Knowledge (XXG)

Di-n-propyl ether

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Due to the shock and light sensitive nature of organic peroxides, dipropyl ether should never be boiled or evaporated to dryness. This concentrates peroxides that may be present, which can then detonate unexpectedly destroying the vessel in which they have deposited or igniting nearby flammable
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O'Neil, Maryadele; Heckelman, Patricia; Koch, Cherie; Roman, Kristin, eds. (2006).
529:(a strong acid) and heat, in the same way other symmetrical ethers may be formed. 183: 456: 519: 334: 130: 17: 443: 436: 429: 402: 355: 170: 498: 467:
Except where otherwise noted, data are given for materials in their
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As is typical of ethers, dipropyl ether may slowly form explosive
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Dipropyl ether can be synthesized by reacting two molecules of
220: 414: 578:are often added to ethers to prevent this process. 574:over long periods in storage. Antioxidants such as 719:Canadian Centre for Occupational Health and Safety 182: 418: 94: 644:(14th ed.). Merck Research Laboratories. 537:This ether may also be prepared by way of the 8: 626:Institute for Occupational Safety and Health 260:InChI=1S/C6H14O/c1-3-5-7-6-4-2/h3-6H2,1-2H3 270:InChI=1/C6H14O/c1-3-5-7-6-4-2/h3-6H2,1-2H3 235: 160: 138: 26: 202: 613: 611: 609: 607: 370:−122 °C (−188 °F; 151 K) 635: 633: 603: 291: 256: 231: 151: 665:Fox, Marye; Whitesell, James (2004). 505:with a sweet odor typical of ethers. 380:90 °C (194 °F; 363 K) 263:Key: POLCUAVZOMRGSN-UHFFFAOYSA-N 7: 461:−18 °C (0 °F; 255 K) 669:. Jones & Bartlett Publishers. 273:Key: POLCUAVZOMRGSN-UHFFFAOYAT 173: 642:Merck Index of Chemicals and Drugs 545:-propoxide, the conjugate base of 25: 557: 321: 37: 691:"Diethyl ether product listing" 471:(at 25 °C , 100 kPa). 549:-propanol, is reacted with an 514:Acid catalyzed ether synthesis 327: 315: 1: 67:Dipropyl ether, normal isomer 501:groups. It is a colorless, 771: 715:"Organic peroxide hazards" 539:Williamson ether synthesis 533:Williamson ether synthesis 667:Organic Chemistry, 3rd ed 622:GESTIS Substance Database 465: 396: 302: 282: 247: 78: 62: 50: 45: 36: 755:Sweet-smelling chemicals 576:butylated hydroxytoluene 527:p-toluenesulfonic acid 425: 424: 407:(fire diamond) 52:Preferred IUPAC name 525:in the presence of 489:is the symmetrical 387:Solubility in water 342: g·mol 33: 750:Symmetrical ethers 475:Infobox references 426: 27: 651:978-0-911910-00-1 592:Diisopropyl ether 572:organic peroxides 483:Chemical compound 481: 480: 350:Colorless liquid 216:CompTox Dashboard 120:Interactive image 65:Propyl ether, di- 16:(Redirected from 762: 729: 728: 726: 725: 711: 705: 704: 702: 701: 687: 681: 680: 662: 656: 655: 637: 628: 615: 561: 553:-propyl halide: 503:flammable liquid 446: 439: 432: 417: 341: 329: 323: 317: 310:Chemical formula 240: 239: 224: 222: 206: 186: 175: 164: 153: 142: 122: 98: 56:1-Propoxypropane 41: 34: 21: 770: 769: 765: 764: 763: 761: 760: 759: 735: 734: 733: 732: 723: 721: 713: 712: 708: 699: 697: 689: 688: 684: 677: 664: 663: 659: 652: 639: 638: 631: 616: 605: 600: 588: 568: 535: 516: 511: 484: 477: 472: 451: 450: 449: 448: 441: 434: 427: 423: 415: 389: 339: 326: 320: 312: 298: 295: 290: 289: 278: 275: 274: 271: 265: 264: 261: 255: 254: 243: 225: 218: 209: 189: 176: 145: 125: 112: 101: 88: 74: 68: 66: 58: 57: 23: 22: 15: 12: 11: 5: 768: 766: 758: 757: 752: 747: 745:Dialkyl ethers 737: 736: 731: 730: 706: 682: 676:978-0763735869 675: 657: 650: 629: 602: 601: 599: 596: 595: 594: 587: 584: 567: 564: 563: 562: 534: 531: 515: 512: 510: 507: 487:Dipropyl ether 482: 479: 478: 473: 469:standard state 466: 463: 462: 459: 453: 452: 442: 435: 428: 413: 412: 411: 410: 408: 399: 398: 394: 393: 392:3 g/L (20 °C) 390: 385: 382: 381: 378: 372: 371: 368: 362: 361: 358: 352: 351: 348: 344: 343: 337: 331: 330: 324: 318: 313: 308: 305: 304: 300: 299: 297: 296: 293: 285: 284: 283: 280: 279: 277: 276: 272: 269: 268: 266: 262: 259: 258: 250: 249: 248: 245: 244: 242: 241: 228: 226: 214: 211: 210: 208: 207: 199: 197: 191: 190: 188: 187: 179: 177: 169: 166: 165: 155: 147: 146: 144: 143: 135: 133: 127: 126: 124: 123: 115: 113: 106: 103: 102: 100: 99: 91: 89: 84: 81: 80: 76: 75: 64: 60: 59: 55: 54: 48: 47: 43: 42: 32:-propyl ether 24: 18:Dipropyl ether 14: 13: 10: 9: 6: 4: 3: 2: 767: 756: 753: 751: 748: 746: 743: 742: 740: 720: 716: 710: 707: 696: 695:Sigma-Aldrich 692: 686: 683: 678: 672: 668: 661: 658: 653: 647: 643: 636: 634: 630: 627: 623: 619: 614: 612: 610: 608: 604: 597: 593: 590: 589: 585: 583: 579: 577: 573: 565: 560: 556: 555: 554: 552: 548: 544: 540: 532: 530: 528: 524: 522: 513: 508: 506: 504: 500: 496: 492: 488: 476: 470: 464: 460: 458: 455: 454: 447: 440: 433: 409: 406: 405: 401: 400: 395: 391: 388: 384: 383: 379: 377: 376:Boiling point 374: 373: 369: 367: 366:Melting point 364: 363: 359: 357: 354: 353: 349: 346: 345: 338: 336: 333: 332: 314: 311: 307: 306: 301: 292: 288: 281: 267: 257: 253: 246: 238: 234: 233:DTXSID8042343 230: 229: 227: 217: 213: 212: 205: 201: 200: 198: 196: 193: 192: 185: 181: 180: 178: 172: 168: 167: 163: 159: 156: 154: 152:ECHA InfoCard 149: 148: 141: 137: 136: 134: 132: 129: 128: 121: 117: 116: 114: 110: 105: 104: 97: 93: 92: 90: 87: 83: 82: 77: 73:-propyl ether 72: 61: 53: 49: 44: 40: 35: 31: 19: 722:. Retrieved 709: 698:. Retrieved 685: 666: 660: 641: 580: 569: 550: 546: 542: 536: 520: 517: 494: 486: 485: 403: 79:Identifiers 70: 63:Other names 29: 509:Preparation 457:Flash point 347:Appearance 303:Properties 158:100.003.518 739:Categories 724:2012-07-03 700:2012-07-03 598:References 360:0.75 g/cm 335:Molar mass 204:42Q250HS4G 131:ChemSpider 107:3D model ( 86:CAS Number 582:liquids. 541:in which 523:-propanol 294:O(CCC)CCC 586:See also 404:NFPA 704 397:Hazards 96:111-43-3 624:of the 620:in the 618:Record 493:of two 356:Density 340:102.177 171:PubChem 673:  648:  566:Safety 499:propyl 287:SMILES 46:Names 491:ether 252:InChI 109:JSmol 671:ISBN 646:ISBN 195:UNII 184:8114 140:7823 221:EPA 174:CID 69:Di- 28:Di- 741:: 717:. 693:. 632:^ 606:^ 325:14 727:. 703:. 679:. 654:. 551:n 547:n 543:n 521:n 497:- 495:n 445:1 438:3 431:1 328:O 322:H 319:6 316:C 223:) 219:( 111:) 71:n 30:n 20:)

Index

Dipropyl ether

Preferred IUPAC name
CAS Number
111-43-3
JSmol
Interactive image
ChemSpider
7823
ECHA InfoCard
100.003.518
Edit this at Wikidata
PubChem
8114
UNII
42Q250HS4G
CompTox Dashboard
DTXSID8042343
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Boiling point
Solubility in water
NFPA 704
1
3

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