Knowledge (XXG)

Phosphorite

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402:: Estuarine environments, or estuaries, are located at the lower parts of rivers that flow into the open sea. Since they are in the seaward section of the drowned valley system they receive sediment from both marine and fluvial sources. These contain facies that are affected by tide and wave fluvial processes. An estuary is considered to stretch from the landward limit of tidal facies to the seaward limit of coastal facies. Phosphorites are often deposited in fjords within estuarine environments. These are estuaries with shallow sill constrictions. During Holocene sea-level rise, fjord estuaries formed by drowning of glacially-eroded U-shaped valleys. 20: 32: 488: 476: 382:. Normally phosphates are deposited in very shallow, near-shore marine or low energy environments. This includes environments such as supratidal zones, littoral or intertidal zones, and most importantly estuarine. Currently, areas of oceanic upwelling cause the formation of phosphates. This is because of the constant stream of phosphate brought from the large, deep ocean reservoir (see below). This cycle allows continuous growth of organisms. 458:
sediment. There are two different environmental conditions in which phosphorites are produced within continental margins. Continental margins can consist of organic rich sedimentation, strong coastal upwelling, and pronounced low oxygen zones. They can also form in conditions such as oxygen rich bottom waters and organic poor sediments.
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from continental weathering, brought out by rivers to the ocean. It is then processed by both micro- and macro-organisms. Diatomaceous plankton, phytoplankton, and zooplankton process and dissolve phosphorus in the water. The bones and teeth of certain fish (e.g. anchovies) absorb phosphorus and are later deposited and buried in the
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Rare earth elements are being found within phosphorites. With increasing demand from modern technology a different method of finding rare earth elements, independent of China, is becoming increasingly important. With yields greater than those from deposits in China, phosphorites offer a new resource
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Intertidal zones are also part of the tidal flat system. The intertidal zone is located within the mean high and low tide levels. It is subject to tidal shifts, which means that it is subaerially exposed once or twice a day. It is not exposed long enough to support the growth of most vegetation. The
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Depending on the pH and salinity levels of the ocean water, organic matter will decay, releasing phosphorus from sediment in shallow basins. Bacteria and enzymes dissolve organic matter on the water–bottom interface, thus returning phosphorus to the beginning of its biogenic cycle. Mineralization of
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Insular phosphorites: Insular phosphorites are located in carbonate islands, plateaus, coral island consisting of a reef surrounding a lagoon or, atoll lagoon, marine lakes. The phosphorite here originates from guano. Replacement of deep sea sediments precipitates, that has been formed in place on
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Continental margin phosphorites: Convergent, passive, upwelling, non-upwelling. This environment accumulates phosphorites in the form of hardgrounds, nodules and granular beds. These accumulate by carbonate fluorapatite precipitation during early diagenesis in the upper few tens of centimeters of
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The heaviest accumulation of phosphorus is mainly on the ocean floor. Phosphorus accumulation occurs from atmospheric precipitation, dust, glacial runoff, cosmic activity, underground hydrothermal volcanic activity, and deposition of organic material. The primary inflow of dissolved phosphorus is
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to apply rock phosphate as a fertilizer in certain soil types and countries, although it has many drawbacks. According to the report it may have higher sustainability compared to more concentrated fertilizers because of reduced manufacturing costs and the possibility of local procurement of the
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Phosphatization: Phosphatization is a type of rare diagenetic processes. It occurs when fluids that are rich in phosphate are leached from guano. These are then concentrated and reprecipitated in limestone. Phosphatized fossils or fragments of original phosphatic shells are important components
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are common phosphate-bearing rocks. Phosphate-rich sedimentary rocks can occur in dark brown to black beds, ranging from centimeter-sized laminae to beds that are several meters thick. Although these thick beds can exist, they are rarely only composed of phosphatic sedimentary rocks. Phosphatic
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The most common occurrence of phosphorites is related to strong marine upwelling of sediments. Upwelling is caused by deep water currents that are brought up to coastal surfaces where a large deposition of phosphorites may occur. This type of environment is the main reason why phosphorites are
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and animal feed supplements and the balance for industrial chemicals. In addition, phosphorus from rock phosphate is also used in food preservatives, baking flour, pharmaceuticals, anticorrosion agents, cosmetics, fungicides, insecticides, detergents, ceramics, water treatment and metallurgy.
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Supratidal environments are part of the tidal flat system where the presence of strong wave activity is non-existent. Tidal flat systems are created along open coasts and relatively low wave energy environments. They can also develop on high energy coasts behind barrier islands where they are
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Seamount phosphorites: These are phosphorites that occur in seamounts, guyots, or flat topped seamounts, seamount ridges. These phosphorites are produced in association with iron and magnesium bearing crusts. In this setting the productivity of phosphorus is recycled within an iron oxidation
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sheltered from the high energy wave action. Within the tidal flat system, the supratidal zone lies in a very high tide level. However, it can be flooded by extreme tides and cut across by tidal channels. This is also subaerially exposed, but is flooded twice a month by spring tides.
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commonly associated with silica and chert. Estuaries are also known as a phosphorus “trap”. This is because coastal estuaries contain a high productivity of phosphorus from marsh grass and benthic algae which allow an equilibrium exchange between living and dead organisms.
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by phosphates. They also can be composed of peloids, ooids, fossils, and clasts that are made up of apatite. There are some phosphorites that are very small and have no distinctive granular textures. This means that their textures are similar to that of collophane, or fine
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Phosphate nodules: These are spherical concentrations that are randomly distributed along the floor of continental shelves. Most phosphorite grains are sand size although particles greater than 2 mm may be present. These larger grains, referred to as
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Bioclastic phosphates or bone beds: Bone beds are bedded phosphate deposits that contain concentrations of small skeletal particles and coprolites. Some also contain invertebrate fossils like brachiopods and become more enriched in
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of Morocco) respectively in 2012 while global production reached 195 Mt. It is thought that in India there are almost 260 million tons of rock phosphate. Other countries with significant production include
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Phosphatic particles, laminae and beds are considered condensed when they have been concentrated. This is helped by the extracting and reworking processes of phosphatic particles or bioturbation.
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alternative to "chemical" phosphate fertilizer which has been further concentrated from it, because it is perceived as being more "natural". According to a report for the FAO, it can be more
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Middleton V. Gerald, 2003 Encyclopedia of Earth Sciences series. Encyclopedia of Sediment and Sedimentary Rocks. Kluwer Academic Publishers. Dordrect, Boston, London. pp 131, 727, 519–524.
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phosphorites are within marine shelf environments. These are in a broad and shallow cratonic setting. This is where granular phosphorites, phosphorite hardgrounds, and nodules occur.
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represents some 15 million years of sedimentation. It reaches a thickness of 420 metres and covers an area of 350,000 km. Commercially mined phosphorites occur in
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is used to concentrate the mined ore to rock phosphate. The mined ore is crushed and washed, creating a slurry, this ore slurry is then treated with
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Galmed, M.A.; Nasr, M.M.; Khater, A.E-S.M. (2020). "Petrology of Early Paleogene phosphorite deposits in Hazm Al-Jalamid, Northwest Saudi Arabia".
809:. Encyclopedia of Earth. Topic ed. Andy Jorgensen. Ed.-in-Chief C.J.Cleveland. National Council for Science and the Environment. Washington DC 840: 711: 19: 1308: 420:, can range up to several tens of centimeters in size. Phosphate nodules are known to occur in significant quantities offshore northern 31: 906: 793: 762: 754: 462:
reduction phosphorus cycle. This cycle can also form glauconite which is normally associated with modern and ancient phosphorites.
160:. Phosphorite deposits often occur in extensive layers, which cumulatively cover tens of thousands of square kilometres of the 1023: 997: 533:
As of 2006, the US is the world's leading producer and exporter of phosphate fertilizers, accounting for about 37% of world P
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oxides. Worldwide, the resources of high-grade ore are declining, and use of lower grade ore may become more attractive.
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Baturin, G.N, Phosphorites on the Sea Floor: Origin, Composition and Distribution. Elsevier. 1981, New York, pp. 24–50
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located within the U.S. that would likely lead to independence from influence of countries outside of the U.S.
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industry, beneficiated rock phosphate must be concentrated to levels of at least 28% phosphorus pentoxide (P
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exports. As of December 2018, the world's total economic demonstrated resource of rock phosphate is 70
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fertilizers. Elemental phosphorus is the base for furnace-grade phosphoric acid, phosphorus pentasulfide,
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after diagenetic processes have occurred. Bioclastic phosphates can also be cemented by phosphate minerals.
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Phosphatic particles that were moved by turbulent or gravity-driven flows and deposited by these flows.
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Emsbo, Poul; McLaughlin, Patrick I.; Breit, George N.; Du Bray, Edward A.; Koenig, Alan E. (2015).
690: 664: 65:. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% 2036: 1271: 1144: 1582: 1294: 880: 636: 589:. Historically, large amounts of phosphates were obtained from deposits on small islands such as 196: 62: 1177:"Sustainable Phosphorus Measures: Strategies and Technologies for Achieving Phosphorus Security" 1039: 514:
for their phosphate content are not particularly common. The two main sources for phosphate are
1123: 475: 1537: 1019: 993: 902: 836: 789: 758: 632: 149: 145: 105: 77:). Marketed phosphate rock is enriched ("beneficiated") to at least 28%, often more than 30% P 2234: 1946: 1733: 1602: 1239: 1198: 1188: 1092: 1059: 966: 942: 872: 590: 417: 356: 157: 58: 1220:"Rare earth elements in sedimentary phosphate deposits: Solution to the global REE crisis?" 2046: 1806: 1659: 620: 605: 496: 480: 184: 161: 36: 1235: 1055: 962: 2239: 2081: 1674: 1597: 1083: 805: 628: 363: 205: 113: 2299: 2284: 2199: 2164: 2011: 1572: 1477: 884: 601: 557: 506:
Deposits which contain phosphate in quantity and concentration which are economic to
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It must also have reasonable amounts of calcium carbonate (5%), and <4% combined
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organic matter can also cause the release of phosphorus back into the ocean water.
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droppings, and rocks containing concentrations of the calcium phosphate mineral,
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of phosphate ore is a process which includes washing, flotation and calcining.
2264: 2249: 2224: 2219: 2129: 2114: 2031: 1999: 1964: 1954: 1936: 1916: 1861: 1841: 1796: 1718: 1703: 1679: 1639: 1612: 1592: 1562: 1522: 1497: 1487: 1482: 1462: 1371: 656: 624: 330: 192: 109: 1244: 1219: 1097: 1040:"The estuarine formation of United States Atlantic Coastal Plain phosphorite" 2279: 2269: 2259: 2244: 2214: 2194: 2179: 2174: 2139: 2134: 2093: 2086: 2051: 2021: 2006: 1984: 1926: 1906: 1901: 1891: 1876: 1856: 1831: 1826: 1821: 1811: 1801: 1776: 1741: 1654: 1622: 1567: 1557: 1532: 1507: 1502: 1442: 1403: 1366: 1193: 1176: 683: 290: 239: 235: 188: 167: 744: 947:"Phosphorus Accumulation in Marine Sediments and Oceanic Phosphorus Cycle" 564:
are the world's largest miners of phosphate rock, with a production of 77
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GarcĂ­a, Marcelo; Correa, Jorge; Maksaev, VĂ­ctor; Townley, Brian (2020).
2274: 2204: 2169: 2144: 2076: 1911: 1851: 1791: 1756: 1649: 1577: 1492: 1452: 1420: 1415: 1331: 1203: 1018:(4th ed.), Pearson Education Inc., Upper Saddle River, NJ, pp. 217–223 586: 561: 527: 294: 286: 282: 274: 270: 262: 247: 201: 153: 971: 946: 619:
This rock phosphate is then either solubilized to produce wet-process
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sedimentary rocks are commonly accompanied by or interbedded with
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Beneficiated rock phosphate is also marketed and accepted as an
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Sedimentary rock containing large amounts of phosphate minerals
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Phosphates that are in pristine conditions have not undergone
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Phosphate ore is mined and beneficiated into rock phosphate.
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Approximately 90% of rock phosphate production is used for
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US Geological Survey Minerals Yearbook 2006 Rock Phosphate
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Tectonic and oceanographic settings of marine phosphorites
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zone contains both suspension sedimentation and bed load.
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Phosphates are known to be deposited in a wide range of
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Fossiliferous peloidal phosphorite, (4.7 cm across),
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Prothero, Donald R.; Schwab, Fred (22 August 2003).
2107: 1945: 1732: 1322: 1138: 1136: 750:Use of Phosphate Rocks for Sustainable Agriculture 148:. Other sources also include chemically dissolved 897:Klein, Cornelis and Cornelius S. Hurlbut, Jr., 568:, 29.4 Mt and 26.8 Mt (including 2.5 Mt in the 597:, but these sources are now largely depleted. 313:Classification of phosphatic sedimentary rocks 108:masses (grain sizes < 1 ÎĽm) referred to as 1302: 1277:International Fertilizer Industry Association 1033: 1031: 8: 1016:Principles of Sedimentology and Stratigraphy 351:Phosphorus cycle, formation and accumulation 928: 926: 924: 922: 920: 918: 916: 914: 1309: 1295: 1287: 824: 822: 820: 818: 816: 491:Phosphorite mine near Oron, Negev, Israel. 1243: 1202: 1192: 1096: 988: 986: 984: 982: 970: 1150:. AIMR Report 2013 (Report). p. 90. 1010: 1008: 1006: 780: 778: 776: 774: 722: 393:Littoral environments/intertidal zones: 788:, Freeman, 1996, 2nd ed. pp. 345–349 738: 736: 734: 732: 730: 728: 726: 712:Phosphate mining in the United States 612:to cause calcium phosphate to become 7: 784:Blatt, Harvey and Robert J. Tracy, 27:, Simplot Mine, Idaho. 4.6 cm wide. 623:, or smelted to produce elemental 14: 901:, Wiley, 1985, 20th ed., p. 360, 755:Food and Agriculture Organization 479:Guano phosphorite mining in the 835:. Macmillan. pp. 265–269. 410:Types of phosphorite deposition 1175:; White, Stuart (2013-01-31). 865:Arabian Journal of Geosciences 743:Zapata, F.; Roy, R.N. (2004). 545:, which occurs principally as 61:that contains high amounts of 1: 224:phosphorites are not common. 227:Phosphorites are known from 216:-sized detrital grains, and 88:The phosphate is present as 440:within some these deposits. 238:, but are more common from 2342: 1064:10.2113/gsecongeo.61.2.251 877:10.1007/s12517-020-05852-3 494: 450:Epeiric sea phosphorites: 354: 380:depositional environments 374:Depositional environments 333:have not been disturbed. 1245:10.1016/j.gr.2014.10.008 1098:10.5027/andgeoV47n1-3260 1014:Boggs, Sam, Jr. (2006). 1362:Basaltic trachyandesite 1342:Alkali feldspar granite 1194:10.3390/agronomy3010086 804:C.Michael Hogan. 2011. 1038:Pevear, D. R. (1966). 645:phosphorus trichloride 492: 484: 400:Estuarine environments 232:banded iron formations 40: 28: 23:Peloidal phosphorite, 1752:Banded iron formation 1129:(Report). p. 10. 951:Biogeochemical Cycles 549:marine phosphorites. 495:Further information: 490: 478: 34: 22: 1262:US Geological Survey 899:Manual of Mineralogy 641:phosphorus pentoxide 251:Phosphoria Formation 67:phosphorus pentoxide 25:Phosphoria Formation 2326:Industrial minerals 1236:2015GondR..27..776E 1161:IFA 2012 statistics 1056:1966EcGeo..61..251P 963:1998GBioC..12..563D 832:Sedimentary Geology 665:chemical fertilizer 2321:Phosphate minerals 2108:Specific varieties 637:ammonium phosphate 493: 485: 471:Production and use 197:carbonate minerals 150:phosphate minerals 146:hydrothermal veins 63:phosphate minerals 41: 29: 2311:Sedimentary rocks 2293: 2292: 1538:Nepheline syenite 1224:Gondwana Research 972:10.1029/98GB02263 842:978-0-7167-3905-0 633:anhydrous ammonia 386:Supratidal zones: 158:metamorphic rocks 106:cryptocrystalline 2333: 2306:Economic geology 2235:Rapakivi granite 1947:Metamorphic rock 1734:Sedimentary rock 1603:Quartz monzonite 1311: 1304: 1297: 1288: 1250: 1249: 1247: 1215: 1209: 1208: 1206: 1196: 1169: 1163: 1158: 1152: 1151: 1149: 1143:Britt, Allison. 1140: 1131: 1130: 1128: 1124:AIMR Report 2019 1120: 1114: 1109: 1103: 1102: 1100: 1074: 1068: 1067: 1044:Economic Geology 1035: 1026: 1012: 1001: 990: 977: 976: 974: 939: 933: 930: 909: 895: 889: 888: 860: 854: 853: 851: 849: 826: 811: 802: 796: 782: 769: 768: 740: 591:Christmas Island 483:of Peru, c. 1860 466:the ocean floor. 357:Phosphorus cycle 195:replacements of 59:sedimentary rock 2341: 2340: 2336: 2335: 2334: 2332: 2331: 2330: 2296: 2295: 2294: 2289: 2103: 2047:Pseudotachylite 1941: 1728: 1660:Tephriphonolite 1318: 1315: 1267:USGS Statistics 1258: 1253: 1217: 1216: 1212: 1171: 1170: 1166: 1159: 1155: 1147: 1142: 1141: 1134: 1126: 1122: 1121: 1117: 1110: 1106: 1076: 1075: 1071: 1037: 1036: 1029: 1013: 1004: 991: 980: 941: 940: 936: 931: 912: 896: 892: 862: 861: 857: 847: 845: 843: 828: 827: 814: 803: 799: 783: 772: 765: 742: 741: 724: 720: 708: 674: 670: 663:For use in the 653: 635:to produce the 621:phosphoric acid 606:Froth flotation 540: 536: 504: 499: 497:Peak phosphorus 481:Chincha Islands 473: 447: 435: 431: 412: 376: 359: 353: 315: 253:of the western 246:sediments. The 143: 139: 135: 131: 127: 123: 119: 104:F typically in 103: 99: 95: 84: 80: 76: 72: 37:Yunnan Province 17: 12: 11: 5: 2339: 2337: 2329: 2328: 2323: 2318: 2313: 2308: 2298: 2297: 2291: 2290: 2288: 2287: 2282: 2277: 2272: 2267: 2262: 2257: 2252: 2247: 2242: 2240:Rhomb porphyry 2237: 2232: 2227: 2222: 2217: 2212: 2207: 2202: 2197: 2192: 2187: 2182: 2177: 2172: 2167: 2162: 2157: 2152: 2147: 2142: 2137: 2132: 2127: 2122: 2117: 2111: 2109: 2105: 2104: 2102: 2101: 2096: 2091: 2090: 2089: 2082:Talc carbonate 2079: 2074: 2069: 2064: 2059: 2054: 2049: 2044: 2039: 2034: 2029: 2024: 2019: 2014: 2009: 2004: 2003: 2002: 1992: 1987: 1982: 1977: 1972: 1967: 1962: 1957: 1951: 1949: 1943: 1942: 1940: 1939: 1934: 1929: 1924: 1919: 1914: 1909: 1904: 1899: 1894: 1889: 1884: 1879: 1874: 1869: 1864: 1859: 1854: 1849: 1844: 1839: 1834: 1829: 1824: 1819: 1814: 1809: 1804: 1799: 1794: 1789: 1784: 1779: 1774: 1769: 1764: 1759: 1754: 1749: 1744: 1738: 1736: 1730: 1729: 1727: 1726: 1721: 1716: 1711: 1706: 1701: 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Rome: 706:See also 631:or with 244:Cenozoic 128:OH or Ca 56:detrital 2275:Unakite 2205:Llanite 2170:Ijolite 2145:Felsite 2077:Suevite 1912:Tillite 1852:Lignite 1792:Coquina 1757:Breccia 1650:Syenite 1578:Picrite 1493:Ijolite 1453:Granite 1421:Diorite 1416:Diabase 1332:Adakite 1232:Bibcode 1052:Bibcode 959:Bibcode 587:Tunisia 562:Morocco 528:apatite 418:nodules 295:Wyoming 287:Florida 283:Algeria 275:Tunisia 271:Morocco 263:Belgium 248:Permian 222:oolitic 202:micrite 154:igneous 2185:Kenyte 2160:Gossan 2057:Schist 2017:Marble 1980:Gneiss 1882:Oolite 1747:Arkose 1645:Sovite 1635:Scoria 1588:Pumice 1548:Norite 1518:Latite 1448:Gabbro 1433:Dunite 1411:Dacite 1357:Basalt 1352:Aplite 1022:  996:  905:  883:  839:  792:  761:  643:, and 583:Jordan 579:Russia 575:Brazil 570:Sahara 556:, the 307:Kansas 259:France 218:pyrite 181:cherts 177:shales 2150:Flint 2072:Slate 2067:Skarn 1932:Varve 1897:Shale 1817:Flint 1772:Chert 1767:Chalk 1148:(PDF) 1127:(PDF) 881:S2CID 595:Nauru 554:China 516:guano 422:Chile 303:Idaho 267:Spain 152:from 1922:Tufa 1867:Marl 1782:Coal 1714:Tuff 1020:ISBN 994:ISBN 903:ISBN 850:2012 837:ISBN 790:ISBN 759:ISBN 682:and 680:iron 651:Uses 593:and 585:and 560:and 520:bird 508:mine 343:(3) 336:(2) 317:(1) 305:and 299:Utah 281:and 242:and 214:silt 170:and 156:and 140:(OH) 2285:Wad 1240:doi 1199:hdl 1189:doi 1093:doi 1060:doi 967:doi 873:doi 524:bat 522:or 512:ore 510:as 234:in 132:(PO 120:(PO 96:(PO 50:or 2302:: 1238:. 1228:27 1226:. 1222:. 1197:. 1183:. 1179:. 1135:^ 1089:47 1087:. 1081:. 1058:. 1048:61 1046:. 1042:. 1030:^ 1005:^ 981:^ 965:. 955:12 953:. 949:. 913:^ 879:. 869:13 867:. 815:^ 773:^ 757:. 747:. 725:^ 647:. 616:. 581:, 577:, 530:. 366:. 309:. 301:, 297:, 293:, 289:, 277:, 273:, 269:, 265:, 261:, 212:, 208:, 179:, 164:. 130:10 116:Ca 92:Ca 69:(P 46:, 1310:e 1303:t 1296:v 1248:. 1242:: 1234:: 1207:. 1201:: 1191:: 1185:3 1101:. 1095:: 1066:. 1062:: 1054:: 1000:. 975:. 969:: 961:: 887:. 875:: 852:. 767:. 673:5 671:O 669:2 539:5 537:O 535:2 434:5 432:O 430:2 428:P 424:. 142:2 138:6 136:) 134:4 126:3 124:) 122:4 118:5 102:3 100:) 98:4 94:5 83:5 81:O 79:2 75:5 73:O 71:2

Index


Phosphoria Formation

Yunnan Province
detrital
sedimentary rock
phosphate minerals
phosphorus pentoxide
fluorapatite
cryptocrystalline
collophane
hydroxyapatite
hydrothermal veins
phosphate minerals
igneous
metamorphic rocks
Earth's crust
Limestones
mudstones
shales
cherts
dolomites
sandstone
diagenetic
carbonate minerals
micrite
organic matter
clay minerals
silt
pyrite

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