24:
191:
116:
37:
23:
630:
Kabešová, M.; Dunaj-Jurčo, M.; Serator, M.; Gažo, J.; Garaj, J. (1976). "The
Crystal Structure of Copper(I) Thiocyanate and Its Relation to the Crystal Structure of Copper(II) Diammine Dithiocyanate Complex".
440:. The double salt only forms from concentrated solutions of CsSCN, into which CuSCN dissolves. From less concentrated solutions, solid CuSCN separates reflecting its low solubility. When brought together with
388:
have been characterized by X-ray crystallography. They both feature copper(I) in a characteristic tetrahedral coordination geometry. The sulfur end of the SCN- ligand is triply
588:
Smith, D. L.; Saunders, V. I. "Preparation and
Structure Refinement of the 2H Polytype of beta-Copper(I) Thiocyanate" Acta Crystallographica B, 1982, volume 38, 907-909.
452:, and brought to crystallisation by concentrating the solution, mixed salts will crystallise out. These are not considered true double salts. As with CsCu (SNC)
416:
is added and then a soluble thiocyanate is added (preferably slowly, while stirring). Copper(I) thiocyanate is precipitated as a white powder. Alternatively, a
1006:
864:
Albini, A.; Fausto, R.; de Melo, J.S.S.; Maldotti, A.; Clementi, C.; Kalyanasundaram, K.; Johnston, L.J.; Harbron, E.; Misawa, H.; Romani, A. (2011).
412:. It is conveniently prepared from relatively dilute solutions of copper(II) in water, such as copper(II) sulphate. To a copper(II) solution
1341:
614:
909:
875:
841:
1655:
1586:
1334:
385:
1660:
999:
658:
Hunter, J. A.; Massie, W. H. S.; Meiklejohn, J.; Reid, J. (1969-01-01). "Thermal rearrangement in copper(II) thiocyanate".
1617:
376:
with formula CuSCN. It is an air-stable, white solid used as a precursor for the preparation of other thiocyanate salts.
357:
1645:
1223:
148:
1263:
932:
169:
992:
496:
404:, especially when heated. It is also formed from copper(II) thiocyanate under water, releasing (among others)
492:
294:
111:
1481:
1365:
1303:
400:
Copper(I) thiocyanate forms from the spontaneous decomposition of black copper(II) thiocyanate, releasing
270:
456:, copper(I) thiocyanate separates out when these mixed salts are redissolved or their solutions diluted.
1650:
1319:
1243:
441:
342:
1609:
525:
CuSCN precipitated on carbon support can be used for conversion of aryl halides to aryl thiocyanates.
1562:
1468:
1397:
1295:
488:
373:
338:
1546:
1497:
1377:
1353:
1327:
1131:
1118:
1081:
186:
63:
1567:
1513:
1489:
1476:
1385:
1275:
1251:
1235:
1065:
1059:
529:
519:
473:
449:
445:
1192:
959:"Solubility and toxic effect of the cuprous thiocyanate antifouling pigment on barnacle larvae"
1413:
1140:
1123:
1054:
1049:
905:
899:
871:
865:
837:
831:
781:
Reece H. Vallance, Douglas F. Twiss and Miss Annie R. Russell (1931). J. Newton Friend (ed.).
760:
675:
610:
323:
1455:
1429:
1076:
1015:
970:
750:
742:
706:
667:
640:
589:
515:
409:
319:
258:
208:
157:
93:
1460:
1109:
1093:
1029:
560:
413:
405:
389:
73:
190:
115:
1442:
1180:
1071:
958:
755:
730:
500:
351:
644:
1639:
671:
533:
484:
469:
465:
247:
137:
104:
1155:
480:
433:
401:
717:
429:
417:
593:
219:
84:
679:
957:
Vetere, V. F.; Pérez, M. C.; Romagnoli, R.; Stupak, M. E.; Amo, B. (1997).
936:
483:, therefore transparent to visible and near infrared light). It is used in
764:
503:·m). This can be improved by various treatments, e.g. exposure to gaseous
746:
731:"Use of cuprous thiocyanate as a short-term continuous marker for faeces"
695:"The Reaction of Copper(II) with Thiocyanate Ions (Letter to the Editor)"
504:
476:
711:
694:
974:
537:
237:
124:
36:
769:
487:
in some third-generation cells as a hole transfer layer. It acts as a
350:
Except where otherwise noted, data are given for materials in their
984:
988:
332:
313:
796:
H.L.Wells (1902). "On some double and triple thiocyanates".
174:
901:
Supported
Reagents: Preparation, Analysis, and Applications
499:. Its hole conductivity is however relatively poor (0.01
536:
include that the compound is white and a more efficient
783:
A text-book of inorganic chemistry, volume VII, part II
392:
so that the coordination sphere for copper is CuS3N.
898:
Clark, J.H.; Kybett, A.P.; Macquarrie, D.J. (1992).
518:
act synergically as a smoke suppressant additive in
1602:
1579:
1216:
1173:
1042:
1022:
819:. J. & A. Churchill, London. pp. 202–203.
785:. Charles Griffin & Company Ltd. p. 282.
136:
72:
1000:
8:
252:1,084 °C (1,983 °F; 1,357 K)
870:. Royal Society of Chemistry. p. 164.
1007:
993:
985:
609:(99 ed.). CRC Press. pp. 5–188.
420:solution may be used as a reducing agent.
189:
114:
92:
15:
754:
710:
156:
1448:
1444:
1161:
1157:
660:Inorganic and Nuclear Chemistry Letters
584:
582:
549:
185:
105:
607:CRC Handbook of Chemistry and Physics
561:"Properties of Copper(I) thiocyanate"
7:
555:
553:
817:The chemistry of cyanogen compounds
528:Copper thiocyanate is used in some
127:
14:
836:. Elsevier Science. p. 256.
428:Copper(I) thiocyanate forms one
35:
22:
354:(at 25 °C , 100 kPa).
963:Journal of Coatings Technology
372:(or cuprous thiocyanate) is a
1:
699:Journal of Chemical Education
645:10.1016/S0020-1693(00)81976-3
605:John Rumble (June 18, 2018).
815:Herbert E. Williams (1915).
672:10.1016/0020-1650(69)80226-6
464:Copper(I) thiocyanate is a
224:121.628 g/mol
1677:
497:dye-sensitized solar cells
798:American Chemical Journal
594:10.1107/S0567740882004361
532:. Advantages compared to
408:and the highly poisonous
348:
305:
201:
56:
48:
43:
34:
21:
833:Nanostructured Materials
1656:Semiconductor materials
933:"Copper in Antifouling"
633:Inorganica Chimica Acta
493:solid-state electrolyte
295:Magnetic susceptibility
904:. Wiley. p. 121.
495:. It is often used in
17:Copper(I) thiocyanate
1661:Coordination polymers
729:Matthew Dick (1969).
693:David Tudela (1993).
370:Copper(I) thiocyanate
343:Potassium thiocyanate
264:8.427·10 g/L (20 °C)
29:Copper(I) thiocyanate
747:10.1136/gut.10.5.408
741:(5): 408–412 (408).
507:or doping with (SCN)
489:P-type semiconductor
374:coordination polymer
339:Ammonium thiocyanate
1646:Copper(I) compounds
712:10.1021/ed070p174.3
530:anti-fouling paints
259:Solubility in water
51:Cuprous thiocyanate
18:
975:10.1007/BF02696144
830:Wilde, G. (2009).
567:. Alfa Aesar 40220
520:polyvinyl chloride
450:barium thiocyanate
358:Infobox references
306:Related compounds
271:Solubility product
16:
1633:
1632:
366:Chemical compound
364:
363:
324:copper(I) cyanide
170:CompTox Dashboard
1668:
1542:
1541:
1540:
1532:
1531:
1523:
1522:
1452:
1166:
1016:Copper compounds
1009:
1002:
995:
986:
979:
978:
954:
948:
947:
945:
944:
935:. Archived from
929:
923:
922:
920:
918:
895:
889:
888:
886:
884:
861:
855:
854:
852:
850:
827:
821:
820:
812:
806:
805:
804:: 245–284 (263).
793:
787:
786:
778:
772:
768:
758:
726:
720:
716:
714:
690:
684:
683:
655:
649:
648:
627:
621:
620:
602:
596:
586:
577:
576:
574:
572:
557:
434:group 1 elements
410:hydrogen cyanide
320:Copper(I) iodide
301:-48.0·10 cm/mol
287:
209:Chemical formula
194:
193:
178:
176:
160:
140:
129:
118:
107:
96:
76:
39:
26:
19:
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1613:
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1527:
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1521:
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1509:
1505:
1501:
1493:
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1472:
1464:
1450:
1446:
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1437:
1433:
1425:
1421:
1417:
1409:
1405:
1401:
1393:
1389:
1381:
1373:
1369:
1361:
1357:
1349:
1345:
1338:
1331:
1323:
1315:
1311:
1307:
1299:
1291:
1287:
1283:
1279:
1271:
1267:
1259:
1255:
1247:
1239:
1231:
1227:
1212:
1208:
1204:
1200:
1196:
1188:
1184:
1169:
1163:
1159:
1154:
1144:
1135:
1127:
1113:
1105:
1101:
1097:
1089:
1085:
1038:
1033:
1018:
1013:
983:
982:
956:
955:
951:
942:
940:
931:
930:
926:
916:
914:
912:
897:
896:
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882:
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863:
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848:
846:
844:
829:
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824:
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809:
795:
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790:
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728:
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723:
692:
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657:
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629:
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604:
603:
599:
587:
580:
570:
568:
559:
558:
551:
546:
510:
462:
455:
439:
426:
414:sulphurous acid
406:thiocyanic acid
398:
382:
367:
360:
355:
341:
335:
316:
298:
285:
281:
279:
261:
211:
197:
179:
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130:
99:
79:
66:
52:
30:
27:
12:
11:
5:
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867:Photochemistry
856:
842:
822:
807:
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616:978-1138561632
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381:
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365:
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352:standard state
349:
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109:
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62:
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28:
13:
10:
9:
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3:
2:
1673:
1662:
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1626:
1616:
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1601:
1595:
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1572:
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1512:
1510:
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1494:
1488:
1486:
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1465:
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1440:
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1396:
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1326:
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1318:
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1302:
1300:
1294:
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1262:
1260:
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1234:
1232:
1222:
1221:
1219:
1215:
1209:
1191:
1189:
1179:
1178:
1176:
1172:
1165:
1153:
1151:
1148:
1146:
1139:
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1130:
1128:
1122:
1120:
1117:
1115:
1108:
1106:
1092:
1090:
1080:
1078:
1075:
1073:
1070:
1068:
1067:
1063:
1061:
1058:
1056:
1053:
1051:
1048:
1047:
1045:
1041:
1035:
1028:
1027:
1025:
1021:
1017:
1010:
1005:
1003:
998:
996:
991:
990:
987:
976:
972:
968:
964:
960:
953:
950:
939:on 2017-04-27
938:
934:
928:
925:
913:
911:9780471187790
907:
903:
902:
894:
891:
879:
877:9781849731652
873:
869:
868:
860:
857:
845:
843:9780080914237
839:
835:
834:
826:
823:
818:
811:
808:
803:
799:
792:
789:
784:
777:
774:
771:
766:
762:
757:
752:
748:
744:
740:
736:
732:
725:
722:
719:
713:
708:
704:
700:
696:
689:
686:
681:
677:
673:
669:
665:
661:
654:
651:
646:
642:
638:
634:
626:
623:
618:
612:
608:
601:
598:
595:
591:
585:
583:
579:
566:
562:
556:
554:
550:
543:
541:
539:
535:
534:cuprous oxide
531:
526:
523:
521:
517:
512:
506:
502:
498:
494:
490:
486:
485:photovoltaics
482:
478:
475:
471:
470:semiconductor
468:conductor, a
467:
459:
457:
451:
447:
443:
435:
431:
423:
421:
419:
415:
411:
407:
403:
395:
393:
391:
387:
384:At least two
379:
377:
375:
371:
359:
353:
347:
344:
340:
337:
334:
329:
328:
325:
321:
318:
315:
310:
309:
304:
300:
296:
292:
291:
283:
276:
272:
268:
267:
263:
260:
256:
255:
251:
249:
248:Melting point
246:
245:
241:
239:
236:
235:
232:white powder
231:
228:
227:
223:
221:
218:
217:
213:
210:
206:
205:
200:
192:
188:
187:DTXSID0034481
184:
183:
181:
171:
167:
166:
159:
155:
154:
152:
150:
147:
146:
139:
135:
134:
132:
126:
122:
121:
117:
113:
110:
108:
106:ECHA InfoCard
103:
102:
95:
91:
90:
88:
86:
83:
82:
75:
71:
70:
68:
65:
61:
60:
55:
47:
42:
38:
33:
25:
20:
1651:Thiocyanates
1149:
1064:
969:(3): 39–45.
966:
962:
952:
941:. Retrieved
937:the original
927:
915:. Retrieved
900:
893:
881:. Retrieved
866:
859:
847:. Retrieved
832:
825:
816:
810:
801:
797:
791:
782:
776:
738:
734:
724:
702:
698:
688:
663:
659:
653:
636:
632:
625:
606:
600:
569:. Retrieved
564:
527:
524:
513:
463:
427:
424:Double salts
402:thiocyanogen
399:
383:
369:
368:
274:
214:CuSCN
57:Identifiers
49:Other names
639:: 161–165.
514:CuSCN with
436:, CsCu(SCN)
430:double salt
418:thiosulfate
229:Appearance
202:Properties
112:100.012.894
1640:Categories
943:2017-04-25
917:14 January
883:14 January
849:14 January
705:(2): 174.
666:(1): 1–4.
565:Chemspider
544:References
386:polymorphs
242:2.88 g/cm
220:Molar mass
158:PW2155WE9H
85:ChemSpider
64:CAS Number
680:0020-1650
571:5 January
491:and as a
442:potassium
432:with the
396:Synthesis
380:Structure
74:1111-67-7
1174:Cu(I,II)
770:PDF copy
718:PDF copy
505:chlorine
477:band gap
390:bridging
297:(χ)
138:11029823
1580:Cu(III)
1482:Cu(SCN)
1023:Cu(0,I)
765:5771673
756:1552857
538:biocide
522:(PVC).
472:with a
333:cations
238:Density
125:PubChem
1603:Cu(IV)
1469:Cu(OH)
1366:Cu(ClO
1354:Cu(ClO
1320:Cu(CN)
1217:Cu(II)
908:
874:
840:
763:
753:
678:
613:
446:sodium
331:Other
314:anions
312:Other
44:Names
1386:Cu(NO
1335:KCuCl
1264:Cu(CF
1252:Cu(CH
1224:Cu(BF
1150:CuSCN
1043:Cu(I)
479:(3.6
94:55204
1568:CuTe
1563:CuTe
1555:COO)
1547:Cu(C
1533:COO)
1515:Cu(C
1502:(AsO
1490:CuSO
1430:Cu(N
1346:CuCl
1328:CuCl
1312:(OH)
1296:CuCO
1276:Cu(C
1268:COO)
1256:COO)
1236:CuBr
1124:CuNO
1119:CuOH
1060:CuCl
1055:CuCN
1050:CuBr
919:2017
906:ISBN
885:2017
872:ISBN
851:2017
838:ISBN
761:PMID
676:ISSN
611:ISBN
573:2016
474:wide
466:hole
460:Uses
284:1.77
149:UNII
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1591:CuF
1477:CuS
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1418:(BO
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