610:
265:
146:
444:
449:
454:
605:
883:
33:
24:
676:
987:
Barium chlorate, when burned with a fuel, produces a vibrant green light. Because it is an oxidizer, a chlorine donor, and contains a metal, this compound produces a green color that is unparalleled. However, due to the instability of all chlorates to sulfur, acids, and ammonium ions, chlorates have
996:
Barium chlorate is toxic to humans and can also harm the environment. It is very harmful to aquatic organisms if it is leached into bodies of water. Chemical spills of this compound, although not common, can harm entire ecosystems and should be prevented. It is necessary to dispose of this compound
608:
633:
800:
The above method does result in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis:
978:
Both the chlorate and the acid should be prepared as dilute solutions before mixing, such that the chloric acid produced is dilute, as concentrated solutions of chloric acid (above 30%) are unstable and prone to decompose, sometimes explosively.
462:
424:
611:
796:
On concentrating and chilling the resulting mixture, barium chlorate precipitates. This is perhaps the most common preparation, exploiting the lower solubility of barium chlorate compared to sodium chlorate.
988:
been banned from use in class C fireworks in the United States. Therefore, more and more firework producers have begun to use more stable compound such as barium nitrate and barium carbonate.
609:
689:
576:
560:
314:
879:; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution.
1119:
1017:
556:
103:
508:
1624:
279:
548:
2324:
2319:
1112:
552:
1048:
540:
696:
2309:
502:
212:
453:
1560:
761:
243:
619:
448:
1576:
2329:
2304:
1586:
1105:
153:
443:
1540:
1263:
1617:
564:
407:
2180:
1914:
141:
2042:
1791:
1195:
1021:
1827:
2163:
1803:
1728:
512:
476:
436:
45:
2057:
1892:
2034:
1987:
1955:
1863:
516:
2218:
1602:
1515:
1437:
740:
260:
1839:
1815:
1368:
1215:
528:
69:
997:
as hazardous waste. The
Environmental Protection Agency (EPA) lists barium chlorate as hazardous.
2314:
1900:
1757:
1716:
1610:
1467:
1268:
876:
520:
544:
532:
494:
1685:
1139:
829:
652:
1765:
1668:
1527:
1491:
1429:
1360:
1231:
1128:
1043:
572:
482:
395:
337:
221:
123:
79:
2086:
1947:
1708:
1507:
1499:
1459:
1454:
1421:
1304:
1296:
1288:
896:
769:
765:
1067:
1081:
264:
145:
1483:
1475:
1449:
1404:
1392:
1332:
1320:
1312:
1280:
1239:
1223:
1179:
1167:
1159:
944:
667:
658:
882:
2298:
1851:
1348:
1340:
1147:
940:
384:
134:
584:
32:
1649:
1416:
1380:
932:
744:
736:
724:
524:
185:
886:
The green seen in this firework is produced by barium chlorate and barium nitrate
536:
640:
732:
356:
114:
23:
232:
1634:
936:
828:
It can also be produced by the reaction of barium carbonate with boiling
639:
632:
625:
618:
591:
728:
374:
172:
154:
1535:
900:
720:
666:
Except where otherwise noted, data are given for materials in their
486:
1097:
490:
196:
102:
92:
626:
580:
1606:
1101:
895:
When exposed to heat, barium chlorate alone will decompose to
943:, which results in a solution of chloric acid and insoluble
568:
248:
603:
389:
413.9 °C (777.0 °F; 687.0 K) (decomposes)
684:
288:
InChI=1S/Ba.2ClHO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2
1091:. New Jersey Department of Health and Human Services.
298:
InChI=1/Ba.2ClHO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2
875:
The reaction initially produces barium chlorate and
184:
607:
78:
1618:
1113:
8:
1625:
1611:
1603:
1120:
1106:
1098:
760:Barium chlorate can be produced through a
263:
144:
122:
15:
743:. It also finds use in the production of
731:, and like all soluble barium compounds,
220:
2225:
2221:
2187:
2183:
2170:
2166:
2093:
2089:
1589:
1579:
939:salts, through its reaction with dilute
881:
1005:
319:
284:
259:
1658:
1633:Salts and covalent derivatives of the
135:
2152:
1011:
1009:
291:Key: ISFLYIRWQDJPDR-UHFFFAOYSA-L
7:
1645:
931:Barium chlorate is used to produce
735:and toxic. It is sometimes used in
301:Key: ISFLYIRWQDJPDR-NUQVWONBAT
175:
1042:Wilson, Elizabeth (July 2, 2001).
14:
674:
452:
447:
442:
31:
22:
1049:Chemical & Engineering News
670:(at 25 °C , 100 kPa).
1089:Hazardous Substance Fact Sheet
1044:"What's That Stuff? Fireworks"
935:, the formal precursor to all
1:
1020:. GeoCities. Archived from
762:double replacement reaction
2346:
2154:
361:304.23 g/mol
1660:
1642:
1135:
664:
423:
418:
330:
310:
275:
62:
57:Chloric acid, barium salt
54:
44:
39:
30:
21:
503:Precautionary statements
408:Magnetic susceptibility
887:
614:
401:27.5 g/100 ml (20 °C)
2325:Pyrotechnic colorants
2320:Pyrotechnic oxidizers
885:
764:between solutions of
613:
992:Environmental Hazard
659:Barium Chlorate MSDS
596:(fire diamond)
2310:Inorganic compounds
396:Solubility in water
18:
888:
877:ammonium carbonate
697:Infobox references
615:
322:.Cl(=O)=O.Cl(=O)=O
16:
2292:
2291:
2286:
2285:
1600:
1599:
1082:"Barium Chlorate"
1068:"Barium Chlorate"
1018:"Barium Chlorate"
830:ammonium chlorate
729:crystalline solid
705:Chemical compound
703:
702:
653:Safety data sheet
477:Hazard statements
379:3.18 g/cm, solid
244:CompTox Dashboard
104:Interactive image
49:Barium dichlorate
2337:
2330:Oxidizing agents
2305:Barium compounds
2228:
2190:
2173:
2096:
1646:
1627:
1620:
1613:
1604:
1592:
1582:
1129:Barium compounds
1122:
1115:
1108:
1099:
1093:
1092:
1086:
1078:
1072:
1071:
1064:
1058:
1057:
1039:
1033:
1032:
1030:
1029:
1013:
727:. It is a white
687:
681:
678:
677:
642:
635:
628:
621:
606:
586:
582:
578:
574:
570:
566:
562:
558:
554:
550:
546:
542:
538:
534:
530:
526:
522:
518:
514:
510:
496:
492:
488:
484:
456:
451:
446:
414:-87.5·10 cm/mol
338:Chemical formula
268:
267:
252:
250:
224:
188:
177:
156:
148:
137:
126:
106:
82:
35:
26:
19:
17:Barium chlorate
2345:
2344:
2340:
2339:
2338:
2336:
2335:
2334:
2295:
2294:
2293:
2288:
2287:
2227:
2223:
2219:
2189:
2185:
2181:
2172:
2168:
2164:
2095:
2091:
2087:
2065:
2061:
2050:
2046:
2038:
2003:
1999:
1991:
1963:
1959:
1951:
1922:
1918:
1908:
1904:
1896:
1871:
1867:
1859:
1855:
1847:
1843:
1835:
1831:
1823:
1819:
1811:
1807:
1799:
1795:
1773:
1769:
1761:
1736:
1732:
1724:
1720:
1712:
1693:
1689:
1672:
1653:
1638:
1631:
1601:
1596:
1591:
1587:
1581:
1577:
1572:
1568:
1564:
1556:
1552:
1548:
1544:
1531:
1523:
1519:
1511:
1503:
1495:
1487:
1479:
1471:
1463:
1445:
1441:
1433:
1425:
1412:
1408:
1400:
1396:
1388:
1384:
1376:
1372:
1364:
1356:
1352:
1344:
1336:
1328:
1324:
1316:
1308:
1300:
1292:
1284:
1276:
1272:
1259:
1255:
1247:
1243:
1235:
1227:
1219:
1211:
1207:
1203:
1199:
1191:
1187:
1183:
1175:
1171:
1163:
1155:
1151:
1143:
1131:
1126:
1096:
1084:
1080:
1079:
1075:
1066:
1065:
1061:
1041:
1040:
1036:
1027:
1025:
1016:Perigrin, Tom.
1015:
1014:
1007:
1003:
994:
985:
983:Commercial uses
974:
970:
966:
962:
958:
954:
929:
922:
918:
914:
910:
897:barium chloride
893:
871:
867:
863:
859:
855:
847:
843:
839:
824:
820:
816:
812:
808:
791:
787:
783:
779:
770:sodium chlorate
766:barium chloride
758:
753:
718:
714:
709:Barium chlorate
706:
699:
694:
693:
692: ?)
683:
679:
675:
671:
647:
646:
645:
644:
637:
630:
623:
616:
612:
604:
505:
479:
465:
439:
411:
398:
350:
346:
340:
326:
323:
318:
317:
306:
303:
302:
299:
293:
292:
289:
283:
282:
271:
253:
246:
227:
207:
191:
178:
166:
129:
109:
96:
85:
72:
58:
50:
12:
11:
5:
2343:
2341:
2333:
2332:
2327:
2322:
2317:
2312:
2307:
2297:
2296:
2290:
2289:
2284:
2283:
2280:
2277:
2274:
2271:
2268:
2265:
2262:
2259:
2256:
2253:
2250:
2247:
2244:
2241:
2237:
2236:
2233:
2230:
2216:
2213:
2210:
2207:
2204:
2201:
2198:
2195:
2192:
2178:
2175:
2161:
2157:
2156:
2153:
2150:
2149:
2146:
2143:
2140:
2137:
2134:
2131:
2128:
2125:
2122:
2119:
2116:
2113:
2110:
2107:
2104:
2101:
2098:
2084:
2080:
2079:
2076:
2073:
2070:
2067:
2063:
2059:
2055:
2052:
2048:
2044:
2040:
2036:
2032:
2029:
2026:
2023:
2020:
2017:
2014:
2011:
2008:
2005:
2001:
1997:
1993:
1989:
1984:
1983:
1980:
1977:
1974:
1971:
1968:
1965:
1961:
1957:
1953:
1949:
1945:
1942:
1939:
1936:
1933:
1930:
1927:
1924:
1920:
1916:
1912:
1910:
1906:
1902:
1898:
1894:
1889:
1888:
1885:
1882:
1879:
1876:
1873:
1869:
1865:
1861:
1857:
1853:
1849:
1845:
1841:
1837:
1833:
1829:
1825:
1821:
1817:
1813:
1809:
1805:
1801:
1797:
1793:
1789:
1786:
1783:
1780:
1777:
1775:
1771:
1767:
1763:
1759:
1754:
1753:
1750:
1747:
1744:
1741:
1738:
1734:
1730:
1726:
1722:
1718:
1714:
1710:
1705:
1704:
1701:
1698:
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1691:
1687:
1683:
1680:
1677:
1674:
1670:
1665:
1664:
1661:
1659:
1657:
1655:
1651:
1644:
1643:
1640:
1639:
1632:
1630:
1629:
1622:
1615:
1607:
1598:
1597:
1595:
1594:
1584:
1574:
1570:
1566:
1562:
1558:
1554:
1550:
1546:
1542:
1538:
1533:
1529:
1525:
1521:
1517:
1513:
1509:
1505:
1501:
1497:
1493:
1489:
1485:
1481:
1477:
1473:
1469:
1465:
1461:
1457:
1452:
1447:
1443:
1439:
1435:
1431:
1427:
1423:
1419:
1414:
1410:
1406:
1402:
1398:
1394:
1390:
1386:
1382:
1378:
1374:
1370:
1366:
1362:
1358:
1354:
1350:
1346:
1342:
1338:
1334:
1330:
1326:
1322:
1318:
1314:
1310:
1306:
1302:
1298:
1294:
1290:
1286:
1282:
1278:
1274:
1270:
1266:
1261:
1257:
1253:
1249:
1245:
1241:
1237:
1233:
1229:
1225:
1221:
1217:
1213:
1209:
1205:
1201:
1197:
1193:
1189:
1185:
1181:
1177:
1173:
1169:
1165:
1161:
1157:
1153:
1149:
1145:
1141:
1136:
1133:
1132:
1127:
1125:
1124:
1117:
1110:
1102:
1095:
1094:
1073:
1059:
1034:
1004:
1002:
999:
993:
990:
984:
981:
976:
975:
972:
968:
964:
960:
956:
952:
945:barium sulfate
928:
925:
924:
923:
920:
916:
912:
908:
892:
889:
873:
872:
869:
865:
861:
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672:
668:standard state
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656:
649:
648:
638:
631:
624:
617:
602:
601:
600:
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597:
588:
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577:P371+P380+P375
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328:
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297:
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286:
278:
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272:
270:
269:
261:DTXSID60890702
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150:
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139:
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119:
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68:
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56:
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51:
48:
42:
41:
37:
36:
28:
27:
13:
10:
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6:
4:
3:
2:
2342:
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2300:
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2242:
2239:
2238:
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2231:
2229:
2217:
2214:
2211:
2208:
2205:
2202:
2199:
2196:
2193:
2191:
2179:
2176:
2174:
2162:
2159:
2158:
2151:
2147:
2144:
2141:
2138:
2135:
2132:
2129:
2126:
2123:
2120:
2117:
2114:
2111:
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2099:
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2085:
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1070:. inchem.org.
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1024:on 2007-10-30
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947:precipitate:
946:
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941:sulfuric acid
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891:Decomposition
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385:Melting point
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136:ECHA InfoCard
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1026:. Retrieved
1022:the original
995:
986:
977:
933:chloric acid
930:
927:Chloric acid
894:
874:
849:
827:
799:
795:
759:
745:chloric acid
737:pyrotechnics
725:chloric acid
708:
707:
592:
468:
425:
369:white solid
197:RTECS number
63:Identifiers
55:Other names
813:O → Ba(ClO
741:green color
463:Signal word
366:Appearance
331:Properties
142:100.033.404
2299:Categories
1028:2007-02-22
1001:References
832:solution:
437:Pictograms
357:Molar mass
222:GRW9DUG818
115:ChemSpider
91:3D model (
80:13477-00-4
70:CAS Number
46:IUPAC name
2315:Chlorates
1056:(27): 30.
780:+ 2 NaClO
756:Synthesis
751:Reactions
719:, is the
573:P370+P378
561:P306+P360
557:P304+P340
553:P304+P312
549:P301+P312
428:labelling
233:UN number
204:FN9770000
163:236-760-7
155:EC Number
1635:chlorate
967:→ 2 HClO
937:chlorate
852:→ Ba(ClO
792:+ 2 NaCl
784:→ Ba(ClO
733:irritant
723:salt of
711:, Ba(ClO
593:NFPA 704
419:Hazards
410:(χ)
2155:
1468:Ba(SCN)
1216:Ba(ClO)
690:what is
688: (
375:Density
351:
173:PubChem
2220:Er(ClO
2182:Pr(ClO
2165:La(ClO
2088:Ra(ClO
2058:Pb(ClO
2043:Hg(ClO
1996:Ba(ClO
1956:Cd(ClO
1901:Sr(ClO
1864:Ga(ClO
1852:Zn(ClO
1840:Cu(ClO
1828:Ni(ClO
1816:Co(ClO
1804:Fe(ClO
1792:Mn(ClO
1766:Ca(ClO
1729:Al(ClO
1717:Mg(ClO
1536:BaZnGa
1430:Ba(OH)
1369:Ba(MnO
1281:Ba(CN)
1269:Ba(ClO
1252:Ba(ClO
1168:Ba(BrO
971:+ BaSO
951:Ba(ClO
915:→ BaCl
907:Ba(ClO
901:oxygen
868:O + CO
860:+ 2 NH
844:+ BaCO
721:barium
685:verify
682:
655:(SDS)
469:Danger
343:Ba(ClO
315:SMILES
40:Names
2035:AuClO
1988:CsClO
1948:AgClO
1915:Y(ClO
1893:RbClO
1709:NaClO
1669:LiClO
1588:BaSiF
1578:BaGeF
1508:BaTiO
1500:BaSnO
1492:BaRuO
1460:BaSeO
1438:Ba(PO
1405:Ba(NO
1393:Ba(NO
1361:BaMnO
1349:Ba(IO
1313:BaFeO
1297:BaCrO
1264:BaClF
1180:Ba(CH
1148:Ba(BO
1085:(PDF)
919:+ 3 O
821:+ 6 H
809:+ 6 H
280:InChI
237:1445
186:26059
124:24273
93:JSmol
1758:KClO
1650:HClO
1528:BaWO
1484:BaSO
1476:BaSO
1455:BaSe
1381:Ba(N
1321:BaFe
1289:BaCl
1232:BaCO
1196:Ba(C
1160:BaBr
899:and
836:2 NH
805:BaCl
776:BaCl
768:and
585:P501
581:P391
569:P330
565:P312
545:P283
541:P280
537:P273
533:P271
529:P270
525:P264
521:P261
517:P221
513:P220
509:P210
495:H411
491:H332
487:H302
483:H271
213:UNII
2282:No
2279:Md
2276:Fm
2273:Es
2270:Cf
2267:Bk
2264:Cm
2261:Am
2258:Pu
2255:Np
2249:Pa
2246:Th
2243:Ac
2240:**
2235:Yb
2232:Tm
2215:Ho
2212:Dy
2209:Tb
2206:Gd
2203:Eu
2200:Sm
2197:Pm
2194:Nd
2177:Ce
2148:Og
2145:Ts
2142:Lv
2139:Mc
2136:Fl
2133:Nh
2130:Cn
2127:Rg
2124:Ds
2121:Mt
2118:Hs
2115:Bh
2112:Sg
2109:Db
2106:Rf
2103:Lr
2100:**
2083:Fr
2078:Rn
2075:At
2072:Po
2069:Bi
2054:Tl
2031:Pt
2028:Ir
2025:Os
2022:Re
2016:Ta
2013:Hf
2010:Lu
1982:Xe
1976:Te
1973:Sb
1970:Sn
1967:In
1944:Pd
1941:Rh
1938:Ru
1935:Tc
1932:Mo
1929:Nb
1926:Zr
1887:Kr
1884:Br
1881:Se
1878:As
1875:Ge
1788:Cr
1782:Ti
1779:Sc
1752:Ar
1749:Cl
1740:Si
1703:Ne
1690:ClO
1676:Be
1663:He
1637:ion
1571:7-x
1561:YBa
1547:1-x
1520:TiO
1450:BaS
1422:BaO
1417:BaO
1341:BaI
1333:BaH
1305:BaF
1240:BaC
1224:BaC
1140:BaB
959:+ H
864:+ H
840:ClO
426:GHS
249:EPA
176:CID
2301::
2252:U
2160:*
2019:W
2007:*
1979:I
1785:V
1746:S
1743:P
1700:F
1697:O
1686:NH
1682:C
1679:B
1565:Cu
1549:Nb
1545:Ba
1541:Sr
1516:Ba
1184:CO
1087:.
1054:79
1052:.
1046:.
1008:^
963:SO
903::
848:+
772::
747:.
641:OX
583:,
579:,
575:,
571:,
567:,
563:,
559:,
555:,
551:,
547:,
543:,
539:,
535:,
531:,
527:,
523:,
519:,
515:,
511:,
493:,
489:,
485:,
430::
2226:2
2224:)
2222:3
2188:2
2186:)
2184:3
2171:2
2169:)
2167:3
2094:2
2092:)
2090:3
2064:2
2062:)
2060:3
2049:2
2047:)
2045:3
2037:3
2002:2
2000:)
1998:3
1990:3
1962:2
1960:)
1958:3
1950:3
1921:3
1919:)
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1907:2
1905:)
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1895:3
1870:3
1868:)
1866:3
1858:2
1856:)
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1834:2
1832:)
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1822:2
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1770:)
1768:3
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1733:)
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1723:2
1721:)
1719:3
1711:3
1692:3
1688:4
1671:3
1652:3
1626:e
1619:t
1612:v
1590:6
1580:6
1569:O
1567:3
1563:2
1555:6
1553:O
1551:2
1543:2
1530:4
1522:4
1518:2
1510:3
1502:3
1494:3
1486:4
1478:3
1470:2
1462:4
1444:2
1442:)
1440:3
1432:2
1424:2
1411:2
1409:)
1407:3
1399:2
1397:)
1395:2
1387:2
1385:)
1383:3
1375:2
1373:)
1371:4
1363:4
1355:2
1353:)
1351:3
1343:2
1335:2
1327:4
1325:O
1323:2
1315:4
1307:2
1299:4
1291:2
1283:2
1275:2
1273:)
1271:4
1258:2
1256:)
1254:3
1246:4
1244:O
1242:2
1234:3
1226:2
1218:2
1210:2
1208:)
1206:2
1204:O
1202:7
1200:H
1198:5
1190:2
1188:)
1186:2
1182:3
1174:2
1172:)
1170:3
1162:2
1154:2
1152:)
1150:2
1142:6
1121:e
1114:t
1107:v
1031:.
973:4
969:3
965:4
961:2
957:2
955:)
953:3
921:2
917:2
913:2
911:)
909:3
870:2
866:2
862:3
858:2
856:)
854:3
850:Q
846:3
842:3
838:4
823:2
819:2
817:)
815:3
811:2
807:2
790:2
788:)
786:3
782:3
778:2
717:2
715:)
713:3
680:Y
634:3
627:0
620:3
349:2
347:)
345:3
251:)
247:(
95:)
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