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since the days of ancient Egypt. It is part of the "pearly pigment found in eye shadow, hair sprays, powders, nail polishes, and other cosmetic products". Owing to the plate-like structure of the BiOCl, its suspensions exhibit optical properties like
469:
441:
535:
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ions (in the image Bi = grey, O = red, Cl = green). These ions are ordered as Cl–Bi–O–Bi–Cl–Cl–Bi–O–Bi–Cl, i.e., with alternating anions (
832:
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523:
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505:
188:
209:
933:
Eggenweiler, U.; Keller, E.; Krämer, V. (2000). "Redetermination of the crystal structures of the 'Arppe compound' Bi
559:
717:
from Bi, and four O atoms forming the other square face, each at a distance of 2.32 Å from Bi. The O atoms are
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713:. The Bi atom is coordinated to four Cl atoms, forming one of the square faces, each at a distance of 3.06
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Focusing on the coordination environment of the individual ions, the bismuth centers adopt a distorted
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827:. Vol. III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America.
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61:
818:
Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Bismoclite".
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1098:
798:
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511:
95:
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Keramidas, K. G.; Voutsas, G. P.; Rentzeperis, P. I. (1993). "The crystal structure of BiOCl".
653:. Previously, until the last decade of the twentieth century, bismuth oxochloride was known as
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703:). The layered structure gives rise to the pearlescent properties of this material.
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645:. Light wave interference from its plate-like structure gives a pearly
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1024:
Carrasco, F. 2009. Diccionario de
Ingredientes Cosmeticos(Paperback)
575:
Except where otherwise noted, data are given for materials in their
766:, called the "Arppe compound" which has a complex layer structure.
780:
650:
94:
84:
641:. It is a lustrous white solid used since antiquity, notably in
563:
1045:
214:
675:
The structure of bismuth oxychloride can be thought of as
593:
1445:
1394:
1366:
1079:
751:When heated above 600 °C, BiOCl converts to
176:
70:
1005:Ullmann's Encyclopedia of Industrial Chemistry
264:InChI=1/Bi.ClH.O/h;1H;/q+1;;/p-1/rBiClO/c2-1-3
1057:
8:
786:BiOCl exists in nature as the rare mineral
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810:
729:BiOCl is formed during the reaction of
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783:. In cosmetic its name is C.I. 77163.
330:Lustrous white crystals with a pearly
127:
853:
851:
257:Key: GLQBXSIPUULYOG-UHFFFAOYSA-M
7:
267:Key: GLQBXSIPUULYOG-JKOFJLRAAJ
167:
14:
733:with water, i.e. the hydrolysis:
254:InChI=1S/Bi.ClH.O/h;1H;/q+1;;/p-1
959:Acta Crystallographica Section B
860:Zeitschrift für Kristallographie
583:
459:
22:
880:10.1524/zkri.1993.205.Part-1.35
579:(at 25 °C , 100 kPa).
801:, is used as a white pigment.
649:light reflectivity similar to
1:
1013:10.1002/14356007.a20_243.pub2
426: = 0.3887 nm,
1007:, 2006 Wiley-VCH, Weinheim.
430: = 0.7354 nm
350:7.78 g/cm (calculated)
47:bismuth(III) oxide chloride
1522:
1003:"Pigments, Inorganic" in
971:10.1107/S0108768100000550
906:Chemistry of the Elements
904:; Earnshaw, Alan (1997).
719:tetrahedrally coordinated
573:
440:
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379:
347:7.36 g/cm (measured)
296:
276:
241:
54:
35:
30:
21:
1034:Bismoclite on Mindat.org
506:Precautionary statements
797:An analogous compound,
790:, which is part of the
725:Synthesis and reactions
945:and the isomorphous Bi
821:Handbook of Mineralogy
660:. It is also known as
45:bismuth oxide chloride
910:Butterworth-Heinemann
902:Greenwood, Norman N.
711:coordination geometry
774:It has been used in
708:square antiprismatic
677:consisting of layers
17:Bismuth oxychloride
872:1993ZK....205...35K
618:Bismuth oxychloride
360:Solubility in water
334:light reflectivity
322: g·mol
43:bismuth oxochloride
18:
1367:Organobismuth(III)
799:bismuth oxynitrate
770:Use and occurrence
721:by four Bi atoms.
622:inorganic compound
606:Infobox references
16:
1501:Bismuth compounds
1488:
1487:
1484:
1483:
1390:
1389:
1073:Bismuth compounds
919:978-0-08-037941-8
866:(Part 1): 35–40.
746:O → BiOCl + 2 HCl
614:Chemical compound
612:
611:
484:Hazard statements
387:Crystal structure
375:soluble in acids
210:CompTox Dashboard
96:Interactive image
1513:
1446:Organobismuth(V)
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908:(2nd ed.).
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731:bismuth chloride
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417:Lattice constant
410:P4/nmm, No. 129
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304:Chemical formula
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912:. p. 572.
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794:mineral group.
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999:Völz, Hans G.
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577:standard state
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536:P305+P351+P338
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1337:subsalicylate
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834:0-9622097-2-4
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643:ancient Egypt
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227:DTXSID2020181
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128:ECHA InfoCard
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1506:Oxychlorides
1130:
1080:Bismuth(III)
1029:
1020:
1004:
1000:
995:
962:
958:
928:
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838:. Retrieved
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728:
705:
674:
664:
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617:
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442:
427:
423:
309:BiOCl
55:Identifiers
36:Other names
840:December 5,
665:pearl white
470:Signal word
405:Space group
365:negligible
327:Appearance
297:Properties
134:100.029.202
1495:Categories
1395:Bismuth(V)
1342:subcitrate
805:References
792:matlockite
788:bismoclite
647:iridescent
454:Pictograms
393:Tetragonal
380:Structure
371:Solubility
332:iridescent
315:Molar mass
198:4ZR792I587
107:ChemSpider
83:3D model (
62:CAS Number
49:bismoclite
979:0108-7681
888:0044-2968
776:cosmetics
671:Structure
656:bismuthyl
628:with the
560:P403+P233
552:P337+P313
548:P332+P313
532:P304+P340
528:P302+P352
445:labelling
155:232-122-7
147:EC Number
72:7787-59-9
39:bismuthyl
987:10877351
658:chloride
436:Hazards
116:10606415
41:chloride
868:Bibcode
662:pigment
630:formula
626:bismuth
599:what is
597: (
476:Warning
340:Density
178:6328152
165:PubChem
1410:Pb(BiO
1301:Bi(OH)
1001:et al.
985:
977:
916:
886:
831:
620:is an
594:verify
591:
320:260.43
281:SMILES
31:Names
1453:Bi(CH
1402:NaBiO
1329:BiFeO
1267:Bi(IO
1239:Bi(NO
1141:BiONO
1131:BiOCl
1087:Bi(CH
825:(PDF)
781:nacre
651:nacre
246:InChI
85:JSmol
1465:Bi(C
1296:BiMn
1259:BiVO
1251:BiPO
1149:BiAs
1136:BiOI
1107:BiCl
1099:BiBr
1091:COO)
983:PMID
975:ISSN
914:ISBN
884:ISSN
842:2011
829:ISBN
738:BiCl
687:and
568:P501
564:P405
556:P362
544:P321
540:P312
524:P280
520:P271
516:P264
512:P261
498:H335
494:H319
490:H315
288:Cl=O
189:UNII
1422:BiF
1382:BiH
1355:BiO
1321:BiH
1291:BiP
1227:(SO
1215:BiI
1207:BiF
1186:(CO
1170:SiO
1009:doi
967:doi
957:".
876:doi
864:205
742:+ H
679:of
624:of
443:GHS
397:tP6
215:EPA
168:CID
1497::
1430:Bi
1309:Bi
1279:Bi
1223:Bi
1199:Te
1195:Bi
1178:Bi
1172:20
1168:12
1166:Bi
1158:Se
1154:Bi
1125:12
1119:Ge
1115:Bi
981:.
973:.
963:56
961:.
955:10
953:Br
951:31
947:24
943:10
941:Cl
939:31
935:24
882:.
874:.
862:.
850:^
763:10
761:Cl
759:31
755:24
753:Bi
701:Bi
695:,
693:Cl
685:Bi
683:,
681:Cl
667:.
639:Cl
633:Bi
566:,
562:,
558:,
554:,
550:,
546:,
542:,
538:,
534:,
530:,
526:,
522:,
518:,
514:,
496:,
492:,
447::
395:,
1475:5
1473:)
1471:5
1469:H
1467:6
1459:5
1457:)
1455:3
1436:5
1434:O
1432:2
1424:5
1416:2
1414:)
1412:3
1404:3
1380:4
1378:H
1376:4
1374:C
1357:6
1353:5
1351:H
1349:7
1347:C
1331:3
1323:3
1315:3
1313:S
1311:2
1303:3
1285:3
1283:O
1281:2
1273:3
1271:)
1269:3
1261:4
1253:4
1245:3
1243:)
1241:3
1233:3
1231:)
1229:4
1225:2
1217:3
1209:3
1201:3
1197:2
1190:)
1188:3
1184:2
1182:O
1180:2
1160:3
1156:2
1143:3
1123:O
1121:3
1117:4
1109:3
1101:3
1093:3
1089:3
1065:e
1058:t
1051:v
1015:.
1011::
989:.
969::
949:O
937:O
922:.
890:.
878::
870::
844:.
757:O
744:2
740:3
715:Å
697:O
689:O
636:O
589:Y
428:c
424:a
217:)
213:(
87:)
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