Knowledge (XXG)

Proton tunneling

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50:. In many molecules that contain hydrogen, the hydrogen atoms are linked to two non-hydrogen atoms via a hydrogen bond at one end and a covalent bond at the other. A hydrogen atom without its electron is reduced to being a proton. Since the electron is no longer bound to the hydrogen atom in a hydrogen bond, this is equivalent to a proton resting in one of the wells of a double well potential as described above. When proton tunneling occurs, the hydrogen bond and covalent bonds are switched. Once proton tunneling occurs, the same proton has the same probability of tunneling back to its original site provided the double well potential is symmetrical. 65:. In essence, the genetic code is contained by a unique arrangement of hydrogen bonds. It is believed that upon the replication of a DNA strand there is a probability for proton tunneling to occur which changes the hydrogen bond configuration; this leads to a slight alteration of the hereditary code which is the basis of mutations. Likewise, proton tunneling is also believed to be responsible for the occurrence of the dysfunction of cells (tumors and cancer) and ageing. 30:
in one site and the appearance of the same proton at an adjacent site separated by a potential barrier. The two available sites are bounded by a double well potential of which its shape, width and height are determined by a set of boundary conditions. According to the
43:, so it has a much lower probability of tunneling; nevertheless, proton tunneling still occurs especially at low temperatures and high pressures where the width of the potential barrier is decreased. 80:) phases of ice is enabled by proton tunneling. The occurrence of correlated proton tunneling in clusters of ice has also been reported recently. 350: 35:, the probability for a particle to tunnel is inversely proportional to its mass and the width of the potential barrier. 345: 202:
Drechsel-Grau, C.; Marx, D. (2014). "Quantum Simulation of Collective Proton Tunneling in Hexagonal Ice Crystals".
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Yen, F.; Gao, T. (2015). "Dielectric Anomaly in Ice near 20 K: Evidence of Macroscopic Quantum Phenomena".
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Proton tunneling occurs in many hydrogen based molecular crystals such as ice. It is believed that the
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Castro Neto, A. H.; Pujol, P.; Fradkin, E. (2006). "Ice: A strongly correlated proton system".
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Löwdin, P. O. (1963). "Proton Tunneling in DNA and its Biological Implications".
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is well-known. A proton is about 2000 times more massive than an
58: 26:involving the instantaneous disappearance of a 8: 46:Proton tunneling is usually associated with 323: 258: 162: 106: 7: 14: 298:Meng, X. Z.; et al. (2015). 224:10.1103/PhysRevLett.112.148302 1: 16:Phenomenon in Quantum Physics 269:10.1021/acs.jpclett.5b00797 367: 181:10.1103/PhysRevB.74.024302 136:10.1103/RevModPhys.35.724 61:strand are connected by 351:Solid state engineering 72:between the hexagonal ( 76:) and orthorhombic ( 316:2015NatPh..11..235M 247:J. Phys. Chem. Lett 216:2014PhRvL.112n8302D 173:2006PhRvB..74b4302C 128:1963RvMP...35..724L 37:Electron tunneling 346:Quantum mechanics 325:10.1038/NPHYS3225 253:(14): 2822–2825. 90:Quantum tunneling 33:WKB approximation 24:quantum tunneling 358: 330: 329: 327: 295: 289: 288: 262: 242: 236: 235: 199: 193: 192: 166: 164:cond-mat/0511092 146: 140: 139: 111: 70:phase transition 20:Proton tunneling 366: 365: 361: 360: 359: 357: 356: 355: 336: 335: 334: 333: 297: 296: 292: 244: 243: 239: 204:Phys. Rev. Lett 201: 200: 196: 148: 147: 143: 113: 112: 108: 103: 86: 17: 12: 11: 5: 364: 362: 354: 353: 348: 338: 337: 332: 331: 310:(3): 235–239. 290: 237: 210:(14): 148302. 194: 141: 122:(3): 724–732. 116:Rev. Mod. Phys 105: 104: 102: 99: 98: 97: 92: 85: 82: 63:hydrogen bonds 48:hydrogen bonds 15: 13: 10: 9: 6: 4: 3: 2: 363: 352: 349: 347: 344: 343: 341: 326: 321: 317: 313: 309: 305: 301: 294: 291: 286: 282: 278: 274: 270: 266: 261: 256: 252: 248: 241: 238: 233: 229: 225: 221: 217: 213: 209: 205: 198: 195: 190: 186: 182: 178: 174: 170: 165: 160: 157:(2): 024302. 156: 152: 145: 142: 137: 133: 129: 125: 121: 117: 110: 107: 100: 96: 95:Hydrogen bond 93: 91: 88: 87: 83: 81: 79: 75: 71: 66: 64: 60: 56: 51: 49: 44: 42: 38: 34: 29: 25: 22:is a type of 21: 307: 303: 293: 250: 246: 240: 207: 203: 197: 154: 151:Phys. Rev. B 150: 144: 119: 115: 109: 67: 52: 45: 19: 18: 340:Categories 260:1508.00215 101:References 55:base pairs 304:Nat. Phys 189:102581583 285:38375110 277:26266868 232:24766024 84:See also 41:electron 312:Bibcode 212:Bibcode 169:Bibcode 124:Bibcode 283:  275:  230:  187:  78:ice XI 74:ice Ih 28:proton 281:S2CID 255:arXiv 185:S2CID 159:arXiv 57:of a 273:PMID 228:PMID 53:The 320:doi 265:doi 220:doi 208:112 177:doi 132:doi 59:DNA 342:: 318:. 308:11 306:. 302:. 279:. 271:. 263:. 249:. 226:. 218:. 206:. 183:. 175:. 167:. 155:74 153:. 130:. 120:35 118:. 328:. 322:: 314:: 287:. 267:: 257:: 251:6 234:. 222:: 214:: 191:. 179:: 171:: 161:: 138:. 134:: 126::

Index

quantum tunneling
proton
WKB approximation
Electron tunneling
electron
hydrogen bonds
base pairs
DNA
hydrogen bonds
phase transition
ice Ih
ice XI
Quantum tunneling
Hydrogen bond
Bibcode
1963RvMP...35..724L
doi
10.1103/RevModPhys.35.724
arXiv
cond-mat/0511092
Bibcode
2006PhRvB..74b4302C
doi
10.1103/PhysRevB.74.024302
S2CID
102581583
Bibcode
2014PhRvL.112n8302D
doi
10.1103/PhysRevLett.112.148302

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