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590:"The Redox Potential of Dithionite and SO from Equilibrium Reactions with Flavodoxins, Methyl Viologen and Hydrogen plus Hydrogenase"
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José Jiménez Barberá; Adolf
Metzger; Manfred Wolf (2000). "Sulfites, Thiosulfates, and Dithionites".
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The unusual structure of the dithionite anion. It has a remarkably long sulfur-sulfur bond.
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Wietelmann, Ulrich; Felderhoff, Michael; Rittmeyer, Peter (2016-09-29) . "Hydrides".
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iron(II) compounds and to remove amorphous iron(III)-bearing mineral phases in
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66:. The dianion has a steric number of 4 and trigonal pyramidal geometry.
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The decomposition of dithionite produces reduced species of
276:
It also undergoes alkaline hydrolytic disproportionation to
551:. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA.
133:
74:
In its main applications, dithionite is generally prepared
54:
with the formula . It is commonly encountered as the salt
336:), but this acid does not exist in any practical sense.
683:
58:. For historical reasons, it is sometimes called
465:International Union of Pure and Applied Chemistry
90:, described by the following idealized equation:
548:Ullmann's Encyclopedia of Industrial Chemistry
510:Ullmann's Encyclopedia of Industrial Chemistry
473:(IUPAC Recommendations 2005). Cambridge (UK):
703:
16:Oxyanion of sulfur at the oxidation number +3
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62:, but it contains no hydrogen and is not a
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347:finds widespread use in industry as a
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399:that can be very aggressive for the
470:Nomenclature of Inorganic Chemistry
682:. You can help Knowledge (XXG) by
607:10.1111/j.1432-1033.1978.tb12269.x
14:
387:analyses (selective extraction).
666:
594:European Journal of Biochemistry
1:
557:10.1002/14356007.a13_199.pub2
351:. It is for example used in
320:It is formally derived from
444:(S, HS) is responsible for
775:
661:
196:Dithionite undergoes acid
18:
638:Chemistry of the Elements
636:; Earnshaw, Alan (1997).
446:stress corrosion cracking
379:(III) oxy-hydroxide into
148:occurs with formation of
519:10.1002/14356007.a25_477
70:Production and reactions
19:Not to be confused with
513:. Weinheim: Wiley-VCH.
754:Chemical process stubs
749:Electrochemistry stubs
678:-related article is a
588:Mayhew, S. G. (2008).
353:bleaching of wood pulp
103:+ 8 NaOH → 4 Na
43:
42:of the dithionite ion.
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642:Butterworth-Heinemann
634:Greenwood, Norman N.
436:) is known to induce
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29:
40:ball-and-stick model
491:Electronic version.
140:is −0.66 V vs
138:reduction potential
391:Harmful properties
340:Use and occurrence
201:disproportionation
88:sodium borohydride
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32:
691:
690:
651:978-0-08-037941-8
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438:pitting corrosion
369:complexing agents
363:Chemical analyses
345:Sodium dithionite
56:sodium dithionite
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744:Sulfur oxyanions
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759:Metal stubs
739:Dithionites
413:Thiosulfate
373:citric acid
205:thiosulfate
723:Categories
452:References
440:, whereas
198:hydrolytic
180:O → 2
48:dithionite
21:dithionate
734:Corrosion
676:corrosion
575:751968805
401:corrosion
355:and some
209:bisulfite
146:oxidation
80:reduction
467:(2005).
52:oxyanion
448:(SCC).
442:sulfide
381:soluble
312:S + 3 H
282:sulfide
278:sulfite
150:sulfite
115:+ NaBO
99:+ 8 SO
76:in situ
64:sulfite
50:is the
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616:648533
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397:sulfur
176:+ 2 H
144:. Its
132:. At
119:+ 6 H
674:This
479:IUPAC
405:steel
680:stub
646:ISBN
612:PMID
571:OCLC
561:ISBN
523:ISBN
483:ISBN
407:and
385:soil
377:iron
357:dyes
308:+ Na
288:3 Na
280:and
261:+ 2
240:O →
207:and
95:NaBH
46:The
602:doi
553:doi
515:doi
475:RSC
403:of
263:HSO
236:+ H
203:to
182:HSO
142:SHE
86:by
82:of
78:by
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324:(H
304:SO
284::
215:2
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134:pH
38:A
711:e
704:t
697:v
686:.
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477:–
431:3
426:O
422:2
417:S
415:(
334:4
332:O
330:2
328:S
326:2
316:O
314:2
310:2
306:3
302:2
298:4
296:O
294:2
292:S
290:2
268:3
256:3
251:O
247:2
242:S
238:2
231:4
226:O
222:2
217:S
187:3
178:2
171:4
166:O
162:2
157:S
123:O
121:2
117:2
113:4
111:O
109:2
107:S
105:2
101:2
97:4
23:.
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