Knowledge (XXG)

Hexafluoro-2-butyne

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Brownridge, Scott; Du, Hongbin; Fairhurst, Shirley A.; Haddon, Robert C.; Oberhammer, Heinz; Parsons, Simon; Passmore, Jack; Schriver, Melbourne J.; Sutcliffe, Leslie H.; Westwood, Nicholas P. C. (2000). "The Isolation, Characterisation, Gas Phase Electron Diffraction and Crystal Structure of the
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cation. This derivative can be reduced to the 7 electron neutral radical. This particular 1,3,5-dithiazole is also rare example of a radical that can be obtained as solid, liquid, and gaseous states. As a gas, it is blue.
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E S Turbanova, A A Petrov (1991). "Perfluoroalkyl(aryl)acetylenes".
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Except where otherwise noted, data are given for materials in their
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Essers, Michael; Haufe, Günter (2006). "Hexafluoro-2-butyne".
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Journal of the Chemical Society, Dalton Transactions
186: 80: 710:Encyclopedia of Reagents for Organic Synthesis 8: 235: 146: 124: 15: 367:−117 °C (−179 °F; 156 K) 686: 291: 256: 231: 377:−25 °C (−13 °F; 248 K) 137: 659:3,4-bis(trifluoromethyl)-1,2-dithiete 263:Key: WBCLXFIDEDJGCC-UHFFFAOYSA-N 7: 273:Key: WBCLXFIDEDJGCC-UHFFFAOYAY 260:InChI=1S/C4F6/c5-3(6,7)1-2-4(8,9)10 177: 270:InChI=1/C4F6/c5-3(6,7)1-2-4(8,9)10 14: 638:HFB is prepared by the action of 559: 462: 457: 321: 31: 22: 765:10.1070/RC1991v060n05ABEH001092 555:(at 25 °C , 100 kPa). 536:Dimethyl acetylenedicarboxylate 50:1,1,1,4,4,4-Hexafluorobut-2-yne 657:It reacts with sulfur to give 604:with the chemical structure CF 421:Occupational safety and health 315: 1: 779:Thermally Stable Radical CF 843: 718:10.1002/047084289X.rn00669 644:acetylenedicarboxylic acid 822:Trifluoromethyl compounds 695:"Hexafluoro-2-butyne 99%" 664:Cycloaddition of HFB and 612:. HFB is a particularly 549: 524: 438: 418: 413: 393: 302: 282: 247: 64: 56: 44: 39: 30: 21: 744:Russian Chemical Reviews 505:Precautionary statements 634:Synthesis and reactions 646:or by the reaction of 628:Diels–Alder reactions 622:, and hence a potent 640:sulfur tetrafluoride 46:Preferred IUPAC name 17:Hexafluoro-2-butyne 757:1991RuCRv..60..501T 652:hexachlorobutadiene 594:Hexafluoro-2-butyne 540:Hexachlorobutadiene 384:Solubility in water 339: g·mol 294:FC(F)(F)C#CC(F)(F)F 18: 817:Alkyne derivatives 672:) gives the 1,2,5- 648:potassium fluoride 582:Infobox references 525:Related compounds 16: 791:(19): 3365–3382. 590:Chemical compound 588: 587: 531:Related compounds 487:Hazard statements 216:CompTox Dashboard 106:Interactive image 834: 801: 800: 797:10.1039/B001489N 775: 769: 768: 738: 732: 731: 705: 699: 698: 697:. Sigma-Aldrich. 691: 572: 566: 563: 562: 520: 516: 512: 498: 494: 466: 461: 338: 323: 317: 310:Chemical formula 240: 239: 224: 222: 190: 179: 158: 150: 139: 128: 108: 84: 35: 26: 19: 842: 841: 837: 836: 835: 833: 832: 831: 807: 806: 805: 804: 786: 782: 777: 776: 772: 740: 739: 735: 728: 707: 706: 702: 693: 692: 688: 683: 671: 666:dithionitronium 636: 611: 607: 591: 584: 579: 578: 577:  ?) 568: 564: 560: 556: 542: 538: 532: 507: 489: 475: 454: 431: 403: 386: 336: 326: 320: 312: 298: 295: 290: 289: 278: 275: 274: 271: 265: 264: 261: 255: 254: 243: 225: 218: 209: 193: 180: 168: 131: 111: 98: 87: 74: 60: 52: 51: 12: 11: 5: 840: 838: 830: 829: 824: 819: 809: 808: 803: 802: 784: 780: 770: 751:(5): 501–523. 733: 726: 700: 685: 684: 682: 679: 669: 635: 632: 609: 605: 589: 586: 585: 580: 558: 557: 553:standard state 550: 547: 546: 533: 530: 527: 526: 522: 521: 508: 503: 500: 499: 490: 485: 482: 481: 476: 471: 468: 467: 455: 450: 447: 446: 436: 435: 432: 429: 426: 425: 416: 415: 411: 410: 404: 399: 396: 395: 391: 390: 387: 382: 379: 378: 375: 369: 368: 365: 359: 358: 355: 349: 348: 347:Colorless gas 345: 341: 340: 334: 328: 327: 324: 318: 313: 308: 305: 304: 300: 299: 297: 296: 293: 285: 284: 283: 280: 279: 277: 276: 272: 269: 268: 266: 262: 259: 258: 250: 249: 248: 245: 244: 242: 241: 228: 226: 214: 211: 210: 208: 207: 203: 201: 195: 194: 192: 191: 183: 181: 173: 170: 169: 167: 166: 162: 160: 152: 151: 141: 133: 132: 130: 129: 121: 119: 113: 112: 110: 109: 101: 99: 92: 89: 88: 86: 85: 77: 75: 70: 67: 66: 62: 61: 58: 54: 53: 49: 48: 42: 41: 37: 36: 28: 27: 13: 10: 9: 6: 4: 3: 2: 839: 828: 827:Fluorocarbons 825: 823: 820: 818: 815: 814: 812: 798: 794: 790: 774: 771: 766: 762: 758: 754: 750: 746: 745: 737: 734: 729: 723: 719: 715: 711: 704: 701: 696: 690: 687: 680: 678: 675: 667: 662: 660: 655: 653: 649: 645: 641: 633: 631: 629: 625: 621: 618: 615: 614:electrophilic 603: 599: 595: 583: 576: 571: 554: 548: 545: 541: 537: 534: 529: 528: 523: 509: 506: 502: 501: 491: 488: 484: 483: 480: 477: 474: 470: 469: 465: 460: 456: 453: 449: 448: 444: 442: 437: 433: 428: 427: 423: 422: 417: 412: 409: 405: 402: 401:Dipole moment 398: 397: 392: 388: 385: 381: 380: 376: 374: 373:Boiling point 371: 370: 366: 364: 363:Melting point 361: 360: 356: 354: 351: 350: 346: 343: 342: 335: 333: 330: 329: 314: 311: 307: 306: 301: 292: 288: 281: 267: 257: 253: 246: 238: 234: 233:DTXSID3061003 230: 229: 227: 217: 213: 212: 205: 204: 202: 200: 197: 196: 189: 185: 184: 182: 176: 172: 171: 164: 163: 161: 159: 154: 153: 149: 145: 142: 140: 138:ECHA InfoCard 135: 134: 127: 123: 122: 120: 118: 115: 114: 107: 103: 102: 100: 96: 91: 90: 83: 79: 78: 76: 73: 69: 68: 63: 55: 47: 43: 38: 34: 29: 25: 20: 788: 773: 748: 742: 736: 709: 703: 689: 674:dithiazolium 663: 656: 637: 602:fluorocarbon 597: 593: 592: 478: 440: 430:Main hazards 419: 199:RTECS number 65:Identifiers 57:Other names 473:Signal word 424:(OHS/OSH): 357:1.602 g/cm 344:Appearance 303:Properties 144:100.010.667 811:Categories 727:0471936235 681:References 650:(KF) with 624:dienophile 620:derivative 452:Pictograms 434:Toxic gas 394:Structure 389:Insoluble 332:Molar mass 117:ChemSpider 93:3D model ( 72:CAS Number 617:acetylene 544:Acetylene 519:P410+P403 443:labelling 206:ES0702500 165:211-732-7 157:EC Number 414:Hazards 82:692-50-2 783:CSNSCCF 753:Bibcode 600:) is a 575:what is 573: ( 353:Density 337:162.034 175:PubChem 724:  570:verify 567:  479:Danger 287:SMILES 40:Names 608:C≡CCF 252:InChI 188:69654 126:62855 95:JSmol 722:ISBN 626:for 515:P311 511:P261 497:H331 493:H280 793:doi 787:". 761:doi 714:doi 668:(NS 642:on 598:HFB 441:GHS 221:EPA 178:CID 59:HFB 813:: 759:. 749:60 747:. 720:. 712:. 661:. 654:. 630:. 517:, 513:, 495:, 445:: 406:0 799:. 795:: 785:3 781:3 767:. 763:: 755:: 730:. 716:: 670:2 610:3 606:3 596:( 565:N 408:D 325:6 322:F 319:4 316:C 223:) 219:( 97:)

Index

Skeletal formula of hexafluoro-2-butyne
Ball-and-stick model of hexafluorobut-2-yne
Preferred IUPAC name
CAS Number
692-50-2
JSmol
Interactive image
ChemSpider
62855
ECHA InfoCard
100.010.667
Edit this at Wikidata
EC Number
PubChem
69654
RTECS number
CompTox Dashboard
DTXSID3061003
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Boiling point
Solubility in water
Dipole moment
D
Occupational safety and health

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