Knowledge (XXG)

1,1-Difluoroethane

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Siegemund, Günter; Schwertfeger, Werner; Feiring, Andrew; Smart, Bruce; Behr, Fred; Vogel, Herward; McKusick, Blaine (2010). "Fluorine Compounds, Organic". In Bohnet, Matthias; Bellussi, Giuseppe; Bus, James; et al. (eds.).
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Most production, use, and emissions of HFC-152a have occurred within Earth's more industrialized and populated northern hemisphere following the substance's introduction in the 1990s. Its concentration in the northern
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in typical EI-MS, major peak at 65 m/z) distinct from anything in air. If mass peaks corresponding to 1,1-difluoroethane are observed immediately after spraying a suspect leak point, leaks may be identified.
880:. Despite its flammability, R152a also presents operating pressures and volumetric cooling capacity (VCC) similar to R134a so it can be used in large chillers or in more particular applications like 1027:
reached an annual average of about 10 parts per trillion by year 2011. The concentration of HFC-152a in the southern troposphere is about 50% lower due to its removal rate (i.e.
731: 985:, added voluntarily to some brands to deter purposeful inhalation, are often not legally required; they do not negate or counteract difluoroethane's intoxicating effects. 660: 1202:
Righetti, Giulia; Zilio, Claudio; Mancin, Simone; Longo, Giovanni A. (2018). "Heat Pipe Finned Heat Exchanger for Heat Recovery: Experimental Results and Modeling".
1683: 369: 1618:"Observations of 1,1-difluoroethane (HFC-152a) at AGAGE and SOGE monitoring stations in 1994–2004 and derived global and regional emission estimates" 1175:
Longo, Giovanni A.; Zilio, Claudio; Righetti, Giulia (2015). "Condensation of the low GWP refrigerant HFC152a inside a Brazed Plate Heat Exchanger".
899: 682: 1438: 876:(GWP) index of 124 and favorable thermophysical properties, 1,1-difluoroethane has been proposed as an environmentally friendly alternative to 930:
study, rats were exposed to up to 25,000 ppm (67,485 mg/m) for six hours daily, five days a week for two years. This has become the
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Difluoroethane is an extremely flammable gas, which decomposes rapidly on heating or burning, producing toxic and irritating fumes, including
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Broussard LA, Brustowicz T, Pittman T, Atkins KD, Presley L (November 1997). "Two traffic fatalities related to the use of difluoroethane".
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Avella J, Wilson JC, Lehrer M (March 2006). "Fatal cardiac arrhythmia after repeated exposure to 1,1-difluoroethane (DFE)".
1045: 738: 1111: 277: 1668: 298: 902:(GC-MS) systems. The cheap and freely available gas has a molecular weight and fragmentation pattern (base peak 51 898:
The molecular weight of difluoroethane is 66, making it a useful and convenient tool for detecting vacuum leaks in
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for this substance. Prolonged exposure to 1,1-difluoroethane has been linked in humans to the development of
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1,1-Difluoroethane is a synthetic substance that is produced by the mercury-catalyzed addition of
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and numerous other retail aerosol products, particularly those subject to stringent
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HFC-152a measured by the Advanced Global Atmospheric Gases Experiment (
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receptors. Fatalities linked to difluoroethane abuse include actress
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Except where otherwise noted, data are given for materials in their
1521:"Difluoroethane Inhalant Abuse, Skeletal Fluorosis, and Withdrawal" 1000: 992: 877: 797:-152a). It is also used as a propellant for aerosol sprays and in 261: 165: 155: 1460:
Novotny, Clara B; Irvin, Sarah; Espiridion, Eduardo D (2019).
1086:"Changes in Atmospheric Constituents and in Radiative Forcing" 903: 778: 1247:
in Linstrom, Peter J.; Mallard, William G. (eds.);
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Custer, Adam; Corse, Andrew; Vazirani, Sondra (June 2020).
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with abuse potential. It appears to act primarily through
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Growth of HFC-152a in Earth's atmosphere since year 2000.
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In addition, 1,1-difluoroethane is also commonly used in
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The American Journal of Forensic Medicine and Pathology
726: 813:(124) and a shorter atmospheric lifetime (1.4 years). 1570:"'Patriot' actress Skye McCole Bartusiak dead at 21" 249: 1314: 1312: 1091:. Cambridge University Press. 2007. p. 212 656: 141: 1144:Ullmann's Encyclopedia of Industrial Chemistry 1112:"Global Warming Potentials of ODS Substitutes" 8: 1252:, NIST Standard Reference Database Number 69 462:−24.7 °C (−12.5 °F; 248.5 K) 1295:National Library of Medicine HSDB Database 318: 227: 205: 28: 1641: 1544: 1495: 1477: 1414: 285: 452:−117 °C (−179 °F; 156 K) 1589: 1587: 1062: 374: 339: 314: 1397:Hahn, T; Avella, J; Lehrer, M (2006). 1177:Experimental Thermal and Fluid Science 218: 1684:Organic compounds with 2 carbon atoms 346:Key: NPNPZTNLOVBDOC-UHFFFAOYSA-N 185: 7: 1189:10.1016/j.expthermflusci.2015.06.010 1116:U.S. Environmental Protection Agency 900:Gas chromatography–mass spectrometry 844:The intermediate in this process is 1616:Greally, B.R.; et al. (2007). 1271:. U.S. National Library of Medicine 356:Key: NPNPZTNLOVBDOC-UHFFFAOYAM 240: 1333:10.1097/01.paf.0000202715.71009.0e 25: 1403:Journal of Analytical Toxicology 932:no-observed-adverse-effect level 716: 617: 612: 343:InChI=1S/C2H4F2/c1-2(3)4/h2H,1H3 65: 1622:Journal of Geophysical Research 1445:. 10 March 2012. Archived from 801:products. As an alternative to 712:(at 25 °C , 100 kPa). 353:InChI=1/C2H4F2/c1-2(3)4/h2H,1H3 785:, where it is often listed as 574:Occupational safety and health 1: 1224:10.1080/01457632.2017.1358483 1046:IPCC list of greenhouse gases 1364:Journal of Forensic Sciences 1568:Duke, Alan (22 July 2014). 1009:) in the lower atmosphere ( 35: 1700: 701:SDS for 1,1-difluoroethane 1204:Heat Transfer Engineering 1146:. John Wiley & Sons. 893:volatile organic compound 807:ozone depletion potential 706: 593: 571: 566: 385: 365: 330: 125: 90: 78: 73: 64: 34: 1152:10.1002/14356007.a11_349 884:finned heat exchangers. 874:global warming potential 811:global warming potential 989:Environmental abundance 759:organofluorine compound 1250:NIST Chemistry WebBook 1118:. 2010. Archived from 1018: 998: 872:With a relatively low 833:HCCH + 2 HF → CH 789:(refrigerant-152a) or 663: 55: 45: 1245:Ethane, 1,1-difluoro- 1004: 996: 971:Skye McCole Bartusiak 954:Difluoroethane is an 662: 102:Ethylidene difluoride 53: 43: 1643:10.1029/2006JD007527 1525:Federal Practitioner 1416:10.1093/jat/30.8.638 1291:"1,1-Difluoroethane" 1265:"1,1-Difluoroethane" 1041:List of refrigerants 895:(VOC) requirements. 645:(fire diamond) 80:Preferred IUPAC name 1634:2007JGRD..112.6308G 1479:10.7759/cureus.5565 1216:2018HTrEn..39.1011R 803:chlorofluorocarbons 588:Extremely flammable 488:Solubility in water 468:Critical point 424:g/mol 105:Ethylidene fluoride 31: 30:1,1-Difluoroethane 1669:Hydrofluorocarbons 1122:on 16 October 2010 1070:1,1-Difluoroethane 1019: 1015:parts-per-trillion 999: 944:cardiac arrhythmia 862:polyvinyl fluoride 751:1,1-Difluoroethane 739:Infobox references 664: 84:1,1-Difluoroethane 56: 46: 29: 1449:on 12 March 2012. 1376:10.1520/JFS14284J 1210:(12): 1011–1023. 917:hydrogen fluoride 823:hydrogen fluoride 809:of zero, a lower 795:hydrofluorocarbon 777:. This colorless 747:Chemical compound 745: 744: 695:Safety data sheet 299:CompTox Dashboard 167:Interactive image 60: 59: 16:(Redirected from 1691: 1679:Greenhouse gases 1648: 1647: 1645: 1613: 1607: 1606: 1604: 1602: 1591: 1582: 1581: 1579: 1577: 1565: 1559: 1558: 1548: 1516: 1510: 1509: 1499: 1481: 1457: 1451: 1450: 1435: 1429: 1428: 1418: 1394: 1388: 1387: 1359: 1353: 1352: 1316: 1307: 1306: 1304: 1302: 1287: 1281: 1280: 1278: 1276: 1261: 1255: 1242: 1236: 1235: 1199: 1193: 1192: 1172: 1166: 1165: 1138: 1132: 1131: 1129: 1127: 1108: 1102: 1101:18 February 2019 1100: 1098: 1096: 1090: 1082: 1076: 1067: 936:coronary disease 763:chemical formula 729: 723: 720: 719: 684: 677: 670: 655: 621: 616: 561: 557: 553: 536: 532: 528: 521: 517: 513: 496: 441: 437: 423: 393:Chemical formula 323: 322: 307: 305: 289: 253: 242: 231: 220: 209: 189: 169: 145: 69: 36: 32: 21: 1699: 1698: 1694: 1693: 1692: 1690: 1689: 1688: 1654: 1653: 1652: 1651: 1615: 1614: 1610: 1600: 1598: 1593: 1592: 1585: 1575: 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1178: 1171: 1168: 1163: 1157: 1153: 1149: 1145: 1137: 1134: 1121: 1117: 1113: 1107: 1104: 1087: 1081: 1078: 1075: 1074:Sigma-Aldrich 1071: 1066: 1063: 1056: 1052: 1049: 1047: 1044: 1042: 1039: 1038: 1034: 1032: 1030: 1026: 1016: 1012: 1008: 1003: 995: 988: 986: 984: 980: 977:and wrestler 976: 972: 968: 964: 957: 949: 947: 945: 941: 937: 933: 929: 924: 922: 918: 910: 908: 905: 901: 896: 894: 890: 885: 883: 879: 875: 867: 865: 863: 860:precursor to 859: 847: 832: 831: 830: 828: 824: 816: 814: 812: 808: 804: 800: 796: 792: 788: 784: 781:is used as a 780: 764: 760: 756: 752: 740: 733: 728: 711: 705: 702: 699: 696: 693: 692: 685: 678: 671: 647: 644: 643: 639: 638: 635: 632: 629: 625: 624: 620: 615: 611: 608: 604: 603: 599: 597: 592: 589: 586: 581: 580: 576: 575: 570: 565: 549: 547: 544: 543: 524: 509: 508: 506: 504: 501: 500: 492: 489: 485: 484: 480: 477: 473: 469: 466: 465: 461: 459: 458:Boiling point 456: 455: 451: 449: 448:Melting point 446: 445: 433: 431: 428: 427: 419: 417: 414: 413: 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Retrieved 1574:. Retrieved 1563: 1528: 1524: 1514: 1472:(9): e5565. 1469: 1465: 1455: 1447:the original 1442: 1433: 1406: 1402: 1392: 1367: 1363: 1357: 1327:(1): 58–60. 1324: 1320: 1299:. Retrieved 1294: 1285: 1273:. Retrieved 1268: 1259: 1248: 1240: 1207: 1203: 1197: 1180: 1176: 1170: 1143: 1136: 1126:20 September 1124:. Retrieved 1120:the original 1115: 1106: 1093:. Retrieved 1080: 1065: 1020: 975:Aaron Carter 953: 925: 914: 897: 886: 871: 843: 820: 805:, it has an 790: 786: 754: 750: 749: 641: 633: 595: 587: 583:Main hazards 572: 518:mmHg) @ 21.1 475: 471: 262:RTECS number 187:ChEMBL325493 126:Identifiers 91:Other names 26: 1601:12 February 1576:24 February 1183:: 509–515. 1025:troposphere 1011:troposphere 889:gas dusters 783:refrigerant 628:Signal word 577:(OHS/OSH): 386:Properties 225:100.000.788 117:Tinned Wind 1658:Categories 1628:(D06308). 1595:"HFC-152a" 1057:References 1051:Canned air 983:Bitterants 956:intoxicant 817:Production 799:gas duster 607:Pictograms 481:113.45 °C 416:Molar mass 287:0B1U8K2ME0 198:ChemSpider 154:3D model ( 133:CAS Number 99:Freon 152a 1537:1078-4497 1488:2168-8184 1232:126263840 979:Mike Bell 973:, singer 967:glutamate 882:heat pipe 858:monomeric 827:acetylene 761:with the 598:labelling 546:Viscosity 533:bar) @ 20 514:kPa (4020 493:0.54% @ 0 269:KI1410000 1555:32669782 1506:31695984 1425:17132266 1349:22312214 1341:16501351 1269:WebWISER 1035:See also 1029:lifetime 856:F), the 791:HFC-152a 757:, is an 642:NFPA 704 567:Hazards 558:cP) @ 25 529:kPa (5.1 438:g/L @ 25 108:HFC-152a 18:HFC-152a 1630:Bibcode 1546:7357883 1497:6820689 1384:9397568 1275:2 April 1212:Bibcode 732:what is 730: ( 430:Density 410: 238:PubChem 143:75-37-6 1553:  1543:  1535:  1504:  1494:  1486:  1466:Cureus 1423:  1382:  1347:  1339:  1301:8 June 1297:. 1994 1230:  1158:  1095:11 May 940:angina 928:DuPont 911:Safety 787:R-152a 727:verify 724:  697:(SDS) 634:Danger 560:  556:  552:  535:  531:  527:  520:  516:  512:  495:  440:  436:  422:  377:FC(F)C 370:SMILES 178:ChEMBL 111:R-152a 74:Names 1572:. CNN 1345:S2CID 1228:S2CID 1089:(PDF) 1007:AGAGE 950:Abuse 926:In a 878:R134a 753:, or 420:66.05 335:InChI 156:JSmol 1603:2021 1578:2019 1551:PMID 1533:ISSN 1502:PMID 1484:ISSN 1421:PMID 1380:PMID 1337:PMID 1303:2010 1277:2022 1156:ISBN 1128:2010 1097:2017 965:and 960:GABA 938:and 919:and 868:Uses 550:8.87 278:UNII 251:6368 207:6128 1638:doi 1626:112 1541:PMC 1492:PMC 1474:doi 1411:doi 1372:doi 1329:doi 1220:doi 1185:doi 1148:doi 1072:at 904:m/z 837:CHF 825:to 779:gas 755:DFE 596:GHS 562:°C 525:510 510:536 497:°C 442:°C 434:900 304:EPA 241:CID 114:DFE 1660:: 1636:. 1624:. 1620:. 1586:^ 1549:. 1539:. 1529:37 1527:. 1523:. 1500:. 1490:. 1482:. 1470:11 1468:. 1464:. 1441:. 1419:. 1407:30 1405:. 1401:. 1378:. 1368:42 1366:. 1343:. 1335:. 1325:27 1323:. 1311:^ 1293:. 1267:. 1226:. 1218:. 1208:39 1206:. 1181:68 1179:. 1154:. 1114:. 981:. 946:. 923:. 864:. 848:(C 829:: 600:: 537:°C 522:°C 478:) 474:, 1646:. 1640:: 1632:: 1605:. 1580:. 1557:. 1508:. 1476:: 1427:. 1413:: 1386:. 1374:: 1351:. 1331:: 1305:. 1279:. 1234:. 1222:: 1214:: 1191:. 1187:: 1164:. 1150:: 1130:. 1099:. 1017:. 962:A 854:3 852:H 850:2 839:2 835:3 793:( 775:2 773:F 771:4 769:H 767:2 765:C 722:Y 683:0 676:4 669:1 476:P 472:T 470:( 408:2 406:F 404:4 402:H 400:2 398:C 306:) 302:( 158:) 20:)

Index

HFC-152a
Difluoroethane
Difluoroethane
Difluoroethane
Preferred IUPAC name
CAS Number
75-37-6
JSmol
Interactive image
ChEMBL
ChEMBL325493
ChemSpider
6128
ECHA InfoCard
100.000.788
Edit this at Wikidata
PubChem
6368
RTECS number
UNII
0B1U8K2ME0
CompTox Dashboard
DTXSID0024050
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point

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