24:
281:
188:
657:
668:
449:
444:
33:
592:
699:
Sigma-Aldrich Co. gives a value for the flash point of isoprenol of 42 °C (108 °F). The difference in the two values does not alter the safety classification of isoprenol as a category 3 flammable liquid under the
701:
457:
424:
704:; but the lower value quoted here (from the New Zealand Environmental Risk Management Authority) would make it a class IC flammable liquid instead of a class II combustible liquid under the U.S.
656:
531:
667:
605:
527:
664:
The thermodynamically preferred prenol with the more substituted double bond cannot be directly formed in the above reaction, but is produced via a subsequent isomerisation:
705:
327:
495:
23:
295:
793:
Kogan, S. B.; Kaliya, M.; Froumin, N. (2006), "Liquid phase isomerization of isoprenol into prenol in hydrogen environment",
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32:
489:
238:
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The reaction of isobutene with formaldehyde to give isoprenol, the first step in the industrial manufacture of prenol.
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The isomerization of isoprenol to prenol, the second step in the industrial manufacture of prenol.
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780:, SIDS Initial Assessment Report, Geneva: United Nations Environment Programme, May 2005
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772:
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732:
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176:
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227:
806:
642:(prenol): global production in 2001 can be estimated as 6–13 thousand tons.
708:
classification (29 C.F.R § 1910.106), and F3 rather than F2 under the
632:
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369:
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This isomerisation reaction is catalyzed by any species which can form an
709:
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Except where otherwise noted, data are given for materials in their
116:
104:
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782:. Major produce in a world is BASF(Germany) and Kuraray(Japan).
683:
of the substrate, for example poisoned palladium catalysts.
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130 to 132 °C (266 to 270 °F; 403 to 405 K)
600:
754:, New Zealand Environmental Risk Management Authority
638:. It is produced industrially as an intermediate to
751:HSNO Chemical Classification Information Database
226:
80:
645:Isoprenol is produced by the reaction between
8:
304:InChI=1S/C5H10O/c1-5(2)3-4-6/h6H,1,3-4H2,2H3
314:InChI=1/C5H10O/c1-5(2)3-4-6/h6H,1,3-4H2,2H3
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307:Key: CPJRRXSHAYUTGL-UHFFFAOYSA-N
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559:36 °C (97 °F; 309 K)
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14:
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586:(at 25 °C , 100 kPa).
1:
807:10.1016/j.apcata.2005.09.010
739:. Retrieved on 2009-08-31..
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374:86.132 g/mol
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490:Precautionary statements
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649:(2-methylpropene) and
774:3-Methyl-2-buten-1-ol
737:3-Methyl-3-buten-1-ol
670:
659:
640:3-methylbut-2-en-1-ol
629:3-methylbut-3-en-1-ol
59:3-Methyl-3-buten-1-ol
50:3-Methylbut-3-en-1-ol
795:Appl. Catal. A: Gen.
46:Preferred IUPAC name
18:
679:without excessive
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662:
613:Infobox references
564:Related compounds
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733:Sigma-Aldrich Co.
621:Chemical compound
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570:Related compounds
472:Hazard statements
260:CompTox Dashboard
106:Interactive image
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584:standard state
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532:P305+P351+P338
528:P303+P361+P353
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801:(2): 231–36,
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710:NFPA 704
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681:hydrogenation
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677:allyl complex
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390:Boiling point
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178:ECHA InfoCard
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146:ChEMBL3561140
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827:Hemiterpenes
798:
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787:
773:
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756:, retrieved
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695:
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663:
651:formaldehyde
644:
628:
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623:
463:
425:
404:
65:Identifiers
57:Other names
791:See, e.g.,
633:hemiterpene
555:Flash point
458:Signal word
384:0.853 g/cm
344:Properties
184:100.011.009
126:CHEBI:62898
821:Categories
758:2009-08-31
720:References
437:Pictograms
370:Molar mass
248:KJ25C8CPFA
157:ChemSpider
93:3D model (
72:CAS Number
17:Isoprenol
712:standard.
647:isobutene
625:Isoprenol
544:P403+P235
540:P370+P378
536:P337+P313
428:labelling
335:OCCC(=C)C
205:212-110-8
197:EC Number
832:Alkenols
419:Hazards
364:O
82:763-32-6
636:alcohol
631:, is a
606:what is
604: (
464:Warning
380:Density
215:PubChem
601:verify
598:
575:Prenol
414:1.433
328:SMILES
137:ChEMBL
40:Names
778:(PDF)
687:Notes
296:InChI
228:12988
166:12448
117:ChEBI
95:JSmol
706:OSHA
548:P501
524:P280
520:P264
516:P243
512:P242
508:P241
504:P240
500:P233
496:P210
482:H319
478:H226
239:UNII
803:doi
799:297
702:GHS
426:GHS
265:EPA
218:CID
823::
797:,
735:,
653:.
546:,
542:,
538:,
534:,
530:,
526:,
522:,
518:,
514:,
510:,
506:,
502:,
498:,
480:,
430::
362:10
810:.
805::
762:.
596:Y
410:)
408:D
405:n
403:(
360:H
358:5
356:C
267:)
263:(
97:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
