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Flash point

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parameters, the procedure for the operator or automated apparatus to follow, and the precision of the test method. Standard test methods are written and controlled by a number of national and international committees and organizations. The three main bodies are the CEN / ISO Joint Working Group on Flash Point (JWG-FP), ASTM D02.8B Flammability Section and the Energy Institute's TMS SC-B-4 Flammability Panel.
164:. In addition to the Penskey-Martens flash point testers, other non-equilibrial testers include TAG and Abel, both of which are capable of cooling the sample below ambient for low flash point materials. The TAG flash point tester adheres to ASTM D56 and has no stirrer, while the Abel flash point testers adheres to IP 170 and ISO 13736 and has a stirring motor so the sample is stirred during testing. 1014: 38: 128:. As temperature increases, vapor pressure increases. As vapor pressure increases, the concentration of vapor of a flammable or combustible liquid in the air increases. Hence, temperature determines the concentration of vapor of the flammable liquid in the air. A certain concentration of a flammable or combustible vapor is necessary to sustain combustion in air, the 1922: 1003: 371: 160:
with the liquid. In both these types, the cups are sealed with a lid through which the ignition source can be introduced. Closed cup testers normally give lower values for the flash point than open cup (typically 5–10 °C or 9–18 °F lower) and are a better approximation to the temperature at which the vapour pressure reaches the
148:. In open cup devices, the sample is contained in an open cup which is heated and, at intervals, a flame brought over the surface. The measured flash point will actually vary with the height of the flame above the liquid surface and, at sufficient height, the measured flash point temperature will coincide with the 167:
The flash point is an empirical measurement rather than a fundamental physical parameter. The measured value will vary with equipment and test protocol variations, including temperature ramp rate (in automated testers), time allowed for the sample to equilibrate, sample volume and whether the sample
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There are two types of closed cup testers: non-equilibrial, such as Pensky-Martens, where the vapours above the liquid are not in temperature equilibrium with the liquid, and equilibrial, such as Small Scale (commonly known as Setaflash), where the vapours are deemed to be in temperature equilibrium
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Flash points of substances are measured according to standard test methods described and defined in a 1938 publication by T.L. Ainsley of South Shields entitled "Sea Transport of Petroleum" (Capt. P. Jansen). The test methodology defines the apparatus required to carry out the measurement, key test
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of the fuel, which is then injected as a high-pressure spray, keeping the fuel-air mix within flammable limits. A diesel-fueled engine has no ignition source (such as the spark plugs in a gasoline engine), so diesel fuel can have a high flash point, but must have a low autoignition temperature.
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is the lowest temperature at which the vapors keep burning after the ignition source is removed. It is higher than the flash point, because at the flash point vapor may not be produced fast enough to sustain combustion. Neither flash point nor fire point depends directly on the ignition source
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flash points also vary with the composition of the fuel. Both Jet A and Jet A-1 have flash points between 38 and 66 °C (100 and 151 °F), close to that of off-the-shelf kerosene. Yet both Jet B and JP-4 have flash points between −23 and −1 °C (−9 and 30 °F).
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of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1)
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D93, IP34, ISO 2719, DIN 51758, JIS K2265 and AFNOR M07-019. Determination of flash point by the Small Scale closed cup method is detailed in ASTM D3828 and D3278, EN ISO 3679 and 3680, and IP 523 and 524.
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temperature, but ignition source temperature is far higher than either the flash or fire point, and can increase the temperature of fuel above the usual ambient temperature to facilitate ignition.
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of fuels. Fuels which have a flash point less than 37.8 °C (100.0 °F) are called flammable, whereas fuels having a flash point above that temperature are called combustible.
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CEN/TR 15138 Guide to Flash Point Testing and ISO TR 29662 Guidance for Flash Point Testing cover the key aspects of flash point testing.
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Methods for determining the flash point of a liquid are specified in many standards. For example, testing by the
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flash points vary between 52 and 96 °C (126 and 205 °F). Diesel is suitable for use in a
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The flash point is a descriptive characteristic that is used to distinguish between
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Lowest temperature at which a volatile material's vapors ignite if given a source
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caused by residual heat in a hot combustion chamber, the fuel must have a high
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Sea Transport of Petroleum, Jansen and Hayes, Ainsley, South Shields 1938
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National Council of Examiners for Engineering and Surveying
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There are two basic types of flash point measurement:
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The best-known example is the 1402:Vehicle fire suppression system 1090:Combustibility and flammability 690:Control of fire by early humans 626:"Auto-Ignition of Cooking Oils" 307:>130 °C (266 °F) 60:, the temperature that causes 1: 1752:Institution of Fire Engineers 1709:Fire Safety Evaluation System 1381:Personal protective equipment 316:(petrol) is a fuel used in a 280:>38 °C (100 °F) 267:>38 °C (100 °F) 254:>52 °C (126 °F) 1823:GHS precautionary statements 1661:Manual fire alarm activation 213:16.6 °C (61.9 °F) 1694:Fire protection engineering 1626:Explosive gas leak detector 1443:Electromagnetic door holder 1276:External water spray system 344:compression-ignition engine 1970: 1870:Harry C. Bigglestone Award 1261:Automatic fire suppression 1201:K-factor (fire protection) 297:424 °C (795 °F) 294:327 °C (621 °F) 283:210 °C (410 °F) 270:210 °C (410 °F) 257:210 °C (410 °F) 244:280 °C (536 °F) 241:−43 °C (−45 °F) 230:215 °C (419 °F) 216:363 °C (685 °F) 29: 1904: 1776:Underwriters Laboratories 1611:Aspirating smoke detector 1271:Detonation flame arrester 1237: 985: 376:Pensky-Martens closed cup 350:until it heats above the 173:Pensky-Martens closed cup 1720:Kitchen exhaust cleaning 1636:Fire alarm control panel 1616:Carbon monoxide detector 1593:Standpipe (firefighting) 1356:Gaseous fire suppression 1121:Enthalpy of vaporization 914:The Combustion Institute 393:Autoignition temperature 352:autoignition temperature 334:autoignition temperature 227:−4 °C (25 °F) 58:autoignition temperature 1563:Pressurisation ductwork 1528:Firewall (construction) 1376:Passive fire protection 1326:Fire suppression system 624:Buda-Ortins, Krystyna. 1954:Threshold temperatures 1739:Industry organizations 1704:Fire-resistance rating 1583:Smoke exhaust ductwork 1558:Penetration (firestop) 1548:Packing (firestopping) 1256:Active fire protection 1216:Spontaneous combustion 756:Spontaneous combustion 583:Engineeringtoolbox.com 555:Engineeringtoolbox.com 379: 175:method is detailed in 45: 1891:Template:Firefighting 1865:Arthur B. Guise Medal 1818:GHS hazard statements 1321:Fire sprinkler system 1301:Fire-retardant fabric 611:www.sciencedirect.com 551:"Flash Point — Fuels" 455:Jansen and Hyams.pp62 373: 318:spark-ignition engine 162:lower flammable limit 130:lower flammable limit 40: 1675:Professions, trades, 1588:Smokeproof enclosure 1448:Electromagnetic lock 1156:Flammability diagram 1067:Fundamental concepts 62:spontaneous ignition 30:For other uses, see 1631:Fire alarm call box 1538:Heat and smoke vent 520:"Coleman Fuel MSDS" 437:www.ehs.iastate.edu 1603:Fire alarm systems 1418:Annulus (firestop) 1346:Flashback arrestor 1311:Fire-safe polymers 1306:Fire retardant gel 1161:Flammability limit 380: 154:Cleveland open cup 124:and is subject to 46: 1936: 1935: 1844:Safety data sheet 1839:List of S-phrases 1834:List of R-phrases 1730:Sprinkler fitting 1621:Circuit integrity 1493:Fire extinguisher 1331:Firefighting foam 1226:Thermal radiation 1026: 1025: 935:List of wildfires 403:Safety data sheet 311: 310: 120:of that liquid's 42:Flaming cocktails 16:(Redirected from 1961: 1924: 1923: 1912: 1911: 1828:Life Safety Code 1433:Compartmentation 1243: 1166:Flammable liquid 1053: 1046: 1039: 1030: 1016: 1005: 1004: 994: 993: 839:Death by burning 801:Individual fires 667: 660: 653: 644: 637: 636: 633:Drum.lib.umd.edu 630: 621: 615: 614: 603: 594: 593: 591: 589: 575: 566: 565: 563: 561: 547: 538: 537: 535: 533: 524: 516: 507: 506: 504: 502: 497:on June 17, 2019 496: 490:. Archived from 485: 477: 468: 462: 456: 453: 447: 446: 444: 443: 429: 423: 420: 263:Jet fuel (A/A-1) 191: 112:have a specific 21: 1969: 1968: 1964: 1963: 1962: 1960: 1959: 1958: 1939: 1938: 1937: 1932: 1900: 1874: 1853: 1781: 1734: 1676: 1670: 1597: 1523:Firestop pillow 1458:Emergency light 1411:Building design 1406: 1397:Tank blanketing 1366:Inerting system 1341:Flame retardant 1291:Fire protection 1286:Fire prevention 1244: 1235: 1100:Dangerous goods 1062: 1060:Fire protection 1057: 1027: 1022: 981: 918: 897: 871: 843: 822: 796: 760: 746:Fire protection 704: 676: 671: 641: 640: 628: 623: 622: 618: 605: 604: 597: 587: 585: 577: 576: 569: 559: 557: 549: 548: 541: 531: 529: 522: 518: 517: 510: 500: 498: 494: 483: 479: 478: 471: 463: 459: 454: 450: 441: 439: 431: 430: 426: 421: 417: 412: 389: 368: 366:Standardization 201: 189: 138: 106: 89:fuels, such as 75: 35: 28: 23: 22: 15: 12: 11: 5: 1967: 1965: 1957: 1956: 1951: 1941: 1940: 1934: 1933: 1931: 1930: 1918: 1905: 1902: 1901: 1899: 1898: 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Retrieved 436: 427: 418: 381: 357: 338: 312: 250:Diesel (2-D) 224:(White Gas) 222:Coleman fuel 202:temperature 200:Autoignition 197:Flash point 182: 170: 168:is stirred. 166: 158: 145: 141: 139: 107: 98:fire hazards 95: 76: 55: 49: 47: 1533:Grease duct 1488:Fire escape 1478:Fire damper 1371:Intumescent 1316:Fire safety 1281:Fire bucket 1176:Flash point 977:Fire making 893:Terra preta 867:Firefighter 741:Flash point 736:Fire piston 532:November 3, 340:Diesel fuel 330:preignition 322:Boyle's Law 238:(gasoline) 136:Measurement 126:Boyle's Law 122:temperature 87:combustible 50:flash point 18:Flash Point 1949:Combustion 1943:Categories 1830:(NFPA 101) 1793:CE marking 1646:Fire drill 1249:Technology 1146:Fire point 1131:Fire class 1111:Detonation 1018:Wiktionary 957:Fire whirl 855:Pyromanias 813:By country 765:Components 721:Combustion 588:January 4, 560:January 4, 501:January 4, 467:, ASTM.org 442:2021-11-10 410:References 398:Fire point 374:Automatic 348:compressed 326:spark plug 150:fire point 146:closed cup 66:fire point 32:Flashpoint 1786:Standards 1715:Fire test 1543:Occupancy 1508:Fire pump 1498:Fire hose 1483:Fire door 1463:Exit sign 1438:Crash bar 1211:Pyrolysis 1206:Pool fire 1171:Flashover 1126:Explosive 1074:Backdraft 962:Blue lava 952:Firestorm 942:Backdraft 930:Wildfires 883:Cremation 751:Pyrolysis 488:Nafaa.org 346:. Air is 303:Biodiesel 291:(canola) 104:Mechanism 79:flammable 1915:Category 1879:See also 1808:EN 16034 1518:Firestop 1473:Fire cut 1196:Jet fire 1186:Gas leak 1102:(HAZMAT) 1085:Boilover 996:Category 387:See also 359:Jet fuel 314:Gasoline 276:Kerosene 187:Examples 142:open cup 118:function 83:gasoline 1927:Commons 1760:(NCEES) 1081:(BLEVE) 1007:Commons 876:Culture 818:By year 808:By type 709:Science 682:History 208:Ethanol 156:(COC). 110:liquids 85:), and 1858:Awards 1772:(SFPE) 1766:(NFPA) 1748:(FEMA) 1711:(FSES) 1011:  1000:  989:  848:People 777:Oxygen 236:Petrol 210:(70%) 91:diesel 64:. The 1849:UL 94 1803:EN 54 1754:(IFE) 1383:(PPE) 923:Other 860:Child 834:Arson 827:Crime 792:Smoke 787:Flame 629:(PDF) 523:(PDF) 495:(PDF) 484:(PDF) 405:(SDS) 194:Fuel 73:Fuels 1798:EN 3 1778:(UL) 782:Heat 772:Fuel 674:Fire 590:2014 562:2014 534:2019 503:2014 177:ASTM 144:and 108:All 48:The 967:Ash 1945:: 631:. 609:. 598:^ 581:. 570:^ 553:. 542:^ 525:. 511:^ 486:. 472:^ 435:. 336:. 93:. 1052:e 1045:t 1038:v 666:e 659:t 652:v 635:. 613:. 592:. 564:. 536:. 505:. 445:. 34:. 20:)

Index

Flash Point
Flashpoint

Flaming cocktails
autoignition temperature
spontaneous ignition
fire point
flammable
gasoline
combustible
diesel
fire hazards
liquids
vapor pressure
function
temperature
Boyle's Law
lower flammable limit
fire point
Cleveland open cup
lower flammable limit
Pensky-Martens closed cup
ASTM
Ethanol
Coleman fuel
Petrol
Diesel (2-D)
Jet fuel (A/A-1)
Kerosene
Vegetable oil

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