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Rydberg atom

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33: 804:), the excited states of the Rydberg series are inaccessible with conventional laser systems. Initial collisional excitation can make up the energy shortfall allowing optical excitation to be used to select the final state. Although the initial step excites to a broad range of intermediate states, the precision inherent in the optical excitation process means that the laser light only interacts with a specific subset of atoms in a particular state, exciting to the chosen final state. 2332: 819: 2321: 1290: 51: 1595: 1622: 2046:
than hydrogen, and so singly-ionized carbon atoms, and the corresponding recombining Rydberg states, exist further from the ionizing stars, in so-called C II regions which form thick shells around H II regions. The larger volume partially compensates for the low abundance of C compared to
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publicly discussed efforts to develop a super wideband radio receiver using Rydberg atoms. In March 2020, the laboratory announced that its scientists analysed the Rydberg sensor's sensitivity to oscillating electric fields over an enormous range of frequencies—from 0 to 10 Hertz (the spectrum to
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was used in combination with strong interactions between two atoms excited in Rydberg state to provide medium that exhibits strongly nonlinear behaviour at the level of individual optical photons. The tuneable interaction between Rydberg states, enabled also first quantum simulation experiments.
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from neutral hydrogen. This allows radio astronomers to study both the neutral and the ionized interstellar medium from the same set of observations. Since RRLs are numerous and weak, common practice is to average the velocity spectra of several neighbouring lines, to improve sensitivity.
1931:, most often observed in form of long-lived clusters. The de-excitation is significantly impeded in Rydberg matter by exchange-correlation effects in the non-uniform electron liquid formed on condensation by the collective valence electrons, which causes extended lifetime of clusters. 1279:
If the outer electron penetrates the inner electron shells, it will “see” more of the charge of the nucleus and hence experience a greater force. In general, the modification to the potential energy is not simple to calculate and must be based on knowledge of the geometry of the ion
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lower than the best laboratory vacuums attainable on Earth, it had been expected that such highly-excited atoms would be frequently destroyed by collisions, rendering the lines unobservable. Improved theoretical analysis showed that this effect had been overestimated, although
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An atom may have two (or more) electrons in highly excited states with comparable orbital radii. In this case, the electron-electron interaction gives rise to a significant deviation from the hydrogen potential. For an atom in a multiple Rydberg state, the additional term,
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Depending on the sign of the projection of the dipole moment onto the local electric field vector, a state may have energy that increases or decreases with field strength (low-field and high-field seeking states respectively). The narrow spacing between adjacent
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is absorbed by the target atom, resulting in a precise final state energy. The problem of producing single state, mono-energetic populations of Rydberg atoms thus becomes the somewhat simpler problem of precisely controlling the frequency of the laser output,
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0.3mm wavelength). The Rydberg sensor can reliably detect signals over the entire spectrum and compare favourably with other established electric field sensor technologies, such as electro-optic crystals and dipole antenna-coupled passive electronics.
1634:=15. The presence of an ion-core that can be polarized and penetrated by the Rydberg electron adds additional terms to the electronic Hamiltonian (resulting in a finite quantum defect) leading to coupling of the different Stark states and hence 1253: 2549:
With the application of a static electric field, the electron feels a continuously changing torque. The resulting trajectory becomes progressively more distorted over time, eventually going through the full range of angular momentum from
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with relatively small intervals in wavelength between them, so they frequently occur in radio spectral observations primarily targeted at other spectral lines. For instance, H166α, H167α, and H168α are very close in wavelength to the
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Labuhn, Henning; Barredo, Daniel; Ravets, Sylvain; de Léséleuc, Sylvain; MacrÏ, Tommaso; Lahaye, Thierry; Browaeys, Antoine (2016). "Tunable two-dimensional arrays of single Rydberg atoms for realizing quantum Ising models".
1819: 2031:.. The record wavelength for hydrogen is λ = 73 cm for H253α, implying atomic diameters of a few microns, and for carbon, λ = 18  metres, from C732α, from atoms with a diameter of 57 micron. 1505:
The three exceptions to the definition of a Rydberg atom as an atom with a hydrogenic potential, have an alternative, quantum mechanical description that can be characterized by the additional term(s) in the atomic
951: 1488: 825:. A comparison of the potential in a hydrogen atom with that in a Rydberg state of a different atom. A large core polarizability has been used in order to make the effect clear. The black curve is the Coulombic 1/ 5224:
Sedlacek, Jonathon A.; Schwettmann, Arne; KĂŒbler, Harald; Löw, Robert; Pfau, Tilman; Shaffer, James P. (2012-09-16). "Microwave electrometry with Rydberg atoms in a vapour cell using bright atomic resonances".
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show that this results in strong interactions between two close Rydberg atoms. Coherent control of these interactions combined with their relatively long lifetime makes them a suitable candidate to realize a
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Rydberg states. Rydberg atoms’ large sizes and susceptibility to perturbation and ionisation by electric and magnetic fields, are an important factor determining the properties of plasmas.
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of the valence electron for each element. This gives helium and carbon lines apparent Doppler shifts of −100 and −140 km/s, respectively, relative to the corresponding hydrogen line.
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due to the recombination of electrons and positive ions; low energy recombination results in fairly stable Rydberg atoms, while recombination of electrons and positive ions with high
2215:, which blocks photons from the more familiar optical transitions. They are also used to measure the temperature of the ionized gas, via the ratio of line intensity to the continuum 2404: 2223:. Since the temperature of H II regions is regulated by line emission from heavier elements such as C, N, and O, recombination lines also indirectly measure their abundance ( 5380:
Pritchard, J. D.; Maxwell, D.; Gauguet, A.; Weatherill, K. J.; Jones, M. P. A.; Adams, C. S. (2010-11-05). "Cooperative Atom-Light Interaction in a Blockaded Rydberg Ensemble".
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Wade, C. G.; Ơibalić, N.; de Melo, N. R.; Kondo, J. M.; Adams, C. S.; Weatherill, K. J. (2016-11-07). "Real-time near-field terahertz imaging with atomic optical fluorescence".
2583:), almost exactly matches the quantum mechanically predicted period for the wavefunction to return to its initial state, demonstrating the classical nature of the Rydberg atom. 1498:
The long lifetimes of Rydberg states with high orbital angular momentum can be explained in terms of the overlapping of wavefunctions. The wavefunction of an electron in a high
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Again, because the kinetic energy of the interaction can contribute to the final internal energies of the constituents, this technique populates a broad range of energy levels.
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Wenger, Trey V.; Dawson, J. R.; Dickey, John M.; Jordan, C. H.; McClure–Griffiths, N. M.; Anderson, L. D.; Armentrout, W. P.; Balser, Dana S.; Bania, T. M. (2021-06-01).
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The radiative decay lifetimes of atoms in metastable states to the ground state are important to understanding astrophysics observations and tests of the standard model.
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can be used to estimate the position of the H II region on the line of sight and so its 3D position in the Galaxy. Because all astrophysical Rydberg atoms are
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even for relatively modest field strengths. The theoretical field strength at which a crossing would occur assuming no coupling between the states is given by the
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Because the electron can retain any arbitrary amount of its initial kinetic energy, this process results in a population with a broad spread of different energies.
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Schauß, P.; Zeiher, J.; Fukuhara, T.; Hild, S.; Cheneau, M.; Macrì, T.; Pohl, T.; Bloch, I.; Gross, C. (2015-03-27). "Crystallization in Ising quantum magnets".
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can have radial velocities up to ±150 km/s, due to their motion relative to Earth as both orbit the centre of the Galaxy. These motions are regular enough that
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state (high angular momentum, “circular orbit”) has very little overlap with the wavefunctions of the inner electrons and hence remains relatively unperturbed.
2327:. Stark - Coulomb potential for a Rydberg atom in a static electric field. An electron in such a potential feels a torque that can change its angular momentum. 3861:
Alves, Marta I. R.; Calabretta, Mark; Davies, Rodney D.; Dickinson, Clive; Staveley-Smith, Lister; Davis, Richard J.; Chen, Tianyue; Barr, Adam (2015-06-21).
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Anderson, L. D.; Luisi, Matteo; Liu, Bin; Wenger, Trey V.; Balser, Dana. S.; Bania, T. M.; Haffner, L. M.; Linville, Dylan J.; Mascoop, J. L. (2021-06-01).
964:. In other words, the electron's orbit resembles the orbit of planets inside a solar system, similar to what was seen in the obsolete but visually useful 1395:
Additional terms in the potential energy expression for a Rydberg state, on top of the hydrogenic Coulomb potential energy require the introduction of a
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values of angular momentum lead to the observed discrete energy levels. A full quantitative derivation of the observed spectrum was derived by
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Rydberg atoms exhibit strong electric-dipole coupling of the atoms to electromagnetic fields and has been used to detect radio communications.
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Coulomb potential (there is no quantum defect) which does not couple the different Stark states. Consequently the energy levels from adjacent
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field) changes the geometry of the potential, dramatically changing the behaviour of the electron. A Coulombic potential does not apply any
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Nogues, G.; Rauschenbeutel, A.; Osnaghi, S.; Brune, M.; Raimond, J. M.; Haroche, S. (1999). "Seeing a single photon without destroying it".
1982:= 90 state. Today, Rydberg atoms of hydrogen, helium and carbon in space are routinely observed via RRLs, the brightest of which are the H 1414: 3862: 1580:
states pass closer to the nucleus potentially penetrating the ion core. A core penetration term must be added to the atomic Hamiltonian.
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Nicholas D. Guise; et al. (Apr 24, 2014). "Measurement of the Kr xviii 3d 2D5/2 lifetime at low energy in a unitary Penning trap".
1901:), effects impossible to detect in ground state atoms become obvious in Rydberg atoms, which demonstrate very large diamagnetic shifts. 561:
Much early experimental work on Rydberg atoms relied on the use of collimated beams of fast electrons incident on ground-state atoms.
2855: 2694: 2296: 2077: 4838:"Fast Multiqubit Gates by Adiabatic Evolution in Interacting Excited-State Manifolds of Rydberg Atoms and Superconducting Circuits" 2991:
T. P. Hezel, et al. (1992). "Classical view of the properties of Rydberg atoms: Application of the correspondence principle".
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The similarity of the effective potential "seen" by the outer electron to the hydrogen potential is a defining characteristic of
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to increase the atoms' internal energy exciting to a broad range of different states including many high-lying Rydberg states,
549:= 1. The study of Rydberg states requires a reliable technique for exciting ground state atoms to states with a large value of 1322: 1122:{\displaystyle U_{ee}={\dfrac {e^{2}}{4\pi \varepsilon _{0}}}\sum _{i<j}{\dfrac {1}{|\mathbf {r} _{i}-\mathbf {r} _{j}|}}.} 1951:
state, and then gradually dropping through the energy levels to the ground state, giving rise to a sequence of recombination
1840:. The presence of additional terms in the potential energy can lead to coupling resulting in avoided crossings as shown for 2711: 729:
in the 1970s allowed a much greater level of control over populations of excited atoms. In optical excitation, the incident
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Firstenberg, Ofer; Peyronel, Thibault; Liang, Qi-Yu; Gorshkov, Alexey V.; Lukin, Mikhail D.; Vuletić, Vladan (2013-09-25).
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effect due to a non-spherically symmetric potential. A core polarization term must be included in the atomic Hamiltonian.
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with electrons, which at these very low densities usually proceeds via the electron re-joining the atom in a very high
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and leads to a condition where the size of the two electron’s orbits are related; a condition sometimes referred to as
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Meyer, David H.; Kunz, Paul D.; Cox, Kevin C. (2021). "Waveguide-Coupled Rydberg Spectrum Analyzer from 0 to 20 GHz".
2993: 2956: 2742: 3033: 1730: 1568:, is periodically localised within the shells of inner electrons and interacts with the full charge of the nucleus. 655: 575: 649:
and a population of neutral atoms of another species, resulting in the formation of a beam of highly excited atoms,
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M. Courtney, et al. (1995). "Classical, semiclassical, and quantum dynamics of lithium in an electric field".
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There are three notable exceptions that can be characterized by the additional term added to the potential energy:
262: 158: 1300:=5 with all allowed values of orbital angular momentum. The black spot denotes the position of the atomic nucleus. 2291:
and quantum matters. High electric dipole moments between Rydberg atomic states are used for radio frequency and
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Gorshkov, Alexey V.; Otterbach, Johannes; Fleischhauer, Michael; Pohl, Thomas; Lukin, Mikhail D. (2011-09-22).
1956: 961: 463: 328: 82: 43: 1893:. As diamagnetic effects scale with the area of the orbit and the area is proportional to the radius squared ( 2494:{\displaystyle |\mathbf {\tau } |=|\mathbf {r} \times \mathbf {F} |=|\mathbf {r} ||\mathbf {F} |\sin \theta } 143:
of the atom is useful in explaining these properties. Classically, an electron in a circular orbit of radius
5679: 4962:"Discrete-Time Quantum-Walk & Floquet Topological Insulators via Distance-Selective Rydberg-Interaction" 4158: 4095: 4032: 3969: 3515: 1870: 1726: 277: 3914: 1645:
The large separation between the electron and ion-core in a Rydberg atom makes possible an extremely large
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Lukin, M. D.; Fleischhauer, M.; Cote, R.; Duan, L. M.; Jaksch, D.; Cirac, J. I.; Zoller, P. (2001-06-26).
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electron in a large orbit far from the ion core; in such an orbit, the outermost electron feels an almost
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Tiarks, Daniel; Schmidt-Eberle, Steffen; Stolz, Thomas; Rempe, Gerhard; DĂŒrr, Stephan (February 2019).
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I. K. Dmitrieva; et al. (1993). "Energies of Doubly Excited States. The Double Rydberg Formula".
1528:, then its wavefunction becomes almost as large as the first (a double Rydberg state). This occurs as 411:
It is now apparent why Rydberg atoms have such peculiar properties: the radius of the orbit scales as
5764: 5719: 5614: 5544: 5465: 5399: 5338: 5234: 5174: 5107: 5042: 4983: 4918: 4859: 4794: 4721: 4648: 4575: 4510: 4445: 4372: 4299: 4177: 4114: 4051: 3988: 3933: 3825: 3766: 3697: 3656: 3645:"Observations of carbon recombination lines at decametric wavelengths in the direction of Cassiopeia" 3571: 3524: 3487: 3478: 3414: 3369: 3320: 3273: 3224: 3176: 3167: 3139: 3087: 3042: 3002: 2965: 2912: 2825: 2751: 2674: 2592: 2395: 1944: 1921: 562: 428: 4895:
Weimer, Hendrik; MĂŒller, Markus; Lesanovsky, Igor; Zoller, Peter; BĂŒchler, Hans Peter (2010-03-14).
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T. Wilk, et al. (2010). "Entanglement of Two Individual Neutral Atoms Using Rydberg Blockade".
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G. Vitrant, et al. (1982). "Rydberg to plasma evolution in a dense gas of very excited atoms".
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to the position vector (always pointing along a line running between the electron and the nucleus):
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There are a variety of other potential applications of Rydberg atoms in cosmology and astrophysics.
1248:{\displaystyle U_{\text{pol}}=-{\frac {e^{2}\alpha _{\text{d}}}{(4\pi \varepsilon _{0})^{2}r^{4}}},} 498:
presented a generalized and more intuitive version of Balmer's formula that came to be known as the
5021:"Rydberg-atom quantum simulation and Chern-number characterization of a topological Mott insulator" 2292: 2039: 2019: 2018: > 100 was surprising, as even in the very low densities of interstellar space, many 502:. This formula indicated the existence of an infinite series of ever more closely spaced discrete 4156:
H. Weimer, et al. (2008). "Quantum Critical Behavior in Strongly Interacting Rydberg Gases".
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L. Isenhower, et al. (2010). "Demonstration of a Neutral Atom Controlled-NOT Quantum Gate".
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emitted in transitions between such states have low frequencies and long wavelengths, even up to
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refers to an atom in which the valence electron(s) have been excited into a formerly unpopulated
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Anderson, David A.; et al. (2021). "An Atomic Receiver for AM and FM Radio Communication".
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and explains why the electron wavefunctions approximate to classical orbits in the limit of the
877:-1 electrons. An electron in the spherically symmetric Coulomb potential has potential energy: 5086:"Rydberg noisy dressing and applications in making soliton molecules and droplet quasicrystals" 3513:
E. A. Manykin, et al. (2006). Samartsev VV (ed.). "Rydberg matter: Properties and decay".
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The time period of the oscillation in angular momentum (the time to complete the trajectory in
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If the valence electron has very low angular momentum (interpreted classically as an extremely
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Another mainstay of early Rydberg atom experiments relied on charge exchange between a beam of
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elliptical orbit), then it may pass close enough to polarise the ion core, giving rise to a 1/
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and the charge that produces it is always attractive so this contribution is always negative,
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J. Murray-Krezan (2008). "The classical dynamics of Rydberg Stark atoms in momentum space".
2682: 2607: 2261: 2220: 2197: 1913: 1635: 1385: 969: 794: 495: 419:= 137 state of hydrogen has an atomic radius ~1 ÎŒm) and the geometric cross-section as 125: 62: 4698:
Jaksch, D.; Cirac, J. I.; Zoller, P.; Rolston, S. L.; CÎté, R.; Lukin, M. D. (2000-09-04).
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In the absence of collisional broadening, the wavelengths of RRLs are modified only by the
1876: 818: 247:{\displaystyle \mathbf {F} =m\mathbf {a} \Rightarrow {ke^{2} \over r^{2}}={mv^{2} \over r}} 4277: 2851: 2612: 2371: 2358:
shows the particular orbits associated with quantum mechanically allowed values. See the
1975: 1940: 499: 5753:
T. P. Hezel, et al. (1992). "Classical view of the Stark effect in hydrogen atoms".
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Friedler, Inbal; Petrosyan, David; Fleischhauer, Michael; Kurizki, Gershon (2005-10-05).
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interpretation of angular momentum states in an electron orbital, illustrating that low-
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J. Neukammer, et al. (1984). "Diamagnetic shift and singlet-triplet mixing of 6s
3196: 2602: 2343: 1952: 1825: 1607:=15. The potential energy found in the electronic Hamiltonian for hydrogen is the 1/ 1558: 1381: 865: 842: 813: 483: 479: 424: 133: 74: 5580: 5435: 5152: 5070: 4946: 4822: 4757: 4684: 4611: 4553: 4538: 4408: 4350: 4262: 4205: 4079: 4016: 3745:"The GBT Diffuse Ionized Gas Survey (GDIGS): Survey Overview and First Data Release" 3544: 3340: 3062: 2954:
M. Haugh, et al. (1966). "Electronic excitation accompanying charge exchange".
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This form of direct optical excitation is generally limited to experiments with the
5650: 5511: 5411: 5366: 5210: 5186: 4627:"Dipole Blockade and Quantum Information Processing in Mesoscopic Atomic Ensembles" 4626: 4587: 4424:"Photon-photon gate via the interaction between two collective Rydberg excitations" 4384: 4311: 4220: 4189: 4142: 4126: 4063: 3454: 2387: 2268: 2201: 2006: = 2 and 3 are also observed. Corresponding lines for helium and carbon are He 1972: 1662: 1564:
The wavefunction of the outer electron in states with low orbital angular momentum
1289: 783: 503: 113: 4660: 3560:"Detection of a Radio Line Due to Excited Hydrogen in the Nebula NGC 6618 (Omega)" 2386:
shows how application of an external electric field (known in atomic physics as a
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Since 2000's Rydberg atoms research encompasses broadly five directions: sensing,
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RRLs are used to detect ionized gas in distant regions of our Galaxy, and also in
1546:. An electron-electron repulsion term must be included in the atomic Hamiltonian. 4699: 2719: 1814:{\displaystyle F_{\text{IT}}={\dfrac {e}{12\pi \varepsilon _{0}a_{0}^{2}n^{5}}}.} 1557:
between the motions of the two outermost electrons. This can be thought of as a
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in other species is generally too high to be accessible with most laser systems.
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T. A. Heim; et al. (1995). "Excitation of high-lying pair-Rydberg states".
2224: 2212: 2035: 454:. These closely spaced Rydberg states form what is commonly referred to as the 17: 5054: 4872: 4837: 4806: 4522: 4457: 3838: 3804:"Metallicity Structure in the Milky Way Disk Revealed by Galactic H ii Regions" 3803: 3779: 3744: 3710: 3675: 3332: 2901:
J. Olmsted (1967). "Excitation of nitrogen triplet states by electron impact".
2837: 2354:-direction. Note that classically all values of angular momentum are allowed; 1653:. There is an energy associated with the presence of an electric dipole in an 4996: 4246: 3802:
Wenger, Trey V.; Balser, Dana S.; Anderson, L. D.; Bania, T. M. (2019-12-16).
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were achieved experimentally. Strongly interacting Rydberg atoms also feature
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Scientists create quantum sensor that covers entire radio frequency spectrum
5556: 3595: 2169: 1959:. The very small differences in energy between Rydberg states differing in 1274:
shows how the polarization term modifies the potential close to the nucleus.
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have a number of peculiar properties including an exaggerated response to
5683: 5153:"Supersolid Vortex Crystals in Rydberg-Dressed Bose-Einstein Condensates" 4716: 4643: 4505: 4422:
Khazali, Mohammadsadegh; Heshami, Khabat; Simon, Christoph (2015-03-17).
3983: 3450:"A new antenna using single atoms could usher in the age of atomic radio" 2339: 1978:
in 1964; the line, designated H90α, was emitted by hydrogen atoms in the
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The large sizes and low binding energies of Rydberg atoms lead to a high
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potential of the hydrogen atom while the dashed red curve includes the 1/
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The existence of the Rydberg series was first demonstrated in 1885 when
4896: 4489:"Long-range interactions and entanglement of slow single-photon pulses" 4276:
Khazali, Mohammadsadegh; Murray, Callum R.; Pohl, Thomas (2019-09-13).
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D. Jaksch, et al. (2000). "Fast Quantum Gates for Neutral Atoms".
3720: 3054: 2932: 1841: 946:{\displaystyle U_{\text{C}}=-{\dfrac {e^{2}}{4\pi \varepsilon _{0}r}}.} 467: 128:
from the electric field of the nucleus such that, from a distance, the
58: 5663: 5246: 4930: 3863:"The HIPASS survey of the Galactic plane in radio recombination lines" 3536: 2977: 2811: 2763: 2034:
RRLs from hydrogen and helium are produced in highly ionized regions (
1603:. Computed energy level spectra of hydrogen in an electric field near 1483:{\displaystyle E_{\text{B}}=-{\frac {\rm {Ry}}{(n-\delta _{l})^{2}}}.} 5151:
Henkel, N.; Cinti, F.; Jain, P.; Pupillo, G.; Pohl, T. (2012-06-26).
2391: 2208: 1964: 1630:. Computed energy level spectra of lithium in an electric field near 1141:
core polarization term in the potential. The interaction between an
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C. E. Theodosiou (1983). "Evaluation of penetration effects in high-
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The first detection of such a radio recombination line (RRL) was by
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Rydberg atoms occur in space due to the dynamic equilibrium between
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Y. N. Gnedin, et al. (2009). "Rydberg atoms in astrophysics".
3820: 3761: 3692: 3409: 3286: 3259: 2196:, the frequencies of transitions for H, He, and C are given by the 1621: 1594: 450:
leading to ever more closely spaced levels converging on the first
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Excited atomic quantum state with high principal quantum number (n)
5539: 5394: 5350: 5169: 5037: 4913: 4789: 4570: 4440: 4367: 4278:"Polariton Exchange Interactions in Multichannel Optical Networks" 4172: 4109: 4046: 3928: 3879: 3315: 2330: 2319: 2265: 1288: 817: 49: 46:=12. Colors show the quantum phase of the highly excited electron. 31: 3676:"The Southern H II Region Discovery Survey. II. The Full Catalog" 2382:
making them extremely susceptible to perturbation by the field.
4554:"All-Optical Quantum Information Processing Using Rydberg Gates" 98: 3076:
L. Neale; et al. (1995). "Core Polarization in Kr VIII".
2275:
behavior, which makes them interesting to study on their own.
2251:
Due to their large size, Rydberg atoms can exhibit very large
2130:{\displaystyle v\approx c(\lambda -\lambda _{0})/\lambda _{0}} 2027:
does eventually limit detectability of the lines at very high
646: 462:
shows some of the energy levels of the lowest three values of
423:. Thus, Rydberg atoms are extremely large, with loosely bound 5019:
Dauphin, A.; MĂŒller, M.; Martin-Delgado, M. A. (2012-11-20).
2817:
Nuclear Instruments and Methods in Physics Research Section B
1832:
Coulomb potential does not couple Stark states from adjacent
1725:-levels in the Rydberg series means that states can approach 1710:{\displaystyle E_{\text{S}}=-\mathbf {d} \cdot \mathbf {F} .} 4221:"A photon–photon quantum gate based on Rydberg interactions" 2565: = 0, to the initial orbit in the opposite sense 3649:
Pisma V Astronomicheskii Zhurnal (Soviet Astronomy Letters)
3260:"Ionic Depression of Series Limits in One-Electron Spectra" 1392:
explains why Rydberg states are susceptible to ionization.
2538:{\displaystyle \theta =\pi \Rightarrow \mathbf {\tau } =0} 1521:, energetically close to the state of the outer electron 132:
looks identical to that experienced by the electron in a
1370:{\displaystyle E_{\text{B}}=-{\frac {\rm {Ry}}{n^{2}}},} 4836:
Khazali, Mohammadsadegh; MĂžlmer, Klaus (2020-06-11).
4771:
Saffman, M.; Walker, T. G.; MĂžlmer, K. (2010-08-18).
2511: 2407: 2178: 2143: 2080: 2060: 1879: 1757: 1742: 1674: 1417: 1325: 1158: 1069: 1019: 1001: 904: 886: 743: 658: 578: 344: 327:'s expression for the orbital radius in terms of the 290: 170: 61:
showing the Rydberg series of the lowest 3 values of
5664:
Army researchers make giant leap in quantum sensing
3119: 3117: 1836:-manifolds resulting in real crossings as shown in 1304:Quantum-mechanically, a state with abnormally high 509:This series was qualitatively explained in 1913 by 5451:"Attractive photons in a quantum nonlinear medium" 2537: 2493: 2184: 2156: 2129: 2066: 1885: 1813: 1709: 1482: 1369: 1247: 1121: 945: 771: 706: 626: 401:{\displaystyle r={n^{2}\hbar ^{2} \over ke^{2}m}.} 400: 311: 246: 4351:"Photon-Photon Interactions via Rydberg Blockade" 3867:Monthly Notices of the Royal Astronomical Society 2211:, because the radio photons are not absorbed by 93:, the farther the electron is from the nucleus, 4552:Paredes-Barato, D.; Adams, C. S. (2014-01-28). 3358:p Yb Rydberg states with large radial extent". 1857:Precision measurements of trapped Rydberg atoms 1316:. In hydrogen the binding energy is given by: 707:{\displaystyle A^{+}+B\rightarrow A^{*}+B^{+}.} 627:{\displaystyle e^{-}+A\rightarrow A^{*}+e^{-}.} 490:of light associated with transitions in atomic 1408:, into the expression for the binding energy: 3397:IEEE Transactions on Antennas and Propagation 1514:If a second electron is excited into a state 8: 3558:Sorochenko, R. L.; Borodzich, É. V. (1965). 1615:-manifolds cross at the Inglis–Teller limit. 1388:. The low binding energy at high values of 494:. Three years later, the Swedish physicist 446:, the energy level spacing falls off like 1/ 3749:The Astrophysical Journal Supplement Series 3680:The Astrophysical Journal Supplement Series 3208: 3206: 2632: 2630: 2628: 2074:, is usually converted to radial velocity, 1935:In astrophysics (Radio recombination lines) 772:{\displaystyle A+\gamma \rightarrow A^{*}.} 438:of a Rydberg electron is proportional to 1/ 2669:Ć ibalić, Nikola; S Adams, Charles (2018). 2014:α, and so on. The discovery of lines with 1986:α lines corresponding to transitions from 873:and the lower electron shells filled with 860:, from a compact ion core consisting of a 65:converging on the first ionization energy. 5713: 5608: 5538: 5485: 5393: 5289: 5168: 5119: 5101: 5036: 4995: 4977: 4912: 4871: 4853: 4788: 4715: 4642: 4569: 4504: 4439: 4366: 4293: 4236: 4171: 4108: 4045: 3982: 3927: 3888: 3878: 3837: 3819: 3778: 3760: 3719: 3709: 3691: 3408: 3314: 3285: 3026: 3024: 2524: 2510: 2477: 2472: 2467: 2462: 2457: 2452: 2444: 2439: 2431: 2426: 2418: 2413: 2408: 2406: 2193: 2177: 2148: 2142: 2121: 2112: 2103: 2079: 2059: 1878: 1798: 1788: 1783: 1773: 1756: 1747: 1741: 1699: 1691: 1679: 1673: 1549:Polarization of the ion core produces an 1468: 1458: 1436: 1434: 1422: 1416: 1356: 1344: 1342: 1330: 1324: 1233: 1223: 1213: 1192: 1182: 1175: 1163: 1157: 1107: 1101: 1096: 1086: 1081: 1075: 1068: 1056: 1042: 1025: 1018: 1006: 1000: 927: 910: 903: 891: 885: 833:term due to polarization of the ion core. 760: 742: 695: 682: 663: 657: 615: 602: 583: 577: 383: 368: 358: 351: 343: 289: 232: 222: 211: 200: 190: 182: 171: 169: 116:that approximate, under some conditions, 4773:"Quantum information with Rydberg atoms" 3448:Oullette, Jennifer (19 September 2018). 2301:Electromagnetically induced transparency 3594:Gordon, M.A.; Sorochenko, R.L. (2009). 2775: 2773: 2624: 2047:H, making the carbon RRLs detectable. 365: 323:Combining these two equations leads to 306: 5688:United States Army Research Laboratory 5668:United States Army Research Laboratory 5084:Khazali, Mohammadsadegh (2021-08-05). 4960:Khazali, Mohammadsadegh (2022-03-03). 4700:"Fast Quantum Gates for Neutral Atoms" 3600:Astrophysics and Space Science Library 2782:"Rydberg Atoms and the Quantum Defect" 2309:United States Army Research Laboratory 2168:wavelength. H II regions in our 3589: 3587: 3585: 2710:Metcalf Research Group (2004-11-08). 7: 2664: 2662: 2378:Rydberg atoms can obtain very large 2200:, except for the slightly different 1927:Condensation of Rydberg atoms forms 2812:"Janne Rydberg – his life and work" 2856:University of Tennessee, Knoxville 2810:I. Martinson; et al. (2005). 2374:. In the presence of an external 1440: 1437: 1348: 1345: 431:by collisions or external fields. 139:In spite of its shortcomings, the 25: 5121:10.1103/PhysRevResearch.3.L032033 3258:D.R. Inglis; et al. (1939). 2299:of individual microwave photons. 1865:Investigating diamagnetic effects 1852:Applications and further research 541:The only truly stable state of a 525:in 1926 following development of 124:. The core electrons shield the 5732:10.1103/PhysRevApplied.15.014053 2473: 2458: 2440: 2432: 1700: 1692: 1620: 1593: 1097: 1082: 183: 172: 3034:Journal of Applied Spectroscopy 2295:sensing and imaging, including 1912:Rydberg atoms form commonly in 1661:, known in atomic physics as a 987:, includes a summation of each 565:processes can use the electron 427:electrons, easily perturbed or 5412:10.1103/physrevlett.105.193603 5187:10.1103/physrevlett.108.265301 4588:10.1103/physrevlett.112.040501 4385:10.1103/physrevlett.107.133602 4312:10.1103/PhysRevLett.123.113605 4190:10.1103/PhysRevLett.101.250601 4127:10.1103/PhysRevLett.104.010503 4064:10.1103/PhysRevLett.104.010502 2521: 2478: 2468: 2463: 2453: 2445: 2427: 2419: 2409: 2370:potential results in a closed 2109: 2090: 2054:, so the measured wavelength, 1465: 1445: 1220: 1200: 1108: 1076: 753: 675: 595: 517:of the hydrogen atom in which 506:converging on a finite limit. 187: 120:orbits of electrons about the 1: 4897:"A Rydberg quantum simulator" 4661:10.1103/physrevlett.87.037901 2637:Gallagher, Thomas F. (1994). 1312:with higher energy and lower 800:(equivalent to a large first 2247:Strongly interacting systems 2157:{\displaystyle \lambda _{0}} 991:of highly excited electrons: 5756:American Journal of Physics 4734:10.1103/physrevlett.85.2208 4001:10.1103/PhysRevLett.85.2208 3946:10.1016/j.newar.2009.07.003 3643:Konovalenko, A. A. (1984). 3596:"Radio Recombination Lines" 3189:10.1088/0953-4075/28/24/015 2994:American Journal of Physics 2957:Journal of Chemical Physics 2878:"The Structure of the Atom" 2780:Nolan, James (2005-05-31). 2743:American Journal of Physics 2297:non-demolition measurements 2279:Current research directions 2230:RRLs are spread across the 1963:by one or a few means that 1296:. Semiclassical orbits for 786:, because the ground state 442:and hence falls off like 1/ 312:{\displaystyle mvr=n\hbar } 5813: 5055:10.1103/physreva.86.053618 4873:10.1103/physrevx.10.021054 4807:10.1103/revmodphys.82.2313 4523:10.1103/physreva.72.043803 4458:10.1103/physreva.91.030301 3500:10.1088/0022-3700/15/2/004 3333:10.1103/PhysRevA.89.040502 2838:10.1016/j.nimb.2005.03.137 2643:Cambridge University Press 2372:Keplerian elliptical orbit 1285:Quantum-mechanical details 811: 641:Charge exchange excitation 557:Electron impact excitation 89:. The higher the value of 4997:10.22331/q-2022-03-03-664 4777:Reviews of Modern Physics 4247:10.1038/s41567-018-0313-7 3808:The Astrophysical Journal 3612:10.1007/978-0-387-09691-9 2876:Niels Bohr (1922-12-11). 2687:10.1088/978-0-7503-1635-4 1553:potential that causes an 545:is the ground state with 109:, long decay periods and 5300:10.1038/nphoton.2016.214 5090:Physical Review Research 3839:10.3847/1538-4357/ab53d3 3780:10.3847/1538-4365/abef65 3711:10.3847/1538-4365/abf4d4 3427:10.1109/TAP.2020.2987112 3382:10.1103/PhysRevA.30.1142 3237:10.1103/PhysRevA.51.3604 3152:10.1103/PhysRevA.28.3098 3100:10.1103/PhysRevA.51.4272 2067:{\displaystyle \lambda } 1957:electromagnetic spectrum 962:correspondence principle 484:simple empirical formula 464:orbital angular momentum 329:principal quantum number 83:principal quantum number 63:orbital angular momentum 57:Energy levels in atomic 5702:Physical Review Applied 5557:10.1126/science.1258351 5382:Physical Review Letters 5157:Physical Review Letters 4704:Physical Review Letters 4631:Physical Review Letters 4558:Physical Review Letters 4355:Physical Review Letters 4282:Physical Review Letters 4159:Physical Review Letters 4096:Physical Review Letters 4033:Physical Review Letters 3970:Physical Review Letters 3516:Proceedings of the SPIE 2394:as the force is always 2380:electric dipole moments 2350:E = -3 x 10 V/m in the 2287:, quantum computation, 2253:electric dipole moments 1871:magnetic susceptibility 793:For atoms with a large 725:The arrival of tunable 42:of a Rydberg atom with 3564:Soviet Physics Doklady 3523:(5): 618105–618105–9. 2716:Stony Brook University 2539: 2495: 2363: 2328: 2186: 2158: 2131: 2068: 2042:). Carbon has a lower 2025:collisional broadening 1887: 1815: 1711: 1647:electric dipole moment 1494:Electron wavefunctions 1484: 1371: 1301: 1249: 1123: 947: 834: 773: 708: 628: 402: 313: 248: 81:that have a very high 66: 47: 3915:New Astronomy Reviews 3265:Astrophysical Journal 2712:"Rydberg Atom Optics" 2561:, to a straight line 2540: 2496: 2334: 2323: 2307:In October 2018, the 2255:. Calculations using 2187: 2159: 2132: 2069: 1888: 1886:{\displaystyle \chi } 1816: 1712: 1638:of the energy levels. 1485: 1372: 1292: 1250: 1124: 948: 821: 774: 709: 629: 537:Methods of production 403: 314: 249: 53: 35: 3890:10.1093/mnras/stv751 3519:. SPIE Proceedings. 3479:Journal of Physics B 3168:Journal of Physics B 2593:Heavy Rydberg system 2509: 2405: 2338:. Trajectory of the 2316:Classical simulation 2176: 2141: 2078: 2058: 1877: 1740: 1672: 1415: 1323: 1156: 999: 972:models of the atom. 884: 808:Hydrogenic potential 741: 656: 576: 563:Inelastic scattering 342: 288: 271:Orbital momentum is 168: 5769:1992AmJPh..60..324H 5724:2021PhRvP..15a4053M 5627:10.1038/nature18274 5619:2016Natur.534..667L 5549:2015Sci...347.1455S 5533:(6229): 1455–1458. 5478:10.1038/nature12512 5470:2013Natur.502...71F 5404:2010PhRvL.105s3603P 5343:1999Natur.400..239N 5239:2012NatPh...8..819S 5179:2012PhRvL.108z5301H 5112:2021PhRvR...3c2033K 5047:2012PhRvA..86e3618D 4988:2022Quant...6..664K 4923:2010NatPh...6..382W 4864:2020PhRvX..10b1054K 4799:2010RvMP...82.2313S 4726:2000PhRvL..85.2208J 4653:2001PhRvL..87c7901L 4580:2014PhRvL.112d0501P 4515:2005PhRvA..72d3803F 4450:2015PhRvA..91c0301K 4377:2011PhRvL.107m3602G 4304:2019PhRvL.123k3605K 4182:2008PhRvL.101y0601W 4119:2010PhRvL.104a0503I 4056:2010PhRvL.104a0502W 3993:2000PhRvL..85.2208J 3938:2009NewAR..53..259G 3830:2019ApJ...887..114W 3771:2021ApJS..254...28A 3702:2021ApJS..254...36W 3661:1984PAZh...10..846K 3576:1966SPhD...10..588S 3529:2006SPIE.6181E..05M 3492:1982JPhB...15L..49V 3419:2021ITAP...69.2455A 3374:1984PhRvA..30.1142N 3325:2014PhRvA..89d0502G 3278:1939ApJ....90..439I 3229:1995PhRvA..51.3604C 3181:1995JPhB...28.5309H 3144:1983PhRvA..28.3098T 3092:1995PhRvA..51.4272N 3047:1993JApSp..59..466D 3007:1992AmJPh..60..329H 2970:1966JChPh..44..837H 2917:1967RadR...31..191O 2830:2005NIMPB.235...17M 2756:2008AmJPh..76.1007M 2679:2018ryph.book.....S 2257:perturbation theory 2040:Warm Ionised Medium 2020:orders of magnitude 1793: 1731:Inglis–Teller limit 1555:angular correlation 515:semiclassical model 159:Newton's second law 147:, about a hydrogen 3055:10.1007/BF00663353 2904:Radiation Research 2722:on August 26, 2005 2673:. IOP Publishing. 2598:Old quantum theory 2535: 2491: 2364: 2329: 2289:quantum simulation 2219:emission from the 2182: 2154: 2127: 2064: 1955:spread across the 1883: 1811: 1806: 1779: 1707: 1585:In external fields 1544:radial correlation 1480: 1367: 1302: 1245: 1119: 1114: 1067: 1050: 943: 938: 835: 769: 721:Optical excitation 704: 624: 543:hydrogen-like atom 398: 309: 244: 130:electric potential 67: 48: 5603:(7609): 667–670. 5337:(6741): 239–242. 5247:10.1038/nphys2423 5025:Physical Review A 4931:10.1038/nphys1614 4842:Physical Review X 4710:(10): 2208–2211. 4493:Physical Review A 4428:Physical Review A 3922:(7–10): 259–265. 3621:978-0-387-09604-9 3537:10.1117/12.675004 3361:Physical Review A 3303:Physical Review A 3216:Physical Review A 3175:(24): 5309–5315. 3131:Physical Review A 3128:Rydberg states". 3079:Physical Review A 2978:10.1063/1.1726773 2764:10.1119/1.2961081 2750:(11): 1007–1011. 2652:978-0-521-02166-1 2213:interstellar dust 2209:external galaxies 2185:{\displaystyle v} 2044:ionization energy 2036:H II regions 1976:radio astronomers 1943:by hot stars and 1805: 1750: 1682: 1636:avoided crossings 1475: 1425: 1362: 1333: 1240: 1195: 1166: 1113: 1052: 1049: 937: 894: 802:ionization energy 531:Werner Heisenberg 527:quantum mechanics 452:ionization energy 393: 242: 217: 77:with one or more 16:(Redirected from 5804: 5781: 5780: 5750: 5744: 5743: 5717: 5697: 5691: 5677: 5671: 5661: 5655: 5654: 5612: 5591: 5585: 5584: 5542: 5522: 5516: 5515: 5489: 5455: 5446: 5440: 5439: 5397: 5377: 5371: 5370: 5326: 5320: 5319: 5293: 5278:Nature Photonics 5273: 5267: 5266: 5221: 5215: 5214: 5172: 5148: 5142: 5141: 5123: 5105: 5081: 5075: 5074: 5040: 5016: 5010: 5009: 4999: 4981: 4957: 4951: 4950: 4916: 4892: 4886: 4885: 4875: 4857: 4833: 4827: 4826: 4792: 4783:(3): 2313–2363. 4768: 4762: 4761: 4719: 4717:quant-ph/0004038 4695: 4689: 4688: 4646: 4644:quant-ph/0011028 4622: 4616: 4615: 4573: 4549: 4543: 4542: 4508: 4506:quant-ph/0503071 4484: 4478: 4477: 4443: 4419: 4413: 4412: 4370: 4346: 4340: 4339: 4297: 4273: 4267: 4266: 4240: 4216: 4210: 4209: 4175: 4153: 4147: 4146: 4112: 4090: 4084: 4083: 4049: 4027: 4021: 4020: 3986: 3984:quant-ph/0004038 3964: 3958: 3957: 3931: 3909: 3903: 3902: 3892: 3882: 3873:(2): 2025–2042. 3858: 3852: 3851: 3841: 3823: 3799: 3793: 3792: 3782: 3764: 3740: 3734: 3733: 3723: 3713: 3695: 3671: 3665: 3664: 3640: 3634: 3633: 3591: 3580: 3579: 3555: 3549: 3548: 3510: 3504: 3503: 3473: 3467: 3466: 3464: 3462: 3445: 3439: 3438: 3412: 3403:(5): 2455–2462. 3392: 3386: 3385: 3368:(2): 1142–1144. 3351: 3345: 3344: 3318: 3298: 3292: 3291: 3289: 3255: 3249: 3248: 3223:(5): 3604–3620. 3210: 3201: 3200: 3162: 3156: 3155: 3138:(5): 3098–3101. 3121: 3112: 3111: 3086:(5): 4272–4275. 3073: 3067: 3066: 3041:(1–2): 466–470. 3028: 3019: 3018: 2988: 2982: 2981: 2951: 2945: 2944: 2898: 2892: 2891: 2889: 2888: 2882: 2873: 2867: 2866: 2864: 2863: 2852:"The Bohr Model" 2848: 2842: 2841: 2807: 2801: 2800: 2798: 2797: 2788:. Archived from 2786:Davidson College 2777: 2768: 2767: 2737: 2731: 2730: 2728: 2727: 2718:. Archived from 2707: 2701: 2700: 2666: 2657: 2656: 2634: 2608:Rydberg molecule 2544: 2542: 2541: 2536: 2528: 2500: 2498: 2497: 2492: 2481: 2476: 2471: 2466: 2461: 2456: 2448: 2443: 2435: 2430: 2422: 2417: 2412: 2273:quantum critical 2262:quantum computer 2191: 2189: 2188: 2183: 2163: 2161: 2160: 2155: 2153: 2152: 2136: 2134: 2133: 2128: 2126: 2125: 2116: 2108: 2107: 2073: 2071: 2070: 2065: 1892: 1890: 1889: 1884: 1820: 1818: 1817: 1812: 1807: 1804: 1803: 1802: 1792: 1787: 1778: 1777: 1758: 1752: 1751: 1748: 1716: 1714: 1713: 1708: 1703: 1695: 1684: 1683: 1680: 1624: 1597: 1489: 1487: 1486: 1481: 1476: 1474: 1473: 1472: 1463: 1462: 1443: 1435: 1427: 1426: 1423: 1386:Rydberg constant 1380:where Ry = 13.6 1376: 1374: 1373: 1368: 1363: 1361: 1360: 1351: 1343: 1335: 1334: 1331: 1310:electron orbital 1254: 1252: 1251: 1246: 1241: 1239: 1238: 1237: 1228: 1227: 1218: 1217: 1198: 1197: 1196: 1193: 1187: 1186: 1176: 1168: 1167: 1164: 1128: 1126: 1125: 1120: 1115: 1112: 1111: 1106: 1105: 1100: 1091: 1090: 1085: 1079: 1070: 1066: 1051: 1048: 1047: 1046: 1030: 1029: 1020: 1014: 1013: 952: 950: 949: 944: 939: 936: 932: 931: 915: 914: 905: 896: 895: 892: 795:valence electron 778: 776: 775: 770: 765: 764: 713: 711: 710: 705: 700: 699: 687: 686: 668: 667: 633: 631: 630: 625: 620: 619: 607: 606: 588: 587: 496:Johannes Rydberg 407: 405: 404: 399: 394: 392: 388: 387: 374: 373: 372: 363: 362: 352: 318: 316: 315: 310: 253: 251: 250: 245: 243: 238: 237: 236: 223: 218: 216: 215: 206: 205: 204: 191: 186: 175: 40:Electron orbital 21: 18:Rydberg blockade 5812: 5811: 5807: 5806: 5805: 5803: 5802: 5801: 5787: 5786: 5785: 5784: 5777:10.1119/1.16875 5752: 5751: 5747: 5699: 5698: 5694: 5678: 5674: 5662: 5658: 5593: 5592: 5588: 5524: 5523: 5519: 5464:(7469): 71–75. 5453: 5448: 5447: 5443: 5379: 5378: 5374: 5328: 5327: 5323: 5275: 5274: 5270: 5233:(11): 819–824. 5223: 5222: 5218: 5150: 5149: 5145: 5083: 5082: 5078: 5018: 5017: 5013: 4959: 4958: 4954: 4894: 4893: 4889: 4835: 4834: 4830: 4770: 4769: 4765: 4697: 4696: 4692: 4624: 4623: 4619: 4551: 4550: 4546: 4486: 4485: 4481: 4421: 4420: 4416: 4348: 4347: 4343: 4275: 4274: 4270: 4218: 4217: 4213: 4155: 4154: 4150: 4092: 4091: 4087: 4029: 4028: 4024: 3977:(10): 2208–11. 3966: 3965: 3961: 3911: 3910: 3906: 3860: 3859: 3855: 3801: 3800: 3796: 3742: 3741: 3737: 3673: 3672: 3668: 3642: 3641: 3637: 3622: 3593: 3592: 3583: 3557: 3556: 3552: 3512: 3511: 3507: 3475: 3474: 3470: 3460: 3458: 3447: 3446: 3442: 3394: 3393: 3389: 3353: 3352: 3348: 3300: 3299: 3295: 3257: 3256: 3252: 3212: 3211: 3204: 3164: 3163: 3159: 3123: 3122: 3115: 3075: 3074: 3070: 3030: 3029: 3022: 3015:10.1119/1.16876 2990: 2989: 2985: 2953: 2952: 2948: 2925:10.2307/3572319 2900: 2899: 2895: 2886: 2884: 2883:. Nobel Lecture 2880: 2875: 2874: 2870: 2861: 2859: 2850: 2849: 2845: 2809: 2808: 2804: 2795: 2793: 2779: 2778: 2771: 2739: 2738: 2734: 2725: 2723: 2709: 2708: 2704: 2697: 2671:Rydberg Physics 2668: 2667: 2660: 2653: 2636: 2635: 2626: 2621: 2613:Rydberg polaron 2589: 2575: 2560: 2507: 2506: 2403: 2402: 2318: 2281: 2249: 2174: 2173: 2144: 2139: 2138: 2117: 2099: 2076: 2075: 2056: 2055: 1994:Weaker lines, H 1941:photoionization 1937: 1910: 1875: 1874: 1867: 1859: 1854: 1794: 1769: 1762: 1743: 1738: 1737: 1675: 1670: 1669: 1643: 1642: 1641: 1640: 1639: 1625: 1617: 1616: 1598: 1587: 1540: 1533: 1526: 1519: 1496: 1464: 1454: 1444: 1418: 1413: 1412: 1407: 1352: 1326: 1321: 1320: 1287: 1265: 1229: 1219: 1209: 1199: 1188: 1178: 1177: 1159: 1154: 1153: 1095: 1080: 1074: 1038: 1031: 1021: 1002: 997: 996: 985: 923: 916: 906: 887: 882: 881: 859: 816: 810: 756: 739: 738: 723: 691: 678: 659: 654: 653: 643: 611: 598: 579: 574: 573: 559: 539: 500:Rydberg formula 476: 379: 375: 364: 354: 353: 340: 339: 286: 285: 266: 228: 224: 207: 196: 192: 166: 165: 107:magnetic fields 28: 23: 22: 15: 12: 11: 5: 5810: 5808: 5800: 5799: 5789: 5788: 5783: 5782: 5763:(4): 324–328. 5745: 5692: 5672: 5656: 5586: 5517: 5441: 5388:(19): 193603. 5372: 5321: 5268: 5227:Nature Physics 5216: 5163:(26): 265301. 5143: 5096:(3): L032033. 5076: 5011: 4952: 4907:(5): 382–388. 4901:Nature Physics 4887: 4828: 4763: 4690: 4617: 4544: 4479: 4414: 4361:(13): 133602. 4341: 4288:(11): 113605. 4268: 4231:(2): 124–126. 4225:Nature Physics 4211: 4166:(25): 250601. 4148: 4085: 4022: 3959: 3904: 3853: 3794: 3735: 3666: 3635: 3620: 3581: 3550: 3505: 3486:(2): L49–L55. 3468: 3440: 3387: 3346: 3293: 3287:10.1086/144118 3250: 3202: 3157: 3113: 3068: 3020: 3001:(4): 329–335. 2983: 2964:(2): 837–839. 2946: 2911:(2): 191–200. 2893: 2868: 2843: 2824:(1–4): 17–22. 2802: 2769: 2732: 2702: 2695: 2658: 2651: 2623: 2622: 2620: 2617: 2616: 2615: 2610: 2605: 2600: 2595: 2588: 2585: 2573: 2558: 2547: 2546: 2534: 2531: 2527: 2523: 2520: 2517: 2514: 2503: 2502: 2490: 2487: 2484: 2480: 2475: 2470: 2465: 2460: 2455: 2451: 2447: 2442: 2438: 2434: 2429: 2425: 2421: 2416: 2411: 2376:electric field 2348:electric field 2317: 2314: 2285:quantum optics 2280: 2277: 2264:. In 2010 two- 2248: 2245: 2232:radio spectrum 2217:bremsstrahlung 2181: 2151: 2147: 2124: 2120: 2115: 2111: 2106: 2102: 2098: 2095: 2092: 2089: 2086: 2083: 2063: 2052:Doppler effect 1953:spectral lines 1936: 1933: 1929:Rydberg matter 1918:kinetic energy 1909: 1906: 1882: 1866: 1863: 1858: 1855: 1853: 1850: 1822: 1821: 1810: 1801: 1797: 1791: 1786: 1782: 1776: 1772: 1768: 1765: 1761: 1755: 1746: 1718: 1717: 1706: 1702: 1698: 1694: 1690: 1687: 1678: 1655:electric field 1626: 1619: 1618: 1599: 1592: 1591: 1590: 1589: 1588: 1586: 1583: 1582: 1581: 1574:semi-classical 1562: 1547: 1538: 1531: 1524: 1517: 1495: 1492: 1491: 1490: 1479: 1471: 1467: 1461: 1457: 1453: 1450: 1447: 1442: 1439: 1433: 1430: 1421: 1403: 1397:quantum defect 1378: 1377: 1366: 1359: 1355: 1350: 1347: 1341: 1338: 1329: 1314:binding energy 1286: 1283: 1282: 1281: 1276: 1275: 1268:polarizability 1266:is the dipole 1263: 1256: 1255: 1244: 1236: 1232: 1226: 1222: 1216: 1212: 1208: 1205: 1202: 1191: 1185: 1181: 1174: 1171: 1162: 1150: 1149: 1130: 1129: 1118: 1110: 1104: 1099: 1094: 1089: 1084: 1078: 1073: 1065: 1062: 1059: 1055: 1045: 1041: 1037: 1034: 1028: 1024: 1017: 1012: 1009: 1005: 993: 992: 983: 958:Rydberg states 954: 953: 942: 935: 930: 926: 922: 919: 913: 909: 902: 899: 890: 857: 812:Main article: 809: 806: 798:binding energy 788:binding energy 780: 779: 768: 763: 759: 755: 752: 749: 746: 722: 719: 715: 714: 703: 698: 694: 690: 685: 681: 677: 674: 671: 666: 662: 642: 639: 635: 634: 623: 618: 614: 610: 605: 601: 597: 594: 591: 586: 582: 567:kinetic energy 558: 555: 538: 535: 523:Wolfgang Pauli 475: 472: 456:Rydberg series 436:binding energy 409: 408: 397: 391: 386: 382: 378: 371: 367: 361: 357: 350: 347: 321: 320: 308: 305: 302: 299: 296: 293: 264: 255: 254: 241: 235: 231: 227: 221: 214: 210: 203: 199: 195: 189: 185: 181: 178: 174: 126:outer electron 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 5809: 5798: 5795: 5794: 5792: 5778: 5774: 5770: 5766: 5762: 5758: 5757: 5749: 5746: 5741: 5737: 5733: 5729: 5725: 5721: 5716: 5711: 5708:(1): 014053. 5707: 5703: 5696: 5693: 5689: 5685: 5681: 5676: 5673: 5669: 5665: 5660: 5657: 5652: 5648: 5644: 5640: 5636: 5632: 5628: 5624: 5620: 5616: 5611: 5606: 5602: 5598: 5590: 5587: 5582: 5578: 5574: 5570: 5566: 5562: 5558: 5554: 5550: 5546: 5541: 5536: 5532: 5528: 5521: 5518: 5513: 5509: 5505: 5501: 5497: 5493: 5488: 5483: 5479: 5475: 5471: 5467: 5463: 5459: 5452: 5445: 5442: 5437: 5433: 5429: 5425: 5421: 5417: 5413: 5409: 5405: 5401: 5396: 5391: 5387: 5383: 5376: 5373: 5368: 5364: 5360: 5356: 5352: 5351:10.1038/22275 5348: 5344: 5340: 5336: 5332: 5325: 5322: 5317: 5313: 5309: 5305: 5301: 5297: 5292: 5287: 5283: 5279: 5272: 5269: 5264: 5260: 5256: 5252: 5248: 5244: 5240: 5236: 5232: 5228: 5220: 5217: 5212: 5208: 5204: 5200: 5196: 5192: 5188: 5184: 5180: 5176: 5171: 5166: 5162: 5158: 5154: 5147: 5144: 5139: 5135: 5131: 5127: 5122: 5117: 5113: 5109: 5104: 5099: 5095: 5091: 5087: 5080: 5077: 5072: 5068: 5064: 5060: 5056: 5052: 5048: 5044: 5039: 5034: 5031:(5): 053618. 5030: 5026: 5022: 5015: 5012: 5007: 5003: 4998: 4993: 4989: 4985: 4980: 4975: 4971: 4967: 4963: 4956: 4953: 4948: 4944: 4940: 4936: 4932: 4928: 4924: 4920: 4915: 4910: 4906: 4902: 4898: 4891: 4888: 4883: 4879: 4874: 4869: 4865: 4861: 4856: 4851: 4848:(2): 021054. 4847: 4843: 4839: 4832: 4829: 4824: 4820: 4816: 4812: 4808: 4804: 4800: 4796: 4791: 4786: 4782: 4778: 4774: 4767: 4764: 4759: 4755: 4751: 4747: 4743: 4739: 4735: 4731: 4727: 4723: 4718: 4713: 4709: 4705: 4701: 4694: 4691: 4686: 4682: 4678: 4674: 4670: 4666: 4662: 4658: 4654: 4650: 4645: 4640: 4637:(3): 037901. 4636: 4632: 4628: 4621: 4618: 4613: 4609: 4605: 4601: 4597: 4593: 4589: 4585: 4581: 4577: 4572: 4567: 4564:(4): 040501. 4563: 4559: 4555: 4548: 4545: 4540: 4536: 4532: 4528: 4524: 4520: 4516: 4512: 4507: 4502: 4499:(4): 043803. 4498: 4494: 4490: 4483: 4480: 4475: 4471: 4467: 4463: 4459: 4455: 4451: 4447: 4442: 4437: 4434:(3): 030301. 4433: 4429: 4425: 4418: 4415: 4410: 4406: 4402: 4398: 4394: 4390: 4386: 4382: 4378: 4374: 4369: 4364: 4360: 4356: 4352: 4345: 4342: 4337: 4333: 4329: 4325: 4321: 4317: 4313: 4309: 4305: 4301: 4296: 4291: 4287: 4283: 4279: 4272: 4269: 4264: 4260: 4256: 4252: 4248: 4244: 4239: 4234: 4230: 4226: 4222: 4215: 4212: 4207: 4203: 4199: 4195: 4191: 4187: 4183: 4179: 4174: 4169: 4165: 4161: 4160: 4152: 4149: 4144: 4140: 4136: 4132: 4128: 4124: 4120: 4116: 4111: 4106: 4103:(1): 010503. 4102: 4098: 4097: 4089: 4086: 4081: 4077: 4073: 4069: 4065: 4061: 4057: 4053: 4048: 4043: 4040:(1): 010502. 4039: 4035: 4034: 4026: 4023: 4018: 4014: 4010: 4006: 4002: 3998: 3994: 3990: 3985: 3980: 3976: 3972: 3971: 3963: 3960: 3955: 3951: 3947: 3943: 3939: 3935: 3930: 3925: 3921: 3917: 3916: 3908: 3905: 3900: 3896: 3891: 3886: 3881: 3876: 3872: 3868: 3864: 3857: 3854: 3849: 3845: 3840: 3835: 3831: 3827: 3822: 3817: 3813: 3809: 3805: 3798: 3795: 3790: 3786: 3781: 3776: 3772: 3768: 3763: 3758: 3754: 3750: 3746: 3739: 3736: 3731: 3727: 3722: 3717: 3712: 3707: 3703: 3699: 3694: 3689: 3685: 3681: 3677: 3670: 3667: 3662: 3658: 3654: 3650: 3646: 3639: 3636: 3631: 3627: 3623: 3617: 3613: 3609: 3605: 3601: 3597: 3590: 3588: 3586: 3582: 3577: 3573: 3569: 3565: 3561: 3554: 3551: 3546: 3542: 3538: 3534: 3530: 3526: 3522: 3518: 3517: 3509: 3506: 3501: 3497: 3493: 3489: 3485: 3481: 3480: 3472: 3469: 3457: 3456: 3451: 3444: 3441: 3436: 3432: 3428: 3424: 3420: 3416: 3411: 3406: 3402: 3398: 3391: 3388: 3383: 3379: 3375: 3371: 3367: 3363: 3362: 3357: 3350: 3347: 3342: 3338: 3334: 3330: 3326: 3322: 3317: 3312: 3309:(4): 040502. 3308: 3304: 3297: 3294: 3288: 3283: 3279: 3275: 3271: 3267: 3266: 3261: 3254: 3251: 3246: 3242: 3238: 3234: 3230: 3226: 3222: 3218: 3217: 3209: 3207: 3203: 3198: 3194: 3190: 3186: 3182: 3178: 3174: 3170: 3169: 3161: 3158: 3153: 3149: 3145: 3141: 3137: 3133: 3132: 3127: 3120: 3118: 3114: 3109: 3105: 3101: 3097: 3093: 3089: 3085: 3081: 3080: 3072: 3069: 3064: 3060: 3056: 3052: 3048: 3044: 3040: 3036: 3035: 3027: 3025: 3021: 3016: 3012: 3008: 3004: 3000: 2996: 2995: 2987: 2984: 2979: 2975: 2971: 2967: 2963: 2959: 2958: 2950: 2947: 2942: 2938: 2934: 2930: 2926: 2922: 2918: 2914: 2910: 2906: 2905: 2897: 2894: 2879: 2872: 2869: 2857: 2853: 2847: 2844: 2839: 2835: 2831: 2827: 2823: 2819: 2818: 2813: 2806: 2803: 2792:on 2015-12-06 2791: 2787: 2783: 2776: 2774: 2770: 2765: 2761: 2757: 2753: 2749: 2745: 2744: 2736: 2733: 2721: 2717: 2713: 2706: 2703: 2698: 2696:9780750316354 2692: 2688: 2684: 2680: 2676: 2672: 2665: 2663: 2659: 2654: 2648: 2644: 2640: 2639:Rydberg Atoms 2633: 2631: 2629: 2625: 2618: 2614: 2611: 2609: 2606: 2604: 2603:Quantum chaos 2601: 2599: 2596: 2594: 2591: 2590: 2586: 2584: 2582: 2577: 2572: 2568: 2564: 2557: 2553: 2532: 2529: 2525: 2518: 2515: 2512: 2505: 2504: 2488: 2485: 2482: 2449: 2436: 2423: 2414: 2401: 2400: 2399: 2397: 2393: 2389: 2385: 2381: 2377: 2373: 2369: 2361: 2357: 2353: 2349: 2345: 2344:hydrogen atom 2341: 2337: 2333: 2326: 2322: 2315: 2313: 2310: 2305: 2302: 2298: 2294: 2290: 2286: 2278: 2276: 2274: 2270: 2267: 2263: 2258: 2254: 2246: 2244: 2241: 2238: 2233: 2228: 2226: 2222: 2218: 2214: 2210: 2205: 2203: 2199: 2195: 2179: 2171: 2167: 2149: 2145: 2122: 2118: 2113: 2104: 2100: 2096: 2093: 2087: 2084: 2081: 2061: 2053: 2048: 2045: 2041: 2037: 2032: 2030: 2026: 2021: 2017: 2013: 2009: 2005: 2001: 1997: 1993: 1989: 1985: 1981: 1977: 1974: 1970: 1966: 1962: 1958: 1954: 1950: 1946: 1945:recombination 1942: 1934: 1932: 1930: 1925: 1923: 1919: 1915: 1907: 1905: 1902: 1900: 1896: 1880: 1872: 1864: 1862: 1856: 1851: 1849: 1847: 1843: 1839: 1835: 1831: 1828:, the pure 1/ 1827: 1826:hydrogen atom 1808: 1799: 1795: 1789: 1784: 1780: 1774: 1770: 1766: 1763: 1759: 1753: 1744: 1736: 1735: 1734: 1732: 1728: 1724: 1704: 1696: 1688: 1685: 1676: 1668: 1667: 1666: 1664: 1660: 1656: 1652: 1648: 1637: 1633: 1629: 1623: 1614: 1610: 1606: 1602: 1596: 1584: 1579: 1575: 1571: 1567: 1563: 1560: 1559:tidal locking 1556: 1552: 1548: 1545: 1541: 1534: 1527: 1520: 1513: 1512: 1511: 1509: 1503: 1501: 1493: 1477: 1469: 1459: 1455: 1451: 1448: 1431: 1428: 1419: 1411: 1410: 1409: 1406: 1402: 1398: 1393: 1391: 1387: 1383: 1364: 1357: 1353: 1339: 1336: 1327: 1319: 1318: 1317: 1315: 1311: 1307: 1299: 1295: 1291: 1284: 1278: 1277: 1273: 1269: 1262: 1258: 1257: 1242: 1234: 1230: 1224: 1214: 1210: 1206: 1203: 1189: 1183: 1179: 1172: 1169: 1160: 1152: 1151: 1147: 1144: 1140: 1136: 1132: 1131: 1116: 1102: 1092: 1087: 1071: 1063: 1060: 1057: 1053: 1043: 1039: 1035: 1032: 1026: 1022: 1015: 1010: 1007: 1003: 995: 994: 990: 986: 978: 977: 976: 973: 971: 967: 963: 959: 940: 933: 928: 924: 920: 917: 911: 907: 900: 897: 888: 880: 879: 878: 876: 872: 869: 868: 863: 856: 852: 848: 844: 840: 839:Rydberg state 837:An atom in a 832: 828: 824: 820: 815: 814:Hydrogen atom 807: 805: 803: 799: 796: 791: 789: 785: 784:alkali metals 766: 761: 757: 750: 747: 744: 737: 736: 735: 732: 728: 720: 718: 701: 696: 692: 688: 683: 679: 672: 669: 664: 660: 652: 651: 650: 648: 640: 638: 621: 616: 612: 608: 603: 599: 592: 589: 584: 580: 572: 571: 570: 568: 564: 556: 554: 552: 548: 544: 536: 534: 532: 528: 524: 520: 516: 512: 507: 505: 504:energy levels 501: 497: 493: 489: 485: 482:discovered a 481: 480:Johann Balmer 473: 471: 469: 465: 461: 457: 453: 449: 445: 441: 437: 432: 430: 426: 422: 418: 414: 395: 389: 384: 380: 376: 369: 359: 355: 348: 345: 338: 337: 336: 334: 330: 326: 303: 300: 297: 294: 291: 284: 283: 282: 280: 279: 274: 269: 267: 260: 239: 233: 229: 225: 219: 212: 208: 201: 197: 193: 179: 176: 164: 163: 162: 160: 156: 155: 150: 146: 142: 137: 135: 134:hydrogen atom 131: 127: 123: 119: 115: 114:wavefunctions 112: 108: 104: 100: 96: 92: 88: 84: 80: 76: 72: 64: 60: 56: 52: 45: 41: 38: 34: 30: 19: 5760: 5754: 5748: 5705: 5701: 5695: 5690:, 2020-03-19 5675: 5670:, 2018-10-25 5659: 5600: 5596: 5589: 5530: 5526: 5520: 5487:1721.1/91605 5461: 5457: 5444: 5385: 5381: 5375: 5334: 5330: 5324: 5284:(1): 40–43. 5281: 5277: 5271: 5230: 5226: 5219: 5160: 5156: 5146: 5093: 5089: 5079: 5028: 5024: 5014: 4969: 4965: 4955: 4904: 4900: 4890: 4845: 4841: 4831: 4780: 4776: 4766: 4707: 4703: 4693: 4634: 4630: 4620: 4561: 4557: 4547: 4496: 4492: 4482: 4431: 4427: 4417: 4358: 4354: 4344: 4285: 4281: 4271: 4228: 4224: 4214: 4163: 4157: 4151: 4100: 4094: 4088: 4037: 4031: 4025: 3974: 3968: 3962: 3919: 3913: 3907: 3870: 3866: 3856: 3811: 3807: 3797: 3752: 3748: 3738: 3683: 3679: 3669: 3652: 3648: 3638: 3603: 3599: 3567: 3563: 3553: 3520: 3514: 3508: 3483: 3477: 3471: 3461:19 September 3459:. Retrieved 3455:Ars Technica 3453: 3443: 3400: 3396: 3390: 3365: 3359: 3355: 3349: 3306: 3302: 3296: 3269: 3263: 3253: 3220: 3214: 3172: 3166: 3160: 3135: 3129: 3125: 3083: 3077: 3071: 3038: 3032: 2998: 2992: 2986: 2961: 2955: 2949: 2908: 2902: 2896: 2885:. Retrieved 2871: 2860:. Retrieved 2858:. 2000-08-10 2846: 2821: 2815: 2805: 2794:. Retrieved 2790:the original 2747: 2741: 2735: 2724:. 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Index

Rydberg blockade

Electron orbital
n

lithium
orbital angular momentum
excited atom
electrons
principal quantum number
on average
atoms
electric
magnetic fields
electron
wavefunctions
classical
nuclei
outer electron
electric potential
hydrogen atom
Bohr model
nucleus
e
Newton's second law
Δ0
quantized
ħ
Bohr
principal quantum number

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