252:
159:
408:
24:
727:
Gagne, R. R.; Spiro, C. L.; Smith, T. J.; Hamann, C. A.; Thies, W. R.; Shiemke, A. D. (1981). "The
Synthesis, Redox Properties, and Ligand Binding of Heterobinuclear Transition-Metal Macrocyclic Ligand Complexes. Measurement of an Apparent Delocalization Energy in a Mixed-Valent CuCu Complex".
416:
388:
482:
787:
291:
478:
595:
688:
Thompson, Laurence K.; Mandal, Sanat K.; Tandon, Santokh S.; Bridson, John N.; Park, Murray K. (1996). "Magnetostructural
Correlations in Bis(μ
599:
804:
692:-phenoxide)-Bridged Macrocyclic Dinuclear Copper(II) Complexes. Influence of Electron-Withdrawing Substituents on Exchange Coupling".
266:
96:
470:
529:
452:
209:
826:
230:
506:
617:
The corresponding reaction of phenol would be expected to lead to formylation of the 4-position vs 2,6-selectivity.
407:
166:
602:
reactions, hence double-addition to a phenol requires forcing conditions. Diformylcresol may be prepared from
498:
494:
607:
486:
154:
755:
116:
758:(July 1998). "Mono- and Diformylation of 4-Substituted Phenols: A New Application of the Duff Reaction".
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649:"Redetermination of the crystal structure of 2,6-diformyl-4-methylphenol, at 200 K, C9H8O3"
490:
218:
136:
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474:
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158:
72:
523:
820:
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373:
147:
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Habarurema, Gratien; Gerber, Thomas I. A.; Hosten, Eric; Betz, Richard (2014).
502:
342:
127:
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23:
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363:
185:
167:
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436:
107:
571:
is the most common isomer and is a white solid at room temperature.
522:
Except where otherwise noted, data are given for materials in their
95:
85:
510:
235:
785:
Brühne, Friedrich; Wright, Elaine (2011). "Benzaldehyde".
275:
InChI=1S/C9H8O3/c1-6-2-7(4-10)9(12)8(3-6)5-11/h2-5,12H,1H3
653:
197:
71:
788:Ullmann's Encyclopedia of Industrial Chemistry
629:, a phenol with only one flanking formyl group
50:2-hydroxy-5-methyl-1,3-benzenedicarboxaldehyde
574:Diformylcresol condenses with amines to give
8:
250:
157:
135:
15:
664:
217:
730:Journal of the American Chemical Society
639:
296:
271:
246:
378:113 °C (235 °F; 386 K)
148:
278:Key: ZBOUXALQDLLARY-UHFFFAOYSA-N
115:
7:
564:OH. The 2,6-diformyl derivative of
600:electrophilic aromatic substitution
188:
40:2-hydroxy-5-methylisophthalaldehyde
14:
406:
326:
22:
526:(at 25 °C , 100 kPa).
332:
320:
1:
797:10.1002/14356007.a03_463.pub2
578:that are widely studied as
48:2,6-diformyl-4-methylphenol
848:
520:
387:
382:
307:
299:CC1=CC(=C(C(=C1)C=O)O)C=O
287:
262:
55:
45:
35:
30:
21:
453:Precautionary statements
791:. Weinheim: Wiley-VCH.
608:Reimer-Tiemann reaction
666:10.1515/ncrs-2014-0171
594:) are fairly strong
580:binucleating ligands
772:10.1055/s-1998-2110
742:10.1021/ja00404a017
694:Inorganic Chemistry
596:deactivating groups
548:with the formula CH
350: g·mol
18:
827:Aromatic aldehydes
756:Lindoy, Leonard F.
530:Infobox references
16:
736:(14): 4073–4081.
706:10.1021/IC9514197
700:(11): 3117–3125.
621:Related compounds
538:Chemical compound
536:
535:
431:Hazard statements
231:CompTox Dashboard
97:Interactive image
839:
811:
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776:
775:
766:(7): 1029–1032.
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546:organic compound
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315:Chemical formula
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627:salicylaldehyde
623:
606:-cresol by the
590:Formyl groups (
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17:Diformylcresol
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806:978-3527306732
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659:(4): 331–332.
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542:Diformylcresol
537:
534:
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524:standard state
521:
518:
517:
483:P305+P351+P338
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612:Duff reaction
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374:Melting point
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149:ECHA InfoCard
146:
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134:
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117:ChEMBL3904097
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573:
566:
541:
540:
422:
389:
358:white solid
56:Identifiers
46:Other names
417:Signal word
368:1.433 g/cm
355:Appearance
308:Properties
155:100.027.971
821:Categories
634:References
401:Pictograms
343:Molar mass
219:V6R37R6AU3
128:ChemSpider
84:3D model (
63:CAS Number
37:IUPAC name
760:Synthesis
592:aldehydes
586:Synthesis
507:P403+P233
499:P337+P313
495:P332+P313
479:P304+P340
475:P302+P352
392:labelling
176:230-768-4
168:EC Number
73:7310-95-4
714:11666507
675:93304005
576:diimines
383:Hazards
832:Phenols
610:or the
569:-cresol
423:Warning
364:Density
348:164.160
186:PubChem
803:
712:
673:
544:is an
292:SMILES
108:ChEMBL
31:Names
671:S2CID
560:(CHO)
267:InChI
199:81744
137:73760
86:JSmol
801:ISBN
764:1998
710:PMID
598:for
515:P501
511:P405
503:P362
491:P321
487:P312
471:P280
467:P271
463:P264
459:P261
445:H335
441:H319
437:H315
210:UNII
793:doi
768:doi
738:doi
734:103
702:doi
661:doi
657:229
390:GHS
236:EPA
189:CID
823::
799:.
762:.
732:.
708:.
698:35
696:.
669:.
655:.
651:.
614:.
582:.
513:,
509:,
505:,
501:,
497:,
493:,
489:,
485:,
481:,
477:,
473:,
469:,
465:,
461:,
443:,
439:,
394::
809:.
795::
774:.
770::
744:.
740::
716:.
704::
690:2
677:.
663::
604:p
567:p
562:2
558:2
556:H
554:6
552:C
550:3
336:3
333:O
330:8
327:H
324:9
321:C
238:)
234:(
88:)
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