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for a year before joining the
National Science Foundation as a program officer in the Chemistry Division. That was followed by two years at the National Academy of Science in the Division of Earth and Life Sciences. His work there included studies and major reports on air pollution and air quality
253:
Tolman was instrumental in the founding of the
Delaware Science Alliance and took a year's leave of absence from DuPont to serve as Chair of the Coordinating Committee to help make the Alliance self-sustaining. The primary goal of the Science Alliances was to link scientists interested in education
254:
to teachers looking for help in the classroom. Programs include an
Elementary Science Olympiad, workshops for volunteers and elementary teachers, summer fellowships in local industry for secondary teachers, and classroom visits and demonstrations by industrial scientists.
419:
S. D. Ittel, C. A. Tolman, A. D. English, and J. P. Jesson, "The
Chemistry of 2-Naphthyl bis Hydride Complexes of Fe, Ru, and Os. 2. Cleavage of sp and sp3 C-H, C-O, and C-X Bonds. Coupling of Carbon Dioxide and Acetonitrile," J. Am. Chem. Soc., 100, 7577
447:
Tolman, C. A.; Druliner, J. D.; Krusic, P. J.; Nappa, M. J.; Seidel, W. C.; Williams, I. D.; Ittel, S. D. Catalytic conversion of cyclohexylhydroperoxide to cyclohexanone and cyclohexanol, Journal of
Molecular Catalysis (1988), 48(1),
457:
John W. Collette, Sharon K. Hake, and Robert D. Lipscomb; The Du Pont Honors
Workshop: A Successful Industry-School Partnership, Chapter 6, pp 55–65 in Partnerships in Chemical Research and Education; ACS Symposium Series, Vol. 478,
1336:
429:
C. A. Tolman, S. D. Ittel, A. D. English, and J. P. Jesson, "Chemistry of 2-Naphthyl- bis
Hydride Complexes of Iron, Ruthenium, and Osmium. 3. Cleavage of sp2 C-H Bonds," J. Am. Chem. Soc., 101, 1742 (1979).
238:
to include the many examples of stable 16 electron square planar d complexes. Later work focused on the activation of C-H bonds by transition metal complexes and free radical oxidation of
438:
Tolman, C. A.; Druliner, J. D.; Nappa, M. J.; Herron, N.; Alkane
Oxidation Studies in Du Pont's Central Research Department; in Act. Funct. Alkanes (1989), 303–60, edited by Craig L Hill
300:, where he helped write the Toolkit for Climate Change Action He served on the Greenhouse Gas Reduction Advisory Committee and the Sea Level Rise Advisory Committee of the State of
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Committee on Review and
Evaluation of the Army Chemical Stockpile Disposal Program; National Research Council (24 November 1999).
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Tolman followed and communicated about climate change issues for over 20 years. He wrote a monthly electronic blog,
364:
Tolman, C. A. (1977). "Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis".
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Tolman served on a number of advisory committees. He chaired the Energy
Committee of the Delaware Chapter of the
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Tolman, C. A. (1972). "The 16 and 18 electron rule in organometallic chemistry and homogeneous catalysis".
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http://participate.lwv.org/c/9217/t/6398/p/salsa/web/common/public/content?content_item_KEY=3766
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194:(October 1938 – April 6, 2024) was an American chemist. He obtained his B.S. in Chemistry from
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in 1965. His early work was on late transition metal complexes with phosphorus ligands. The
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Thesis: The Microwave Spectrum and Vibration-Rotation Interaction in 1,1-Difluorocyclopentane
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Tooele Chemical Agent Disposal Facility: Update on National Research Council Recommendations
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Tolman died in Maris Grove, Pennsylvania, on April 6, 2024, at the age of 85.
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Tolman was presented the Delaware Audubon Conservation Award at the Delaware
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198:. He earned his Ph.D. in Chemistry as a microwave spectroscopist from
728:
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Statement of Conscience on the Threat of Global Warming/Climate Change
1214:(incl. The Playhouse on Rodney Square, formerly the DuPont Playhouse)
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Massachusetts Institute of Technology School of Science alumni
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Upon retirement from DuPont in 1996, Tolman taught at
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which was adopted by their General Assembly in 2006.
288:, and was a member of the Advocacy Committee of the
1226:
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856:
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292:. He was on the Energy Committee of the Delaware
609:"Obituaries in Wilmington, DE | The News Journal"
296:, and the Climate Change Task Force of the U.S.
226:are named after him. In 1972, he proposed the
645:
8:
563:"Delaware Audubon – Conservation Award 2009"
652:
638:
630:
259:Delaware Technical & Community College
153:Delaware Technical & Community College
122:Delaware Audubon Conservation Award (2009)
29:
18:
525:"Threat of Global Warming/Climate Change"
246:, an intermediate in the manufacture of
1248:NASCAR Cup Series career of Jeff Gordon
322:
590:
580:
1180:Winterthur Museum, Garden and Library
196:Massachusetts Institute of Technology
80:Massachusetts Institute of Technology
7:
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311:Annual Meeting on October 9, 2009.
85:University of California - Berkeley
279:Unitarian Universalist Association
14:
1255:The DuPont Show with June Allyson
551:- posted on the web in June 2010.
1285:
1276:
1275:
697:
1244:Hendrick Motorsports Car No. 24
561:Delaware Audubon Society; Inc.
1332:Scientists from Salt Lake City
1327:21st-century American chemists
1322:20th-century American chemists
342:. C. A. Tolman. Archived from
1:
482:. National Academies Press.
168:National Academy of Sciences
16:American chemist (1938–2024)
914:Anthony Joseph Arduengo III
843:DuPont Experimental Station
224:Tolman electronic parameter
163:National Science Foundation
99:Tolman electronic parameter
1358:
1201:DuPont v. Kolon Industries
1190:Consolidation Coal Company
1271:
1145:Hagley Museum and Library
1125:Atlas Chemical Industries
1064:Howard Ensign Simmons Jr.
919:Jacques Antoine Bidermann
695:
185:
126:
28:
1262:DuPont Show of the Month
864:Éleuthère Irénée du Pont
1150:Hercules Powder Company
838:DuPont Central Research
290:Delaware Nature Society
273:. He helped write the
228:16 and 18 electron rule
216:DuPont Central Research
148:DuPont Central Research
909:Jeffery Stanford Agate
884:Francis Irénée du Pont
879:Francis Gurney du Pont
298:League of Women Voters
294:League of Women Voters
263:University of Delaware
242:for the production of
202:under the guidance of
158:University of Delaware
1029:William Dale Phillips
504:"CLIMATE CHANGE NEWS"
204:William Dulaney Gwinn
180:William Dulaney Gwinn
1094:Edgar S. Woolard Jr.
407:10.1039/CS9720100337
192:Chadwick Alma Tolman
48:Salt Lake City, Utah
1170:Savannah River Site
1024:Charles J. Pedersen
994:Edward G. Jefferson
984:Charles O. Holliday
820:Antec International
684:Alexander M. Cutler
466:, November 18, 1992
379:10.1021/cr60307a002
271:Climate Change News
138:Inorganic chemistry
1115:DuPont (1802–2017)
1099:Nathaniel C. Wyeth
1079:Chadwick A. Tolman
1074:Frederick N. Tebbe
1054:Richard R. Schrock
974:Richard Goodmanson
959:Curtis J. Crawford
954:Thomas M. Connelly
904:T. Coleman du Pont
615:. The News Journal
613:delawareonline.com
593:has generic name (
23:Chadwick A. Tolman
1299:
1298:
1155:Kinetic Chemicals
1140:Eleutherian Mills
1134:Manhattan Project
1049:Irving S. Shapiro
1044:William K. Reilly
944:Wallace Carothers
899:Pierre S. du Pont
869:Alfred I. du Pont
489:978-0-309-06882-6
464:978-0-8412-2173-4
340:"Dr. Chad Tolman"
220:Tolman cone angle
189:
188:
128:Scientific career
95:Tolman cone angle
1349:
1289:
1288:
1279:
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1175:Wilmington Trust
1004:Stephanie Kwolek
999:Ellen J. Kullman
939:Richard H. Brown
701:
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565:. Archived from
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236:18-Electron rule
175:Doctoral advisor
62:
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1302:
1301:
1300:
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1212:DuPont Building
1195:DuPont analysis
1103:
1089:Charles M. Vest
1034:Roy J. Plunkett
1019:George Parshall
1014:Rudolph Pariser
934:Donaldson Brown
852:
848:DuPont Building
830:
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810:
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679:Edward D. Breen
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569:on 3 March 2016
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395:Chem. Soc. Rev.
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309:Audubon Society
232:Irving Langmuir
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76:Alma mater
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1207:Du Pont Motors
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1165:Remington Arms
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1160:Nemours Estate
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1120:Du Pont family
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929:Norman Borlaug
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894:Lammot du Pont
891:
886:
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874:Eugene du Pont
871:
866:
860:
858:
857:Notable people
854:
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829:Divisions and
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812:joint ventures
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373:(3): 313–348.
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214:Tolman joined
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113:Global Warming
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91:Known for
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63:(aged 85)
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35:Tolman in 1976
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1342:DuPont people
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1069:Charles Stine
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924:Samuel Bodman
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890:
889:Henry du Pont
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346:on 2011-08-13
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200:U.C. Berkeley
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103:Tolman's rule
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81:
78:
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69:
66:Maris Grove,
59:April 6, 2024
58:
54:
49:
43:
39:
32:
27:
20:
1260:
1253:
1199:
1078:
989:Steven Ittel
969:Linda Fisher
949:Uma Chowdhry
807:Subsidiaries
617:. Retrieved
612:
603:
571:. Retrieved
567:the original
556:
544:
532:. Retrieved
528:
519:
507:. Retrieved
498:
478:
471:
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443:
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425:
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398:
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348:. Retrieved
344:the original
334:
325:
313:
306:
283:
274:
270:
268:
266:management.
256:
252:
230:, extending
213:
191:
190:
144:Institutions
127:
110:of organics
68:Pennsylvania
61:(2024-04-06)
44:October 1938
1317:2024 deaths
1312:1938 births
1239:Pioneer 250
1234:Tour DuPont
1227:Sponsorship
1084:Earl Tupper
1009:James Lynah
979:Jeff Gordon
573:19 February
534:19 February
509:19 February
286:Sierra Club
244:adipic acid
240:cyclohexane
1306:Categories
831:facilities
401:(3): 337.
367:Chem. Rev.
350:2011-03-21
318:References
106:Selective
1130:B Reactor
671:directors
668:Selected
210:Biography
108:oxidation
1281:Category
1218:Chemours
754:Neoprene
707:Products
619:14 April
583:cite web
302:Delaware
277:for the
1291:Commons
1108:History
729:Hypalon
529:UUA.org
420:(1978).
1185:Conoco
793:Zodiaq
784:Vespel
774:Teflon
769:Sorona
744:Kevlar
739:Kapton
734:Kalrez
714:Corian
661:DuPont
486:
462:
448:129–48
134:Fields
119:Awards
70:, U.S.
50:, U.S.
797:Zytel
789:Viton
779:Tyvek
764:Nylon
759:Nomex
749:Mylar
724:Freon
719:FE-13
248:nylon
809:and
621:2024
595:help
575:2016
536:2016
511:2016
484:ISBN
460:ISBN
261:and
222:and
56:Died
41:Born
403:doi
375:doi
234:'s
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611:.
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585:}}
581:{{
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538:.
513:.
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409:.
405::
399:1
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377::
353:.
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
