Knowledge (XXG)

Linear chain compound

Source 📝

20: 189: 174: 566:
Grate, J. W.; Moore, L. K.; Janzen, D. E.; Veltkamp, D. J.; Kaganove, S.; Drew, S. M.; Mann, K. R. (2002). "Steplike Response Behavior of a New Vapochromic Platinum Complex Observed with Simultaneous Acoustic Wave Sensor and Optical Reflectance Measurements".
664:
Mino, Y; Mochizuki, E; Kai, Y; Kurosawa, H (2001). "Reversible Interconversion between Dinuclear Sandwich and Half-Sandwich Complexes: Unique Dynamic Behavior of a Pd-Pd Moiety Surrounded by an sp-Carbon Framework".
635:
Buss, C.E.; Anderson, C.E.; Pomije, M. K.; Lutz, C. M.; Britton, D.; Mann, K. R. (1998). "Structural Investigations of Vapochromic Behavior. X-ray Single-Crystal and Powder Diffraction Studies of for M = Pt or Pd".
718: 524:
Hua, Shao-An; Liu, Isiah Po-Chun; Hasanov, Hasan; Huang, Gin-Chen; Ismayilov, Rayyat Huseyn; Chiu, Chien-Lan; Yeh, Chen-Yu; Lee, Gene-Hsiang; Peng, Shie-Ming (2010).
693:
Murahashi, T; Nagai, Okuno, T; Matsutani, T; Kurosawa, H. (2000). "Synthesis and ligand substitution reactions of a homoleptic acetonitrile dipalladium(I) complex".
312: 526:"Probing the electronic communication of linear heptanickel and nonanickel string complexes by utilizing two redox-active [Ni2(napy)4]3+ moieties" 55: 785: 749: 394: 193: 19: 495: 352: 67: 780: 166:(EMACs) are molecules or ions that consist of a finite, often short, linear strings of metal atoms, surrounded by organic 775: 410:
Huq, Fazlul; Skapski, Andrzej C. (1974). "Refinement of the crystal structure of acetylacetonatodicarbonylrhodium(I)".
338:
Bera, J. K.; Dunbar, K. R. (2002). "Chain Compounds Based on Transition Metal Backbones: New Life for an Old Topic".
163: 281: 599:\-(C2H5)C6H4)2(CN)2, a Crystalline Vapoluminescent Compound That Detects Vapor-Phase Aromatic Hydrocarbons". 770: 90: 23: 712: 340: 280:
Not only do these olefin-stabilized metal chains constitute a significant contribution to the field of
478:
Ginsberg, A. P.; Koepke, J. W.; Sprinkle, C. R. (2007). "Linear-Chain Iridium Carbonyl Halides".
427: 268: 525: 86: 745: 667: 638: 617: 601: 548: 491: 390: 356: 35: 737: 700: 675: 646: 609: 577: 540: 483: 458: 419: 382: 348: 303:. The technique is used to obtain single crystals of low-dimensional electrical conductors. 43: 108:
gives an electrically conductive derivative upon oxidation, e.g., with bromine to give
764: 695: 431: 732:
Williams, Jack M (1989). "Highly Conducting and Superconducting Synthetic Metals".
569: 300: 741: 463: 446: 487: 386: 51: 274:
materials, or materials which change color when exposed to different vapors.
82: 31: 621: 552: 360: 277:
Linear chains of Pd-Pd bonds protected by a "π-electron sheath" are known.
211:
One group of platinum chains is based on alternating cations and anions of
353:
10.1002/1521-3773(20021202)41:23<4453::AID-ANIE4453>3.0.CO;2-1
595:
Buss, C.E.; Mann, K.R. (2002). "Synthesis and Characterization of Pt(CN\-
16:
Materials made of one-dimensional arrays of metal-metal bonded molecules
423: 288: 679: 650: 613: 581: 704: 544: 285: 271: 167: 188: 187: 173: 18: 203:) showing the "stacking" of the individual planar units through 510:
F. Albert Cotton, Carlos A. Murillo, Richard A. Walton (eds.),
47: 93:. Another example is the partially oxidized derivatives of 299:
Some linear chain compounds are produced or fabricated by
445:
Tsuji, Yuta; Hoffmann, Roald; Miller, Joel S. (2016).
125:, where x ~0.05. Related chlorides have the formulae 42:
are materials composed of one-dimensional arrays of
284:, both the complex's metal atom structures and the 377:Miller, Joel S. (1982). Miller, Joel S (ed.). 8: 717:: CS1 maint: multiple names: authors list ( 70:. Thus, upon crystallization, molecules of 462: 26:is an example of a linear chain compound. 372: 370: 262: 255: 251: 247: 243: 233: 229: 214: 199: 180: 172: 154: 150: 146: 142: 135: 128: 118: 111: 104: 96: 73: 323: 162:In contrast to linear chain compounds, 710: 333: 331: 329: 327: 194:Dicarbonyl(acetylacetonato)rhodium(I) 7: 267:. These may be able to be used as 736:. Vol. 26. pp. 386–394. 512:Multiple Bonds Between Metal Atoms 291:themselves can conduct a current. 14: 101:. The otherwise ordinary complex 482:. Vol. 19. pp. 18–22. 379:Extended Linear Chain Compounds 514:, 3rd edition, Springer (2005) 66:Most examples are composed of 1: 786:Semiconductor material types 81:distances of about 326  85:. Classic examples include 802: 742:10.1002/9780470132579.ch70 464:10.1016/j.poly.2015.09.050 192:Portion of the lattice of 164:extended metal atom chains 50:. Such materials exhibit 488:10.1002/9780470132500.ch5 387:10.1007/978-1-4613-3249-7 282:organometallic chemistry 68:square planar complexes 447:"Revisiting Ir(CO)3Cl" 301:electrocrystallization 208: 205:Rh···Rh 185: 79:Rh···Rh 40:linear chain compounds 27: 781:Molecular electronics 412:J. Cryst. Mol. Struct 341:Angew. Chem. Int. Ed. 191: 176: 22: 776:Conductive polymers 734:Inorganic Syntheses 533:Dalton Transactions 480:Inorganic Syntheses 381:. Springer-Verlag. 91:Magnus's green salt 24:Magnus's green salt 424:10.1007/BF01220097 209: 186: 44:metal-metal bonded 28: 751:978-0-470-13257-9 699:(17): 1689–1690. 680:10.1021/ja010027y 674:(28): 6927–6928. 668:J. Am. Chem. Soc. 651:10.1021/ja981218c 645:(31): 7783–7790. 639:J. Am. Chem. Soc. 614:10.1021/ja011986v 602:J. Am. Chem. Soc. 582:10.1021/cm0104506 396:978-1-4613-3251-0 347:(23): 4453–4457. 36:materials science 793: 756: 755: 729: 723: 722: 716: 708: 705:10.1039/b004726k 690: 684: 683: 661: 655: 654: 632: 626: 625: 608:(6): 1031–1039. 592: 586: 585: 576:(3): 1058–1066. 563: 557: 556: 545:10.1039/b923125k 530: 521: 515: 508: 502: 501: 475: 469: 468: 466: 442: 436: 435: 407: 401: 400: 374: 365: 364: 335: 266: 258: 236: 218: 206: 202: 183: 158: 138: 124: 107: 100: 95:[Pt(oxalate) 80: 76: 801: 800: 796: 795: 794: 792: 791: 790: 761: 760: 759: 752: 731: 730: 726: 709: 692: 691: 687: 663: 662: 658: 634: 633: 629: 594: 593: 589: 565: 564: 560: 528: 523: 522: 518: 509: 505: 498: 477: 476: 472: 444: 443: 439: 409: 408: 404: 397: 376: 375: 368: 337: 336: 325: 321: 309: 297: 264: 260: 257: 253: 249: 245: 238: 235: 231: 224: 216: 212: 204: 201: 197: 182: 178: 156: 152: 148: 144: 140: 137: 133: 126: 123: 116: 109: 106: 102: 98: 94: 87:Krogmann's salt 78: 75: 71: 64: 17: 12: 11: 5: 799: 797: 789: 788: 783: 778: 773: 771:Nanotechnology 763: 762: 758: 757: 750: 724: 685: 656: 627: 587: 558: 539:(16): 3890–6. 516: 503: 496: 470: 437: 418:(6): 411–418. 402: 395: 366: 322: 320: 317: 316: 315: 308: 305: 296: 293: 63: 60: 15: 13: 10: 9: 6: 4: 3: 2: 798: 787: 784: 782: 779: 777: 774: 772: 769: 768: 766: 753: 747: 743: 739: 735: 728: 725: 720: 714: 706: 702: 698: 697: 696:Chem. Commun. 689: 686: 681: 677: 673: 670: 669: 660: 657: 652: 648: 644: 641: 640: 631: 628: 623: 619: 615: 611: 607: 604: 603: 598: 591: 588: 583: 579: 575: 572: 571: 562: 559: 554: 550: 546: 542: 538: 534: 527: 520: 517: 513: 507: 504: 499: 497:9780470132500 493: 489: 485: 481: 474: 471: 465: 460: 456: 452: 448: 441: 438: 433: 429: 425: 421: 417: 413: 406: 403: 398: 392: 388: 384: 380: 373: 371: 367: 362: 358: 354: 350: 346: 343: 342: 334: 332: 330: 328: 324: 318: 314: 311: 310: 306: 304: 302: 294: 292: 290: 287: 283: 278: 275: 273: 270: 241: 227: 222: 207:interactions. 195: 190: 175: 171: 169: 165: 160: 132: 122: 115: 92: 88: 84: 69: 61: 59: 57: 53: 49: 46:molecules or 45: 41: 37: 33: 25: 21: 733: 727: 713:cite journal 694: 688: 671: 666: 659: 642: 637: 630: 605: 600: 596: 590: 573: 570:Chem. Mater. 568: 561: 536: 532: 519: 511: 506: 479: 473: 454: 450: 440: 415: 411: 405: 378: 344: 339: 313:platinum pop 298: 279: 276: 239: 225: 220: 213:[Pt(CNR) 210: 198:Rh(acac)(CO) 161: 130: 120: 113: 72:Rh(acac)(CO) 65: 56:conductivity 39: 29: 457:: 141–149. 295:Methodology 269:vapochromic 261:[Pt(CN) 77:stack with 54:electrical 52:anisotropic 765:Categories 451:Polyhedron 319:References 32:chemistry 622:11829612 553:20372713 432:96977904 361:12458505 307:See also 153:·½H 103:IrBr(CO) 62:Examples 289:ligands 168:ligands 748:  620:  551:  494:  430:  393:  359:  286:olefin 272:sensor 259:) and 145:Ir(CO) 529:(PDF) 428:S2CID 219:(R = 184:EMAC. 746:ISBN 719:link 618:PMID 549:PMID 492:ISBN 391:ISBN 357:PMID 223:Pr, 139:and 134:(CO) 127:IrCl 117:(CO) 110:IrBr 89:and 48:ions 34:and 738:doi 701:doi 676:doi 672:123 647:doi 643:120 610:doi 606:124 578:doi 541:doi 484:doi 459:doi 455:103 420:doi 383:doi 349:doi 242:-(C 177:An 143:0.6 30:In 767:: 744:. 715:}} 711:{{ 616:. 574:14 547:. 537:39 535:. 531:. 490:. 453:. 449:. 426:. 414:. 389:. 369:^ 355:. 345:41 326:^ 250:)C 237:, 234:23 230:12 228:-C 179:Ni 170:. 159:. 149:Cl 129:1+ 119:3− 112:1+ 83:pm 58:. 38:, 754:. 740:: 721:) 707:. 703:: 682:. 678:: 653:. 649:: 624:. 612:: 597:p 584:. 580:: 555:. 543:: 500:. 486:: 467:. 461:: 434:. 422:: 416:4 399:. 385:: 363:. 351:: 265:] 263:4 256:4 254:H 252:6 248:5 246:H 244:2 240:p 232:H 226:c 221:i 217:] 215:4 200:2 196:( 181:9 157:O 155:2 151:2 147:2 141:K 136:3 131:x 121:x 114:x 105:3 99:] 97:2 74:2

Index


Magnus's green salt
chemistry
materials science
metal-metal bonded
ions
anisotropic
conductivity
square planar complexes
pm
Krogmann's salt
Magnus's green salt
extended metal atom chains
ligands


Dicarbonyl(acetylacetonato)rhodium(I)
vapochromic
sensor
organometallic chemistry
olefin
ligands
electrocrystallization
platinum pop




Angew. Chem. Int. Ed.
doi

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.