Knowledge (XXG)

Inductive cleavage

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To neutralize the positive charge on the ionization site a single two-electron transfer must be made. Neutralization of the positive charge at the ionization site is performed at the expense of the atom adjacent to the ionization site, transferring the positive charge to this atom as a result of the
96: 173: 66:"Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)" 27:. Since inductive cleavage does not require unpairing and re-pairing electrons it can occur at both radical cationic and cationic sites. 202: 166: 159: 197: 192: 139: 36: 20: 143: 110: 77: 131: 24: 186: 44: 106: 101: 105:, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) " 114: 82: 65: 23:, is the charge-initiated counterpoint to radical initiated 147: 35:Generally this topic is discussed when covering 167: 39:and occurs generally by the same mechanisms. 8: 174: 160: 81: 56: 7: 128: 126: 146:. You can help Knowledge (XXG) by 102:Compendium of Chemical Terminology 14: 130: 1: 107:α-cleavage (alpha-cleavage) 219: 203:Analytical chemistry stubs 125: 70:Pure and Applied Chemistry 115:10.1351/goldbook.A00004 83:10.1351/pac199163101541 64:Todd, J. F. J. (1991). 140:analytical chemistry 138:This article about 17:Inductive cleavage 198:Mass spectrometry 193:Organic reactions 155: 154: 37:mass spectrometry 31:Mass spectrometry 21:organic chemistry 210: 176: 169: 162: 134: 127: 117: 94: 88: 87: 85: 61: 218: 217: 213: 212: 211: 209: 208: 207: 183: 182: 181: 180: 123: 121: 120: 95: 91: 63: 62: 58: 53: 33: 12: 11: 5: 216: 214: 206: 205: 200: 195: 185: 184: 179: 178: 171: 164: 156: 153: 152: 135: 119: 118: 89: 55: 54: 52: 49: 32: 29: 25:alpha-cleavage 13: 10: 9: 6: 4: 3: 2: 215: 204: 201: 199: 196: 194: 191: 190: 188: 177: 172: 170: 165: 163: 158: 157: 151: 149: 145: 141: 136: 133: 129: 124: 116: 112: 108: 104: 103: 98: 93: 90: 84: 79: 75: 71: 67: 60: 57: 50: 48: 46: 45:bond cleavage 40: 38: 30: 28: 26: 22: 18: 148:expanding it 137: 122: 100: 92: 76:(10): 1541. 73: 69: 59: 41: 34: 16: 15: 187:Categories 51:References 142:is a 97:IUPAC 19:, in 144:stub 111:doi 109:". 78:doi 189:: 99:, 74:63 72:. 68:. 47:. 175:e 168:t 161:v 150:. 113:: 86:. 80::

Index

organic chemistry
alpha-cleavage
mass spectrometry
bond cleavage
"Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)"
doi
10.1351/pac199163101541
IUPAC
Compendium of Chemical Terminology
α-cleavage (alpha-cleavage)
doi
10.1351/goldbook.A00004
Stub icon
analytical chemistry
stub
expanding it
v
t
e
Categories
Organic reactions
Mass spectrometry
Analytical chemistry stubs

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