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Photovoltaic effect

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and the maximum power Pmax. The first studies about the behavior of PV cells under varying conditions of G and T date back several decades ago.1-4 In general, it is known that VOC shows a significant inverse correlation with T, whereas for ISC that correlation is direct, but weaker, so that this increment does not compensate for the decrease of VOC. As a consequence, Pmax reduces when T increases. This correlation between the output power of a solar cell and its junction working temperature depends on the semiconductor material,2 and it is due to the influence of T on the concentration, lifetime, and mobility of the intrinsic carriers, that is, electrons and holes, inside the PV cell.
195:. When conductive or semiconductive material is heated by absorption of electromagnetic radiation, the heating can lead to increased temperature gradients in the semiconductor material or differentials between materials. These thermal differences in turn may generate a voltage because the electron energy levels are shifted differently in different areas, creating a potential difference between those areas which in turn create an electric current. The relative contributions of the photovoltaic effect versus the Seebeck effect depend on many characteristics of the constituent materials. 27: 608: 203:
PV effect is suggested to be a result of the relative shift and realignment between the quasi-Fermi levels of the semiconductors adjacent to the junction/interface under the nonequilibrium conditions. The electrons flow in the external circuit back and forth to balance the potential difference between two electrodes. The organic solar cell, which the materials have no initial carrier concentration, does not have the AC PV effect.
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The performance of a photovoltaic module depends on the environmental conditions, mainly on the global incident irradiance G on the module plane. However, the temperature T of the p–n junction also influences the main electrical parameters: the short-circuit current ISC, the open-circuit voltage VOC,
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in 2017. The AC PV effect is the generation of alternating current (AC) in the nonequilibrium states when the light periodically shines at the junction or interface of material. The AC PV effect is based on the capacitive model that the current strongly depends on the frequency of the chopper. The AC
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Techniques for estimating these coefficients from experimental data can be found in the literature. Few studies analyse the variation of the series resistance with respect to the cell or module temperature. This dependency is studied by suitably processing the current–voltage curve. The temperature
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nanofilm. It is found that except for the DC output generated by the conventional PV effect based on a p–n junction, AC current is also produced when a flashing light is illuminated at the interface. The AC PV effect does not follow Ohm's law, being based on the capacitive model that the current
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The temperature sensitivity is usually described by some temperature coefficients, each one expressing the derivative of the parameter it refers to with respect to the junction temperature. The values of these parameters can be found in any PV module data sheet; they are the following:
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strongly depends on the frequency of the chopper, but voltage is independent of the frequency. The peak current of AC at high switching frequency can be much higher than that from DC. The magnitude of the output is also associated with the light absorption of materials.
245:. In the case of a semiconductor p–n (diode) junction solar cell, illuminating the material creates an electric current because excited electrons and the remaining holes are swept in different directions by the built-in electric field of the depletion region. 77:(or voltage) is produced by the separation of charges, and the light has to have a sufficient energy to overcome the potential barrier for excitation. The physical essence of the difference is usually that photoelectric emission separates the charges by 130:
and an electric current, and thus some of the light energy is converted into electric energy. The photovoltaic effect can also occur when two photons are absorbed simultaneously in a process called
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All above effects generate direct current, the first demonstration of the alternating current photovoltaic effect (AC PV) was done by Dr. Haiyang Zou and Prof. Zhong Lin Wang at the
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absorb energy and, being excited, jump to the conduction band and become free. These excited electrons diffuse, and some reach the rectifying junction (usually a diode
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Zou, Haiyang; Dai, Guozhang; Wang, Aurelia Chi; Li, Xiaogan; Zhang, Steven L.; Ding, Wenbo; Zhang, Lei; Zhang, Ying; Wang, Zhong Lin (2020-02-03).
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in 1884, but it had a very poor efficiency. However, the most familiar form of the photovoltaic effect uses solid-state devices, mainly in
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and photovoltaic emission separates them by diffusion, but some "hot carrier" photovoltaic devices concepts blur this distinction.
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In addition to the direct photovoltaic excitation of free electrons, an electric current can also arise through the
114:. When sunlight or other sufficiently energetic light is incident upon the photodiode, the electrons present in the 1463: 1453: 1240: 950: 722: 539: 1468: 787: 515: 371:
R.Delamare, O.Bulteel, D.Flandre, Conversion lumière/électricité: notions fondamentales et exemples de recherche
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coefficient of the series resistance is estimated by using the single diode model or the double diode one.
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is now usually used when the electron is ejected out of the material (usually into a vacuum) and
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The AC PV is operated at the non-equilibrium conditions. The first study was based on a p-Si/TiO
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used when the excited charge carrier is still contained within the material. In either case, an
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give their energy to electrons in the depletion or quasi-neutral regions. These move from the
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Piliougine, M.; Oukaja, A.; Sidrach-de-Cardona, M.; Spagnuolo, G. (2021).
222:– α Coefficient of variation of ISC with respect to T, given by ∂ISC/∂T. 219:– β Coefficient of variation of VOC with respect to T, given by ∂VOC/∂T. 157: 103: 58: 455: 145: 93:
in 1839, used an electrochemical cell. He explained his discovery in
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to a higher-energy state. The main distinction is that the term
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Power for the World - The Emergence of Electricity from the Sun
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Piliougine, M.; Spagnuolo, G.; Sidrach-de-Cardona, M. (2020).
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The first demonstration of the photovoltaic effect, by
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covered with a thin film of gold, was experimented by
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Progress in Photovoltaics: Research and Applications
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Belgium: Pan Stanford Publishing. p. 6. 241:source is sunlight, and the devices are called 102:The first solar cell, consisting of a layer of 540: 8: 1161: 1050: 633: 547: 533: 525: 406: 383:"Alternating Current Photovoltaic Effect" 144:illustration of the photovoltaic effect. 96:Comptes rendus de l'Académie des sciences 164:are accelerated by drift electric field 284: 237:In most photovoltaic applications, the 1104:Financial incentives for photovoltaics 182:, which gives scattering photocurrent. 23:Electric current generation from light 7: 1421: 339:IEEE Industrial Electronics Magazine 268:Electromotive force in solar cells 175:, or by scattering electric field 38:is the generation of voltage and 14: 1215:Building-integrated photovoltaics 1420: 1409: 1408: 618: 612: 606: 200:Georgia Institute of Technology 42:in a material upon exposure to 132:two-photon photovoltaic effect 1: 1220:Passive solar building design 646:Passive solar building design 156:. Depending on the location, 495:10.1016/j.renene.2020.08.026 1485: 723:Photovoltaic power station 297:www.chemistryexplained.com 15: 1404: 788:artificial photosynthesis 604: 562: 207:Effect of the temperature 171:, which gives generation 30:Mafate Marla solar panel 1324:Solar water disinfection 818:Thermoelectric generator 351:10.1109/MIE.2015.2485182 16:Not to be confused with 1032:Solar Shade Control Act 813:Space-based solar power 516:The photovoltaic effect 310:Palz, Wolfgang (2010). 1396:Solar power by country 1071:Thermal energy storage 696:Nanocrystal solar cell 651:Solar air conditioning 408:10.1002/adma.201907249 183: 31: 1277:Salt evaporation pond 1246:Hybrid solar lighting 1066:Phase-change material 263:Theory of solar cells 140: 126:). This generates an 29: 1449:Electrical phenomena 803:Solar thermal rocket 273:Photoelectric effect 79:ballistic conduction 67:photoelectric effect 55:photoelectric effect 18:Photoelectric effect 1371:Solar water heating 1145:Solar water heating 1061:Grid energy storage 808:Solar updraft tower 717:Photovoltaic module 712:Photovoltaic effect 666:Solar water heating 399:2020AdM....3207249Z 128:electromotive force 71:photovoltaic effect 36:photovoltaic effect 1199:Solar-powered pump 793:Solar-pumped laser 706:Photovoltaic array 701:Organic solar cell 684:and related topics 387:Advanced Materials 184: 75:electric potential 32: 1464:Quantum chemistry 1454:Energy conversion 1436: 1435: 1379: 1378: 1361:Solar combisystem 1319:Soil solarization 1225:Urban heat island 1153: 1152: 1125:Electric aircraft 1040: 1039: 756:Solar power tower 124:Galvani potential 1476: 1469:Electrochemistry 1424: 1423: 1412: 1411: 1366:Solar controller 1162: 1051: 751:Parabolic trough 634: 622: 616: 610: 598:Solar 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pond 279:References 46:. It is a 1194:Row cover 926:Lithuania 846:Australia 746:Heliostat 503:225364125 464:233976803 417:0935-9648 239:radiation 158:electrons 61:or other 1415:Category 1384:See also 1234:Lighting 1208:Building 1087:Adoption 1076:seasonal 1047:and uses 991:Thailand 961:Portugal 956:Pakistan 586:Concepts 577:Timeline 425:32009275 359:13343534 257:See also 104:selenium 59:electron 48:physical 1427:Commons 1296:Cooking 1054:Storage 1001:Ukraine 976:Somalia 966:Romania 941:Myanmar 936:Morocco 891:Germany 886:Georgia 881:Denmark 856:Belgium 851:Austria 841:Armenia 836:Albania 638:Thermal 593:The Sun 572:Outline 395:Bibcode 187:Physics 152:to the 146:Photons 85:History 996:Turkey 931:Mexico 921:Kosovo 906:Israel 896:Greece 866:Canada 861:Brazil 501:  462:  423:  415:  357:  320:  1025:Legal 1016:Yemen 986:Spain 916:Japan 911:Italy 901:India 871:China 567:Index 499:S2CID 460:S2CID 355:S2CID 180:scatt 169:drift 162:holes 44:light 1169:and 786:and 421:PMID 413:ISSN 318:ISBN 160:and 34:The 491:doi 487:162 452:doi 403:doi 347:doi 1445:: 497:. 485:. 481:. 458:. 448:29 446:. 442:. 419:. 411:. 401:. 391:32 389:. 385:. 353:. 341:. 295:. 134:. 548:e 541:t 534:v 505:. 493:: 466:. 454:: 427:. 405:: 397:: 361:. 349:: 343:9 326:. 299:. 250:2 177:E 166:E 20:.

Index

Photoelectric effect

electric current
light
physical
photoelectric effect
electron
charge carrier
electric potential
ballistic conduction
Edmond Becquerel
Comptes rendus de l'Académie des sciences
selenium
Charles Fritts
photodiodes
valence band
p–n junction
Galvani potential
electromotive force
two-photon photovoltaic effect

Band diagram
Photons
valence band
conduction band
electrons
holes
photocurrent
Seebeck effect
Georgia Institute of Technology

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