Knowledge (XXG)

Cobalt(II) naphthenate

Source 📝

330: 428:
Cobalt Naphthenate is a moderately toxic substance which can cause a range of acute and chronic conditions, and it is also a carcinogen. It is most commonly used diluted in mineral spirit or mineral oil. Safety equipment must be used to avoid eye and skin contact. The pure compound has a high vapor
401:. The fact that naphthenates are mixtures helps to confer high solubility. A second virtue of these species is their low cost. A well-defined compound that exhibits many of the properties of cobalt naphthenate is the cobalt(II) complex of 420:. Such species are sometimes classified as active driers. Active driers are catalysts that feature redox-active metal centers. Such centers promote redox reactions with hydroperoxide-containing intermediates. 343: 75: 405:. Often in technical literature, naphthenates are described as salts, but they are probably also non-ionic coordination complexes with structures similar to 185: 496: 150: 463: 501: 389:. Metal naphthenates are not well defined in conventional chemical sense that they are mixtures. They are widely employed 350: 312: 412:
The catalytic properties of cobalt(II) naphthenates are similar to those of related compounds containing
402: 374: 41: 429:
density of 3.9 (air = 1), and a low vapor pressure of 1 mm Hg at 25 °C (77 °F).
459: 306: 95: 451: 378: 280: 208: 51: 370: 478: 159:
InChI=1S/2C11H8O2.Co/c2*12-11(13)10-6-5-8-3-1-2-4-9(8)7-10;/h2*1-7H,(H,12,13);/q;;+2/p-2
321: 169:
InChI=1/2C11H8O2.Co/c2*12-11(13)10-6-5-8-3-1-2-4-9(8)7-10;/h2*1-7H,(H,12,13);/q;;+2/p-2
490: 269: 259: 120: 406: 382: 398: 296: 386: 231: 86: 455: 413: 390: 249: 107: 366: 320:
Except where otherwise noted, data are given for materials in their
394: 131: 74: 64: 393:
because they are soluble in the nonpolar substrates, such as the
417: 446:
Poth, Ulrich (2001). "Drying Oils and Related Products".
338: 479:
https://nj.gov/health/eoh/rtkweb/documents/fs/0523.pdf
274:> 150 °C (302 °F; 423 K) 119: 50: 448:Ullmann's Encyclopedia of Industrial Chemistry 301:48.89 °C (120.00 °F; 322.04 K) 8: 193:c1ccc2cc(ccc2c1)C(=O).c1ccc2cc(ccc2c1)C(=O). 94: 15: 438: 190: 155: 264:140 °C (284 °F; 413 K) 162:Key: IFSWBZCGMGEHLE-UHFFFAOYSA-L 7: 244:brown amorphous or bluish-red solid 172:Key: IFSWBZCGMGEHLE-NUQVWONBAA 110: 14: 328: 324:(at 25 °C , 100 kPa). 1: 518: 236:401.02 g/mol 497:Salts of carboxylic acids 318: 290: 201: 181: 146: 34: 26: 21: 456:10.1002/14356007.a09_055 17:Cobalt(II) naphthenate 375:coordination complexes 363:Cobalt(II) naphthenate 502:Cobalt(II) compounds 403:2-ethylhexanoic acid 369:(II) derivatives of 424:Toxicity and safety 377:are widely used as 281:Solubility in water 18: 407:basic zinc acetate 351:Infobox references 16: 379:oil drying agents 359:Chemical compound 357: 356: 307:Safety data sheet 254:0.96 g/cm, solid 76:Interactive image 509: 481: 476: 470: 469: 443: 385:crosslinking of 371:naphthenic acids 365:is a mixture of 341: 335: 332: 331: 209:Chemical formula 123: 112: 98: 78: 54: 19: 517: 516: 512: 511: 510: 508: 507: 506: 487: 486: 485: 484: 477: 473: 466: 445: 444: 440: 435: 426: 360: 353: 348: 347: 346:  ?) 337: 333: 329: 325: 283: 225: 221: 217: 211: 197: 194: 189: 188: 177: 174: 173: 170: 164: 163: 160: 154: 153: 142: 126: 113: 101: 81: 68: 57: 44: 30: 12: 11: 5: 515: 513: 505: 504: 499: 489: 488: 483: 482: 471: 464: 437: 436: 434: 431: 425: 422: 358: 355: 354: 349: 327: 326: 322:standard state 319: 316: 315: 310: 303: 302: 299: 293: 292: 288: 287: 284: 279: 276: 275: 272: 266: 265: 262: 256: 255: 252: 246: 245: 242: 238: 237: 234: 228: 227: 223: 219: 215: 212: 207: 204: 203: 199: 198: 196: 195: 192: 184: 183: 182: 179: 178: 176: 175: 171: 168: 167: 165: 161: 158: 157: 149: 148: 147: 144: 143: 141: 140: 136: 134: 128: 127: 125: 124: 116: 114: 106: 103: 102: 100: 99: 91: 89: 83: 82: 80: 79: 71: 69: 62: 59: 58: 56: 55: 47: 45: 40: 37: 36: 32: 31: 28: 24: 23: 13: 10: 9: 6: 4: 3: 2: 514: 503: 500: 498: 495: 494: 492: 480: 475: 472: 467: 461: 457: 453: 449: 442: 439: 432: 430: 423: 421: 419: 415: 410: 408: 404: 400: 396: 392: 388: 384: 380: 376: 372: 368: 364: 352: 345: 340: 323: 317: 314: 311: 308: 305: 304: 300: 298: 295: 294: 289: 285: 282: 278: 277: 273: 271: 270:Boiling point 268: 267: 263: 261: 260:Melting point 258: 257: 253: 251: 248: 247: 243: 240: 239: 235: 233: 230: 229: 213: 210: 206: 205: 200: 191: 187: 180: 166: 156: 152: 145: 138: 137: 135: 133: 130: 129: 122: 118: 117: 115: 109: 105: 104: 97: 93: 92: 90: 88: 85: 84: 77: 73: 72: 70: 66: 61: 60: 53: 49: 48: 46: 43: 39: 38: 33: 25: 20: 474: 447: 441: 427: 411: 383:autoxidative 362: 361: 313:External SDS 132:RTECS number 35:Identifiers 27:Other names 399:linseed oil 387:drying oils 297:Flash point 241:Appearance 202:Properties 491:Categories 465:3527306730 433:References 397:resins or 232:Molar mass 87:ChemSpider 63:3D model ( 52:61789-51-3 42:CAS Number 29:Naphtolite 414:manganese 391:catalysts 373:. These 139:QK8925000 381:for the 291:Hazards 121:14048876 96:21241700 344:what is 342: ( 250:Density 226: 108:PubChem 462:  367:cobalt 339:verify 336:  309:(SDS) 186:SMILES 22:Names 395:alkyd 286:none 151:InChI 65:JSmol 460:ISBN 418:iron 416:and 452:doi 214:CoC 111:CID 493:: 458:. 450:. 409:. 220:14 216:22 468:. 454:: 334:N 224:4 222:O 218:H 67:)

Index

CAS Number
61789-51-3
JSmol
Interactive image
ChemSpider
21241700
PubChem
14048876
RTECS number
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Boiling point
Solubility in water
Flash point
Safety data sheet
External SDS
standard state
verify
what is
Infobox references
cobalt
naphthenic acids
coordination complexes
oil drying agents
autoxidative
drying oils

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.