185:
335:
24:
531:
Anteunis, M. (1962). "Studies of the
Grignard Reaction. II. Kinetics of the Reaction of Dimethylmagnesium with Benzophenone and of Methylmagnesium Bromide-Magnesium Bromide with Pinacolone".
348:
484:
The linear chain structure seen for dimethylmagnesium is also observed for diethylmagnesium and dimethylberyllium. Di(tert-butyl)magnesium is however a dimer.
224:
669:
Houben-Weyl
Methods of Organic Chemistry Vol. XIII/2a, 4th Edition Organometallic Compounds of Group II of the Periodic Table (except mercury)
703:
677:
579:
830:
199:
835:
355:
142:
476:, featuring tetrahedral magnesium centres, each surrounded by bridging methyl groups. The Mg-C distances are 224 pm.
163:
793:
Starowieyski, Kazimierz B.; Lewinski, Janusz; Wozniak, Robert; Lipkowski, Janusz; Chrost, Andrzej (2003). "Di-
391:
371:
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Fischer, Reinald; Görls, Helmar; Meisinger, Philippe R.; Suxdorf, Regina; Westerhausen, Matthias (2019).
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620:"Structure–Solubility Relationship of 1,4-Dioxane Complexes of Di(hydrocarbyl)magnesium"
184:
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422:
In such procedures, the dimethylmagnesium exists as the ether adduct, not the polymer.
326:
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533:
778:
131:
504:(1935). "The Preparation of Dialkylmagnesium Compounds from Grignard Reagents".
426:
571:
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Like other dialkylmagnesium compounds, dimethylmagnesium is prepared by adding
378:
solid. Dimethylmagnesium is used in the synthesis of organometallic compounds.
769:
375:
272:
97:
453:
Mg. Related methods have been applied to other dialkylmagnesium compounds.
653:
635:
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517:
387:
285:
118:
810:
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Except where otherwise noted, data are given for materials in their
746:
85:
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23:
168:
472:. The material is a polymer with the same connectivity as
566:. Inorganic Syntheses. Vol. 19. pp. 262–265.
343:
468:
The structure of this compound has been determined by
672:(in German), Georg Thieme Verlag, 2014, p. 215,
456:
Dimethylmagnesium can also be prepared by combining
562:Richard A. Andersen, Geoffrey Wilkinson (1979).
130:
61:
613:
611:
8:
797:-butylmagnesium: Synthesis and Structure".
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698:(in German), CRC Press, p. 2273,
695:Dictionary of Organometallic Compounds
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211:Key: KZLUHGRPVSRSHI-UHFFFAOYSA-N
7:
121:
14:
441:. This precipitation drives the
429:causes precipitation of solid MgX
265:
333:
259:
22:
329:(at 25 °C , 100 kPa).
624:Chemistry – A European Journal
253:
1:
733:10.1016/S0022-328X(00)82217-2
402:MgX + 2 dioxane ⇌ (CH
857:
692:Jane E. Macintyre (1994),
572:10.1002/9780470132500.ch61
831:Organomagnesium compounds
770:10.1107/S0365110X51001100
323:
306:
240:
220:
195:
45:
35:
30:
21:
372:organomagnesium compound
208:InChI=1S/2CH3.Mg/h2*1H3;
779:2027/mdp.39015095081207
749:Acta Crystallographica
636:10.1002/chem.201903120
392:methylmagnesium halide
470:X-ray crystallography
836:Pyrophoric materials
439:coordination polymer
762:1951AcCry...4..348S
721:J. Organomet. Chem.
630:(55): 12830–12841.
546:10.1021/jo01049a060
518:10.1021/ja01314a059
443:Schlenk equilibrium
297:Solubility in water
280: g·mol
18:
356:Infobox references
307:Related compounds
17:Dimethylmagnesium
16:
811:10.1021/om030091j
805:(12): 2458–2463.
705:978-0-412-43060-2
679:978-3-13-180654-3
581:978-0-471-04542-7
512:(11): 2238–2240.
480:Related compounds
474:silicon disulfide
390:to a solution of
368:Dimethylmagnesium
364:Chemical compound
362:
361:
313:Related compounds
164:CompTox Dashboard
87:Interactive image
40:Dimethylmagnesium
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506:J. Am. Chem. Soc
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374:. It is a white
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318:Dibutylmagnesium
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248:Chemical formula
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799:Organometallics
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460:and magnesium.
458:dimethylmercury
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727:(4): 314–321.
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756:(4): 348–52.
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564:Bis Magnesium
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534:J. Org. Chem.
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425:Addition of
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367:
366:
46:Identifiers
502:Cope, A. C.
433:(μ-dioxane)
427:1,4-dioxane
414:(μ-dioxane)
382:Preparation
290:0.96 g/cm3
241:Properties
825:Categories
488:References
464:Properties
445:toward (CH
410:Mg + MgX
376:pyrophoric
273:Molar mass
152:3CAY272DHS
98:ChemSpider
74:3D model (
53:CAS Number
37:IUPAC name
600:ignored (
590:cite book
63:2999-74-8
841:Polymers
654:31328293
107:10430979
758:Bibcode
645:7027550
388:dioxane
349:what is
347: (
302:Reacts
286:Density
119:PubChem
702:
676:
652:
642:
578:
370:is an
344:verify
341:
278:54.375
225:SMILES
31:Names
200:InChI
132:18141
76:JSmol
795:tert
700:ISBN
674:ISBN
650:PMID
602:help
576:ISBN
437:, a
398:2 CH
143:UNII
807:doi
774:hdl
766:doi
729:doi
640:PMC
632:doi
568:doi
542:doi
514:doi
169:EPA
122:CID
827::
803:22
801:.
772:.
764:.
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628:25
626:.
622:.
610:^
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592:}}
588:{{
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538:27
510:57
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266:Mg
232:CC
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731::
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634::
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520:.
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451:2
449:)
447:3
435:2
431:2
418:↓
416:2
412:2
408:2
406:)
404:3
400:3
339:N
263:6
260:H
257:2
254:C
171:)
167:(
78:)
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