Knowledge (XXG)

Idrialite

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Stephen A. Wise, Robert M. Campbell, W. Raymond West, Milton L. Lee, Keith D. Bartle (1986): "Characterization of polycyclic aromatic hydrocarbon minerals curtisite, idrialite and pendletonite using high-performance liquid chromatography, gas chromatography, mass spectrometry and nuclear magnetic
531:(PAHs) consisting of six specific PAH structural series with each member of a series differing from the previous member by addition of another aromatic ring. The curtisite and idrialite samples contained many of the same components but in considerably different relative amounts. 417:
that gave off flammable gases. The mineral was described in 1925 and named "curtisite" after the local resident L. Curtis who called attention to it. The crystals are square or six sided flakes, 1 mm in diameter, yellow to
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Curtisite is also associated with small amounts of a dark brown oil, that appears to be responsible for some of the yellow color and most of the fluorescence, and can be separated by recrystallization.
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Frank, Otakar; JehliÄŤka, Jan; Edwards, Howell G.M. (December 2007). "Raman spectroscopy as tool for the characterization of thio-polyaromatic hydrocarbons in organic minerals".
347:, but was eventually found to consist of the same compounds as idrialite, in somewhat different amounts. Thus curtisite is now considered to be merely a variety of idrialite. 490:. The material purified by repeated recrystallization melts at 360-370 C while turning very black. It sublimes giving very thin iridescent colors. 883:
T. A. Geissman, K. Y. Sun, and J. Murdoch (1967): "Organic minerals. Picine and chrysene as constituents of the mineral Curtisite (idrialite)".
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Max Blumer (1975): "Curtisite, idrialite and pendletonite, polycyclic aromatic hydrocarbon minerals: Their composition and origin"
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F. E. Wright and E. T. Allen (1925): "Curtisite, a new organic mineral from Skaggs Springs, Sonoma County, California (abstract)"
941: 172: 562:- and dimethyl-substituted homologues; the major components in the idrialite sample were higher-molecular-weight PAH, i.e. 946: 547: 543: 103: 936: 383: 824: 528: 391: 387: 83: 501: 563: 539: 567: 513: 162: 850: 625: 586: 463: 410: 581:
Based on the composition, it was conjectured that the compounds were produced by medium-temperature
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at elevated temperatures in the subsurface and by recrystallization during migration.
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Idrialite was first described in 1832 for an occurrence in the Idrija region west of
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Idrialite, Skaggs Springs Mine, Sonoma County, California (size: 6.3 x 4.1 x 1.8 cm
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Curtisite and idrialite have been found to be unique complex mixtures of over 100
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In the Skaggs Springs occurrence, the mineral occurs in a hot spring area of the
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Curtisite, a new organic mineral from Skaggs Springs, Sonoma County, California
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crystals, is usually greenish yellow to light brown in color with bluish
245: 17: 791: 712: 638: 613: 673: 487: 479: 475: 451: 443: 427: 403: 574:(MW 328), in addition to the compounds found in the curtisite sample. 434:(mercuric sulfide), which had been deposited in that order before it. 559: 535: 483: 395: 372: 368: 364: 303: 843:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
794:" page at the Mindat.org online database. Accessed on 2020-08-28. 715:" page at the Mindat.org online database. Accessed on 2020-08-28. 423: 693:". Online document at Webmineral.com. Accessed on 2020-08-28. 534:
The major PAH constituents of the curtisite sample were:
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The Curtisite variety is only slightly soluble in hot
920:. The Chemical Society of Great Britain. p. 167. 585:
of organic matter, then further modified by extended
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studies indicate that it may be a mixture of complex
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ores in the source locality. A mineral found in the
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Allen (1930): " 26: 774:, volume 16, issue 4, pages 245-256. 7: 614:"IMA–CNMNC approved mineral symbols" 538:(a PAH with 5 fused benzene rings), 359:, northwestern Slovenia, mixed with 728:Catalogue of Minerals and Synonyms 25: 313:The mineral has also been called 294:Idrialite usually occurs as soft 343:was described in 1925 and named 134:c = 27.75 ; Z = 4 917:Journal of the Chemical Society 390:, and in the Knoxville Mine in 240:X = pale yellow; Y = Z = yellow 1: 780:10.1016/0009-2541(75)90064-9 757:10.1016/0009-2541(86)90148-8 887:, volume 23, pages 793-794. 831:, volume 15, pages 169-173. 157:{001}, perfect; {100}, poor 973: 952:Minerals described in 1832 438:Composition and properties 863:10.1016/j.saa.2006.12.033 807:, volume 11, pages 67-67. 747:resonance spectroscopy". 725:Egleston, Thomas (1889). 529:polyaromatic hydrocarbons 34: 897:Thomson, Thomas (1838). 689:Dave Barthelmy (2012): " 566:(molecular weight 316), 548:benzophenanthrothiophene 351:Discovery and occurrence 327:It has also been called 413:, around a vent in the 392:Napa County, California 691:Idrialite Mineral Data 674:Handbook of Mineralogy 618:Mineralogical Magazine 544:11H-indenophenanthrene 502:benzonaphthothiophenes 486:, and over 10% in hot 430:(arsenic sulfide) and 190:Vitreous to adamantine 942:Orthorhombic minerals 829:American Mineralogist 805:American Mineralogist 564:benzonaphthofluorenes 94:Strunz classification 947:Luminescent minerals 568:benzoindenofluorenes 516:(chemical formula: C 504:(chemical formula: C 464:carbon tetrachloride 411:Franciscan formation 329:inflammable cinnabar 302:. It is named after 855:2007AcSpA..68.1065F 639:10.1180/mgm.2021.43 630:2021MinM...85..291W 612:Warr, L.N. (2021). 514:dinaphthothiophenes 132:a = 8.07, b = 6.42 122:Unknown space group 104:Dana classification 494:Raman spectroscopy 205:Optical properties 274: 273: 16:(Redirected from 964: 937:Organic minerals 922: 921: 911: 905: 904: 894: 888: 881: 875: 874: 849:(4): 1065–1069. 838: 832: 821: 808: 801: 795: 788: 782: 772:Chemical Geology 768: 759: 749:Chemical Geology 744: 733: 732: 722: 716: 709: 694: 687: 678: 665: 652: 651: 641: 609: 482:, about 2.5% in 478:; about 1.5% in 460:carbon bisulfide 375:associated with 214:Refractive index 196:Specific gravity 177: 68: 67:(repeating unit) 39: 27: 21: 972: 971: 967: 966: 965: 963: 962: 961: 927: 926: 925: 913: 912: 908: 896: 895: 891: 882: 878: 840: 839: 835: 822: 811: 802: 798: 789: 785: 769: 762: 745: 736: 724: 723: 719: 710: 697: 688: 681: 666: 655: 611: 610: 606: 602: 552:indenofluorenes 540:dibenzofluorene 523: 519: 511: 507: 456:petroleum ether 440: 432:metacinnabarite 353: 290: 286: 229: 225: 221: 175: 133: 121: 78: 74: 66: 65: 56:Organic mineral 42: 23: 22: 15: 12: 11: 5: 970: 968: 960: 959: 954: 949: 944: 939: 929: 928: 924: 923: 906: 889: 876: 833: 809: 796: 783: 760: 734: 717: 695: 679: 653: 624:(3): 291–320. 603: 601: 598: 521: 517: 509: 505: 439: 436: 424:opaline silica 352: 349: 337:Skaggs Springs 288: 284: 272: 271: 269: 265: 264: 261: 252: 251: 248: 242: 241: 238: 232: 231: 227: 223: 219: 216: 210: 209: 206: 202: 201: 198: 192: 191: 188: 182: 181: 178: 169: 168: 165: 159: 158: 155: 149: 148: 145: 141: 140: 139:Identification 136: 135: 130: 124: 123: 116: 114:Crystal system 110: 109: 106: 100: 99: 96: 90: 89: 86: 80: 79: 76: 72: 69: 59: 58: 53: 49: 48: 44: 43: 40: 32: 31: 24: 14: 13: 10: 9: 6: 4: 3: 2: 969: 958: 955: 953: 950: 948: 945: 943: 940: 938: 935: 934: 932: 919: 918: 910: 907: 902: 901: 893: 890: 886: 880: 877: 872: 868: 864: 860: 856: 852: 848: 844: 837: 834: 830: 826: 820: 818: 816: 814: 810: 806: 800: 797: 793: 787: 784: 781: 777: 773: 767: 765: 761: 758: 754: 750: 743: 741: 739: 735: 730: 729: 721: 718: 714: 708: 706: 704: 702: 700: 696: 692: 686: 684: 680: 676: 675: 670: 664: 662: 660: 658: 654: 649: 645: 640: 635: 631: 627: 623: 619: 615: 608: 605: 599: 597: 595: 590: 588: 587:equilibration 584: 579: 575: 573: 570:(MW 304) and 569: 565: 561: 557: 553: 549: 545: 541: 537: 532: 530: 525: 515: 503: 499: 495: 491: 489: 485: 481: 477: 474:, or boiling 473: 472:diethyl ether 469: 465: 461: 457: 453: 449: 445: 437: 435: 433: 429: 425: 421: 416: 412: 407: 405: 401: 397: 393: 389: 386:, in western 385: 384:Sonoma County 380: 378: 374: 370: 366: 362: 358: 350: 348: 346: 342: 338: 334: 330: 326: 322: 321: 316: 311: 309: 305: 301: 297: 292: 282: 278: 270: 266: 262: 260: 257: 253: 249: 247: 243: 239: 237: 233: 217: 215: 211: 207: 203: 199: 197: 193: 189: 187: 183: 179: 174: 170: 166: 164: 160: 156: 154: 150: 146: 142: 137: 131: 129: 125: 120: 117: 115: 111: 107: 105: 101: 97: 95: 91: 87: 85: 81: 70: 64: 60: 57: 54: 50: 45: 38: 33: 28: 19: 916: 909: 899: 892: 884: 879: 846: 842: 836: 828: 804: 799: 786: 771: 748: 727: 720: 672: 621: 617: 607: 591: 580: 576: 558:, and their 533: 526: 498:hydrocarbons 492: 448:amyl acetate 441: 408: 381: 354: 344: 339:location of 328: 319: 318: 314: 312: 300:fluorescence 296:orthorhombic 293: 276: 275: 259:fluorescence 119:Orthorhombic 572:benzopicene 388:Lake County 281:hydrocarbon 256:Ultraviolet 236:Pleochroism 208:Biaxial (+) 108:50.03.08.01 931:Categories 885:Experentia 600:References 500:including 468:chloroform 341:California 306:, town in 279:is a rare 268:References 173:Mohs scale 167:Conchoidal 84:IMA symbol 792:Curtisite 713:Idrialite 669:Idrialite 648:235729616 583:pyrolysis 420:pistachio 415:sandstone 357:Ljubljana 345:curtisite 315:idrialine 277:Idrialite 226:= 1.734 n 222:= 1.557 n 128:Unit cell 30:Idrialite 18:Curtisite 871:17307383 594:idrialin 556:chrysene 400:Slovakia 377:cinnabar 333:cinnabar 320:branderz 308:Slovenia 246:2V angle 176:hardness 163:Fracture 153:Cleavage 98:10.BA.20 52:Category 851:Bibcode 626:Bibcode 512:S) and 488:aniline 480:toluene 476:benzene 452:butanol 444:acetone 428:realgar 404:Ukraine 63:Formula 47:General 957:Idrija 869:  646:  560:methyl 536:picene 524:S). 484:xylene 396:France 373:gypsum 369:quartz 365:pyrite 325:German 317:, and 304:Idrija 230:= 2.07 186:Luster 644:S2CID 200:1.236 144:Color 867:PMID 402:and 371:and 361:clay 859:doi 827:". 776:doi 753:doi 634:doi 323:in 250:84° 180:1.5 933:: 865:. 857:. 847:68 845:. 812:^ 763:^ 737:^ 698:^ 682:^ 656:^ 642:. 632:. 622:85 620:. 616:. 596:. 554:, 550:, 546:, 542:, 522:12 518:20 510:10 506:16 470:, 466:, 462:, 454:, 450:, 446:, 426:, 406:. 398:, 379:. 367:, 363:, 291:. 289:14 285:22 88:Id 77:14 73:22 873:. 861:: 853:: 790:" 778:: 755:: 711:" 667:" 650:. 636:: 628:: 520:H 508:H 287:H 228:Îł 224:β 220:α 218:n 75:H 71:C 20:)

Index

Curtisite

Organic mineral
Formula
IMA symbol
Strunz classification
Dana classification
Crystal system
Orthorhombic
Unit cell
Cleavage
Fracture
Mohs scale
Luster
Specific gravity
Refractive index
Pleochroism
2V angle
Ultraviolet
fluorescence
hydrocarbon
orthorhombic
fluorescence
Idrija
Slovenia
German
cinnabar
Skaggs Springs
California
Ljubljana

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