1174:
27:
1158:
1482:
1474:
1190:
1452:
294:
175:
1495:
1389:
558:
1355:
553:
543:
677:
548:
673:
36:
1060:
1784:
847:
678:
676:
566:
523:
2462:
Blanco-Urgoiti, Jaime; Añorbe, Loreto; Pérez-Serrano, Leticia; Domínguez, Gema; Pérez-Castells, Javier (2004). "The Pauson–Khand reaction, a powerful synthetic tool for the synthesis of complex molecules".
648:
1481:
1120:
The minor isomer has no bridging carbonyl ligands, but instead has a direct bond between the cobalt centres and eight terminal carbonyl ligands, four on each metal atom. It can be summarised by the formula
1473:
132:
3911:
125:
694:
26:
1444:
primary alcohol. The preparation of the cyclic siloxane moiety immediately prior to the introduction of the dicobalt octacarbonyl ensures that the product is formed with the desired
1960:
1923:
749:
860:
1173:
2036:
1072:
process) contains two bridging carbonyl ligands linking the cobalt centres and six terminal carbonyl ligands, three on each metal. It can be summarised by the formula
679:
1157:
1982:
1025:, which degrades near room temperature to dicobalt octacarbonyl and hydrogen. It can also be prepared by heating cobalt metal to above 250 °C in a stream of
1930:
that workers should not be exposed to concentrations greater than 0.1 mg/m over an eight-hour time-weighted average, without the proper respiratory gear.
2941:
343:
3593:
2678:
Xiao, W.; Feng, X.; Ruffieux, P.; Gröning, O.; Müllen, K.; Fasel, R. (18 June 2008). "Self-Assembly of Chiral
Molecular Honeycomb Networks on Au(111)".
2297:
Garcia, Thelma Y.; Fettinger, James C.; Olmstead, Marilyn M.; Balch, Alan L. (2009). "Splendid symmetry: Crystallization of an unbridged isomer of Co
1189:
2719:
2680:
79:
Cobalt carbonyl (2:8), di-mu-Carbonylhexacarbonyldicobalt, Cobalt octacarbonyl, Cobalt tetracarbonyl dimer, Dicobalt carbonyl, Octacarbonyldicobalt
1136:
symmetry. It features an unbridged cobalt–cobalt bond that is 2.70 Å in length in the solid structure when crystallized together with
3429:
3173:
1470:. Symmetrical diphenylacetylenes form 6-substituted hexaphenylbenzenes, while asymmetrical diphenylacetylenes form a mixture of two isomers.
3566:
3398:
3122:
3066:
2988:
2649:
Vij, V.; Bhalla, V.; Kumar, M. (8 August 2016). "Hexaarylbenzene: Evolution of
Properties and Applications of Multitalented Scaffold".
1416:
Intramolecular Pauson–Khand reactions, where the starting material contains both the alkene and alkyne moieties, are possible. In the
1117:
distances are 1.80 and 1.90 Å, respectively. Analysis of the bonding suggests the absence of a direct cobalt–cobalt bond.
2886:
2811:
2633:
2201:
2165:
2089:
2003:
701:
308:
3334:
2934:
2383:
Teobald, Barry J. (2002). "The
Nicholas reaction: The use of dicobalt hexacarbonyl-stabilised propargylic cations in synthesis".
1852:
1787:
2576:
Nakayama, Atsushi; Kogure, Noriyuki; Kitajima, Mariko; Takayama, Hiromitsu (2011). "Asymmetric Total
Synthesis of a Pentacyclic
3906:
3661:
3289:
2524:
2053:
504:
1451:
3267:
3230:
3203:
2118:
1581:
644:
867:
3327:
1621:
1587:
1540:
1354:
1222:
1015:
626:
241:
557:
3901:
3673:
3628:
3501:
3490:
3471:
3274:
2927:
1294:
272:
2829:
652:
552:
3316:
2758:
1927:
1818:
1811:
773:
760:
1363:
3512:
182:
2260:(2012). "The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds".
3643:
3219:
1445:
910:
3528:
1348:
687:
542:
3732:
3464:
3422:
2540:
Gibson, Susan E.; Stevenazzi, Andrea (2003). "The Pauson–Khand
Reaction: The Catalytic Age Is Here!".
2319:
2262:
2253:
170:
3617:
3536:
3256:
2749:
2223:
1847:
Like many metal carbonyls, dicobalt octacarbonyl abstracts halides from alkyl halides. Upon reaction with
918:
3586:
3196:
3166:
3154:
2582:
2542:
2420:
2385:
1590:
1329:
1069:
883:
580:
547:
535:
63:
2354:
Nicholas, Kenneth M. (1987). "Chemistry and synthetic utility of cobalt-complexed propargyl cations".
1260:
Salts of this form are also intermediates in the cyanide synthesis pathway for dicobalt octacarbonyl.
3636:
3346:
2625:
2428:
1987:
1459:
1417:
1137:
829:
2116:(1977). "Infrared spectra of matrix-isolated dicobalt octacarbonyl. Evidence for the third isomer".
289:
3245:
3016:
2856:
Nestle, Mara O.; Hallgren, John E.; Seyferth, Dietmar; Dawson, Peter; Robinson, Brian H. (2007). "μ
1568:
1095:
1003:
825:
614:
91:
1494:
1388:
3238:
2444:
1729:
1577:
1429:
1268:
Halogens and related reagents cleave the Co–Co bond to give pentacoordinated halotetracarbonyls:
821:
618:
636:
3376:
3088:
3038:
2882:
2807:
2629:
2617:
2598:
2558:
2520:
2481:
2336:
2279:
2197:
2185:
2161:
2113:
2085:
2049:
1999:
1807:
1467:
1463:
1325:
1030:
914:
798:
804:
152:
3381:
3354:
3093:
2874:
2838:
2799:
2767:
2728:
2714:
2689:
2660:
2651:
2590:
2550:
2512:
2473:
2436:
2394:
2365:
2328:
2271:
2232:
2153:
2127:
2041:
1991:
1662:
1502:
1441:
1410:
1217:
Dicobalt octacarbonyl is reductively cleaved by alkali metals and related reagents, such as
961:
922:
594:
442:
371:
2418:; Khand, I. U. (1977). "Uses of Cobalt-Carbonyl Acetylene Complexes in Organic Synthesis".
1340:. The alkyne reacts first with dicobalt octacarbonyl, from which is generated a stabilized
250:
101:
3445:
3106:
3050:
3046:
3009:
3000:
2710:
2502:(1991). "The Pauson–Khand Cycloaddition Reaction for Synthesis of Cyclopentenones".
2465:
2356:
1919:
1674:
1536:
1506:
1498:
1026:
934:
2754:"Organometallic chemistry at the threshold of a new millennium. Retrospect and prospect"
2432:
1980:; Stambuli, James P.; Chou, Teh-Chang; Hong, Bor-Cherng (2014). "Octacarbonyldicobalt".
1720:. These bulky derivatives are more selective catalysts for hydroformylation reactions. "
1109:) but with one fewer bridging carbonyl. The Co–Co distance is 2.52 Å, and the Co–CO
293:
174:
3788:
3654:
3482:
3456:
3408:
3188:
3147:
3140:
3132:
3033:
3023:
2950:
2499:
2440:
2193:
1371:
1218:
1091:
898:
838:
632:
453:
2398:
35:
3895:
2866:
2842:
2803:
2257:
1606:
1597:
1432:, Takayama and co-workers used an intramolecular Pauson–Khand reaction to cyclise an
957:
431:
421:
163:
2448:
2150:
Dicobalt
Octacarbonyl, Cobalt Nitrosyl Tricarbonyl, and Cobalt Tetracarbonyl Hydride
1413:
for the alkyne. This complex itself can also be used in the Pauson–Khand reaction.
2965:
2901:
2415:
1977:
1804:
940:, although multiple structural isomers are known. Some of the carbonyl ligands are
602:
2045:
2034:
Donaldson, John Dallas; Beyersmann, Detmar (2005). "Cobalt and Cobalt
Compounds".
1995:
214:
640:
2664:
2516:
2504:
1721:
1337:
737:
713:
2878:
2157:
2912:
2237:
2218:
1956:
1915:
1574:
1422:
1059:
953:
392:
143:
2772:
2753:
2081:
1848:
1686:
1341:
586:
261:
2919:
2602:
2594:
2562:
2554:
2485:
2340:
2283:
1485:
Asymmetric diphenylacetylene cyclotrimerization using dicobalt octacarbonyl
610:
1477:
Symmetric diphenylacetylene cyclotrimerization using dicobalt octacarbonyl
1385:, though newer methods that are more efficient have since been developed:
3098:
2795:
1725:
1670:
1658:
1517:
1426:
941:
926:
906:
700:
693:
686:
659:
2732:
2369:
2131:
1347:
that reacts with the incoming nucleophile and the product then forms by
3028:
2275:
1783:
1555:
999:
902:
411:
201:
183:
50:
2693:
1054:. In solution, there are two isomers known that rapidly interconvert:
598:
2477:
2332:
1666:
1406:
1367:
1344:
1333:
1297:
is produced by treatment of dicobalt octacarbonyl with nitric oxide:
1051:
937:
930:
469:
837:
Except where otherwise noted, data are given for materials in their
590:
2717:(1961). "The Reaction of Cobalt Hydrotetracarbonyl with Olefins".
1493:
1433:
486:
476:
225:
131:
124:
114:
2217:
Sumner, G. Gardner; Klug, Harold P.; Alexander, Leroy E. (1964).
786:
606:
2923:
2790:
1561:
The alkene ligand inserts into the cobalt–hydride bond
1480:
1472:
1450:
1387:
1353:
1058:
277:
671:
426:
51 to 52 °C (124 to 126 °F; 324 to 325 K)
2827:
Chini, P. (1968). "The closed metal carbonyl clusters".
1409:
to form a stable covalent complex, which is useful as a
998:
The preparation is often carried out in the presence of
2186:"Hydrogenation of Organic Compounds with Synthesis Gas"
1006:(II) complex that reacts with carbon monoxide to yield
855:
2152:. Inorganic Syntheses. Vol. 2. pp. 238–243.
1332:
whereby an alkoxy group located on the α-carbon of an
1961:
National
Institute for Occupational Safety and Health
1924:
National
Institute for Occupational Safety and Health
2107:
2105:
2103:
2101:
1677:for this hydroformylation is shown in the diagram.
1370:, an alkene, and carbon monoxide cyclize to give a
1050:It exist as a mixture of rapidly interconverting
2219:"The crystal structure of dicobalt octacarbonyl"
1817:Heating causes decarbonylation and formation of
436:52 °C (126 °F; 325 K) decomposes
213:
3912:Chemical compounds containing metal–metal bonds
1593:the aldehyde product, regenerating the catalyst
675:
100:
2037:Ullmann's Encyclopedia of Industrial Chemistry
1983:Encyclopedia of Reagents for Organic Synthesis
956:solid. It is synthesised by the high pressure
2935:
2071:
2069:
2067:
2065:
1685:The CO ligands can be replaced with tertiary
8:
2913:CDC - NIOSH Pocket Guide to Chemical Hazards
2148:Gilmont, Paul; Blanchard, Arthur A. (1946).
356:O=C=(=C=O)(=C=O)(=C=O)(=C=O)(=C=O)(=C=O)=C=O
351:O=C=1(=C=O)(=C=O)C(=O)(=C=O)(=C=O)(=C=O)C1=O
2785:
2783:
1068:The major isomer (on the left in the above
2942:
2928:
2920:
2792:Comprehensive Organometallic Chemistry III
2744:
2742:
1866:, by a reaction that can be idealised as:
292:
173:
151:
18:
2771:
2236:
2179:
2177:
2029:
2027:
2025:
2023:
2021:
2019:
2017:
2015:
1564:An additional carbonyl ligand coordinates
1221:. The resulting salts protonate to give
952:Dicobalt octacarbonyl an orange-colored,
921:. It is the parent member of a family of
249:
2720:Journal of the American Chemical Society
2681:Journal of the American Chemical Society
1972:
1970:
1955:NIOSH Pocket Guide to Chemical Hazards.
1910:
1906:
1892:
1888:
1884:
1880:
1876:
1872:
1862:
1858:
1839:
1835:
1831:
1827:
1798:
1794:
1782:
1770:
1766:
1762:
1758:
1754:
1750:
1746:
1742:
1738:
1714:
1710:
1704:
1692:
1649:
1645:
1641:
1637:
1626:
1616:
1612:
1547:
1527:
1523:
1512:
1401:
1397:
1381:
1377:
1311:
1307:
1303:
1286:
1282:
1278:
1274:
1252:
1248:
1239:
1235:
1231:
1128:
1124:
1105:
1101:
1083:
1079:
1075:
1043:
1039:
1021:
1009:
1002:, converting the cobalt(II) salt into a
990:
986:
982:
978:
974:
970:
893:
889:
383:
379:
2864:-Benzylidyne-Tris(Tricarbonylcobalt)".
2705:
2703:
2622:Fiesers' Reagents for Organic Synthesis
2078:Organometallics: A Concise Introduction
1938:
1153:
348:
317:InChI=1S/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2
313:
288:
2975:
2076:Elschenbroich, C.; Salzer, A. (1992).
1950:
1948:
1946:
1944:
1942:
327:InChI=1/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2
164:
3777:
2410:
2408:
320:Key: MQIKJSYMMJWAMP-UHFFFAOYSA-N
7:
2961:
2143:
2141:
1914:a volatile source of cobalt(0), is
1458:Dicobalt octacarbonyl can catalyze
330:Key: MQIKJSYMMJWAMP-UHFFFAOYAG
204:
2441:10.1111/j.1749-6632.1977.tb41819.x
14:
1810:compound structurally related to
1853:methylidynetricobaltnonacarbonyl
1788:Methylidynetricobaltnonacarbonyl
1571:into the cobalt–alkyl bond
1188:
1172:
1156:
1148:Isomers of dicobalt octacarbonyl
948:Synthesis, structure, properties
845:
556:
551:
546:
541:
34:
25:
2830:Inorganica Chimica Acta Reviews
1596:An unproductive and reversible
917:, and is central to much known
841:(at 25 °C , 100 kPa).
2804:10.1016/B0-08-045047-4/00096-0
1779:Conversion to higher carbonyls
505:Occupational safety and health
1:
2399:10.1016/S0040-4020(02)00315-0
2046:10.1002/14356007.a07_281.pub2
1996:10.1002/047084289X.ro001.pub3
1543:to form the active catalyst,
1029:gas at about 200 to 300
754:(US health exposure limits):
2843:10.1016/0073-8085(68)80013-0
1622:cobalt tetracarbonyl hydride
1541:cobalt tetracarbonyl hydride
1440:-butyldiphenylsilyl (TBDPS)
1264:Reactions with electrophiles
1223:tetracarbonyl cobalt hydride
1016:cobalt tetracarbonyl hydride
2665:10.1021/acs.chemrev.6b00144
2517:10.1002/0471264180.or040.01
1295:Cobalt tricarbonyl nitrosyl
1094:. This structure resembles
726:or concentration (LD, LC):
3928:
3779:
2879:10.1002/9780470132517.ch53
2759:Pure and Applied Chemistry
2158:10.1002/9780470132333.ch76
2080:(2nd ed.). Weinheim:
1819:tetracobalt dodecacarbonyl
1812:tetracobalt dodecacarbonyl
1665:– the conversion of
397:341.95 g/mol
2977:
2958:
2238:10.1107/S0365110X64001803
1014:. Acidification produces
835:
810:
748:
722:
522:
502:
497:
462:
364:
339:
304:
84:
76:
62:
57:
33:
24:
2580:Alkaloid: Huperzine-Q".
1922:upon decomposition. The
1238:+ 2 Na → 2 Na[Co(CO)
911:organometallic chemistry
627:Precautionary statements
2773:10.1351/pac200173020209
2618:"Dicobalt Octacarbonyl"
2320:Chemical Communications
2263:Chemical Communications
2184:Orchin, Milton (1953).
1466:and its derivatives to
1349:oxidative demetallation
1336:is replaced by another
817:Related metal carbonyls
3907:Organocobalt compounds
2595:10.1002/anie.201103550
2555:10.1002/anie.200200547
2224:Acta Crystallographica
1814:
1681:Substitution reactions
1603:
1486:
1478:
1455:
1392:
1374:, can be catalyzed by
1359:
1320:Reactions with alkynes
1063:
919:organocobalt chemistry
682:
458:0.7 mmHg (20 °C)
20:Dicobalt octacarbonyl
2626:John Wiley & Sons
2583:Angew. Chem. Int. Ed.
2543:Angew. Chem. Int. Ed.
2421:Ann. N. Y. Acad. Sci.
2190:Advances in Catalysis
1988:John Wiley & Sons
1786:
1497:
1484:
1476:
1454:
1391:
1364:Pauson–Khand reaction
1358:The Nicholas reaction
1357:
1330:substitution reaction
1062:
933:atoms bound to eight
884:organocobalt compound
880:Dicobalt octacarbonyl
744:15 mg/kg (oral, rat)
681:
518:Potential carcinogen
67:Octacarbonyldicobalt(
2628:. pp. 251–252.
2616:Ho, Tse-Lok (2016).
2254:Green, Malcolm L. H.
2252:Green, Jennifer C.;
2196:. pp. 385–415.
1724:" Lewis bases, e.g.
1460:alkyne trimerisation
1418:asymmetric synthesis
1251:] + H → H[Co(CO)
830:Nickel tetracarbonyl
664:(fire diamond)
2733:10.1021/ja01480a017
2433:1977NYASA.295....2P
2370:10.1021/ar00138a001
2270:(94): 11481–11503.
2132:10.1021/ic50168a037
2119:Inorganic Chemistry
1096:diiron nonacarbonyl
1004:pentacyanocobaltate
826:Diiron nonacarbonyl
443:Solubility in water
405:red-orange crystals
21:
3902:Carbonyl complexes
2860:-Methylidyne and μ
2798:. pp. 1–119.
2276:10.1039/c2cc35304k
2114:Brown, Theodore L.
1815:
1730:disproportionation
1657:This hydride is a
1604:
1567:A carbonyl ligand
1554:The cobalt centre
1487:
1479:
1468:hexaphenylbenzenes
1456:
1393:
1360:
1064:
868:Infobox references
822:Iron pentacarbonyl
811:Related compounds
789:(Immediate danger)
683:
19:
3889:
3888:
3883:
3882:
2727:(19): 4023–4027.
2715:Breslow, David S.
2694:10.1021/ja7106542
2688:(28): 8910–8912.
2659:(16): 9565–9627.
2589:(35): 8025–8028.
2549:(16): 1800–1810.
2393:(21): 4133–4170.
2327:(46): 7143–7145.
1990:. pp. 1–26.
1851:, it converts to
1588:dihidrydo complex
1539:dissociates from
1464:diphenylacetylene
1326:Nicholas reaction
1310:+ 2 NO → 2 Co(CO)
1285:→ 2 Br[Co(CO)
915:organic synthesis
886:with composition
876:Chemical compound
874:
873:
799:Safety data sheet
718:-23 °C (-9.4 °F)
581:Hazard statements
273:CompTox Dashboard
133:Interactive image
126:Interactive image
16:Chemical compound
3919:
3359:
2962:
2944:
2937:
2930:
2921:
2915:
2910:
2904:
2902:Cole Parmer MSDS
2899:
2893:
2892:
2853:
2847:
2846:
2824:
2818:
2817:
2787:
2778:
2777:
2775:
2746:
2737:
2736:
2711:Heck, Richard F.
2707:
2698:
2697:
2675:
2669:
2668:
2652:Chemical Reviews
2646:
2640:
2639:
2624:. Vol. 28.
2613:
2607:
2606:
2573:
2567:
2566:
2537:
2531:
2530:
2496:
2490:
2489:
2478:10.1039/b300976a
2459:
2453:
2452:
2412:
2403:
2402:
2380:
2374:
2373:
2351:
2345:
2344:
2333:10.1039/b915083h
2294:
2288:
2287:
2249:
2243:
2242:
2240:
2214:
2208:
2207:
2181:
2172:
2171:
2145:
2136:
2135:
2112:Sweany, Ray L.;
2109:
2096:
2095:
2073:
2060:
2059:
2031:
2010:
2009:
1978:Pauson, Peter L.
1974:
1965:
1964:
1952:
1913:
1895:
1891:+ 36 CO + 6 CoBr
1865:
1843:
1802:
1801:
1774:
1719:
1703:
1702:
1699:
1689:ligands to give
1663:hydroformylation
1653:
1648:→ 2 H[Co(CO)
1630:
1619:
1551:
1550:
1531:
1515:
1503:hydroformylation
1490:Hydroformylation
1411:protective group
1404:
1384:
1315:
1290:
1256:
1243:
1192:
1176:
1160:
1131:
1108:
1086:
1046:
1038:2 Co + 8 CO → Co
1024:
1013:
994:
929:consists of two
925:catalysts. Each
923:hydroformylation
896:
858:
852:
849:
848:
703:
696:
689:
674:
654:
650:
646:
642:
638:
634:
620:
616:
612:
608:
604:
600:
596:
592:
588:
560:
555:
550:
545:
386:
372:Chemical formula
297:
296:
281:
279:
253:
217:
206:
185:
177:
166:
155:
135:
128:
104:
38:
29:
22:
3927:
3926:
3922:
3921:
3920:
3918:
3917:
3916:
3892:
3891:
3890:
3885:
3884:
3792:
3736:
3681:
3677:
3669:
3665:
3660:
3658:
3653:
3651:
3647:
3642:
3640:
3632:
3627:
3625:
3621:
3613:
3609:
3605:
3601:
3597:
3592:
3590:
3570:
3532:
3524:
3520:
3516:
3511:
3509:
3505:
3500:
3498:
3494:
3486:
3481:
3479:
3475:
3470:
3468:
3460:
3455:
3453:
3449:
3441:
3437:
3433:
3428:
3426:
3412:
3402:
3385:
3360:
3357:
3350:
3342:
3338:
3333:
3331:
3326:
3324:
3320:
3315:
3313:
3309:
3301:
3297:
3293:
3288:
3286:
3282:
3278:
3273:
3271:
3266:
3264:
3260:
3255:
3253:
3249:
3244:
3242:
3234:
3229:
3227:
3223:
3215:
3211:
3207:
3202:
3200:
3192:
3187:
3185:
3181:
3177:
3172:
3170:
3162:
3158:
3153:
3151:
3146:
3144:
3136:
3126:
3110:
3105:
3102:
3078:
3074:
3070:
3054:
3049:
3045:
3042:
3022:
3020:
3015:
3013:
3004:
2996:
2992:
2969:
2954:
2948:
2918:
2911:
2907:
2900:
2896:
2889:
2863:
2859:
2855:
2854:
2850:
2826:
2825:
2821:
2814:
2794:. Vol. 7.
2789:
2788:
2781:
2748:
2747:
2740:
2709:
2708:
2701:
2677:
2676:
2672:
2648:
2647:
2643:
2636:
2615:
2614:
2610:
2575:
2574:
2570:
2539:
2538:
2534:
2527:
2500:Schore, Neil E.
2498:
2497:
2493:
2466:Chem. Soc. Rev.
2461:
2460:
2456:
2414:
2413:
2406:
2382:
2381:
2377:
2357:Acc. Chem. Res.
2353:
2352:
2348:
2316:
2312:
2308:
2304:
2300:
2296:
2295:
2291:
2251:
2250:
2246:
2216:
2215:
2211:
2204:
2192:. Vol. 5.
2183:
2182:
2175:
2168:
2147:
2146:
2139:
2111:
2110:
2099:
2092:
2075:
2074:
2063:
2056:
2033:
2032:
2013:
2006:
1976:
1975:
1968:
1954:
1953:
1940:
1936:
1920:carbon monoxide
1912:
1908:
1904:
1902:
1894:
1890:
1886:
1882:
1878:
1874:
1870:
1864:
1860:
1856:
1841:
1837:
1833:
1829:
1825:
1800:
1796:
1792:
1791:
1781:
1772:
1768:
1764:
1760:
1756:
1752:
1748:
1744:
1740:
1736:
1718:
1712:
1708:
1700:
1697:
1696:
1694:
1690:
1683:
1675:catalytic cycle
1651:
1647:
1643:
1639:
1635:
1628:
1624:
1618:
1614:
1610:
1602:
1549:
1545:
1544:
1537:Carbon monoxide
1529:
1525:
1521:
1514:
1510:
1507:terminal alkene
1499:Catalytic cycle
1492:
1403:
1399:
1395:
1383:
1379:
1375:
1322:
1313:
1309:
1305:
1301:
1288:
1284:
1280:
1276:
1272:
1266:
1254:
1250:
1246:
1241:
1237:
1233:
1229:
1215:
1210:
1205:
1204:
1203:
1200:
1198:
1193:
1184:
1182:
1177:
1168:
1166:
1161:
1150:
1149:
1141:
1135:
1130:
1126:
1122:
1116:
1112:
1107:
1103:
1099:
1090:
1085:
1081:
1077:
1073:
1045:
1041:
1037:
1027:carbon monoxide
1023:
1019:
1011:
1007:
992:
988:
984:
980:
977:Co + 8 CO + 2 H
976:
972:
968:
950:
935:carbon monoxide
895:
891:
887:
877:
870:
865:
864:
863: ?)
854:
850:
846:
842:
828:
824:
818:
790:
777:
764:
741:
735:
708:
707:
706:
705:
698:
691:
684:
680:
672:
629:
583:
569:
538:
515:
492:
484:
482:
472:
445:
406:
385:
381:
377:
374:
360:
357:
352:
347:
346:
335:
332:
331:
328:
322:
321:
318:
312:
311:
300:
282:
275:
256:
236:
220:
207:
195:
158:
138:
118:
107:
94:
80:
72:
53:
48:
44:
39:
17:
12:
11:
5:
3925:
3923:
3915:
3914:
3909:
3904:
3894:
3893:
3887:
3886:
3881:
3880:
3877:
3874:
3871:
3868:
3865:
3862:
3859:
3856:
3853:
3850:
3847:
3844:
3841:
3838:
3834:
3833:
3830:
3827:
3824:
3821:
3818:
3815:
3812:
3809:
3806:
3803:
3800:
3797:
3794:
3790:
3786:
3782:
3781:
3778:
3775:
3774:
3771:
3768:
3765:
3762:
3759:
3756:
3753:
3750:
3747:
3744:
3741:
3738:
3734:
3730:
3727:
3724:
3721:
3718:
3715:
3711:
3710:
3707:
3704:
3701:
3698:
3695:
3692:
3689:
3686:
3683:
3679:
3675:
3671:
3667:
3663:
3656:
3649:
3645:
3638:
3634:
3630:
3623:
3619:
3615:
3611:
3607:
3603:
3599:
3595:
3588:
3584:
3581:
3578:
3575:
3572:
3568:
3564:
3560:
3559:
3556:
3553:
3550:
3547:
3544:
3541:
3538:
3534:
3530:
3526:
3522:
3518:
3514:
3507:
3503:
3496:
3492:
3488:
3484:
3477:
3473:
3466:
3462:
3458:
3451:
3447:
3443:
3439:
3435:
3431:
3424:
3420:
3417:
3414:
3410:
3406:
3404:
3400:
3396:
3392:
3391:
3388:
3383:
3379:
3374:
3371:
3368:
3365:
3362:
3356:
3352:
3348:
3344:
3340:
3336:
3329:
3322:
3318:
3311:
3307:
3303:
3299:
3295:
3291:
3284:
3280:
3276:
3269:
3262:
3258:
3251:
3247:
3240:
3236:
3232:
3225:
3221:
3217:
3213:
3209:
3205:
3198:
3194:
3190:
3183:
3179:
3175:
3168:
3164:
3160:
3156:
3149:
3142:
3138:
3134:
3130:
3128:
3124:
3120:
3116:
3115:
3112:
3108:
3100:
3096:
3091:
3086:
3083:
3080:
3076:
3072:
3068:
3064:
3060:
3059:
3056:
3052:
3040:
3036:
3031:
3026:
3018:
3011:
3007:
3002:
2998:
2994:
2990:
2986:
2982:
2981:
2978:
2976:
2974:
2972:
2967:
2960:
2959:
2956:
2955:
2951:Metal carbonyl
2949:
2947:
2946:
2939:
2932:
2924:
2917:
2916:
2905:
2894:
2887:
2861:
2857:
2848:
2819:
2812:
2779:
2766:(2): 209–220.
2738:
2699:
2670:
2641:
2634:
2608:
2568:
2532:
2525:
2491:
2454:
2404:
2375:
2364:(6): 207–214.
2346:
2314:
2310:
2306:
2302:
2298:
2289:
2258:Parkin, Gerard
2244:
2231:(6): 732–742.
2209:
2202:
2194:Academic Press
2173:
2166:
2137:
2126:(2): 415–421.
2097:
2090:
2061:
2054:
2011:
2004:
1966:
1937:
1935:
1932:
1901:
1898:
1897:
1896:
1845:
1844:
1780:
1777:
1776:
1775:
1682:
1679:
1655:
1654:
1601:
1600:
1594:
1584:
1572:
1565:
1562:
1559:
1552:
1533:
1491:
1488:
1372:cyclopentenone
1366:, in which an
1321:
1318:
1317:
1316:
1292:
1291:
1265:
1262:
1258:
1257:
1244:
1219:sodium amalgam
1214:
1211:
1209:
1206:
1202:
1201:
1196:
1194:
1187:
1185:
1180:
1178:
1171:
1169:
1164:
1162:
1155:
1152:
1151:
1147:
1146:
1145:
1139:
1133:
1114:
1110:
1088:
1066:
1065:
1048:
1047:
996:
995:
960:of cobalt(II)
949:
946:
899:metal carbonyl
875:
872:
871:
866:
844:
843:
839:standard state
836:
833:
832:
819:
816:
813:
812:
808:
807:
802:
795:
794:
791:
785:
782:
781:
778:
772:
769:
768:
765:
759:
756:
755:
746:
745:
742:
733:
731:
728:
727:
720:
719:
716:
710:
709:
699:
692:
685:
670:
669:
668:
667:
665:
656:
655:
649:P304+P340+P310
630:
625:
622:
621:
584:
579:
576:
575:
570:
565:
562:
561:
539:
534:
531:
530:
520:
519:
516:
513:
510:
509:
500:
499:
495:
494:
490:
480:
473:
468:
465:
464:
460:
459:
456:
454:Vapor pressure
450:
449:
446:
441:
438:
437:
434:
428:
427:
424:
418:
417:
414:
408:
407:
403:
399:
398:
395:
389:
388:
375:
370:
367:
366:
362:
361:
359:
358:
355:
353:
350:
342:
341:
340:
337:
336:
334:
333:
329:
326:
325:
323:
319:
316:
315:
307:
306:
305:
302:
301:
299:
298:
290:DTXSID10895040
285:
283:
271:
268:
267:
264:
258:
257:
255:
254:
246:
244:
238:
237:
235:
234:
230:
228:
222:
221:
219:
218:
210:
208:
200:
197:
196:
194:
193:
189:
187:
179:
178:
168:
160:
159:
157:
156:
148:
146:
140:
139:
137:
136:
129:
121:
119:
112:
109:
108:
106:
105:
97:
95:
90:
87:
86:
82:
81:
78:
74:
73:
66:
60:
59:
55:
54:
46:
42:
40:
31:
30:
15:
13:
10:
9:
6:
4:
3:
2:
3924:
3913:
3910:
3908:
3905:
3903:
3900:
3899:
3897:
3878:
3875:
3872:
3869:
3866:
3863:
3860:
3857:
3854:
3851:
3848:
3845:
3842:
3839:
3836:
3835:
3831:
3828:
3825:
3822:
3819:
3816:
3813:
3810:
3807:
3804:
3801:
3798:
3795:
3793:
3787:
3784:
3783:
3776:
3772:
3769:
3766:
3763:
3760:
3757:
3754:
3751:
3748:
3745:
3742:
3739:
3737:
3731:
3728:
3725:
3722:
3719:
3716:
3713:
3712:
3708:
3705:
3702:
3699:
3696:
3693:
3690:
3687:
3684:
3682:
3672:
3670:
3659:
3652:
3641:
3635:
3633:
3626:
3616:
3614:
3591:
3585:
3582:
3579:
3576:
3573:
3571:
3565:
3562:
3561:
3557:
3554:
3551:
3548:
3545:
3542:
3539:
3537:
3535:
3533:
3527:
3525:
3510:
3499:
3489:
3487:
3480:
3469:
3463:
3461:
3454:
3444:
3442:
3427:
3421:
3418:
3415:
3413:
3407:
3405:
3403:
3397:
3394:
3393:
3389:
3387:
3380:
3378:
3375:
3372:
3369:
3366:
3363:
3361:
3353:
3351:
3345:
3343:
3332:
3325:
3314:
3304:
3302:
3287:
3272:
3265:
3254:
3243:
3237:
3235:
3228:
3218:
3216:
3201:
3195:
3193:
3186:
3171:
3165:
3163:
3152:
3145:
3139:
3137:
3131:
3129:
3127:
3121:
3118:
3117:
3113:
3111:
3104:
3097:
3095:
3092:
3090:
3087:
3084:
3081:
3079:
3065:
3062:
3061:
3057:
3055:
3048:
3044:
3037:
3035:
3032:
3030:
3027:
3025:
3021:
3014:
3008:
3006:
2999:
2997:
2987:
2984:
2983:
2979:
2973:
2971:
2964:
2963:
2957:
2952:
2945:
2940:
2938:
2933:
2931:
2926:
2925:
2922:
2914:
2909:
2906:
2903:
2898:
2895:
2890:
2888:9780470132517
2884:
2880:
2876:
2872:
2869:
2868:
2867:Inorg. Synth.
2852:
2849:
2844:
2840:
2836:
2832:
2831:
2823:
2820:
2815:
2813:9780080450476
2809:
2805:
2801:
2797:
2793:
2786:
2784:
2780:
2774:
2769:
2765:
2761:
2760:
2755:
2751:
2750:Halpern, Jack
2745:
2743:
2739:
2734:
2730:
2726:
2722:
2721:
2716:
2712:
2706:
2704:
2700:
2695:
2691:
2687:
2683:
2682:
2674:
2671:
2666:
2662:
2658:
2654:
2653:
2645:
2642:
2637:
2635:9781118942819
2631:
2627:
2623:
2619:
2612:
2609:
2604:
2600:
2596:
2592:
2588:
2585:
2584:
2579:
2572:
2569:
2564:
2560:
2556:
2552:
2548:
2545:
2544:
2536:
2533:
2528:
2522:
2518:
2514:
2510:
2507:
2506:
2501:
2495:
2492:
2487:
2483:
2479:
2475:
2471:
2468:
2467:
2458:
2455:
2450:
2446:
2442:
2438:
2434:
2430:
2426:
2423:
2422:
2417:
2416:Pauson, P. L.
2411:
2409:
2405:
2400:
2396:
2392:
2388:
2387:
2379:
2376:
2371:
2367:
2363:
2359:
2358:
2350:
2347:
2342:
2338:
2334:
2330:
2326:
2322:
2321:
2293:
2290:
2285:
2281:
2277:
2273:
2269:
2265:
2264:
2259:
2255:
2248:
2245:
2239:
2234:
2230:
2226:
2225:
2220:
2213:
2210:
2205:
2203:9780080565095
2199:
2195:
2191:
2187:
2180:
2178:
2174:
2169:
2167:9780470132333
2163:
2159:
2155:
2151:
2144:
2142:
2138:
2133:
2129:
2125:
2121:
2120:
2115:
2108:
2106:
2104:
2102:
2098:
2093:
2091:3-527-28165-7
2087:
2083:
2079:
2072:
2070:
2068:
2066:
2062:
2057:
2051:
2047:
2043:
2040:. Wiley-VCH.
2039:
2038:
2030:
2028:
2026:
2024:
2022:
2020:
2018:
2016:
2012:
2007:
2005:9780470842898
2001:
1997:
1993:
1989:
1985:
1984:
1979:
1973:
1971:
1967:
1962:
1958:
1951:
1949:
1947:
1945:
1943:
1939:
1933:
1931:
1929:
1925:
1921:
1918:and releases
1917:
1899:
1869:
1868:
1867:
1854:
1850:
1824:
1823:
1822:
1820:
1813:
1809:
1806:
1789:
1785:
1778:
1753:→ 2 [Co(C
1735:
1734:
1733:
1731:
1727:
1723:
1717:
1707:
1688:
1680:
1678:
1676:
1672:
1668:
1664:
1660:
1634:
1633:
1632:
1623:
1608:
1607:Hydrogenation
1599:
1598:side reaction
1595:
1592:
1589:
1585:
1583:
1579:
1576:
1573:
1570:
1566:
1563:
1560:
1558:to the alkene
1557:
1553:
1542:
1538:
1535:
1534:
1519:
1508:
1504:
1500:
1496:
1489:
1483:
1475:
1471:
1469:
1465:
1461:
1453:
1449:
1447:
1443:
1439:
1436:containing a
1435:
1431:
1428:
1425:
1424:
1419:
1414:
1412:
1408:
1390:
1386:
1373:
1369:
1365:
1356:
1352:
1350:
1346:
1343:
1339:
1335:
1331:
1327:
1319:
1300:
1299:
1298:
1296:
1271:
1270:
1269:
1263:
1261:
1247:Na[Co(CO)
1245:
1228:
1227:
1226:
1224:
1220:
1212:
1207:
1191:
1186:
1179:non-bridged D
1175:
1170:
1159:
1154:
1144:
1142:
1118:
1097:
1093:
1071:
1061:
1057:
1056:
1055:
1053:
1036:
1035:
1034:
1032:
1028:
1017:
1005:
1001:
967:
966:
965:
963:
959:
958:carbonylation
955:
947:
945:
943:
939:
936:
932:
928:
924:
920:
916:
912:
908:
904:
901:is used as a
900:
885:
881:
869:
862:
857:
840:
834:
831:
827:
823:
820:
815:
814:
809:
806:
803:
800:
797:
796:
792:
788:
784:
783:
780:TWA 0.1 mg/m
779:
776:(Recommended)
775:
771:
770:
766:
763:(Permissible)
762:
758:
757:
753:
752:
747:
743:
739:
730:
729:
725:
721:
717:
715:
712:
711:
704:
697:
690:
666:
663:
662:
658:
657:
631:
628:
624:
623:
585:
582:
578:
577:
574:
571:
568:
564:
563:
559:
554:
549:
544:
540:
537:
533:
532:
528:
526:
521:
517:
512:
511:
507:
506:
501:
496:
488:
478:
474:
471:
470:Dipole moment
467:
466:
461:
457:
455:
452:
451:
447:
444:
440:
439:
435:
433:
432:Boiling point
430:
429:
425:
423:
422:Melting point
420:
419:
415:
413:
410:
409:
404:
401:
400:
396:
394:
391:
390:
376:
373:
369:
368:
363:
354:
349:
345:
338:
324:
314:
310:
303:
295:
291:
287:
286:
284:
274:
270:
269:
265:
263:
260:
259:
252:
248:
247:
245:
243:
240:
239:
232:
231:
229:
227:
224:
223:
216:
212:
211:
209:
203:
199:
198:
191:
190:
188:
186:
181:
180:
176:
172:
169:
167:
165:ECHA InfoCard
162:
161:
154:
150:
149:
147:
145:
142:
141:
134:
130:
127:
123:
122:
120:
116:
111:
110:
103:
99:
98:
96:
93:
89:
88:
83:
75:
70:
65:
61:
56:
52:
37:
32:
28:
23:
3305:
2908:
2897:
2870:
2865:
2851:
2834:
2828:
2822:
2791:
2763:
2757:
2724:
2718:
2685:
2679:
2673:
2656:
2650:
2644:
2621:
2611:
2586:
2581:
2577:
2571:
2546:
2541:
2535:
2508:
2503:
2494:
2472:(1): 32–42.
2469:
2464:
2457:
2424:
2419:
2390:
2384:
2378:
2361:
2355:
2349:
2324:
2318:
2292:
2267:
2261:
2247:
2228:
2222:
2212:
2189:
2149:
2123:
2117:
2077:
2035:
1981:
1903:
1846:
1816:
1805:organocobalt
1765:][Co(CO)
1715:
1705:
1684:
1656:
1625:H[Co(CO)
1605:
1582:acyl complex
1457:
1446:conformation
1437:
1421:
1415:
1405:reacts with
1394:
1361:
1323:
1293:
1267:
1259:
1216:
1195:nonbridged D
1119:
1067:
1049:
1008:K[Co(CO)
997:
951:
879:
878:
805:External SDS
750:
723:
660:
572:
524:
514:Main hazards
503:
226:RTECS number
85:Identifiers
77:Other names
68:
2873:: 226–229.
2505:Org. React.
2427:(1): 2–14.
2386:Tetrahedron
1928:recommended
1430:huperzine-Q
1342:propargylic
1338:nucleophile
1070:equilibrium
738:median dose
724:Lethal dose
714:Flash point
567:Signal word
508:(OHS/OSH):
402:Appearance
365:Properties
171:100.030.454
3896:Categories
3355:(Cu(CO)Cl)
2578:Lycopodium
2526:0471264180
2389:(Review).
2360:(Review).
2055:3527306730
1934:References
1916:pyrophoric
1591:eliminates
1575:Dihydrogen
1423:Lycopodium
954:pyrophoric
536:Pictograms
463:Structure
448:insoluble
416:1.87 g/cm
393:Molar mass
251:MDH533S43Q
144:ChemSpider
113:3D model (
102:10210-68-1
92:CAS Number
64:IUPAC name
49:soaked in
3335:HC(Co(CO)
3024:(HC=CH)CO
3017:(C=C)(CO)
2953:complexes
2837:: 31–51.
2082:Wiley-VCH
1849:bromoform
1687:phosphine
1671:aldehydes
1620:produces
1442:protected
1314:NO + 2 CO
1213:Reduction
1208:Reactions
1163:Bridged C
1132:and has D
1127:Co-Co(CO)
1113:and Co–CO
1087:and has C
653:P403+P233
527:labelling
262:UN number
233:GG0300000
192:233-514-0
184:EC Number
2796:Elsevier
2752:(2001).
2603:21751323
2563:12722067
2511:: 1–90.
2486:14737507
2449:84203764
2341:19921010
2284:23047247
1963:(NIOSH).
1883:→ 4 HCCo
1879:+ 4 CHBr
1745:N + 3 Co
1728:, cause
1726:pyridine
1659:catalyst
1569:migrates
1518:aldehyde
1516:) to an
1501:for the
1427:alkaloid
1111:terminal
1092:symmetry
1078:Co(μ-CO)
927:molecule
907:catalyst
661:NFPA 704
498:Hazards
493:isomer)
3780:
2429:Bibcode
1957:"#0147"
1808:cluster
1667:alkenes
1580:to the
1556:π bonds
1546:HCo(CO)
1420:of the
1407:alkynes
1052:isomers
1020:HCo(CO)
1000:cyanide
938:ligands
903:reagent
897:. This
861:what is
859: (
483:isomer)
412:Density
387:
202:PubChem
153:2007057
51:hexanes
3789:La(CO)
3733:Sg(CO)
3655:Os(CO)
3637:Os(CO)
3629:Re(CO)
3567:Ba(CO)
3529:Pd(CO)
3483:Ru(CO)
3465:Ru(CO)
3457:Tc(CO)
3438:Mo(CO)
3423:Mo(CO)
3399:Sr(CO)
3347:Ni(CO)
3328:Co(CO)
3298:Fe(CO)
3283:Fe(CO)
3268:Fe(CO)
3239:Fe(CO)
3231:Mn(CO)
3212:Cr(CO)
3197:Cr(CO)
3159:Ti(CO)
3148:Ti(CO)
3141:Ti(CO)
3133:Sc(CO)
3123:Ca(CO)
3107:(ClCO)
3047:H(CO)F
2885:
2810:
2632:
2601:
2561:
2523:
2484:
2447:
2339:
2282:
2200:
2164:
2088:
2052:
2002:
1900:Safety
1842:+ 4 CO
1773:+ 8 CO
1673:. The
1511:RCH=CH
1368:alkyne
1345:cation
1334:alkyne
1255:] + Na
1199:isomer
1183:isomer
1167:isomer
1115:bridge
1082:Co(CO)
989:+ 4 CH
942:labile
931:cobalt
882:is an
856:verify
853:
801:(SDS)
573:Danger
344:SMILES
58:Names
3587:W(CO)
3409:Y(CO)
3189:V(CO)
3182:V(CO)
3167:V(CO)
3051:(FCO)
3010:C(CO)
2445:S2CID
2305:in Co
1803:, an
1505:of a
1434:enyne
1328:is a
969:2 (CH
962:salts
793:N.D.
767:none
751:NIOSH
475:1.33
309:InChI
266:3281
215:25049
115:JSmol
69:Co—Co
3678:(CO)
3666:(CO)
3648:(CO)
3622:(CO)
3610:(CO)
3521:(CO)
3506:(CO)
3495:(CO)
3476:(CO)
3450:(CO)
3377:SeCO
3321:(CO)
3310:(CO)
3261:(CO)
3250:(CO)
3224:(CO)
3075:(CO)
3067:Mg(O
2993:(CO)
2883:ISBN
2808:ISBN
2630:ISBN
2599:PMID
2559:PMID
2521:ISBN
2482:PMID
2337:PMID
2325:2009
2309:(CO)
2301:(CO)
2280:PMID
2268:2012
2198:ISBN
2162:ISBN
2086:ISBN
2050:ISBN
2000:ISBN
1926:has
1909:(CO)
1887:(CO)
1875:(CO)
1871:9 Co
1861:(CO)
1857:HCCo
1838:(CO)
1834:→ Co
1830:(CO)
1826:2 Co
1797:(CO)
1793:HCCo
1749:(CO)
1737:12 C
1722:Hard
1695:(CO)
1661:for
1640:(CO)
1615:(CO)
1586:The
1578:adds
1438:tert
1400:(CO)
1380:(CO)
1362:The
1324:The
1306:(CO)
1281:+ Br
1277:(CO)
1234:(CO)
1123:(CO)
1104:(CO)
1074:(CO)
1042:(CO)
993:COOH
985:(CO)
981:→ Co
973:COO)
913:and
905:and
892:(CO)
787:IDLH
645:P280
641:P273
637:P260
633:P201
619:H412
615:H361
611:H351
607:H330
603:H317
599:H315
595:H304
591:H302
587:H251
382:(CO)
242:UNII
45:(CO)
3879:No
3876:Md
3873:Fm
3870:Es
3867:Cf
3864:Bk
3861:Cm
3858:Am
3855:Pu
3852:Np
3846:Pa
3843:Th
3840:Ac
3837:**
3832:Yb
3829:Tm
3826:Er
3823:Ho
3820:Dy
3817:Tb
3814:Gd
3811:Eu
3808:Sm
3805:Pm
3802:Nd
3799:Pr
3796:Ce
3773:Og
3770:Ts
3767:Lv
3764:Mc
3761:Fl
3758:Nh
3755:Cn
3752:Rg
3749:Ds
3746:Mt
3743:Hs
3740:Bh
3729:Db
3726:Rf
3723:Lr
3720:**
3717:Ra
3714:Fr
3709:Rn
3706:At
3703:Po
3700:Bi
3697:Pb
3694:Tl
3691:Hg
3688:Au
3685:Pt
3583:Ta
3580:Hf
3577:Lu
3563:Cs
3558:Xe
3552:Te
3549:Sb
3546:Sn
3543:In
3540:Cd
3419:Nb
3416:Zr
3395:Rb
3390:Kr
3373:As
3370:Ge
3367:Ga
3364:Zn
3114:Ar
3094:SCO
3089:PCO
3085:Si
3082:Al
3063:Na
3058:Ne
3034:OCO
3029:NCO
3005:BCO
2985:Li
2980:He
2875:doi
2839:doi
2800:doi
2768:doi
2729:doi
2690:doi
2686:130
2661:doi
2657:116
2591:doi
2551:doi
2513:doi
2474:doi
2437:doi
2425:295
2395:doi
2366:doi
2329:doi
2317:".
2272:doi
2233:doi
2154:doi
2128:doi
2042:doi
1992:doi
1709:(PR
1669:to
1644:+ H
1609:of
1530:CHO
1522:RCH
1462:of
1351:.
1031:atm
909:in
774:REL
761:PEL
525:GHS
278:EPA
205:CID
3898::
3849:U
3785:*
3680:12
3674:Ir
3668:10
3662:Os
3650:12
3644:Os
3624:10
3618:Re
3594:(C
3574:*
3555:I
3517:Cl
3513:Rh
3508:16
3502:Rh
3497:12
3491:Rh
3478:12
3472:Ru
3452:10
3446:Tc
3386:CO
3382:Br
3323:12
3317:Co
3306:Co
3263:12
3257:Fe
3246:Fe
3226:10
3220:Mn
3155:Cp
3119:K
3103:CO
3099:Cl
3043:CO
2989:Be
2970:CO
2881:.
2871:20
2833:.
2806:.
2782:^
2764:73
2762:.
2756:.
2741:^
2725:83
2723:.
2713:;
2702:^
2684:.
2655:.
2620:.
2597:.
2587:50
2557:.
2547:42
2519:.
2509:40
2480:.
2470:33
2443:.
2435:.
2407:^
2391:58
2362:20
2335:.
2323:.
2315:60
2278:.
2266:.
2256:;
2229:17
2227:.
2221:.
2188:.
2176:^
2160:.
2140:^
2124:16
2122:.
2100:^
2084:.
2064:^
2048:.
2014:^
1998:.
1986:.
1969:^
1959:.
1941:^
1905:Co
1855:,
1840:12
1821::
1790:,
1761:N)
1732::
1691:Co
1636:Co
1631::
1611:Co
1532:):
1526:CH
1448:.
1396:Co
1376:Co
1302:Co
1273:Co
1230:Co
1225::
1197:2d
1181:3d
1165:2v
1143:.
1140:60
1134:4d
1100:Fe
1089:2v
1033::
1018:,
964::
944:.
888:Co
734:50
732:LD
651:,
647:,
643:,
639:,
635:,
617:,
613:,
609:,
605:,
601:,
597:,
593:,
589:,
529::
491:3d
489:(D
485:0
481:2v
479:(C
378:Co
41:Co
3791:8
3735:6
3676:4
3664:3
3657:4
3646:3
3639:5
3631:5
3620:2
3612:6
3608:2
3606:W
3604:2
3602:)
3600:5
3598:H
3596:5
3589:6
3569:8
3531:4
3523:2
3519:2
3515:2
3504:6
3493:4
3485:4
3474:3
3467:5
3459:5
3448:2
3440:3
3436:8
3434:H
3432:7
3430:C
3425:6
3411:8
3401:8
3384:2
3358:n
3349:4
3341:3
3339:)
3337:3
3330:4
3319:4
3312:8
3308:2
3300:3
3296:4
3294:H
3292:4
3290:C
3285:3
3281:6
3279:H
3277:4
3275:C
3270:4
3259:3
3252:9
3248:2
3241:5
3233:5
3222:2
3214:3
3210:6
3208:H
3206:6
3204:C
3199:6
3191:6
3184:4
3180:5
3178:H
3176:5
3174:C
3169:6
3161:2
3157:2
3150:6
3143:7
3135:8
3125:8
3109:2
3101:2
3077:2
3073:2
3071:)
3069:3
3053:2
3041:2
3039:F
3019:2
3012:2
3003:3
3001:H
2995:4
2991:2
2968:2
2966:H
2943:e
2936:t
2929:v
2891:.
2877::
2862:3
2858:3
2845:.
2841::
2835:2
2816:.
2802::
2776:.
2770::
2735:.
2731::
2696:.
2692::
2667:.
2663::
2638:.
2605:.
2593::
2565:.
2553::
2529:.
2515::
2488:.
2476::
2451:.
2439::
2431::
2401:.
2397::
2372:.
2368::
2343:.
2331::
2313:C
2311:8
2307:2
2303:8
2299:2
2286:.
2274::
2241:.
2235::
2206:.
2170:.
2156::
2134:.
2130::
2094:.
2058:.
2044::
2008:.
1994::
1911:8
1907:2
1893:2
1889:9
1885:3
1881:3
1877:8
1873:2
1863:9
1859:3
1836:4
1832:8
1828:2
1799:9
1795:3
1771:2
1769:]
1767:4
1763:6
1759:5
1757:H
1755:5
1751:8
1747:2
1743:5
1741:H
1739:5
1716:x
1713:)
1711:3
1706:x
1701:8
1698:−
1693:2
1652:]
1650:4
1646:2
1642:8
1638:2
1629:]
1627:4
1617:8
1613:2
1548:3
1528:2
1524:2
1520:(
1513:2
1509:(
1402:8
1398:2
1382:8
1378:2
1312:3
1308:8
1304:2
1289:]
1287:4
1283:2
1279:8
1275:2
1253:4
1249:4
1242:]
1240:4
1236:8
1232:2
1138:C
1129:4
1125:4
1106:9
1102:2
1098:(
1084:3
1080:2
1076:3
1044:8
1040:2
1022:4
1012:]
1010:4
991:3
987:8
983:2
979:2
975:2
971:3
894:8
890:2
851:N
740:)
736:(
702:1
695:3
688:4
487:D
477:D
384:8
380:2
280:)
276:(
117:)
71:)
47:8
43:2
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.