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Stress corrosion cracking

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141: 133: 748: 960:: In 1988, Aloha Airlines Flight 243 experienced a partial fuselage failure due to SCC. The Boeing 737-200 was flying from Hilo to Honolulu, Hawaii when a section of the fuselage ruptured, causing a decompression event. The investigation into the failure found that SCC had occurred in the aluminum skin of the fuselage due to the repeated pressurization and depressurization cycles of the aircraft. The incident led to changes in maintenance procedures and inspections for aircraft to prevent similar failures in the future. 831: 954:: In 2001, a section of the Trans-Alaska Pipeline failed due to SCC. The pipeline is used to transport crude oil from the North Slope of Alaska to the Valdez Marine Terminal. The failure occurred when a 34-foot section of the pipeline ruptured, causing a spill of over 285,000 gallons of crude oil. The investigation into the failure found that SCC had occurred in the pipeline due to the presence of water and bacteria, which had created a corrosive environment. 762: 755: 36: 723: 937:, suddenly failed. The main chain joint failed and the entire structure fell into the river, killing 46 people who were traveling in vehicles across the bridge. Rust in the eyebar joint had caused a stress corrosion crack, which went critical as a result of high bridge loading and low temperature. The failure was exacerbated by a high level of 891: 840:
rate at which chemical reactants can be transported to the tip of the crack. In region III, crack propagation is independent of its environment, having reached a critical stress intensity. Chemicals other than water, like ammonia, can induce subcritical crack propagation in silica glass, but they must have an
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Material Selection: Choosing the right material for a specific environment can help prevent SCC. Materials with higher resistance to corrosion and stress corrosion cracking should be used in corrosive environments. For example, using stainless steel instead of carbon steel in a marine environment can
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Subcritical crack propagation in glasses falls into three regions. In region I, the velocity of crack propagation increases with ambient humidity due to stress-enhanced chemical reaction between the glass and water. In region II, crack propagation velocity is diffusion controlled and dependent on the
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or other surface treatments. Unexpected and premature failure of chemical process equipment, for example, due to stress corrosion cracking constitutes a serious hazard in terms of safety of personnel, operating facilities and the environment. By weakening the reliability of these types of equipment,
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to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is
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submarine periscope: In 2009, the periscope of the submarine USS Hartford failed due to SCC. The periscope is used to provide a view of the surface while the submarine is submerged. The failure occurred when the periscope was extended through the hull of the submarine, causing seawater to enter the
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Illustrated are regions of different crack propagation under stress corrosion cracking. In region I, crack propagation is dominated by chemical attack of strained bonds in the crack. In region II, propagation is controlled by diffusion of chemical into the crack. In region III, the stress intensity
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are precisely controlled both in location and intensity and can be applied to mitigate sharp transitions into tensile regions. Laser peening imparts deep compressive residual stresses on the order of 10 to 20 times deeper than conventional shot peening, making them significantly more beneficial at
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being most sensitive to degradation. Ozone cracks form in products under tension, but the critical strain is very small. The cracks are always oriented at right angles to the strain axis, so will form around the circumference in a rubber tube bent over. Such cracks are dangerous when they occur in
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Protective Coatings: Applying a protective coating or barrier can help prevent corrosive substances from coming into contact with the metal surface, thus reducing the likelihood of SCC. For example, using an epoxy coating on the interior surface of a pipeline can reduce the likelihood of
304:, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly 948:
periscope's seal. The seawater caused SCC to occur in the periscope's steel support structure, which led to the periscope falling back into the submarine. Fortunately, there were no injuries, but the submarine had to be taken out of service for repairs.
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Cathodic Protection: Cathodic protection is a technique used to protect metals from corrosion by applying a small electrical current to the metal surface. This technique can also help prevent SCC by reducing the corrosion potential of the
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This effect is significantly less common in ceramics which are typically more resilient to chemical attack. Although phase changes are common in ceramics under stress these usually result in toughening rather than failure (see
1108: 822:). Recent studies have shown that the same driving force for this toughening mechanism can also enhance oxidation of reduced cerium oxide, resulting in slow crack growth and spontaneous failure of dense ceramic bodies. 148:. Cracks which would normally have been invisible are detectable due to the magnetic particles clustering at the crack openings. The scale at the bottom is in centimeters (each division indicates a millimeter). 880:
Inspection and Maintenance: Regular inspections and maintenance can help detect SCC before it causes a failure. This includes visual inspections, non-destructive testing, and monitoring of environmental
1348: 1201: 911:, belonging to the Tennessee Gas Pipeline exploded and burned from SCC on March 4, 1965, killing 17 people. At least 9 others were injured, and 7 homes 450 feet from the rupture were destroyed. 730:
For example, the fracture surface of a fuel connector showed the progressive growth of the crack from acid attack (Ch) to the final cusp (C) of polymer. In this case the failure was caused by
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of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure.
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Environmental Controls: Controlling the environment around the metal can help prevent SCC. For example, reducing the temperature or acidity of the environment can help prevent SCC.
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sidewalls, but are now seen rarely thanks to the use of these additives. On the other hand, the problem does recur in unprotected products such as rubber tubing and seals.
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ASM Handbook Volume 11 "Failure Analysis and Prevention" (2002) "Stress-Corrosion Cracking" Revised by W.R. Warke, American Society of Metals. Pages 1738-1820
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Munnings, C.; Badwal, S. P. S.; Fini, D. (20 February 2014). "Spontaneous stress-induced oxidation of Ce ions in Gd-doped ceria at room temperature".
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have been known to crack in an unexpectedly brittle manner in a whole variety of aqueous environments, especially when chlorides are present.
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fuel pipes because the cracks will grow from the outside exposed surfaces into the bore of the pipe, so fuel leakage and fire may follow.
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ASM International, Metals Handbook (Desk Edition) Chapter 32 (Failure Analysis), American Society for Metals, (1997) pp 32โ€“24 to 32โ€“26
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A close-up of the surface of a steel pipeline showing stress corrosion cracking (two clusters of small black lines) revealed by
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preventing SCC. Laser peening is widely used in the aerospace and power generation industries in gas fired turbine engines.
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attack, another form of SCC in polymers. Tiny traces of the gas in the air will attack double bonds in rubber chains, with
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predicts that failure should not occur. That is, in the presence of a corrodent, cracks develop and propagate well below
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facilitate the evolution and the enrichment of hydrogen during the process of SCC, thus increasing the SCC intensity.
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Stress corrosion cracking caused by tension developed in an unsuitably welded reinforcement collar
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growth, i.e. small surface flaws propagate (usually smoothly) under conditions where
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Hsu, Jeremy (March 23, 2009). "USS Hartford Periscope Snaps, Falls Into Submarine".
1150: 742:. The degradation reaction is the reverse of the synthesis reaction of the polymer: 1506: 845: 1223: 687:, when products are exposed to specific solvents or aggressive chemicals such as 1476: 739: 35: 17: 1488: 754: 722: 320:
from fabrication (e.g. cold working); the residual stresses can be relieved by
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2015 International Conference on Transportation Information and Safety (ICTIS)
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Wachtman, John B.; Cannon, W. Roger; Matthewson, M. John (11 September 2009).
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where attacking agents do not necessarily degrade the materials chemically.
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reaches its critical value and propagates independent of its environment.
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With the possible exception of the latter, which is a special example of
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is sensitive to attack by alkalis, but not by acids. On the other hand,
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Wachtman, John B.; Cannon, W. Roger; Matthewson, M. John. "Chapter 8".
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in the eyebar. The disaster led to a nationwide reappraisal of bridges.
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environment. It can lead to unexpected and sudden failure of normally
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such failures also adversely affect productivity and profitability.
1036: โ€“ Form of stress-corrosion cracking of brass cartridge cases 889: 829: 781: 760: 721: 712: 688: 510: 499: 354: 338: 334: 297: 139: 131: 899: 806: 719:, and nylon mouldings will crack when attacked by strong acids. 601:). The subcritical value of the stress intensity, designated as 237: 1024: โ€“ Cracks in many different elastomers due to ozone attack 1042: โ€“ Form of hydrogen embrittlement due to hydrogen sulfide 801:
can be prevented by adding anti-ozonants to the rubber before
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Lewis, Peter Rhys; Reynolds, Ken; Gagg, Colin (2003-09-29).
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The stresses can be the result of the crevice loads due to
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Close-up of broken nylon fuel pipe connector caused by SCC
1438:"The Policy Dynamics of the Trans-Alaska Pipeline System" 715:
is sensitive to degradation by acids, a process known as
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A 32-inch diameter gas transmission pipeline, north of
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Corrective Action Order Regarding the TGP 100 Pipeline
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Pages displaying wikidata descriptions as a fallback
1274:, ASM International, pp. 191โ€“220, 2017-01-01, 1000: โ€“ Study of propagation of cracks in materials 703:are readily degraded by acids, and SCC is a likely 60:. Unsourced material may be challenged and removed. 663: 631: 593: 1006: โ€“ Brittle failure of thermoplastic polymers 1268:"Irradiation-Assisted Stress-Corrosion Cracking" 805:. Ozone cracks were commonly seen in automobile 1224:"Peening for mitigation of PWSCC in alloy 600" 994: โ€“ Study of failure in polymeric products 857:The compressive residual stresses imparted by 316:, or can be caused by the type of assembly or 1475:Hong-bing, Du; Qing-qing, Zhang (June 2015). 1068:(Desk ed.). American Society for Metals. 262: 8: 1419:"Report: Sub crew caused Hartford collision" 914:SCC caused the catastrophic collapse of the 1222:Crooker, Paul; Sims, William (2011-06-09). 27:Growth of cracks in a corrosive environment 375: 269: 255: 151: 1079:Gu, B.; Luo, J.; Mao, X. (January 1999). 651: 650: 644: 613: 612: 606: 581: 580: 574: 333:Stress corrosion cracking mainly affects 120:Learn how and when to remove this message 288:) is the growth of crack formation in a 1436:Busenberg, George J. (September 2011). 1056: 776:Cracks can be formed in many different 707:mechanism. Polymers are susceptible to 154: 1417:Grogan, Jennifer (November 17, 2009). 985: โ€“ branch of forensic engineering 1168:(2nd ed.). John Wiley and Sons. 345:also affects other materials such as 7: 1542:from the original on 3 December 2022 1262: 1260: 1258: 1256: 1254: 341:. A comparable effect also known as 58:adding citations to reliable sources 632:{\displaystyle K_{\mathrm {Iscc} }} 655: 652: 623: 620: 617: 614: 585: 582: 25: 1557:Mechanical Properties of Ceramics 1280:10.31399/asm.tb.sccmpe2.t55090191 1166:Mechanical Properties of Ceramics 664:{\displaystyle K_{\mathrm {Ic} }} 594:{\displaystyle K_{\mathrm {Ic} }} 523:caustic stress corrosion cracking 1454:10.1111/j.1541-1338.2011.00508.x 1341:"17 Killed As Gas Line Explodes" 1064:"Chapter 32: Failure Analysis". 753: 746: 567:critical stress intensity factor 34: 1351:from the original on 2021-11-02 1240:from the original on 2022-10-06 1204:from the original on 2022-12-06 1111:from the original on 2023-02-21 734:of the polymer by contact with 45:needs additional citations for 1371:Forensic Materials Engineering 983:Forensic materials engineering 1: 1010:Environmental stress fracture 1004:Environmental stress cracking 866:reduce the likelihood of SCC. 709:environmental stress cracking 681:environmental stress cracking 343:environmental stress cracking 992:Forensic polymer engineering 146:magnetic particle inspection 218:Metal-induced embrittlement 69:"Stress corrosion cracking" 1606: 1489:10.1109/ictis.2015.7232149 1483:. IEEE. pp. 780โ€“786. 918:in December 1967, when an 513:cracks in the presence of 208:Liquid metal embrittlement 1442:Review of Policy Research 1272:Stress-Corrosion Cracking 1143:10.1007/s11581-014-1079-2 958:Aloha Airlines Flight 243 639:, may be less than 1% of 502:crack in the presence of 282:Stress corrosion cracking 223:Stress corrosion cracking 1530:ASTM (5 November 2018). 1012: โ€“ Material failure 794:nitrile butadiene rubber 155:Mechanical failure modes 1345:The Washington Observer 1040:Sulfide stress cracking 909:Natchitoches, Louisiana 228:Sulfide stress cracking 1016:Hydrogen embrittlement 903: 836: 773: 727: 665: 633: 595: 198:Hydrogen embrittlement 149: 137: 1590:Materials degradation 1379:10.1201/9780203484531 1174:10.1002/9780470451519 952:Trans-Alaska Pipeline 893: 833: 764: 725: 666: 634: 596: 143: 135: 1585:Engineering failures 977:Forensic engineering 643: 605: 573: 314:stress concentration 54:improve this article 1028:Polymer degradation 898:, as seen from the 679:A similar process ( 547:high-tensile steels 213:Mechanical overload 1580:Fracture mechanics 998:Fracture mechanics 971:Forensic chemistry 904: 837: 774: 728: 661: 629: 591: 563:fracture mechanics 369:and lower applied 150: 138: 1498:978-1-4799-8694-1 1388:978-0-203-48453-1 1289:978-1-62708-266-2 1097:10.5006/1.3283971 923:suspension bridge 820:Zirconium dioxide 790:styrene-butadiene 555:hydrogen cracking 485: 484: 318:residual stresses 279: 278: 173:Corrosion fatigue 130: 129: 122: 104: 16:(Redirected from 1597: 1560: 1551: 1549: 1547: 1511: 1510: 1472: 1466: 1465: 1433: 1427: 1426: 1414: 1408: 1407: 1399: 1393: 1392: 1366: 1360: 1359: 1357: 1356: 1337: 1331: 1330: 1328: 1321: 1313: 1307: 1306: 1305: 1304: 1264: 1249: 1248: 1246: 1245: 1239: 1228: 1219: 1213: 1212: 1210: 1209: 1194: 1188: 1187: 1161: 1155: 1154: 1137:(8): 1117โ€“1126. 1126: 1120: 1119: 1117: 1116: 1076: 1070: 1069: 1061: 988: 886:Notable failures 757: 750: 670: 668: 667: 662: 660: 659: 658: 638: 636: 635: 630: 628: 627: 626: 600: 598: 597: 592: 590: 589: 588: 493:stainless steels 393:SCC environment 376: 271: 264: 257: 152: 125: 118: 114: 111: 105: 103: 62: 38: 30: 21: 18:Stress corrosion 1605: 1604: 1600: 1599: 1598: 1596: 1595: 1594: 1565: 1564: 1563: 1554: 1545: 1543: 1529: 1514: 1499: 1474: 1473: 1469: 1435: 1434: 1430: 1416: 1415: 1411: 1401: 1400: 1396: 1389: 1368: 1367: 1363: 1354: 1352: 1347:. 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Retrieved 1088: 1084: 1074: 1065: 1059: 945:USS Hartford 846:proton donor 838: 816: 792:rubber, and 775: 729: 683:) occurs in 678: 552: 522: 518: 402: 396: 388: 382: 364: 332: 311: 285: 281: 280: 222: 116: 107: 97: 90: 83: 76: 64: 52:Please help 47:verification 44: 925:across the 844:site and a 740:car battery 539:solutions ( 1569:Categories 1355:2023-02-21 1303:2023-04-26 1244:2022-06-01 1208:2023-02-21 1115:2023-02-21 1047:References 927:Ohio River 852:Prevention 778:elastomers 732:hydrolysis 717:hydrolysis 701:polyesters 537:ammoniacal 490:austenitic 458:Al-3Mg-7Zn 409:13Cr steel 329:Mechanisms 80:newspapers 1575:Corrosion 1462:1541-132X 1105:0010-9312 1085:Corrosion 535:crack in 504:chlorides 497:aluminium 478:0.6 M KCl 472:Ti-6Al-1V 450:OH (pH 7) 322:annealing 306:corrosive 290:corrosive 168:Corrosion 1540:Archived 1536:astm.org 1349:Archived 1235:Archived 1202:Archived 1151:95469920 1109:Archived 965:See also 881:factors. 813:Ceramics 685:polymers 675:Polymers 527:nitrates 488:Certain 429:42% MgCl 423:18Cr-8Ni 351:ceramics 347:polymers 243:Yielding 193:Fracture 163:Buckling 1517:Sources 1507:2908608 1423:The Day 1298:7010172 1231:nrc.gov 705:failure 693:alkalis 440:Cu-30Zn 415:3% NaCl 294:ductile 188:Fouling 183:Fatigue 94:scholar 1546:1 June 1505:  1495:  1460:  1385:  1296:  1286:  1180:  1149:  1131:Ionics 1103:  920:eyebar 874:metal. 848:site. 772:tubing 525:) and 517:(e.g. 515:alkali 500:alloys 379:Alloy 365:Lower 361:Metals 335:metals 298:alloys 296:metal 203:Impact 96:  89:  82:  75:  67:  1503:S2CID 1327:(PDF) 1320:(PDF) 1238:(PDF) 1227:(PDF) 1147:S2CID 1052:Notes 826:Glass 782:ozone 713:Nylon 689:acids 559:crack 511:steel 509:mild 403:MN/m 389:MN/m 355:glass 178:Creep 101:JSTOR 87:books 1548:2022 1493:ISBN 1458:ISSN 1383:ISBN 1294:OSTI 1284:ISBN 1178:ISBN 1101:ISSN 902:side 900:Ohio 870:SCC. 807:tire 691:and 521:and 495:and 400:Iscc 353:and 337:and 238:Wear 73:news 1485:doi 1450:doi 1375:doi 1276:doi 1170:doi 1139:doi 1093:doi 929:at 780:by 768:in 481:20 443:200 435:10 426:200 418:12 286:SCC 56:by 1571:: 1538:. 1534:. 1501:. 1491:. 1479:. 1456:. 1446:28 1444:. 1440:. 1421:. 1381:. 1343:. 1292:, 1282:, 1270:, 1253:^ 1233:. 1229:. 1200:. 1176:. 1145:. 1135:20 1133:. 1107:. 1099:. 1089:55 1087:. 1083:. 933:, 788:, 671:. 543:); 475:60 467:5 461:25 453:1 446:NH 412:60 386:Ic 367:pH 357:. 349:, 1559:. 1550:. 1509:. 1487:: 1464:. 1452:: 1425:. 1406:. 1391:. 1377:: 1358:. 1278:: 1247:. 1211:. 1186:. 1172:: 1153:. 1141:: 1118:. 1095:: 656:c 653:I 648:K 624:c 621:c 618:s 615:I 610:K 586:c 583:I 578:K 569:( 529:; 448:4 431:2 397:K 383:K 284:( 270:e 263:t 256:v 123:) 117:( 112:) 108:( 98:ยท 91:ยท 84:ยท 77:ยท 50:. 20:)

Index

Stress corrosion

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magnetic particle inspection
Buckling
Corrosion
Corrosion fatigue
Creep
Fatigue
Fouling
Fracture
Hydrogen embrittlement
Impact
Liquid metal embrittlement
Mechanical overload
Metal-induced embrittlement
Stress corrosion cracking
Sulfide stress cracking
Thermal shock

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