle 1527: 1521: 1515: 1509: 1474: 1465: 1452: 1446: 1440: 1417: 1411: 1405: 1402: 1396: 1395: 1365: 1309:to U.S. shores. 1285:cyclopentadienyl 1266: 1250: 1234: 1219: 1196: 1180: 1164: 1144: 1124: 1108: 1084: 711:On returning to 707:DuPont 1984–1999 691: 671: 655: 639: 623: 469: 453: 239:Hydrogen Storage 151:Doctoral advisor 33: 19: 16:American chemist 7617: 7616: 7612: 7611: 7610: 7608: 7607: 7606: 7527: 7526: 7525: 7520: 7464: 7367: 7361:Polymer science 7317:Click chemistry 7312:Green chemistry 7206:Ocean chemistry 7182:Biogeochemistry 7128: 7044: 7016:Total synthesis 6979:Stereochemistry 6965: 6915: 6832:Surface science 6822:Thermochemistry 6791: 6734: 6705:Crystallography 6610: 6582: 6576: 6546: 6541: 6515: 6464: 6414: 6356: 6315: 6254: 6248: 6224:Old Observatory 6219:New Observatory 6172: 6138:George H. Denny 6123: 6117: 6108: 6082: 6078: 6067: 6063: 6060: 6030: 6025: 5989: 5948: 5944:Willard Airport 5908: 5904:Residence halls 5853: 5847: 5843:Spurlock Museum 5800: 5794: 5790:Uni High School 5707: 5696: 5686: 5647: 5607: 5603:Marching Illini 5557: 5530:Chief Illiniwek 5518: 5494:Braggin' Rights 5482: 5421: 5390: 5324: 5314: 5217: 5211: 5167:Gies (Business) 5129: 5116: 5112: 5106: 5095: 5091: 5088: 5058: 5053: 5025: 4980: 4970:DuPont Building 4953:DuPont analysis 4861: 4847:Charles M. Vest 4792:Roy J. Plunkett 4777:George Parshall 4772:Rudolph Pariser 4692:Donaldson Brown 4610: 4606:DuPont Building 4588: 4582: 4568: 4559: 4460: 4451: 4437:Edward D. Breen 4427: 4421: 4416: 4386: 4381: 4361: 4300: 4259: 4238: 4195: 4091:Under the Couch 4069: 4003: 3967: 3941: 3932: 3891: 3887: 3884: 3814: 3809: 3801: 3797: 3789: 3785: 3777: 3773: 3765: 3761: 3753: 3749: 3721: 3720: 3716: 3676: 3675: 3671: 3641: 3640: 3636: 3604: 3600: 3596: 3595: 3591: 3567: 3566: 3562: 3532: 3531: 3527: 3499: 3498: 3494: 3460: 3459: 3455: 3419: 3418: 3414: 3386: 3385: 3381: 3353: 3352: 3348: 3325: 3324: 3320: 3297: 3296: 3292: 3272:Liebigs Annalen 3268: 3267: 3263: 3239: 3238: 3229: 3205: 3204: 3200: 3164: 3163: 3159: 3135: 3134: 3130: 3108: 3107: 3103: 3071: 3066: 3065: 3061: 3038: 3037: 3033: 3013:Organometallics 3009: 3008: 3004: 2974: 2973: 2962: 2939: 2938: 2934: 2911: 2910: 2906: 2879: 2878: 2874: 2851: 2850: 2843: 2819: 2818: 2814: 2790: 2789: 2782: 2762:Organometallics 2758: 2757: 2750: 2719: 2718: 2714: 2691: 2690: 2686: 2663: 2662: 2658: 2635: 2634: 2627: 2604: 2603: 2599: 2576: 2575: 2571: 2551:Liebigs Annalen 2547: 2546: 2539: 2516: 2515: 2508: 2481: 2480: 2473: 2449: 2448: 2444: 2421: 2420: 2413: 2386: 2385: 2378: 2361: 2354: 2352: 2338: 2337: 2333: 2321:A.J. Arduengo " 2320: 2309: 2287: 2286: 2277: 2270: 2263: 2262: 2258: 2251: 2244: 2243: 2239: 2232: 2225: 2224: 2220: 2210: 2208: 2191: 2190: 2186: 2176: 2174: 2156: 2155: 2151: 2144: 2137: 2136: 2132: 2125: 2118: 2117: 2113: 2106: 2099: 2098: 2094: 2087: 2080: 2079: 2075: 2052: 2051: 2044: 2021: 2020: 2013: 1982: 1981: 1977: 1953: 1952: 1948: 1924: 1923: 1919: 1896: 1895: 1891: 1868: 1867: 1863: 1848: 1847: 1843: 1791: 1790: 1786: 1762: 1761: 1757: 1745:A.J. Arduengo " 1744: 1740: 1713: 1712: 1708: 1684: 1683: 1679: 1652: 1651: 1647: 1624: 1623: 1619: 1596: 1595: 1591: 1568: 1567: 1563: 1555: 1550: 1549: 1536: 1528: 1524: 1516: 1512: 1475: 1468: 1462:Wayback Machine 1453: 1449: 1441: 1420: 1412: 1408: 1403: 1399: 1378:(11): 913–921. 1367: 1366: 1357: 1353: 1315: 1306: 1280: 1273: 1267: 1258: 1255:external viewer 1251: 1242: 1239:external viewer 1235: 1226: 1224:external viewer 1220: 1211: 1208:external viewer 1204: 1197: 1188: 1185:external viewer 1181: 1172: 1169:external viewer 1165: 1156: 1153:external viewer 1145: 1136: 1125: 1116: 1113:external viewer 1109: 1100: 1097:external viewer 1085: 1075: 1021: 1014: 1007: 1000: 909:stable carbenes 886:catalytic cycle 883: 838:stable carbenes 709: 702: 699:external viewer 692: 683: 680:external viewer 672: 663: 660:external viewer 656: 647: 644:external viewer 640: 631: 628:external viewer 624: 614: 548:and a carbonyl 523: 507:inorganic acids 484: 477: 474:external viewer 470: 461: 458:external viewer 454: 444: 418: 413: 391:. On return to 373:Research Fellow 357:Research Leader 314: 247: 208: 142: 137: 132: 127: 89: 83: 57:Alma mater 52: 51:, Florida, U.S. 46: 44: 43: 24: 17: 12: 11: 5: 7615: 7613: 7605: 7604: 7599: 7594: 7589: 7584: 7579: 7574: 7569: 7564: 7559: 7554: 7549: 7544: 7539: 7529: 7528: 7522: 7521: 7519: 7518: 7506: 7494: 7482: 7469: 7466: 7465: 7463: 7462: 7457: 7452: 7447: 7442: 7437: 7432: 7427: 7422: 7417: 7416: 7415: 7405: 7398: 7397: 7396: 7386: 7381: 7375: 7373: 7369: 7368: 7366: 7365: 7364: 7363: 7358: 7353: 7343: 7342: 7341: 7331: 7330: 7329: 7324: 7319: 7314: 7304: 7303: 7302: 7291: 7290: 7289: 7288: 7283: 7273: 7268: 7267: 7266: 7261: 7250: 7249: 7248: 7247: 7245:Soil chemistry 7237: 7236: 7235: 7230: 7223:Food chemistry 7220: 7218:Carbochemistry 7215: 7213:Clay chemistry 7210: 7209: 7208: 7203: 7192: 7191: 7190: 7189: 7184: 7174: 7168:Astrochemistry 7164:Cosmochemistry 7161: 7160: 7159: 7154: 7149: 7147:Radiochemistry 7138: 7136: 7130: 7129: 7127: 7126: 7121: 7116: 7111: 7106: 7104:Neurochemistry 7101: 7096: 7095: 7094: 7084: 7083: 7082: 7072: 7071: 7070: 7065: 7054: 7052: 7046: 7045: 7043: 7042: 7037: 7035:Petrochemistry 7032: 7027: 7022: 7013: 7008: 7003: 6998: 6993: 6988: 6987: 6986: 6975: 6973: 6967: 6966: 6964: 6963: 6958: 6953: 6948: 6947: 6946: 6936: 6931: 6925: 6923: 6917: 6916: 6914: 6913: 6908: 6903: 6898: 6896:Spin chemistry 6893: 6891:Photochemistry 6888: 6883: 6878: 6876:Femtochemistry 6873: 6872: 6871: 6861: 6856: 6851: 6846: 6845: 6844: 6834: 6829: 6824: 6819: 6818: 6817: 6812: 6801: 6799: 6793: 6792: 6790: 6789: 6788: 6787: 6777: 6772: 6767: 6762: 6761: 6760: 6750: 6744: 6742: 6736: 6735: 6733: 6732: 6727: 6722: 6717: 6712: 6707: 6702: 6701: 6700: 6695: 6688:Chromatography 6685: 6680: 6679: 6678: 6673: 6668: 6658: 6657: 6656: 6651: 6646: 6641: 6631: 6626: 6620: 6618: 6612: 6611: 6609: 6608: 6606:Periodic table 6603: 6598: 6593: 6587: 6584: 6583: 6577: 6575: 6574: 6567: 6560: 6552: 6543: 6542: 6540: 6539: 6533: 6527: 6520: 6517: 6516: 6514: 6513: 6508: 6503: 6498: 6493: 6488: 6483: 6478: 6472: 6470: 6466: 6465: 6463: 6462: 6457: 6452: 6447: 6440: 6435: 6428: 6422: 6420: 6416: 6415: 6413: 6412: 6405: 6404: 6403: 6393: 6386: 6381: 6374: 6368: 6366: 6362: 6361: 6358: 6357: 6355: 6354: 6349: 6347:Rhoads Stadium 6344: 6339: 6334: 6329: 6323: 6321: 6317: 6316: 6314: 6313: 6308: 6303: 6298: 6293: 6288: 6283: 6278: 6273: 6267: 6265: 6258: 6250: 6249: 6247: 6246: 6241: 6236: 6231: 6226: 6221: 6216: 6211: 6206: 6201: 6196: 6191: 6186: 6180: 6178: 6174: 6173: 6171: 6170: 6165: 6163:Julia Tutwiler 6160: 6155: 6153:Autherine Lucy 6150: 6145: 6140: 6135: 6129: 6127: 6119: 6118: 6111: 6109: 6107: 6106: 6101: 6096: 6090: 6088: 6084: 6083: 6072: 6069: 6068: 6061: 6059: 6058: 6051: 6044: 6036: 6027: 6026: 6024: 6023: 6018: 6013: 6011:Public transit 6008: 6003: 5997: 5995: 5991: 5990: 5988: 5987: 5985:Notable people 5982: 5977: 5972: 5967: 5962: 5956: 5954: 5950: 5949: 5947: 5946: 5941: 5936: 5931: 5926: 5920: 5918: 5914: 5913: 5910: 5909: 5907: 5906: 5901: 5896: 5891: 5886: 5881: 5879:Boneyard Creek 5876: 5871: 5863: 5857: 5855: 5849: 5848: 5846: 5845: 5840: 5835: 5830: 5825: 5820: 5815: 5810: 5804: 5802: 5796: 5795: 5793: 5792: 5787: 5782: 5777: 5772: 5767: 5762: 5757: 5752: 5747: 5742: 5737: 5732: 5727: 5722: 5719:Altgeld Chimes 5711: 5709: 5700: 5692: 5691: 5688: 5687: 5685: 5684: 5677: 5670: 5663: 5655: 5653: 5649: 5648: 5646: 5645: 5640: 5639: 5638: 5633: 5621: 5615: 5613: 5609: 5608: 5606: 5605: 5600: 5595: 5592: 5587: 5582: 5576: 5574: 5567: 5563: 5562: 5559: 5558: 5556: 5555: 5550: 5532: 5526: 5524: 5520: 5519: 5517: 5516: 5511: 5506: 5501: 5496: 5490: 5488: 5484: 5483: 5481: 5480: 5475: 5470: 5465: 5463:Illinois Field 5460: 5455: 5450: 5445: 5440: 5435: 5429: 5427: 5423: 5422: 5420: 5419: 5414: 5409: 5404: 5398: 5396: 5392: 5391: 5389: 5388: 5383: 5378: 5373: 5368: 5363: 5358: 5353: 5348: 5343: 5337: 5335: 5328: 5320: 5319: 5316: 5315: 5313: 5312: 5307: 5302: 5297: 5292: 5287: 5282: 5277: 5272: 5267: 5262: 5257: 5252: 5247: 5242: 5237: 5232: 5227: 5221: 5219: 5213: 5212: 5210: 5209: 5204: 5199: 5194: 5189: 5184: 5179: 5174: 5169: 5164: 5159: 5154: 5149: 5144: 5139: 5133: 5131: 5122: 5118: 5117: 5100: 5097: 5096: 5089: 5087: 5086: 5079: 5072: 5064: 5055: 5054: 5052: 5051: 5041: 5030: 5027: 5026: 5024: 5023: 5016: 5009: 4999: 4994: 4988: 4986: 4982: 4981: 4979: 4978: 4973: 4967: 4965:Du Pont Motors 4962: 4955: 4950: 4945: 4940: 4935: 4930: 4925: 4923:Remington Arms 4920: 4918:Nemours Estate 4915: 4910: 4905: 4900: 4895: 4885: 4880: 4878:Du Pont family 4875: 4869: 4867: 4863: 4862: 4860: 4859: 4854: 4849: 4844: 4839: 4834: 4829: 4824: 4819: 4817:Joseph Shivers 4814: 4809: 4804: 4799: 4797:John J. Raskob 4794: 4789: 4784: 4779: 4774: 4769: 4764: 4759: 4754: 4749: 4744: 4739: 4734: 4729: 4724: 4722:John T. Dillon 4719: 4714: 4709: 4704: 4699: 4694: 4689: 4687:Norman Borlaug 4684: 4679: 4674: 4669: 4664: 4659: 4654: 4652:Lammot du Pont 4649: 4644: 4639: 4634: 4632:Eugene du Pont 4629: 4624: 4618: 4616: 4615:Notable people 4612: 4611: 4609: 4608: 4603: 4598: 4592: 4590: 4587:Divisions and 4584: 4583: 4581: 4580: 4574: 4572: 4570:joint ventures 4561: 4560: 4558: 4557: 4552: 4549: 4544: 4539: 4534: 4529: 4524: 4519: 4514: 4509: 4504: 4499: 4494: 4489: 4484: 4479: 4474: 4468: 4466: 4462: 4461: 4454: 4452: 4450: 4449: 4447:Rajiv L. Gupta 4444: 4439: 4433: 4431: 4423: 4422: 4417: 4415: 4414: 4407: 4400: 4392: 4383: 4382: 4380: 4379: 4366: 4363: 4362: 4360: 4359: 4354: 4349: 4347:Ramblin' Wreck 4344: 4339: 4334: 4329: 4324: 4319: 4314: 4308: 4306: 4302: 4301: 4299: 4298: 4291: 4284: 4279: 4271: 4269: 4265: 4264: 4261: 4260: 4258: 4257: 4252: 4246: 4244: 4240: 4239: 4237: 4236: 4231: 4226: 4221: 4216: 4210: 4208: 4201: 4197: 4196: 4194: 4193: 4191:Clough Commons 4188: 4183: 4178: 4177: 4176: 4166: 4159: 4152: 4147: 4142: 4137: 4132: 4127: 4125:Junior's Grill 4122: 4115: 4108: 4103: 4098: 4093: 4088: 4083: 4077: 4075: 4071: 4070: 4068: 4067: 4062: 4057: 4052: 4047: 4042: 4037: 4032: 4027: 4022: 4017: 4015:Yellow Jackets 4011: 4009: 4005: 4004: 4002: 4001: 3996: 3991: 3986: 3981: 3975: 3973: 3969: 3968: 3966: 3965: 3960: 3955: 3949: 3947: 3943: 3942: 3935: 3933: 3931: 3930: 3925: 3920: 3915: 3910: 3905: 3899: 3897: 3893: 3892: 3885: 3883: 3882: 3875: 3868: 3860: 3854: 3853: 3847: 3839: 3833: 3827: 3813: 3812:External links 3810: 3808: 3807: 3795: 3783: 3771: 3759: 3747: 3714: 3669: 3650:(6): 404–411. 3634: 3602: 3598: 3589: 3578:(3): 488–495. 3560: 3525: 3492: 3453: 3412: 3379: 3346: 3318: 3290: 3279:(1): 176–179. 3261: 3227: 3198: 3157: 3146:(2): 143–144. 3128: 3101: 3059: 3031: 3002: 2983:(3): 251–265. 2960: 2932: 2921:(1): 572–573. 2904: 2872: 2841: 2812: 2801:(1–2): 13–18. 2780: 2748: 2712: 2684: 2656: 2625: 2597: 2569: 2558:(2): 365–374. 2537: 2506: 2471: 2442: 2411: 2400:(1): 361–363. 2376: 2331: 2307: 2275: 2256: 2237: 2218: 2184: 2149: 2130: 2111: 2092: 2073: 2042: 2011: 1975: 1946: 1935:(3): 627–647. 1917: 1889: 1861: 1841: 1784: 1755: 1738: 1706: 1695:(4): 405–408. 1677: 1645: 1617: 1589: 1561: 1534: 1522: 1510: 1501:-dihalothiones 1466: 1447: 1418: 1406: 1397: 1354: 1352: 1349: 1348: 1347: 1341: 1335: 1332: 1329: 1321:Fellow of the 1319: 1314: 1311: 1305: 1302: 1279: 1276: 1275: 1274: 1268: 1261: 1259: 1252: 1245: 1243: 1236: 1229: 1227: 1221: 1214: 1212: 1202: 1198: 1191: 1189: 1182: 1175: 1173: 1166: 1159: 1157: 1149:Edge Inversion 1146: 1139: 1137: 1133:Edge Inversion 1126: 1119: 1117: 1110: 1103: 1101: 1086: 1079: 1056:phosphinidenes 1046:, and carbene• 1019: 1012: 1005: 998: 975:in the form a 881: 855:stable carbene 729:edge inversion 708: 705: 704: 703: 693: 686: 684: 673: 666: 664: 657: 650: 648: 641: 634: 632: 625: 618: 599:edge inversion 522: 519: 500:trimethylsilyl 492:Howard Simmons 483: 480: 479: 478: 471: 464: 462: 455: 448: 417: 414: 412: 409: 313: 310: 246: 243: 231:President Bush 212:Tampa, Florida 207: 204: 200:stable carbene 163: 162: 159: 158: 153: 147: 146: 121: 117: 116: 103: 99: 98: 92: 91: 80:Humboldt Prize 78:Alexander von 76: 72: 71: 68: 67:Known for 64: 63: 58: 54: 53: 47: 41: 39: 35: 34: 26: 25: 22: 15: 13: 10: 9: 6: 4: 3: 2: 7614: 7603: 7600: 7598: 7595: 7593: 7590: 7588: 7585: 7583: 7580: 7578: 7575: 7573: 7572:DuPont people 7570: 7568: 7565: 7563: 7560: 7558: 7555: 7553: 7550: 7548: 7545: 7543: 7540: 7538: 7537:Living people 7535: 7534: 7532: 7517: 7516: 7507: 7505: 7504: 7499: 7495: 7493: 7492: 7483: 7481: 7480: 7471: 7470: 7467: 7461: 7458: 7456: 7453: 7451: 7450:Chemical bond 7448: 7446: 7443: 7441: 7438: 7436: 7433: 7431: 7428: 7426: 7423: 7421: 7418: 7414: 7411: 7410: 7409: 7406: 7403: 7399: 7395: 7392: 7391: 7390: 7387: 7385: 7382: 7380: 7377: 7376: 7374: 7370: 7362: 7359: 7357: 7354: 7352: 7349: 7348: 7347: 7344: 7340: 7339:Stoichiometry 7337: 7336: 7335: 7332: 7328: 7325: 7323: 7320: 7318: 7315: 7313: 7310: 7309: 7308: 7305: 7301: 7298: 7297: 7296: 7295:Nanochemistry 7293: 7292: 7287: 7284: 7282: 7279: 7278: 7277: 7274: 7272: 7269: 7265: 7262: 7260: 7257: 7256: 7255: 7252: 7251: 7246: 7243: 7242: 7241: 7238: 7234: 7231: 7229: 7226: 7225: 7224: 7221: 7219: 7216: 7214: 7211: 7207: 7204: 7202: 7199: 7198: 7197: 7194: 7193: 7188: 7185: 7183: 7180: 7179: 7178: 7175: 7173: 7169: 7165: 7162: 7158: 7155: 7153: 7150: 7148: 7145: 7144: 7143: 7140: 7139: 7137: 7135: 7131: 7125: 7122: 7120: 7117: 7115: 7112: 7110: 7107: 7105: 7102: 7100: 7097: 7093: 7090: 7089: 7088: 7085: 7081: 7078: 7077: 7076: 7073: 7069: 7066: 7064: 7061: 7060: 7059: 7056: 7055: 7053: 7051: 7047: 7041: 7038: 7036: 7033: 7031: 7028: 7026: 7023: 7021: 7020:Semisynthesis 7017: 7014: 7012: 7009: 7007: 7004: 7002: 6999: 6997: 6994: 6992: 6989: 6985: 6982: 6981: 6980: 6977: 6976: 6974: 6972: 6968: 6962: 6959: 6957: 6954: 6952: 6949: 6945: 6942: 6941: 6940: 6937: 6935: 6932: 6930: 6927: 6926: 6924: 6922: 6918: 6912: 6909: 6907: 6904: 6902: 6899: 6897: 6894: 6892: 6889: 6887: 6884: 6882: 6879: 6877: 6874: 6870: 6867: 6866: 6865: 6862: 6860: 6857: 6855: 6854:Sonochemistry 6852: 6850: 6849:Cryochemistry 6847: 6843: 6842:Micromeritics 6840: 6839: 6838: 6835: 6833: 6830: 6828: 6825: 6823: 6820: 6816: 6813: 6811: 6808: 6807: 6806: 6803: 6802: 6800: 6798: 6794: 6786: 6783: 6782: 6781: 6778: 6776: 6773: 6771: 6768: 6766: 6763: 6759: 6756: 6755: 6754: 6751: 6749: 6746: 6745: 6743: 6741: 6737: 6731: 6728: 6726: 6723: 6721: 6720:Wet chemistry 6718: 6716: 6713: 6711: 6708: 6706: 6703: 6699: 6696: 6694: 6691: 6690: 6689: 6686: 6684: 6681: 6677: 6674: 6672: 6669: 6667: 6664: 6663: 6662: 6659: 6655: 6652: 6650: 6647: 6645: 6642: 6640: 6637: 6636: 6635: 6632: 6630: 6627: 6625: 6622: 6621: 6619: 6617: 6613: 6607: 6604: 6602: 6599: 6597: 6594: 6592: 6589: 6588: 6585: 6581: 6573: 6568: 6566: 6561: 6559: 6554: 6553: 6550: 6537: 6534: 6531: 6528: 6525: 6522: 6521: 6518: 6512: 6509: 6507: 6504: 6502: 6499: 6497: 6496:"The Machine" 6494: 6492: 6489: 6487: 6484: 6482: 6479: 6477: 6474: 6473: 6471: 6467: 6461: 6458: 6456: 6453: 6451: 6448: 6446: 6445: 6441: 6439: 6436: 6434: 6433: 6429: 6427: 6424: 6423: 6421: 6417: 6411: 6410: 6406: 6402: 6399: 6398: 6397: 6394: 6392: 6391: 6390:Lucy v. Adams 6387: 6385: 6382: 6380: 6379: 6375: 6373: 6370: 6369: 6367: 6363: 6353: 6350: 6348: 6345: 6343: 6340: 6338: 6335: 6333: 6330: 6328: 6325: 6324: 6322: 6318: 6312: 6309: 6307: 6304: 6302: 6299: 6297: 6294: 6292: 6289: 6287: 6284: 6282: 6279: 6277: 6274: 6272: 6269: 6268: 6266: 6262: 6259: 6257: 6251: 6245: 6242: 6240: 6237: 6235: 6232: 6230: 6227: 6225: 6222: 6220: 6217: 6215: 6212: 6210: 6207: 6205: 6202: 6200: 6197: 6195: 6192: 6190: 6187: 6185: 6182: 6181: 6179: 6175: 6169: 6166: 6164: 6161: 6159: 6158:Vivian Malone 6156: 6154: 6151: 6149: 6146: 6144: 6141: 6139: 6136: 6134: 6131: 6130: 6128: 6126: 6120: 6115: 6105: 6102: 6100: 6099:School of Law 6097: 6095: 6092: 6091: 6089: 6085: 6081: 6075: 6070: 6066: 6057: 6052: 6050: 6045: 6043: 6038: 6037: 6034: 6022: 6019: 6017: 6014: 6012: 6009: 6007: 6004: 6002: 5999: 5998: 5996: 5992: 5986: 5983: 5981: 5978: 5976: 5973: 5971: 5968: 5966: 5963: 5961: 5958: 5957: 5955: 5951: 5945: 5942: 5940: 5939:Research Park 5937: 5935: 5932: 5930: 5927: 5925: 5924:Allerton Park 5922: 5921: 5919: 5915: 5905: 5902: 5900: 5897: 5895: 5892: 5890: 5887: 5885: 5882: 5880: 5877: 5875: 5872: 5870: 5868: 5864: 5862: 5859: 5858: 5856: 5850: 5844: 5841: 5839: 5836: 5834: 5831: 5829: 5826: 5824: 5821: 5819: 5816: 5814: 5811: 5809: 5806: 5805: 5803: 5797: 5791: 5788: 5786: 5783: 5781: 5778: 5776: 5773: 5771: 5768: 5766: 5763: 5761: 5758: 5756: 5753: 5751: 5748: 5746: 5743: 5741: 5738: 5736: 5733: 5731: 5728: 5726: 5723: 5720: 5716: 5713: 5712: 5710: 5704: 5701: 5699: 5693: 5683: 5682: 5678: 5676: 5675: 5671: 5669: 5668: 5664: 5662: 5661: 5657: 5656: 5654: 5650: 5644: 5641: 5637: 5634: 5632: 5631: 5627: 5626: 5625: 5622: 5620: 5617: 5616: 5614: 5610: 5604: 5601: 5599: 5596: 5593: 5591: 5588: 5586: 5583: 5581: 5578: 5577: 5575: 5571: 5568: 5564: 5554: 5551: 5548: 5547:Oskee Wow-Wow 5544: 5540: 5536: 5533: 5531: 5528: 5527: 5525: 5521: 5515: 5512: 5510: 5507: 5505: 5502: 5500: 5497: 5495: 5492: 5491: 5489: 5485: 5479: 5476: 5474: 5471: 5469: 5466: 5464: 5461: 5459: 5456: 5454: 5451: 5449: 5446: 5444: 5441: 5439: 5436: 5434: 5431: 5430: 5428: 5424: 5418: 5415: 5413: 5410: 5408: 5405: 5403: 5400: 5399: 5397: 5393: 5387: 5384: 5382: 5379: 5377: 5374: 5372: 5369: 5367: 5364: 5362: 5359: 5357: 5354: 5352: 5349: 5347: 5344: 5342: 5339: 5338: 5336: 5332: 5329: 5327: 5321: 5311: 5308: 5306: 5303: 5301: 5298: 5296: 5293: 5291: 5288: 5286: 5283: 5281: 5278: 5276: 5273: 5271: 5268: 5266: 5263: 5261: 5258: 5256: 5253: 5251: 5248: 5246: 5243: 5241: 5238: 5236: 5233: 5231: 5228: 5226: 5223: 5222: 5220: 5214: 5208: 5205: 5203: 5200: 5198: 5195: 5193: 5190: 5188: 5185: 5183: 5180: 5178: 5175: 5173: 5170: 5168: 5165: 5163: 5160: 5158: 5155: 5153: 5150: 5148: 5145: 5143: 5140: 5138: 5135: 5134: 5132: 5126: 5123: 5119: 5115: 5109: 5103: 5098: 5094: 5085: 5080: 5078: 5073: 5071: 5066: 5065: 5062: 5050: 5042: 5040: 5032: 5031: 5028: 5022: 5021: 5017: 5015: 5014: 5010: 5007: 5003: 5000: 4998: 4995: 4993: 4990: 4989: 4987: 4983: 4977: 4974: 4971: 4968: 4966: 4963: 4961: 4960: 4956: 4954: 4951: 4949: 4946: 4944: 4941: 4939: 4936: 4934: 4931: 4929: 4926: 4924: 4921: 4919: 4916: 4914: 4911: 4909: 4906: 4904: 4901: 4899: 4896: 4893: 4889: 4886: 4884: 4881: 4879: 4876: 4874: 4871: 4870: 4868: 4864: 4858: 4855: 4853: 4850: 4848: 4845: 4843: 4840: 4838: 4835: 4833: 4830: 4828: 4827:Charles Stine 4825: 4823: 4820: 4818: 4815: 4813: 4810: 4808: 4805: 4803: 4800: 4798: 4795: 4793: 4790: 4788: 4785: 4783: 4780: 4778: 4775: 4773: 4770: 4768: 4765: 4763: 4760: 4758: 4755: 4753: 4750: 4748: 4745: 4743: 4740: 4738: 4735: 4733: 4730: 4728: 4725: 4723: 4720: 4718: 4715: 4713: 4710: 4708: 4705: 4703: 4700: 4698: 4695: 4693: 4690: 4688: 4685: 4683: 4682:Samuel Bodman 4680: 4678: 4675: 4673: 4670: 4668: 4665: 4663: 4660: 4658: 4655: 4653: 4650: 4648: 4647:Henry du Pont 4645: 4643: 4640: 4638: 4635: 4633: 4630: 4628: 4625: 4623: 4620: 4619: 4617: 4613: 4607: 4604: 4602: 4599: 4597: 4594: 4593: 4591: 4585: 4579: 4576: 4575: 4573: 4571: 4566: 4562: 4556: 4553: 4550: 4548: 4545: 4543: 4540: 4538: 4535: 4533: 4530: 4528: 4525: 4523: 4520: 4518: 4515: 4513: 4510: 4508: 4505: 4503: 4500: 4498: 4495: 4493: 4490: 4488: 4485: 4483: 4480: 4478: 4475: 4473: 4470: 4469: 4467: 4463: 4458: 4448: 4445: 4443: 4440: 4438: 4435: 4434: 4432: 4430: 4424: 4420: 4413: 4408: 4406: 4401: 4399: 4394: 4393: 4390: 4378: 4377: 4368: 4367: 4364: 4358: 4355: 4353: 4350: 4348: 4345: 4343: 4340: 4338: 4335: 4333: 4330: 4328: 4325: 4323: 4320: 4318: 4315: 4313: 4310: 4309: 4307: 4303: 4297: 4296: 4292: 4290: 4289: 4285: 4283: 4280: 4278: 4277: 4273: 4272: 4270: 4266: 4256: 4253: 4251: 4248: 4247: 4245: 4241: 4235: 4232: 4230: 4227: 4225: 4222: 4220: 4217: 4215: 4212: 4211: 4209: 4205: 4202: 4198: 4192: 4189: 4187: 4184: 4182: 4179: 4175: 4172: 4171: 4170: 4167: 4164: 4160: 4157: 4153: 4151: 4148: 4146: 4145:Marching Band 4143: 4141: 4138: 4136: 4133: 4131: 4128: 4126: 4123: 4121: 4120: 4116: 4114: 4113: 4109: 4107: 4104: 4102: 4099: 4097: 4094: 4092: 4089: 4087: 4084: 4082: 4079: 4078: 4076: 4072: 4066: 4063: 4061: 4058: 4056: 4053: 4051: 4048: 4046: 4043: 4041: 4038: 4036: 4033: 4031: 4028: 4026: 4023: 4021: 4018: 4016: 4013: 4012: 4010: 4006: 4000: 3997: 3995: 3992: 3990: 3987: 3985: 3982: 3980: 3977: 3976: 3974: 3970: 3964: 3961: 3959: 3956: 3954: 3951: 3950: 3948: 3944: 3939: 3929: 3926: 3924: 3921: 3919: 3916: 3914: 3911: 3909: 3906: 3904: 3901: 3900: 3898: 3894: 3890: 3881: 3876: 3874: 3869: 3867: 3862: 3861: 3858: 3851: 3848: 3846: 3844: 3840: 3837: 3834: 3831: 3828: 3825: 3820: 3816: 3815: 3811: 3804: 3799: 3796: 3792: 3787: 3784: 3780: 3775: 3772: 3768: 3763: 3760: 3756: 3751: 3748: 3743: 3739: 3735: 3731: 3730: 3725: 3718: 3715: 3710: 3706: 3702: 3698: 3694: 3690: 3686: 3682: 3681: 3673: 3670: 3665: 3661: 3657: 3653: 3649: 3645: 3638: 3635: 3630: 3626: 3622: 3618: 3614: 3610: 3609: 3593: 3590: 3585: 3581: 3577: 3574: 3573: 3564: 3561: 3556: 3552: 3548: 3544: 3540: 3536: 3529: 3526: 3521: 3517: 3513: 3509: 3508: 3503: 3496: 3493: 3488: 3484: 3480: 3476: 3472: 3468: 3464: 3457: 3454: 3449: 3445: 3441: 3437: 3433: 3429: 3428: 3423: 3416: 3413: 3408: 3404: 3400: 3396: 3395: 3390: 3383: 3380: 3375: 3371: 3367: 3363: 3362: 3357: 3350: 3347: 3342: 3338: 3334: 3331: 3330: 3322: 3319: 3314: 3310: 3306: 3303: 3302: 3294: 3291: 3286: 3282: 3278: 3274: 3273: 3265: 3262: 3257: 3253: 3249: 3245: 3244: 3236: 3234: 3232: 3228: 3223: 3219: 3215: 3211: 3210: 3202: 3199: 3194: 3190: 3186: 3182: 3178: 3174: 3173: 3168: 3161: 3158: 3153: 3149: 3145: 3141: 3140: 3132: 3129: 3124: 3120: 3116: 3112: 3105: 3102: 3097: 3093: 3089: 3085: 3081: 3077: 3070: 3063: 3060: 3055: 3051: 3047: 3044: 3043: 3035: 3032: 3027: 3023: 3019: 3015: 3014: 3006: 3003: 2998: 2994: 2990: 2986: 2982: 2978: 2971: 2969: 2967: 2965: 2961: 2956: 2952: 2948: 2945: 2944: 2936: 2933: 2928: 2924: 2920: 2917: 2916: 2908: 2905: 2900: 2896: 2892: 2889: 2888: 2883: 2876: 2873: 2868: 2864: 2860: 2857: 2856: 2848: 2846: 2842: 2837: 2833: 2829: 2825: 2824: 2816: 2813: 2808: 2804: 2800: 2796: 2795: 2787: 2785: 2781: 2776: 2772: 2768: 2764: 2763: 2755: 2753: 2749: 2744: 2740: 2736: 2732: 2728: 2725: 2724: 2716: 2713: 2708: 2704: 2700: 2697: 2696: 2688: 2685: 2680: 2676: 2672: 2669: 2668: 2660: 2657: 2652: 2648: 2644: 2641: 2640: 2632: 2630: 2626: 2621: 2617: 2613: 2610: 2609: 2601: 2598: 2593: 2589: 2585: 2582: 2581: 2573: 2570: 2565: 2561: 2557: 2553: 2552: 2544: 2542: 2538: 2533: 2529: 2525: 2522: 2521: 2513: 2511: 2507: 2502: 2498: 2494: 2491: 2490: 2485: 2478: 2476: 2472: 2467: 2463: 2459: 2455: 2454: 2446: 2443: 2438: 2434: 2430: 2427: 2426: 2418: 2416: 2412: 2407: 2403: 2399: 2396: 2395: 2390: 2383: 2381: 2377: 2372: 2366: 2350: 2349:Seed Magazine 2346: 2344: 2335: 2332: 2328: 2324: 2318: 2316: 2314: 2312: 2308: 2303: 2299: 2295: 2291: 2284: 2282: 2280: 2276: 2266: 2260: 2257: 2247: 2241: 2238: 2228: 2222: 2219: 2207: 2203: 2199: 2197: 2188: 2185: 2172: 2168: 2164: 2162: 2153: 2150: 2140: 2134: 2131: 2121: 2115: 2112: 2102: 2096: 2093: 2083: 2077: 2074: 2069: 2065: 2061: 2058: 2057: 2049: 2047: 2043: 2038: 2034: 2030: 2027: 2026: 2018: 2016: 2012: 2007: 2003: 1999: 1995: 1991: 1988: 1987: 1979: 1976: 1971: 1967: 1963: 1959: 1958: 1950: 1947: 1942: 1938: 1934: 1931: 1930: 1921: 1918: 1913: 1909: 1905: 1902: 1901: 1893: 1890: 1885: 1881: 1877: 1874: 1873: 1865: 1862: 1857: 1853: 1845: 1842: 1837: 1833: 1829: 1825: 1821: 1817: 1813: 1809: 1805: 1801: 1800: 1795: 1788: 1785: 1780: 1776: 1772: 1769: 1768: 1759: 1756: 1752: 1748: 1742: 1739: 1734: 1730: 1726: 1723: 1722: 1717: 1710: 1707: 1702: 1698: 1694: 1690: 1689: 1681: 1678: 1673: 1669: 1665: 1662: 1661: 1656: 1649: 1646: 1641: 1637: 1633: 1630: 1629: 1621: 1618: 1613: 1609: 1605: 1602: 1601: 1593: 1590: 1585: 1581: 1577: 1574: 1573: 1565: 1562: 1554: 1547: 1545: 1543: 1541: 1539: 1535: 1531: 1526: 1523: 1519: 1514: 1511: 1507: 1503: 1502: 1498: 1493: 1492: 1488: 1487: 1482: 1481: 1473: 1471: 1467: 1463: 1459: 1456: 1451: 1448: 1444: 1439: 1437: 1435: 1433: 1431: 1429: 1427: 1425: 1423: 1419: 1415: 1410: 1407: 1401: 1398: 1393: 1389: 1385: 1381: 1377: 1373: 1372: 1364: 1362: 1360: 1356: 1350: 1345: 1342: 1339: 1336: 1333: 1330: 1328: 1324: 1320: 1317: 1316: 1312: 1310: 1303: 1301: 1299: 1298:Xylochemistry 1295: 1291: 1286: 1277: 1271: 1265: 1260: 1256: 1249: 1244: 1240: 1233: 1228: 1225: 1218: 1213: 1209: 1205: 1195: 1190: 1186: 1179: 1174: 1170: 1163: 1158: 1154: 1150: 1143: 1138: 1134: 1130: 1123: 1118: 1114: 1107: 1102: 1098: 1094: 1090: 1083: 1078: 1076: 1073: 1069: 1063: 1061: 1057: 1053: 1049: 1045: 1041: 1038: 1034: 1030: 1026: 1022: 1015: 1008: 1001: 994: 990: 986: 982: 978: 974: 970: 967: 964: 961: 958: 955: 952: 949: 946: 943: 940: 937: 934: 930: 927: 924: 921: 918: 914: 910: 905: 903: 899: 895: 891: 887: 884: 877: 872: 868: 864: 860: 856: 852: 847: 843: 839: 835: 830: 828: 827:intermediates 824: 820: 817: 816:electrophilic 813: 809: 805: 801: 797: 793: 789: 785: 781: 777: 776:cross-linking 773: 769: 765: 761: 757: 753: 749: 744: 742: 738: 734: 730: 726: 722: 718: 714: 706: 700: 696: 690: 685: 681: 677: 670: 665: 661: 654: 649: 645: 638: 633: 629: 622: 617: 615: 612: 608: 604: 600: 596: 592: 588: 584: 580: 576: 572: 567: 563: 559: 555: 551: 547: 546:nitrile ylide 543: 540: 536: 532: 528: 520: 518: 516: 512: 508: 504: 501: 497: 493: 489: 481: 475: 468: 463: 459: 452: 447: 445: 442: 439: 435: 431: 427: 423: 415: 410: 408: 406: 402: 398: 394: 390: 386: 382: 378: 374: 370: 366: 362: 358: 354: 349: 347: 343: 339: 335: 331: 327: 323: 319: 311: 309: 307: 303: 299: 294: 292: 288: 284: 280: 276: 272: 269:, advised by 268: 264: 260: 256: 252: 244: 242: 240: 236: 232: 227: 226: 221: 217: 213: 205: 203: 201: 197: 193: 192:Xylochemistry 189: 185: 181: 177: 173: 169: 160: 157: 154: 152: 148: 145: 140: 135: 130: 125: 122: 118: 115: 111: 107: 104: 100: 97: 93: 87: 81: 77: 73: 69: 65: 62: 59: 55: 50: 40: 36: 32: 27: 20: 7513: 7501: 7489: 7477: 7327:Biosynthesis 7177:Geochemistry 7092:Pharmacology 7068:Cell biology 7058:Biochemistry 6886:Spectroscopy 6785:VSEPR theory 6634:Spectroscopy 6578:Branches of 6535: 6529: 6523: 6486:Crimsonettes 6442: 6430: 6407: 6388: 6376: 6244:Strode House 6073: 5899:Morrow Plots 5866: 5760:Main Library 5755:Lincoln Hall 5750:Illini Union 5715:Altgeld Hall 5679: 5674:Ninth Letter 5672: 5665: 5658: 5628: 5624:Illini Media 5585:Dial-A-Carol 5566:Student life 5553:Orange Krush 5504:Northwestern 5371:Men's tennis 5147:Architecture 5101: 5018: 5011: 4957: 4747:Steven Ittel 4727:Linda Fisher 4707:Uma Chowdhry 4565:Subsidiaries 4369: 4293: 4286: 4274: 4117: 4110: 4081:Antico Pizza 4074:Student life 3923:Liberal Arts 3842: 3798: 3786: 3774: 3762: 3750: 3733: 3727: 3717: 3684: 3678: 3672: 3647: 3643: 3637: 3612: 3606: 3592: 3575: 3570: 3563: 3538: 3534: 3528: 3511: 3505: 3495: 3470: 3466: 3456: 3431: 3425: 3415: 3398: 3392: 3382: 3365: 3359: 3349: 3332: 3327: 3321: 3304: 3299: 3293: 3276: 3270: 3264: 3247: 3241: 3213: 3207: 3201: 3176: 3170: 3160: 3143: 3137: 3131: 3114: 3110: 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Index

A picture of A. J. Arduengo from June '09 working on his 2008 Saffron Yellow Lotus (California Edition) Elise. The rear of the Elise is pictured in the background and the car is raised on a hydraulic lift. Arduengo is standing in front of the car inside the lift structure. He has a wrench in his right hand and is resting against a lift cross-member. He is wearing a black and tan Hawaiian Shirt and smiling.
Tampa
Georgia Institute of Technology
Humboldt Prize
American Association for the Advancement of Science
Inorganic chemistry
Organic chemistry
Valency
Georgia Institute of Technology
University of Alabama
Technische Universität - Braunschweig
DuPont Central Research
University of Illinois
Doctoral advisor
E.M. Burgess
Georgia Institute of Technology
Chemistry
University of Alabama
Braunschweig University of Technology
Xylochemistry
valency
stable carbene
Tampa, Florida
Atlanta
Georgia
Atlanta Journal-Constitution
President Bush
United States Department of Energy
Hydrogen Storage
Walker High School

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