Knowledge (XXG)

ISO 31-8

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pH has no fundamental meaning; its official definition is a practical one. However, in the restricted range of dilute aqueous solutions having amount-of-substance concentrations less than 0.1 mol/L, and being neither strongly alkaline nor strongly acidic (2 < pH < 12), the definition is
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The mole is the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kg of C. When the mole is used, the elementary entities must be specified and may be atoms, molecules, ions, electrons, other particles, or specific groups of such particles.
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and adds in some cases in parentheses the Latin name for information, where the standard symbol has no relation to the English name of the element. Since the 1992 edition of the standard was published, some elements with atomic number above 103 have been discovered and renamed.
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of a galvanic cell that differs from the above one only by the replacement of the solution X of unknown pH, pH(X), by a solution S of a known standard pH, pH(S). Then obtain the pH of X as
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Defined this way, pH is a quantity of dimension 1, that is it has no unit. Values pH(S) for a range of standard solutions S are listed in
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Ratio of the average mass per molecule or specified entity of a substance to 1/12 of the mass of an atom of the nuclide C
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In the tables of quantities and their units, the ISO 31-8 standard shows symbols for substances as subscripts (e.g.,
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Attached subscripts or superscripts specifying a nucleotide or molecule have the following meanings and positions:
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Symbols for chemical elements shall be written in roman (upright) type. The symbol is not followed by a full-stop.
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Ratio of the average mass per atom of an element to 1/12 of the mass of an atom of the nuclide C
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Definitions of pH scales, standard reference values, measurement of pH, and related terminology
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denotes the activity coefficient of a typical uni-univalent electrolyte in the solution.
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may be indicated in the right superscript position (e.g., state of ionization Na)
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The definition applies to unbound atoms of C, at rest and in their ground state.
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reference electrode | concentrated solution of KCl | solution X | H
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Number of molecules or other elementary entities in a system
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The list given in ISO 31-8:1992 was quoted from the 1998
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Annex B: Symbols for chemical elements and nucleides
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Both quantities depend on the nuclidic composition.
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Quantities, Units and Symbols in Physical Chemistry
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Annex A: Names and symbols of the chemical elements
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For a solution X, first measure the 146:number of molecules or other elementary entities 259:, giving the names and standard symbols of the 396:and then also measure the electromotive force 517: 8: 524: 510: 502: 54: 63: 16:Part of international standard ISO 31 7: 29:that defines names and symbols for 14: 257:list of elements by atomic number 2815: 2814: 1: 2867: 2810: 543: 462:thermodynamic temperature 347:If necessary, a state of 321:The number of atoms of a 197: 107: 104: 101: 60: 57: 314:) is shown in the left 129:relative molecular mass 110:atomic/molecular weight 325:is shown in the right 263:from atomic number 1 ( 255:This annex contains a 24:international standard 87:relative atomic mass 51:Quantities and units 373:electromotive force 168:amount of substance 2841:Physical chemistry 537:by standard number 452:molar gas constant 318:position (e.g., N) 40:physical chemistry 2846:Molecular physics 2828: 2827: 551:ISO romanizations 407:pH(X) = pH(S) + ( 329:position (e.g., N 261:chemical elements 246:Normative annexes 202: 201: 44:molecular physics 2858: 2818: 2817: 538: 526: 519: 512: 503: 442:Faraday constant 108:Formerly called 55: 2866: 2865: 2861: 2860: 2859: 2857: 2856: 2855: 2831: 2830: 2829: 2824: 2806: 2730: 2456: 1608: 557: 539: 536: 530: 498: 483: 420: 413: 402: 391: 380: 362: 343: 332: 289: 253: 248: 241: 237: 229: 222: 215: 207: 138: 122: 120: 113: 96: 53: 22:is the part of 17: 12: 11: 5: 2864: 2862: 2854: 2853: 2848: 2843: 2833: 2832: 2826: 2825: 2823: 2822: 2811: 2808: 2807: 2805: 2804: 2799: 2794: 2789: 2784: 2779: 2774: 2769: 2764: 2759: 2754: 2749: 2744: 2738: 2736: 2732: 2731: 2729: 2728: 2723: 2718: 2713: 2710: 2705: 2700: 2695: 2690: 2685: 2680: 2675: 2670: 2665: 2660: 2655: 2650: 2645: 2640: 2635: 2630: 2625: 2620: 2615: 2610: 2605: 2600: 2595: 2590: 2585: 2580: 2575: 2570: 2565: 2560: 2555: 2550: 2545: 2540: 2535: 2530: 2525: 2520: 2515: 2510: 2505: 2500: 2495: 2490: 2485: 2480: 2475: 2470: 2464: 2462: 2458: 2457: 2455: 2454: 2449: 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577: 575: 572: 570: 567: 566: 564: 560: 556: 555:IEC standards 552: 548: 547:ISO standards 542: 534: 527: 522: 520: 515: 513: 508: 507: 504: 500: 495: 491: 479: 478: 477: 473: 471: 463: 459: 456: 453: 449: 446: 443: 439: 436: 435: 434: 428: 424: 417: 410: 406: 405: 404: 399: 387: 386: 385: 384: 383:galvanic cell 377: 374: 370: 369:operationally 366: 359: 354: 353:excited state 350: 346: 339: 338:proton number 335: 328: 324: 320: 317: 313: 309: 305: 304: 303: 297: 296: 295: 292: 286: 284: 281: 278:"Green Book" 277: 272: 270: 267:, H) to 109 ( 266: 262: 258: 250: 245: 243: 233: 226: 219: 212: 204: 196: 191: 188: 186: 183: 181: 178: 174: 171: 169: 166: 165: 162: 159: 156: 153: 151: 148: 145: 144: 140: 135: 132: 130: 127: 126: 117: 111: 98: 93: 90: 88: 85: 84: 80: 77: 74: 71: 68: 67: 56: 50: 48: 46: 45: 41: 36: 32: 28: 25: 21: 2673:27000 series 653: 493: 489: 487: 474: 467: 457: 447: 437: 432: 426: 422: 415: 408: 397: 395: 375: 363: 301: 293: 290: 273: 254: 231: 224: 217: 210: 208: 176: 172: 149: 133: 115: 109: 91: 38: 19: 18: 2461:20000–29999 1613:10000–19999 367:is defined 360:Annex C: pH 316:superscript 312:mass number 269:unnilennium 37:related to 2835:Categories 2240:16949 (TS) 1837:11941 (TR) 535:standards 476:such that 349:ionization 323:nucleotide 294:Examples: 75:Definition 31:quantities 2195:15926 WIP 1559:9592/9593 1484:9000/9001 1372:8805/8806 480:pH = −log 327:subscript 298:H He C Ca 114:Example: 58:Quantity 2820:Category 545:List of 271:, Une). 265:hydrogen 64:Remarks 20:ISO 31-8 2721:29199-2 2593:23094-2 2588:23094-1 2578:23090-3 2447:19794-5 2442:19775-1 2230:16612-2 2220:16355-1 1909:13406-2 1867:12234-2 1635:10118-3 460:is the 450:is the 440:is the 381:of the 81:Symbol 2851:ISO 31 2735:30000+ 1574:9797-1 1382:8820-5 1327:8501-1 883:1073-2 878:1073-1 562:1–9999 488:where 484:± 0.02 433:where 429:ln 10) 351:or an 72:Symbol 27:ISO 31 2802:80000 2797:56000 2792:55000 2787:50001 2782:45001 2777:42010 2772:40500 2767:39075 2762:38500 2757:37001 2752:32000 2747:31000 2742:30170 2726:29500 2716:29148 2712:29110 2708:28000 2703:27729 2698:27006 2693:27005 2688:27002 2683:27001 2678:27000 2668:26324 2663:26300 2658:26262 2653:26000 2648:25964 2643:25178 2638:24728 2633:24707 2628:24617 2623:24613 2618:24517 2613:23941 2608:23360 2603:23271 2598:23270 2583:23092 2573:23009 2568:23008 2563:23003 2558:23000 2553:22537 2548:22395 2543:22301 2538:22300 2533:22275 2528:22000 2523:21827 2518:21500 2513:21122 2508:21047 2503:21001 2498:21000 2493:20830 2488:20802 2483:20400 2478:20121 2473:20022 2468:20000 2452:19831 2437:19770 2432:19757 2427:19752 2422:19600 2417:19510 2412:19509 2407:19508 2402:19507 2397:19506 2392:19505 2387:19503 2382:19502 2377:19501 2372:19500 2367:19439 2362:19407 2357:19136 2352:19125 2347:19115 2342:19114 2325:19092 2320:19011 2315:19005 2310:18916 2305:18629 2300:18245 2295:18181 2290:18014 2285:18004 2280:17799 2275:17506 2270:17442 2265:17369 2260:17203 2255:17100 2250:17025 2245:17024 2235:16750 2225:16485 2215:16262 2210:16023 2205:15938 2200:15930 2190:15926 2185:15924 2180:15919 2175:15897 2170:15707 2158:15706 2153:15693 2148:15686 2143:15511 2138:15504 2133:15438 2128:15445 2111:15444 2106:15408 2101:15398 2096:15291 2091:15288 2086:15189 2081:15022 2076:14971 2071:14882 2066:14764 2061:14698 2056:14651 2051:14649 2046:14644 2041:14617 1989:14496 1984:14443 1979:14396 1974:14289 1969:14224 1964:14031 1959:14000 1954:13818 1949:13816 1944:13616 1939:13584 1934:13568 1929:13567 1924:13490 1919:13485 1914:13450 1904:13399 1899:13250 1894:13216 1877:13211 1872:12620 1862:12207 1857:12182 1852:12052 1847:12006 1842:11992 1832:11941 1822:11940 1817:11898 1812:11889 1807:11801 1802:11785 1797:11784 1792:11783 1787:11544 1782:11404 1777:11179 1772:11172 1767:11170 1762:11073 1757:10967 1752:10962 1747:10957 1742:10861 1737:10746 1732:10664 1727:10646 1722:10628 1717:10589 1712:10585 1707:10383 1675:10303 1670:10279 1665:10218 1660:10206 1655:10179 1650:10165 1645:10161 1640:10160 1630:10116 1625:10007 1620:10006 276:IUPAC 205:Notes 61:Unit 35:units 1700:-238 1604:9995 1599:9985 1594:9984 1589:9945 1584:9899 1579:9897 1569:9660 1564:9594 1554:9564 1549:9529 1544:9506 1539:9496 1534:9407 1529:9362 1524:9314 1519:9293 1514:9241 1509:9227 1504:9141 1499:9126 1494:9075 1489:9036 1479:8879 1432:-8-I 1387:8859 1377:8807 1367:8691 1362:8652 1357:8651 1352:8632 1347:8613 1342:8601 1337:8583 1332:8571 1322:8373 1317:8217 1312:8178 1307:8093 1302:8000 1297:7942 1292:7816 1287:7813 1282:7812 1277:7811 1272:7810 1267:7736 1262:7637 1250:7498 1245:7200 1240:7185 1235:7098 1230:7064 1225:7027 1220:7010 1215:7002 1210:7001 1205:6943 1200:6709 1195:6523 1190:6438 1185:6429 1180:6425 1175:6385 1170:6373 1165:6346 1160:6344 1155:6166 1150:5964 1145:5807 1140:5800 1135:5776 1130:5775 1125:5725 1120:5428 1115:5427 1110:5426 1105:5218 1100:4909 1095:4217 1090:4165 1085:4157 1080:4031 1075:3977 1070:3950 1065:3901 1060:3864 1055:3602 1050:3601 1045:3307 1040:3297 1018:3166 1013:3103 1008:3029 1003:2921 998:2852 993:2848 988:2788 983:2720 978:2711 973:2709 968:2533 963:2281 958:2240 953:2146 948:2145 943:2108 938:2047 933:2033 928:2022 923:2015 918:2014 913:1989 908:1745 903:1629 898:1538 893:1413 888:1155 873:1007 868:1004 863:1000 686:68-1 392:| Pt 336:The 306:The 198:... 185:mole 102:one 78:Name 69:Name 42:and 33:and 2034:-20 2029:-17 2024:-14 2019:-12 2014:-11 2009:-10 1695:-28 1690:-22 1685:-21 1680:-11 1472:-16 1467:-15 1462:-14 1457:-13 1452:-12 1447:-11 1442:-10 858:999 853:965 848:898 843:860 838:843 833:838 828:764 823:732 818:704 813:690 808:668 803:657 798:646 766:639 761:519 756:518 751:500 746:361 741:306 736:302 731:262 726:261 721:259 716:233 711:228 706:226 701:217 696:216 691:128 679:-13 674:-12 669:-11 664:-10 533:ISO 425:/ ( 344:Gd) 242:). 189:mol 175:, ( 157:one 2837:: 2335:-2 2330:-1 2163:-2 2121:-9 2116:-3 2004:-6 1999:-3 1994:-2 1887:-2 1882:-1 1826:-2 1437:-9 1427:-8 1422:-7 1417:-6 1412:-5 1407:-4 1402:-3 1397:-2 1392:-1 1255:-1 1033:-3 1028:-2 1023:-1 791:-6 786:-5 781:-3 776:-2 771:-1 659:-9 654:-8 649:-7 644:-6 639:-5 634:-4 629:-3 624:-1 619:-0 614:31 609:17 604:16 553:– 549:– 482:10 427:RT 421:) 414:− 365:pH 342:64 238:SO 234:(H 223:, 216:, 105:1 47:. 1828:) 1824:( 599:9 594:7 589:6 584:4 579:3 574:2 569:1 525:e 518:t 511:v 497:1 494:y 490:c 464:. 458:T 454:; 448:R 444:; 438:F 423:F 419:X 416:E 412:S 409:E 401:S 398:E 390:2 379:X 376:E 333:) 331:2 310:( 240:4 236:2 232:c 228:B 225:p 221:B 218:w 214:B 211:c 179:) 177:ν 173:n 160:1 150:N 137:r 134:M 119:r 116:A 112:. 95:r 92:A

Index

international standard
ISO 31
quantities
units
physical chemistry
molecular physics
relative atomic mass
relative molecular mass
amount of substance
mole
list of elements by atomic number
chemical elements
hydrogen
unnilennium
IUPAC
Quantities, Units and Symbols in Physical Chemistry
nucleon number
mass number
superscript
nucleotide
subscript
proton number
ionization
excited state
pH
operationally
electromotive force
galvanic cell
Faraday constant
molar gas constant

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