163:
105:
191:
3228:
3223:
3218:
3561:
133:
778:
765:
758:
751:
744:
737:
730:
703:
691:
684:
677:
802:: Indicates that these materials may not be loaded, transported or stored together in the same transport vehicle or storage facility during the course of transportation, unless separated in a manner that, in the event of leakage from packages under conditions normally incident to transportation, commingling of hazardous materials would not occur.
518:
dust or mist, more than 90 percent of the particles available for inhalation in the test must have a diameter of 10 micrometres or less if it is reasonably foreseeable that such concentrations could be encountered by a human during transport. The result is expressed in mg/L of air for dusts and mists or in mL/m of air (
1867:: A liquid in Division 6.1 meeting criteria for Packing Group I, Hazard Zones A or B stated in paragraph (a)(2) of this section is a material poisonous by inhalation subject to the additional hazard communication requirements in 49CFR 172.203(m)(3), 49CFR 172.313 and Table 1 of 49CFR 172.504(e) of this subchapter.
3085:
data on the poisonous (toxic) constituent substances, the mixture may be assigned a packing group and hazard zone based on simplified threshold toxicity tests. When these threshold tests are used, the most restrictive packing group and hazard zone must be determined and used for the transportation of
517:
for acute toxicity on inhalation means that concentration of vapor, mist, or dust which, administered by continuous inhalation for one hour to both male and female young adult albino rats, causes death within 14 days in half of the animals tested. If the material is administered to the animals as a
291:
For purposes of classifying and assigning packing groups to mixtures possessing oral or dermal toxicity hazards according to the criteria in 49CFR 173.133(a)(1), it is necessary to determine the acute LD50 of the mixture. If a mixture contains more than one active constituent, one of the following
275:
for acute dermal toxicity means that dose of the material which, administered by continuous contact for 24 hours with the shaved intact skin (avoiding abrading) of an albino rabbit, causes death within 14 days in half of the animals tested. The number of animals tested must be sufficient to give
264:
for acute oral toxicity means that dose of the material administered to both male and female young adult albino rats which causes death within 14 days in half the animals tested. The number of animals tested must be sufficient to give statistically valid results and be in conformity with good
838:
The packing group of
Division 6.1 materials shall be as assigned in Column 5 of the 49CFR 172.101 Table. When the 49CFR 172.101 Table provides more than one packing group or hazard zone for a hazardous material, the packing group and hazard zone shall be determined by applying the following
1875:
3. When the packing group determined by applying these criteria is different for two or more (oral, dermal or inhalation) routes of administration, the packing group assigned to the material shall be that indicated for the highest degree of toxicity for any of the routes of administration.
808:: Packages with "Poison" or "Poison Inhalation Hazard" markings, or a "Poison" marking with "PG III" or "PG III" beside a "Poison" label, may not be transported with foodstuffs, feed, or any other edible material, intended for consumption by humans or animals. For exceptions see §177.841(e)
236:: May be used instead of POISON placard on 454 kg (1001 lb) or more gross weight of poisonous materials that are not in Hazard Zone A or B (see Assignment of packing groups and hazard zones below). For international shipments the label must say Toxic if it will be worded.
65:
on inhalation of not more than 4 mg/L; or a material with a saturated vapor concentration in air at 20 °C (68 °F) of more than one-fifth of the LC50 for acute toxicity on inhalation of vapors and with an LC50 for acute toxicity on inhalation of vapors of not more than 5000 mL/m;
3357:
3332:
427:
298:
If reliable, accurate data is not available, classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents;
2104:
3187:
38:
Is presumed to be toxic to humans because it falls within any one of the following categories when tested on laboratory animals (whenever possible, animal test data that has been reported in the chemical literature should be
3418:
3207:
2541:
34:: Poisonous material is a material, other than a gas, which is known to be so toxic to humans as to afford a hazard to health during transportation, or which, in the absence of adequate data on human toxicity:
3069:
2933:
2806:
2684:
2367:
1807:
1695:
1586:
1477:
1358:
2. The packing group and hazard zone assignments for liquids (see 49CFR 173.115(c) of this subpart for gases) based on inhalation of vapors shall be in accordance with the following Table:
3385:
3352:
3337:
3107:
2982:
2270:
1859:
309:
3264:
3111:
939:
893:
242:: May be used instead of POISON placard on 454 kg (1001 lb) or more gross weight of Poison PG III materials (see Assignment of packing groups and hazard zones below).
1417:
982:
1747:
1526:
2454:
may be calculated according to Raoult's Law using appropriate activity coefficients. Where activity coefficients are not available, the coefficient may be assumed to be 1.0.
1635:
1953:
2597:
1304:
3468:
2719:
2199:
1879:
4. Notwithstanding the provisions of this paragraph, the packing group and hazard zone of a tear gas substance is as assigned in Column 5 of the 49CFR 172.101 Table.
1257:
1158:
1059:
2846:
1947:
1915:
1281:
1182:
1111:
1035:
2425:
2229:
2164:
1351:
1234:
1205:
1135:
1011:
3322:
2452:
2395:
2134:
1328:
1088:
499:
3375:
3166:
471:
451:
3482:
796:: These materials may not be loaded, transported, or stored together in the same transport vehicle or storage facility during the course of transportation.
1885:
The packing group and hazard zone for
Division 6.1 mixtures that are poisonous (toxic) by inhalation may be determined by one of the following methods:
3458:
3197:
224:
of poisonous materials that are not in Hazard Zone A or B (see
Assignment of packing groups and hazard zones below). For U.S. Domestic Use only.
3317:
842:
1. The packing group assignment for routes of administration other than inhalation of vapors shall be in accordance with the following table:
3274:
2466:
3279:
3118:
2987:
2851:
2724:
2602:
3523:
3254:
276:
statistically valid results and be in conformity with good pharmacological practices. The result is expressed in mg/kg body mass.
2280:
3307:
3259:
162:
3548:
3395:
1752:
1640:
1531:
1422:
3583:
3564:
3347:
3284:
3152:
3159:
104:
230:: Any quantity of a material that is in Hazard Zone A or B (see Assignment of packing groups and hazard zones below).
3202:
3192:
3244:
790:
The absence of any hazard class or division or a blank space in the table indicates that no restrictions apply.
3528:
3503:
422:{\displaystyle {\tfrac {C_{A}}{T_{A}}}+{\tfrac {C_{B}}{T_{B}}}+{\tfrac {C_{Z}}{T_{Z}}}={\tfrac {100}{T_{M}}}}
3478:
2952:
190:
2234:
1823:
905:
859:
817:
United States Code of
Federal Regulations, Title 49 CFR §177.848 - Segregation of hazardous materials.
1383:
953:
3249:
1713:
1492:
2099:{\displaystyle LC_{50}(mixture)={\cfrac {1}{\textstyle \sum _{i=1}^{n}{\cfrac {f_{i}}{LC_{50i}}}}}}
1604:
3538:
74:
132:
2576:
1286:
2698:
2171:
1239:
1140:
1041:
519:
85:
2825:
1922:
1890:
1263:
1164:
1093:
1017:
3342:
2400:
2204:
2139:
1333:
1216:
1187:
1117:
993:
522:) for vapors. See 49CFR 173.133(b) for LC50 determination for mixtures and for limit tests.
295:
Obtain reliable acute oral and dermal toxicity data on the actual mixture to be transported;
2430:
2373:
2112:
1310:
1070:
477:
3513:
3236:
3313:
European
Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)
3508:
456:
436:
62:
1917:
data is available on each of the poisonous (toxic) substances comprising the mixture:
3577:
3533:
49:: A liquid or solid with an LD50 for acute oral toxicity of not more than 300 mg/kg.
3428:
3312:
221:
19:
is a material, other than a gas, known to be so toxic to humans that it presents a
3302:
55:. A material with an LD50 for acute dermal toxicity of not more than 1000 mg/kg.
1811:
The criteria for
Packing Groups I and II, Hazard Zones A, B and C are not met.
2275:
2. The volatility of each component substance is estimated using the formula:
3419:
Globally
Harmonized System of Classification and Labelling of Chemicals (GHS)
3518:
2548:(mixture) and R, the packing group for the mixture is determined as follows:
3074:
The criteria for
Packing Groups I, Hazard Zones A, B and Packing Group II.
3543:
3448:
3327:
292:
methods may be used to determine the oral or dermal LD50 of the mixture:
3438:
453:= the percent concentration of constituent A, B ... Z in the mixture;
3144:
2536:{\displaystyle R=\textstyle \sum _{i=1}^{n}{\tfrac {f_{i}}{LC_{50i}}}}
265:
pharmacological practices. The result is expressed in mg/kg body mass.
20:
2938:
The criteria for
Packing Group I, Hazard Zones A and B are not met.
1699:
The criteria for
Packing Group I, Hazard Zones A and B are not met.
2550:
1820:: V is the saturated vapor concentration in air of the material in
1360:
844:
829:
529:
279:
2427:
component substance in kPa at 20°C and one atmospheric pressure.
77:, which causes extreme irritation, especially in confined spaces.
3148:
302:
If reliable, accurate data is not available, apply the formula:
3108:
Pipeline and Hazardous Materials Safety Administration (PHMSA)
2811:
The criteria for Packing Group I, Hazard Zone A, are not met.
3064:{\displaystyle LC_{50}(mixture)\leq 5000{\tfrac {mL}{m^{3}}}}
2928:{\displaystyle LC_{50}(mixture)\leq 3000{\tfrac {mL}{m^{3}}}}
2801:{\displaystyle LC_{50}(mixture)\leq 1000{\tfrac {mL}{m^{3}}}}
1590:
The criteria for Packing Group I. Hazard Zone A are not met.
2679:{\displaystyle LC_{50}(mixture)\leq 200{\tfrac {mL}{m^{3}}}}
3117:. Government Publishing Office. p. 853. Archived from
3208:
List of accidents involving natural gas and oil production
2362:{\displaystyle V_{i}=P_{i}\times {\tfrac {10^{6}}{101.3}}}
2064:
2045:
2015:
2003:
95:
3386:
Pipeline and Hazardous Materials Safety Administration
3353:
UN Recommendations on the Transport of Dangerous Goods
3188:
Accidents involving transport or storage of ammunition
3038:
2963:
2902:
2775:
2653:
2499:
2476:
2333:
2311:
2239:
2067:
2048:
2020:
2018:
2006:
1828:
1776:
1664:
1555:
1446:
958:
910:
864:
401:
372:
343:
314:
73:
Is an irritating material, with properties similar to
3265:
HAZMAT Class 5 Oxidizing agents and organic peroxides
3112:"49 CFR 177.848 - Segregation of hazardous materials"
2990:
2955:
2854:
2828:
2727:
2701:
2605:
2579:
2469:
2433:
2403:
2376:
2283:
2237:
2207:
2174:
2142:
2115:
1956:
1925:
1893:
1826:
1755:
1716:
1643:
1607:
1534:
1495:
1425:
1386:
1336:
1313:
1289:
1266:
1242:
1219:
1190:
1167:
1143:
1120:
1096:
1073:
1044:
1020:
996:
956:
908:
862:
480:
459:
439:
312:
126:
98:
1802:{\displaystyle LC_{50}\leq 5000{\tfrac {mL}{m^{3}}}}
1690:{\displaystyle LC_{50}\leq 3000{\tfrac {mL}{m^{3}}}}
1581:{\displaystyle LC_{50}\leq 1000{\tfrac {mL}{m^{3}}}}
3496:
3409:
3366:
3293:
3235:
3180:
1472:{\displaystyle LC_{50}\leq 200{\tfrac {mL}{m^{3}}}}
473:= the oral LD50 values of constituent A, B ... Z;
3063:
2976:
2927:
2840:
2800:
2713:
2678:
2591:
2535:
2446:
2419:
2389:
2361:
2264:
2223:
2193:
2158:
2128:
2098:
1941:
1909:
1853:
1801:
1741:
1689:
1629:
1580:
1520:
1471:
1411:
1345:
1322:
1298:
1275:
1251:
1228:
1199:
1176:
1152:
1129:
1105:
1082:
1053:
1029:
1005:
976:
933:
887:
493:
465:
445:
421:
3469:Workplace Hazardous Materials Information System
3459:Hazardous Materials Identification System (HMIS)
1861:at 20 °C and standard atmospheric pressure.
3323:Hazardous Substances and New Organisms Act 1996
1949:of the mixture is estimated using the formula:
3270:HAZMAT Class 6 Toxic and infectious substances
3376:United Nations Economic Commission for Europe
3160:
8:
185:
157:
127:
99:
3483:Dangerous Substances Directive (67/548/EEC)
3167:
3153:
3145:
3052:
3037:
2998:
2989:
2962:
2954:
2916:
2901:
2862:
2853:
2827:
2789:
2774:
2735:
2726:
2700:
2667:
2652:
2613:
2604:
2578:
2519:
2505:
2498:
2492:
2481:
2468:
2438:
2432:
2408:
2402:
2381:
2375:
2347:
2332:
2317:
2310:
2301:
2288:
2282:
2253:
2238:
2236:
2212:
2206:
2182:
2173:
2147:
2141:
2120:
2114:
2076:
2068:
2054:
2049:
2042:
2036:
2025:
2019:
2007:
2000:
1964:
1955:
1933:
1924:
1901:
1892:
1842:
1827:
1825:
1790:
1775:
1763:
1754:
1733:
1715:
1678:
1663:
1651:
1642:
1621:
1606:
1569:
1554:
1542:
1533:
1512:
1494:
1460:
1445:
1433:
1424:
1403:
1385:
1335:
1312:
1288:
1265:
1241:
1218:
1189:
1166:
1142:
1119:
1095:
1072:
1043:
1019:
995:
957:
955:
909:
907:
863:
861:
485:
479:
458:
438:
410:
400:
388:
378:
371:
359:
349:
342:
330:
320:
313:
311:
2457:3. The ratio of the volatility to the LC
833:Class 6 Packing Groups and Hazard Zones
3099:
3443:United Kingdom, Australia, New Zealand
3318:Hazardous Materials Transportation Act
3275:HAZMAT Class 7 Radioactive substances
2977:{\displaystyle R\geq {\tfrac {1}{5}}}
540:
501:= the oral LD50 value of the mixture.
220:: 454 kg (1001 lb) or more
7:
3193:Accidents involving ammonium nitrate
2265:{\displaystyle {\tfrac {mL}{m^{3}}}}
2201:= means lethal concentration of the
1854:{\displaystyle {\tfrac {mL}{m^{3}}}}
635:
630:
620:
615:
610:
605:
600:
595:
590:
585:
580:
575:
570:
565:
560:
555:
550:
545:
537:
3358:US Committee on Hazardous Materials
3280:HAZMAT Class 8 Corrosive substances
61:: A dust or mist with an LC50 for
14:
2544:4. Using the calculated values LC
2461:is calculated using the formula:
1370:Vapor Concentration and Toxicity
934:{\displaystyle {\tfrac {mg}{kg}}}
888:{\displaystyle {\tfrac {mg}{kg}}}
3560:
3559:
3524:High production volume chemicals
3255:HAZMAT Class 3 Flammable liquids
3226:
3221:
3216:
1412:{\displaystyle V\geq 500LC_{50}}
977:{\displaystyle {\tfrac {mg}{L}}}
776:
763:
756:
749:
742:
735:
728:
701:
689:
682:
675:
189:
161:
131:
103:
3338:Midwest hazardous work training
3308:Australian Dangerous Goods Code
3260:HAZMAT Class 4 Flammable solids
1742:{\displaystyle V\geq .2LC_{50}}
1521:{\displaystyle V\geq 10LC_{50}}
3549:Substance of very high concern
3380:United Nations - International
3028:
3004:
2892:
2868:
2765:
2741:
2643:
2619:
2356:
2329:
1994:
1970:
1:
3396:National Transport Commission
3203:Accidents involving pipelines
3198:Accidents involving fireworks
1630:{\displaystyle V\geq LC_{50}}
3348:Safe handling of carcinogens
3285:HAZMAT Class 9 Miscellaneous
2556:
2553:
1366:
1363:
533:Load and Segregation Chart
3600:
2560:Ratio of Volatility and LC
2397:= partial pressure of the
789:
784:
777:
764:
757:
750:
743:
736:
729:
702:
690:
683:
676:
532:
240:PG III (Packing Group III)
184:
156:
3557:
3245:HAZMAT Class 1 Explosives
3214:
2592:{\displaystyle R\geq 500}
2559:
1816:
1369:
1299:{\displaystyle \leq 1000}
188:
160:
130:
102:
3529:Nickel hydrazine nitrate
3504:Consumption of Tide Pods
2714:{\displaystyle R\geq 10}
2194:{\displaystyle LC_{50i}}
1252:{\displaystyle \leq 300}
1153:{\displaystyle \leq 200}
1054:{\displaystyle \leq 0.2}
647:
642:
625:
3479:European hazard symbols
3449:NFPA 704 'Fire diamond'
3237:Dangerous cargo classes
2841:{\displaystyle R\geq 1}
2231:component substance in
2166:component of the liquid
2136:= mole fraction of the
1942:{\displaystyle LC_{50}}
1910:{\displaystyle LC_{50}}
1276:{\displaystyle >200}
1177:{\displaystyle >0.2}
1106:{\displaystyle \leq 50}
1030:{\displaystyle \leq 50}
509:Lethal Concentration 50
23:during transportation.
3065:
2978:
2929:
2842:
2802:
2715:
2680:
2593:
2537:
2497:
2448:
2421:
2420:{\displaystyle i^{th}}
2391:
2363:
2266:
2225:
2224:{\displaystyle i^{th}}
2195:
2160:
2159:{\displaystyle i^{th}}
2130:
2100:
2041:
1943:
1911:
1855:
1803:
1743:
1691:
1631:
1582:
1522:
1473:
1413:
1347:
1346:{\displaystyle \leq 4}
1324:
1300:
1277:
1253:
1230:
1229:{\displaystyle >50}
1201:
1200:{\displaystyle \leq 2}
1178:
1154:
1131:
1130:{\displaystyle >50}
1107:
1084:
1055:
1031:
1007:
1006:{\displaystyle \leq 5}
978:
935:
889:
495:
467:
447:
423:
3066:
2979:
2930:
2843:
2803:
2716:
2681:
2594:
2538:
2477:
2449:
2447:{\displaystyle P_{i}}
2422:
2392:
2390:{\displaystyle P_{i}}
2364:
2267:
2226:
2196:
2161:
2131:
2129:{\displaystyle f_{i}}
2101:
2021:
1944:
1912:
1856:
1804:
1744:
1692:
1632:
1583:
1523:
1474:
1414:
1348:
1325:
1323:{\displaystyle >2}
1301:
1278:
1254:
1231:
1202:
1179:
1155:
1132:
1108:
1085:
1083:{\displaystyle >5}
1056:
1032:
1008:
979:
936:
890:
496:
494:{\displaystyle T_{M}}
468:
448:
424:
3296:laws and regulations
3250:HAZMAT Class 2 Gases
3081:In the absence of LC
2988:
2953:
2852:
2826:
2725:
2699:
2603:
2577:
2467:
2431:
2401:
2374:
2281:
2235:
2205:
2172:
2140:
2113:
1954:
1923:
1891:
1824:
1753:
1714:
1641:
1605:
1532:
1493:
1423:
1384:
1334:
1311:
1287:
1264:
1240:
1217:
1188:
1165:
1141:
1118:
1094:
1071:
1042:
1018:
994:
954:
906:
860:
478:
457:
437:
310:
283:Determining Acute LD
178:: Packing Group III
3584:Hazardous materials
3367:Regulatory agencies
3333:Hong Kong ship laws
3294:Hazardous materials
3175:Hazardous materials
3110:(October 1, 2011).
2066:
2047:
2017:
2005:
943:Inhalation Toxicity
526:Compatibility table
197:Hazardous Materials
169:Hazardous Materials
139:Hazardous Materials
111:Hazardous Materials
59:Inhalation Toxicity
3539:Nuclear fuel cycle
3410:Hazardous material
3061:
3059:
2974:
2972:
2925:
2923:
2838:
2798:
2796:
2711:
2676:
2674:
2589:
2533:
2532:
2530:
2444:
2417:
2387:
2359:
2354:
2327:
2262:
2260:
2221:
2191:
2156:
2126:
2096:
2092:
2090:
2086:
2061:
2012:
1939:
1907:
1851:
1849:
1799:
1797:
1739:
1687:
1685:
1627:
1578:
1576:
1518:
1469:
1467:
1409:
1343:
1320:
1296:
1273:
1249:
1226:
1197:
1174:
1150:
1127:
1103:
1080:
1051:
1027:
1003:
974:
972:
931:
929:
885:
883:
491:
463:
443:
419:
417:
395:
366:
337:
17:Poisonous material
3571:
3570:
3412:labelling systems
3369:and organizations
3181:List of accidents
3091:
3090:
3079:
3078:
3058:
2971:
2922:
2795:
2673:
2529:
2353:
2326:
2259:
2094:
2088:
2065:
2046:
2016:
2004:
1873:
1872:
1848:
1796:
1684:
1575:
1466:
1356:
1355:
971:
928:
882:
823:
822:
818:
520:parts per million
506:
505:
466:{\displaystyle T}
446:{\displaystyle C}
416:
394:
365:
336:
228:Inhalation Hazard
214:
213:
210:
209:
182:
181:
152:
151:
124:
123:
3591:
3563:
3562:
3343:NA/UN exceptions
3230:
3229:
3225:
3224:
3220:
3219:
3169:
3162:
3155:
3146:
3134:
3133:
3131:
3129:
3123:
3116:
3104:
3070:
3068:
3067:
3062:
3060:
3057:
3056:
3047:
3039:
3003:
3002:
2983:
2981:
2980:
2975:
2973:
2964:
2934:
2932:
2931:
2926:
2924:
2921:
2920:
2911:
2903:
2867:
2866:
2847:
2845:
2844:
2839:
2807:
2805:
2804:
2799:
2797:
2794:
2793:
2784:
2776:
2740:
2739:
2720:
2718:
2717:
2712:
2685:
2683:
2682:
2677:
2675:
2672:
2671:
2662:
2654:
2618:
2617:
2598:
2596:
2595:
2590:
2551:
2542:
2540:
2539:
2534:
2531:
2528:
2527:
2526:
2510:
2509:
2500:
2496:
2491:
2453:
2451:
2450:
2445:
2443:
2442:
2426:
2424:
2423:
2418:
2416:
2415:
2396:
2394:
2393:
2388:
2386:
2385:
2368:
2366:
2365:
2360:
2355:
2352:
2351:
2342:
2334:
2328:
2322:
2321:
2312:
2306:
2305:
2293:
2292:
2271:
2269:
2268:
2263:
2261:
2258:
2257:
2248:
2240:
2230:
2228:
2227:
2222:
2220:
2219:
2200:
2198:
2197:
2192:
2190:
2189:
2165:
2163:
2162:
2157:
2155:
2154:
2135:
2133:
2132:
2127:
2125:
2124:
2105:
2103:
2102:
2097:
2095:
2093:
2091:
2089:
2087:
2085:
2084:
2083:
2062:
2060:
2059:
2058:
2043:
2040:
2035:
2013:
2011:
2001:
1969:
1968:
1948:
1946:
1945:
1940:
1938:
1937:
1916:
1914:
1913:
1908:
1906:
1905:
1860:
1858:
1857:
1852:
1850:
1847:
1846:
1837:
1829:
1808:
1806:
1805:
1800:
1798:
1795:
1794:
1785:
1777:
1768:
1767:
1748:
1746:
1745:
1740:
1738:
1737:
1696:
1694:
1693:
1688:
1686:
1683:
1682:
1673:
1665:
1656:
1655:
1636:
1634:
1633:
1628:
1626:
1625:
1587:
1585:
1584:
1579:
1577:
1574:
1573:
1564:
1556:
1547:
1546:
1527:
1525:
1524:
1519:
1517:
1516:
1478:
1476:
1475:
1470:
1468:
1465:
1464:
1455:
1447:
1438:
1437:
1418:
1416:
1415:
1410:
1408:
1407:
1361:
1352:
1350:
1349:
1344:
1329:
1327:
1326:
1321:
1305:
1303:
1302:
1297:
1282:
1280:
1279:
1274:
1258:
1256:
1255:
1250:
1235:
1233:
1232:
1227:
1206:
1204:
1203:
1198:
1183:
1181:
1180:
1175:
1159:
1157:
1156:
1151:
1136:
1134:
1133:
1128:
1112:
1110:
1109:
1104:
1089:
1087:
1086:
1081:
1060:
1058:
1057:
1052:
1036:
1034:
1033:
1028:
1012:
1010:
1009:
1004:
983:
981:
980:
975:
973:
967:
959:
940:
938:
937:
932:
930:
927:
919:
911:
894:
892:
891:
886:
884:
881:
873:
865:
845:
830:
813:
780:
779:
767:
766:
760:
759:
753:
752:
746:
745:
739:
738:
732:
731:
705:
704:
693:
692:
686:
685:
679:
678:
530:
500:
498:
497:
492:
490:
489:
472:
470:
469:
464:
452:
450:
449:
444:
428:
426:
425:
420:
418:
415:
414:
402:
396:
393:
392:
383:
382:
373:
367:
364:
363:
354:
353:
344:
338:
335:
334:
325:
324:
315:
280:
193:
186:
165:
158:
135:
128:
107:
100:
96:
3599:
3598:
3594:
3593:
3592:
3590:
3589:
3588:
3574:
3573:
3572:
3567:
3553:
3514:Dangerous goods
3497:Hazardous goods
3492:
3411:
3405:
3368:
3362:
3295:
3289:
3231:
3227:
3222:
3217:
3212:
3176:
3173:
3138:
3137:
3127:
3125:
3124:on 16 July 2019
3121:
3114:
3106:
3105:
3101:
3096:
3084:
3072:
3048:
3040:
2994:
2986:
2985:
2951:
2950:
2936:
2912:
2904:
2858:
2850:
2849:
2824:
2823:
2809:
2785:
2777:
2731:
2723:
2722:
2697:
2696:
2663:
2655:
2609:
2601:
2600:
2575:
2574:
2563:
2549:
2547:
2543:
2515:
2511:
2501:
2465:
2464:
2460:
2455:
2434:
2429:
2428:
2404:
2399:
2398:
2377:
2372:
2371:
2343:
2335:
2313:
2297:
2284:
2279:
2278:
2249:
2241:
2233:
2232:
2208:
2203:
2202:
2178:
2170:
2169:
2143:
2138:
2137:
2116:
2111:
2110:
2072:
2063:
2050:
2044:
2014:
2002:
1960:
1952:
1951:
1929:
1921:
1920:
1897:
1889:
1888:
1868:
1862:
1838:
1830:
1822:
1821:
1809:
1786:
1778:
1759:
1751:
1750:
1729:
1712:
1711:
1697:
1674:
1666:
1647:
1639:
1638:
1617:
1603:
1602:
1588:
1565:
1557:
1538:
1530:
1529:
1508:
1491:
1490:
1456:
1448:
1429:
1421:
1420:
1399:
1382:
1381:
1332:
1331:
1309:
1308:
1285:
1284:
1262:
1261:
1238:
1237:
1215:
1214:
1186:
1185:
1163:
1162:
1139:
1138:
1116:
1115:
1092:
1091:
1069:
1068:
1040:
1039:
1016:
1015:
992:
991:
960:
952:
951:
950:
946:
944:
920:
912:
904:
903:
902:
898:
897:Dermal Toxicity
874:
866:
858:
857:
856:
852:
840:
828:
812:
528:
516:
511:
502:
481:
476:
475:
455:
454:
435:
434:
429:
406:
384:
374:
355:
345:
326:
316:
308:
307:
286:
274:
269:Dermal Toxicity
263:
254:
249:
94:
53:Dermal Toxicity
29:
12:
11:
5:
3597:
3595:
3587:
3586:
3576:
3575:
3569:
3568:
3558:
3555:
3554:
3552:
3551:
3546:
3541:
3536:
3531:
3526:
3521:
3516:
3511:
3509:Crotonaldehyde
3506:
3500:
3498:
3494:
3493:
3491:
3490:
3489:
3488:
3487:European Union
3476:
3475:
3474:
3466:
3465:
3464:
3456:
3455:
3454:
3446:
3445:
3444:
3436:
3435:
3434:
3426:
3425:
3424:
3415:
3413:
3407:
3406:
3404:
3403:
3402:
3401:
3393:
3392:
3391:
3383:
3382:
3381:
3372:
3370:
3364:
3363:
3361:
3360:
3355:
3350:
3345:
3340:
3335:
3330:
3325:
3320:
3315:
3310:
3305:
3299:
3297:
3291:
3290:
3288:
3287:
3282:
3277:
3272:
3267:
3262:
3257:
3252:
3247:
3241:
3239:
3233:
3232:
3215:
3213:
3211:
3210:
3205:
3200:
3195:
3190:
3184:
3182:
3178:
3177:
3174:
3172:
3171:
3164:
3157:
3149:
3143:
3142:
3141:49 CFR 173.132
3136:
3135:
3098:
3097:
3095:
3092:
3089:
3088:
3082:
3077:
3076:
3055:
3051:
3046:
3043:
3036:
3033:
3030:
3027:
3024:
3021:
3018:
3015:
3012:
3009:
3006:
3001:
2997:
2993:
2970:
2967:
2961:
2958:
2948:
2945:
2941:
2940:
2919:
2915:
2910:
2907:
2900:
2897:
2894:
2891:
2888:
2885:
2882:
2879:
2876:
2873:
2870:
2865:
2861:
2857:
2837:
2834:
2831:
2821:
2818:
2814:
2813:
2792:
2788:
2783:
2780:
2773:
2770:
2767:
2764:
2761:
2758:
2755:
2752:
2749:
2746:
2743:
2738:
2734:
2730:
2710:
2707:
2704:
2694:
2691:
2687:
2686:
2670:
2666:
2661:
2658:
2651:
2648:
2645:
2642:
2639:
2636:
2633:
2630:
2627:
2624:
2621:
2616:
2612:
2608:
2588:
2585:
2582:
2572:
2569:
2565:
2564:
2561:
2558:
2555:
2554:Packing Group
2545:
2525:
2522:
2518:
2514:
2508:
2504:
2495:
2490:
2487:
2484:
2480:
2475:
2472:
2463:
2458:
2441:
2437:
2414:
2411:
2407:
2384:
2380:
2358:
2350:
2346:
2341:
2338:
2331:
2325:
2320:
2316:
2309:
2304:
2300:
2296:
2291:
2287:
2273:
2272:
2256:
2252:
2247:
2244:
2218:
2215:
2211:
2188:
2185:
2181:
2177:
2167:
2153:
2150:
2146:
2123:
2119:
2082:
2079:
2075:
2071:
2057:
2053:
2039:
2034:
2031:
2028:
2024:
2010:
1999:
1996:
1993:
1990:
1987:
1984:
1981:
1978:
1975:
1972:
1967:
1963:
1959:
1936:
1932:
1928:
1918:
1904:
1900:
1896:
1886:
1882:
1881:
1871:
1870:
1845:
1841:
1836:
1833:
1814:
1813:
1793:
1789:
1784:
1781:
1774:
1771:
1766:
1762:
1758:
1736:
1732:
1728:
1725:
1722:
1719:
1709:
1706:
1702:
1701:
1681:
1677:
1672:
1669:
1662:
1659:
1654:
1650:
1646:
1624:
1620:
1616:
1613:
1610:
1600:
1597:
1593:
1592:
1572:
1568:
1563:
1560:
1553:
1550:
1545:
1541:
1537:
1515:
1511:
1507:
1504:
1501:
1498:
1488:
1485:
1481:
1480:
1463:
1459:
1454:
1451:
1444:
1441:
1436:
1432:
1428:
1406:
1402:
1398:
1395:
1392:
1389:
1379:
1376:
1372:
1371:
1368:
1365:
1364:Packing Group
1354:
1353:
1342:
1339:
1319:
1316:
1306:
1295:
1292:
1272:
1269:
1259:
1248:
1245:
1225:
1222:
1212:
1208:
1207:
1196:
1193:
1173:
1170:
1160:
1149:
1146:
1126:
1123:
1113:
1102:
1099:
1079:
1076:
1066:
1062:
1061:
1050:
1047:
1037:
1026:
1023:
1013:
1002:
999:
989:
985:
984:
970:
966:
963:
948:
941:
926:
923:
918:
915:
900:
895:
880:
877:
872:
869:
854:
849:
835:
834:
827:
826:Packing groups
824:
821:
820:
810:
809:
803:
797:
787:
786:
782:
781:
774:
771:
768:
761:
754:
747:
740:
733:
726:
723:
720:
717:
714:
709:
706:
699:
694:
687:
680:
673:
668:
663:
657:
656:
651:
646:
640:
639:
634:
629:
624:
619:
614:
609:
604:
599:
594:
589:
584:
579:
574:
569:
564:
559:
554:
549:
544:
539:
535:
534:
527:
524:
514:
510:
507:
504:
503:
488:
484:
462:
442:
413:
409:
405:
399:
391:
387:
381:
377:
370:
362:
358:
352:
348:
341:
333:
329:
323:
319:
306:
305:
304:
303:
300:
296:
288:
287:
284:
278:
277:
272:
266:
261:
253:
252:Lethal Dose 50
250:
248:
245:
244:
243:
237:
231:
225:
212:
211:
208:
207:
200:
199:
194:
183:
180:
179:
172:
171:
166:
154:
153:
150:
149:
142:
141:
136:
125:
122:
121:
114:
113:
108:
93:
90:
79:
78:
70:
69:
68:
67:
63:acute toxicity
56:
50:
41:
40:
28:
25:
13:
10:
9:
6:
4:
3:
2:
3596:
3585:
3582:
3581:
3579:
3566:
3556:
3550:
3547:
3545:
3542:
3540:
3537:
3535:
3534:Nuclear flask
3532:
3530:
3527:
3525:
3522:
3520:
3517:
3515:
3512:
3510:
3507:
3505:
3502:
3501:
3499:
3495:
3486:
3485:
3484:
3480:
3477:
3472:
3471:
3470:
3467:
3462:
3461:
3460:
3457:
3452:
3451:
3450:
3447:
3442:
3441:
3440:
3437:
3433:International
3432:
3431:
3430:
3427:
3423:International
3422:
3421:
3420:
3417:
3416:
3414:
3408:
3399:
3398:
3397:
3394:
3389:
3388:
3387:
3384:
3379:
3378:
3377:
3374:
3373:
3371:
3365:
3359:
3356:
3354:
3351:
3349:
3346:
3344:
3341:
3339:
3336:
3334:
3331:
3329:
3326:
3324:
3321:
3319:
3316:
3314:
3311:
3309:
3306:
3304:
3301:
3300:
3298:
3292:
3286:
3283:
3281:
3278:
3276:
3273:
3271:
3268:
3266:
3263:
3261:
3258:
3256:
3253:
3251:
3248:
3246:
3243:
3242:
3240:
3238:
3234:
3209:
3206:
3204:
3201:
3199:
3196:
3194:
3191:
3189:
3186:
3185:
3183:
3179:
3170:
3165:
3163:
3158:
3156:
3151:
3150:
3147:
3140:
3139:
3120:
3113:
3109:
3103:
3100:
3093:
3087:
3086:the mixture.
3075:
3053:
3049:
3044:
3041:
3034:
3031:
3025:
3022:
3019:
3016:
3013:
3010:
3007:
2999:
2995:
2991:
2968:
2965:
2959:
2956:
2949:
2946:
2943:
2942:
2939:
2917:
2913:
2908:
2905:
2898:
2895:
2889:
2886:
2883:
2880:
2877:
2874:
2871:
2863:
2859:
2855:
2835:
2832:
2829:
2822:
2819:
2816:
2815:
2812:
2790:
2786:
2781:
2778:
2771:
2768:
2762:
2759:
2756:
2753:
2750:
2747:
2744:
2736:
2732:
2728:
2708:
2705:
2702:
2695:
2692:
2689:
2688:
2668:
2664:
2659:
2656:
2649:
2646:
2640:
2637:
2634:
2631:
2628:
2625:
2622:
2614:
2610:
2606:
2586:
2583:
2580:
2573:
2570:
2567:
2566:
2552:
2523:
2520:
2516:
2512:
2506:
2502:
2493:
2488:
2485:
2482:
2478:
2473:
2470:
2462:
2439:
2435:
2412:
2409:
2405:
2382:
2378:
2369:
2348:
2344:
2339:
2336:
2323:
2318:
2314:
2307:
2302:
2298:
2294:
2289:
2285:
2276:
2254:
2250:
2245:
2242:
2216:
2213:
2209:
2186:
2183:
2179:
2175:
2168:
2151:
2148:
2144:
2121:
2117:
2108:
2107:
2106:
2080:
2077:
2073:
2069:
2055:
2051:
2037:
2032:
2029:
2026:
2022:
2008:
1997:
1991:
1988:
1985:
1982:
1979:
1976:
1973:
1965:
1961:
1957:
1934:
1930:
1926:
1902:
1898:
1894:
1884:
1883:
1880:
1877:
1869:
1866:
1843:
1839:
1834:
1831:
1819:
1815:
1812:
1791:
1787:
1782:
1779:
1772:
1769:
1764:
1760:
1756:
1734:
1730:
1726:
1723:
1720:
1717:
1710:
1707:
1704:
1703:
1700:
1679:
1675:
1670:
1667:
1660:
1657:
1652:
1648:
1644:
1622:
1618:
1614:
1611:
1608:
1601:
1598:
1595:
1594:
1591:
1570:
1566:
1561:
1558:
1551:
1548:
1543:
1539:
1535:
1513:
1509:
1505:
1502:
1499:
1496:
1489:
1486:
1483:
1482:
1461:
1457:
1452:
1449:
1442:
1439:
1434:
1430:
1426:
1404:
1400:
1396:
1393:
1390:
1387:
1380:
1377:
1374:
1373:
1362:
1359:
1340:
1337:
1317:
1314:
1307:
1293:
1290:
1270:
1267:
1260:
1246:
1243:
1223:
1220:
1213:
1210:
1209:
1194:
1191:
1171:
1168:
1161:
1147:
1144:
1124:
1121:
1114:
1100:
1097:
1077:
1074:
1067:
1064:
1063:
1048:
1045:
1038:
1024:
1021:
1014:
1000:
997:
990:
987:
986:
968:
964:
961:
942:
924:
921:
916:
913:
896:
878:
875:
870:
867:
851:Oral Toxicity
850:
847:
846:
843:
837:
836:
832:
831:
825:
819:
816:
807:
804:
801:
798:
795:
792:
791:
788:
783:
775:
772:
769:
762:
755:
748:
741:
734:
727:
724:
721:
718:
715:
713:
710:
707:
700:
698:
695:
688:
681:
674:
672:
669:
667:
664:
662:
659:
658:
655:
652:
650:
645:
641:
638:
633:
628:
623:
618:
613:
608:
603:
598:
593:
588:
583:
578:
573:
568:
563:
558:
553:
548:
543:
536:
531:
525:
523:
521:
508:
486:
482:
474:
460:
440:
432:
411:
407:
403:
397:
389:
385:
379:
375:
368:
360:
356:
350:
346:
339:
331:
327:
321:
317:
301:
297:
294:
293:
290:
289:
282:
281:
270:
267:
259:
258:Oral Toxicity
256:
255:
251:
246:
241:
238:
235:
232:
229:
226:
223:
219:
216:
215:
205:
202:
201:
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187:
177:
174:
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170:
167:
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159:
155:
147:
144:
143:
140:
137:
134:
129:
119:
116:
115:
112:
109:
106:
101:
97:
91:
89:
87:
83:
76:
72:
71:
64:
60:
57:
54:
51:
48:
47:Oral Toxicity
45:
44:
43:
42:
37:
36:
35:
33:
26:
24:
22:
21:health hazard
18:
3269:
3126:. Retrieved
3119:the original
3102:
3080:
3073:
2937:
2810:
2557:Hazard Zone
2456:
2277:
2274:
1950:
1878:
1874:
1864:
1863:
1817:
1810:
1698:
1589:
1367:Hazard Zone
1357:
841:
814:
811:
805:
799:
793:
711:
696:
670:
666:Any Quantity
665:
660:
653:
648:
643:
636:
631:
626:
621:
616:
611:
606:
601:
596:
591:
586:
581:
576:
571:
566:
561:
556:
551:
546:
541:
512:
433:
430:
268:
257:
239:
233:
227:
222:gross weight
217:
203:
196:
175:
168:
148:: Biohazard
145:
138:
117:
110:
82:Division 6.2
81:
80:
58:
52:
46:
32:Division 6.1
31:
30:
16:
15:
3303:AIR Shipper
945:(Dust/Mist)
3094:References
86:Biohazards
3519:Explosive
3400:Australia
3032:≤
2960:≥
2896:≤
2833:≥
2769:≤
2706:≥
2647:≤
2584:≥
2479:∑
2308:×
2023:∑
1770:≤
1721:≥
1658:≤
1612:≥
1549:≤
1500:≥
1440:≤
1391:≥
1338:≤
1291:≤
1244:≤
1192:≤
1145:≤
1098:≤
1046:≤
1022:≤
998:≤
839:criteria:
247:Lethality
146:Class 6.2
120:: Poison
118:Class 6.1
27:Divisions
3578:Category
3565:Category
3544:Sedaxane
3328:HAZWOPER
206:: Toxic
92:Placards
75:tear gas
3439:Hazchem
3128:16 July
2370:where:
1919:1. The
815:Source:
538:
431:where:
204:Class 6
176:Class 6
3473:Canada
3429:UN ADR
2109:where
1887:Where
1865:Note 2
1818:Note 1
848:Group
773:
770:
725:
722:
719:
716:
708:
542:Weight
218:Poison
39:used):
3481:from
3122:(PDF)
3115:(PDF)
3071:; and
2935:; and
2808:; and
2324:101.3
234:Toxic
3130:2019
3035:5000
2984:and
2944:III
2899:3000
2848:and
2772:1000
2721:and
2599:and
1773:5000
1705:III
1661:3000
1552:1000
1330:but
1315:>
1294:1000
1283:but
1268:>
1236:but
1221:>
1211:III
1184:but
1169:>
1137:but
1122:>
1090:but
1075:>
785:Key
661:6.1A
271:: LD
260:: LD
3463:USA
3453:USA
3390:USA
2817:II
2650:200
2587:500
1596:II
1443:200
1394:500
1271:200
1247:300
1172:0.2
1148:200
1065:II
1049:0.2
627:6.1
622:5.2
617:5.1
612:4.3
607:4.2
602:4.1
592:2.3
587:2.2
582:2.2
577:2.1
572:1.6
567:1.5
562:1.4
557:1.3
552:1.2
547:1.1
404:100
3580::
3083:50
3000:50
2947:D
2864:50
2820:C
2737:50
2709:10
2693:B
2690:I
2615:50
2571:A
2568:I
2562:50
2546:50
2521:50
2459:50
2315:10
2184:50
2078:50
1966:50
1935:50
1903:50
1765:50
1749:;
1735:50
1724:.2
1708:D
1653:50
1637:;
1623:50
1599:C
1544:50
1528:;
1514:50
1503:10
1487:B
1484:I
1479:.
1435:50
1419:;
1405:50
1378:A
1375:I
1224:50
1125:50
1101:50
1025:50
988:I
949:50
947:LC
901:50
899:LD
855:50
853:LD
515:50
513:LC
299:or
285:50
273:50
262:50
88:.
84::
66:or
3168:e
3161:t
3154:v
3132:.
3054:3
3050:m
3045:L
3042:m
3029:)
3026:e
3023:r
3020:u
3017:t
3014:x
3011:i
3008:m
3005:(
2996:C
2992:L
2969:5
2966:1
2957:R
2918:3
2914:m
2909:L
2906:m
2893:)
2890:e
2887:r
2884:u
2881:t
2878:x
2875:i
2872:m
2869:(
2860:C
2856:L
2836:1
2830:R
2791:3
2787:m
2782:L
2779:m
2766:)
2763:e
2760:r
2757:u
2754:t
2751:x
2748:i
2745:m
2742:(
2733:C
2729:L
2703:R
2669:3
2665:m
2660:L
2657:m
2644:)
2641:e
2638:r
2635:u
2632:t
2629:x
2626:i
2623:m
2620:(
2611:C
2607:L
2581:R
2524:i
2517:C
2513:L
2507:i
2503:f
2494:n
2489:1
2486:=
2483:i
2474:=
2471:R
2440:i
2436:P
2413:h
2410:t
2406:i
2383:i
2379:P
2357:]
2349:3
2345:m
2340:L
2337:m
2330:[
2319:6
2303:i
2299:P
2295:=
2290:i
2286:V
2255:3
2251:m
2246:L
2243:m
2217:h
2214:t
2210:i
2187:i
2180:C
2176:L
2152:h
2149:t
2145:i
2122:i
2118:f
2081:i
2074:C
2070:L
2056:i
2052:f
2038:n
2033:1
2030:=
2027:i
2009:1
1998:=
1995:)
1992:e
1989:r
1986:u
1983:t
1980:x
1977:i
1974:m
1971:(
1962:C
1958:L
1931:C
1927:L
1899:C
1895:L
1844:3
1840:m
1835:L
1832:m
1792:3
1788:m
1783:L
1780:m
1761:C
1757:L
1731:C
1727:L
1718:V
1680:3
1676:m
1671:L
1668:m
1649:C
1645:L
1619:C
1615:L
1609:V
1571:3
1567:m
1562:L
1559:m
1540:C
1536:L
1510:C
1506:L
1497:V
1462:3
1458:m
1453:L
1450:m
1431:C
1427:L
1401:C
1397:L
1388:V
1341:4
1318:2
1195:2
1078:5
1001:5
969:L
965:g
962:m
925:g
922:k
917:g
914:m
879:g
876:k
871:g
868:m
806:E
800:O
794:X
712:O
697:O
671:E
654:A
649:B
644:A
637:8
632:7
597:3
487:M
483:T
461:T
441:C
412:M
408:T
398:=
390:Z
386:T
380:Z
376:C
369:+
361:B
357:T
351:B
347:C
340:+
332:A
328:T
322:A
318:C
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