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Dithionate

Source šŸ“

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due to the presence of the Sā€“S bond. Generally, dithionates form stable compounds that are not readily oxidised or reduced. Strong oxidants oxidise them to
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Baran M.P., Bugay O.A., Kolesnik S. P., Maksimenko V. M., Teslenko V. V., Petrenko T. L. Desrosiers M. F.
577: 525: 722: 545: 77: 67: 879: 231: 699: 491: 103: 750: 758: 726: 691: 656: 646: 560: 472:. Aqueous solutions of dithionates are quite stable and can be boiled without decomposition. 177: 800: 746: 714: 446: 298: 113: 476: 457: 619: 235: 157: 430: 371: 362: 357: 873: 450: 449:
is sometimes written in a semistructural format, as . It is the first member of the
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G.S. Murthy, R.L. Eager, and K.J. McCallum Can. J. Chem. 49(22),(1971), 3733
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Chemical Data (2nd ed.). Oxford: Pergamon (published 1984). Entry 63.
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Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution
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and barium dithionate has been proposed as the basis for a radiation
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Except where otherwise noted, data are given for materials in their
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The structure of the dithionate ion in the solid state is
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O, whereas in the anhydrous potassium salt it is nearly
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InChI=1S/H2O6S2/c1-7(2,3)8(4,5)6/h(H,1,2,3)(H,4,5,6)/p-2
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Skeletal formula of dithionate with assorted dimensions
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The sulfur atoms of the dithionate ion are in the +5
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Structures of Some Copper (II) Complexes Containing
674:International Union of Pure and Applied Chemistry 556:Compounds containing the dithionate ion include: 753:; Murillo, Carlos A.; Bochmann, Manfred (1999), 624:Chemical Entities of Biological Interest (ChEBI) 201: 112: 757:(6th ed.), New York: Wiley-Interscience, 682:(IUPAC Recommendations 2005). Cambridge (UK): 8: 709: 707: 517:The dithionate ion can act as a bidentate 464:and strong reducing agents reduce them to 234: 176: 25: 626:. UK: European Bioinformatics Institute. 611: 280: 255: 230: 789:Barium dithionate as an EPR dosemeter 262:Key: RMGVZKRVHHSUIM-UHFFFAOYSA-L 156: 7: 479:of crystalline dithionates produces 841:Bulletin of the Yamagata University 679:Nomenclature of Inorganic Chemistry 494:ions. The unpaired electron in the 192: 777:Radiation Chemistry of Dithionates 51:Ball and stick model of dithionate 14: 637:Perrin, D. D., ed. (1982) . 858: 508:electron paramagnetic resonance 374:(at 25 Ā°C , 100 kPa). 793:Radiation Protection Dosimetry 620:"Dithionate(2āˆ’) (CHEBI:29209)" 1: 506:radical can be detected with 755:Advanced Inorganic Chemistry 334:160.126 g mol 32: 901: 18: 719:Chemistry of the Elements 717:; Earnshaw, Alan (1997). 368: 291: 271: 246: 96: 76: 66: 61: 31: 19:Not to be confused with 594:barium dithionate, BaS 52: 42: 867:at Wikimedia Commons 723:Butterworth-Heinemann 715:Greenwood, Norman N. 82:Bis(trioxidosulfate)( 78:Systematic IUPAC name 50: 40: 578:potassium dithionate 751:Wilkinson, Geoffrey 700:Electronic version. 28: 805:10.1093/rpd/nci531 378:Infobox references 53: 43: 26: 863:Media related to 747:Cotton, F. Albert 732:978-0-08-037941-8 561:sodium dithionate 386:Chemical compound 384: 383: 215:CompTox Dashboard 138:Interactive image 57: 56: 892: 885:Sulfur oxyanions 862: 847: 836: 835: 834: 826: 825: 813: 807: 786: 780: 774: 768: 767: 743: 737: 736: 721:(2nd ed.). 711: 702: 671: 665: 664: 634: 628: 627: 616: 505: 504: 503: 490: 489: 488: 447:chemical formula 421: 420: 419: 411: 410: 323: 322: 321: 313: 312: 299:Chemical formula 239: 238: 223: 221: 205: 194: 180: 160: 140: 116: 33: 29: 900: 899: 895: 894: 893: 891: 890: 889: 870: 869: 856: 851: 850: 833: 830: 829: 828: 824: 821: 820: 819: 817: 814: 810: 787: 783: 775: 771: 765: 745: 744: 740: 733: 713: 712: 705: 698:. p. 130. 672: 668: 653: 636: 635: 631: 618: 617: 613: 608: 601: 597: 591: 587: 583: 574: 570: 566: 554: 543: 539: 535: 531: 502: 499: 498: 497: 495: 487: 484: 483: 482: 480: 458:oxidation state 444: 440: 436: 418: 415: 414: 413: 409: 406: 405: 404: 402: 387: 380: 375: 348: 320: 317: 316: 315: 311: 308: 307: 306: 304: 301: 287: 284: 279: 278: 267: 264: 263: 260: 254: 253: 242: 224: 217: 208: 195: 183: 163: 143: 130: 119: 106: 92: 91: 72: 24: 17: 12: 11: 5: 898: 896: 888: 887: 882: 872: 871: 865:Dithionate ion 855: 854:External links 852: 849: 848: 831: 822: 808: 781: 769: 763: 738: 731: 703: 666: 651: 629: 610: 609: 607: 604: 603: 602: 599: 595: 592: 589: 585: 581: 575: 572: 568: 564: 553: 550: 541: 537: 533: 529: 500: 485: 442: 438: 434: 431:dithionic acid 416: 407: 385: 382: 381: 376: 372:standard state 369: 366: 365: 363:Dithionic acid 360: 358:Conjugate acid 354: 353: 350: 346: 336: 335: 332: 326: 325: 318: 309: 302: 297: 294: 293: 289: 288: 286: 285: 282: 274: 273: 272: 269: 268: 266: 265: 261: 258: 257: 249: 248: 247: 244: 243: 241: 240: 232:DTXSID60163807 227: 225: 213: 210: 209: 207: 206: 198: 196: 188: 185: 184: 182: 181: 173: 171: 165: 164: 162: 161: 153: 151: 145: 144: 142: 141: 133: 131: 124: 121: 120: 118: 117: 109: 107: 102: 99: 98: 94: 93: 81: 80: 74: 73: 70: 64: 63: 59: 58: 55: 54: 44: 15: 13: 10: 9: 6: 4: 3: 2: 897: 886: 883: 881: 878: 877: 875: 868: 866: 861: 853: 846:, 1,(2001), 7 845: 842: 838: 812: 809: 806: 802: 798: 794: 790: 785: 782: 778: 773: 770: 766: 764:0-471-19957-5 760: 756: 752: 748: 742: 739: 734: 728: 724: 720: 716: 710: 708: 704: 701: 697: 696:0-85404-438-8 693: 689: 685: 681: 680: 675: 670: 667: 662: 658: 654: 652:0-08-029214-3 648: 644: 640: 633: 630: 625: 621: 615: 612: 605: 593: 579: 576: 562: 559: 558: 557: 551: 549: 547: 527: 522: 520: 515: 513: 509: 493: 478: 477:Ī³-irradiation 473: 471: 467: 463: 459: 454: 452: 451:polythionates 448: 432: 429:derived from 428: 425: 400: 396: 395:metabisulfate 392: 379: 373: 367: 364: 361: 359: 356: 355: 351: 345: 341: 338: 337: 333: 331: 328: 327: 303: 300: 296: 295: 290: 281: 277: 270: 256: 252: 245: 237: 233: 229: 228: 226: 216: 212: 211: 204: 200: 199: 197: 191: 187: 186: 179: 175: 174: 172: 170: 167: 166: 159: 155: 154: 152: 150: 147: 146: 139: 135: 134: 132: 128: 123: 122: 115: 111: 110: 108: 105: 101: 100: 95: 89: 85: 79: 75: 69: 65: 60: 49: 45: 39: 35: 34: 30: 22: 857: 843: 840: 815: 811: 796: 792: 788: 784: 776: 772: 754: 741: 718: 677: 669: 638: 632: 623: 614: 555: 523: 516: 474: 455: 394: 390: 388: 343: 97:Identifiers 87: 83: 880:Dithionates 470:dithionites 292:Properties 158:CHEBI:29209 27:Dithionate 874:Categories 606:References 391:dithionate 330:Molar mass 169:ChemSpider 125:3D model ( 114:14781-81-8 104:CAS Number 71:Dithionate 68:IUPAC name 21:dithionite 839:Ishii M. 552:Compounds 526:staggered 512:dosimeter 283:()()-()() 676:(2005). 661:82-16524 546:eclipsed 466:sulfites 462:sulfates 427:oxoanion 799:, 202; 492:radical 445:. Its 422:, is a 340:Acidity 324: 203:3082075 190:PubChem 178:2339557 761:  729:  694:  659:  649:  519:ligand 424:sulfur 276:SMILES 62:Names 795:2006 688:IUPAC 643:IUPAC 528:in Na 399:anion 251:InChI 149:ChEBI 127:JSmol 90:)(2āˆ’) 759:ISBN 727:ISBN 692:ISBN 657:LCCN 647:ISBN 563:, Na 475:The 468:and 393:(or 389:The 352:0.5 837:Ion 801:doi 797:120 684:RSC 580:, K 540:Ā·2H 433:, H 220:EPA 193:CID 16:Ion 876:: 749:; 725:. 706:^ 690:. 655:. 641:. 622:. 548:. 521:. 514:. 496:SO 481:SO 453:. 401:, 397:) 349:) 342:(p 844:5 832:6 827:O 823:2 818:S 803:: 735:. 686:ā€“ 663:. 600:6 598:O 596:2 590:6 588:O 586:2 584:S 582:2 573:6 571:O 569:2 567:S 565:2 542:2 538:6 536:O 534:2 532:S 530:2 501:3 486:3 443:6 441:O 439:2 437:S 435:2 417:6 412:O 408:2 403:S 347:a 344:K 319:6 314:O 310:2 305:S 222:) 218:( 129:) 88:S 86:ā€” 84:S 23:.

Index

dithionite
Skeletal formula of dithionate with assorted dimensions
Ball and stick model of dithionate
IUPAC name
Systematic IUPAC name
CAS Number
14781-81-8
JSmol
Interactive image
ChEBI
CHEBI:29209
ChemSpider
2339557
PubChem
3082075
CompTox Dashboard
DTXSID60163807
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Acidity
Conjugate acid
Dithionic acid
standard state
Infobox references
anion
sulfur
oxoanion

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