343:. He developed the paradigm of Lewis base activation of Lewis acids and successfully applied it to the asymmetric addition of a broad range of nucleophiles to silyl ketene acetals, iodo- and bromo-functionalization of alkenes, and enantioselective thio- and seleno-functionalization of alkenes. His work has yielded several Lewis base catalysts that are chiral phosphoramide derivatives. Unlike other organocatalysts, the Lewis base catalysts operate without the assistance of
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since 1994 and the editor-in-chief and president from 2008 to 2019. Denmark is known for his intensity and enthusiasm as an advisor and for his strict adherence to the 'Swiss method' of organic synthesis, compound characterization, and reporting of experimental methods. Students who worked with him
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An additional area of research for the
Denmark group is the observation and characterization of the pre-transmetalation species of the boron-palladium adduct in
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Significant interests of
Denmark's also include asymmetric catalysis with main group elements, also known as Lewis base catalysis, which is a subclass of
414:
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early in his research career later recalled their self-description as "Denmark's
Disciples" in a retrospective recognizing his contributions.
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993:
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Synthetic, Mechanistic and
Computational Studies on AE Inspired Chemistry: From Polyene Cyclizations to Origin of Biomolecular Homochirality
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285:. Denmark was the third Eschenmoser lecturer at the ETH ZĂĽrich in 2018, the first former Eschenmoser graduate student thus honored.
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332:. His work on the palladium-catalyzed cross-coupling reaction with vinylsilanol and arylrsilanol has been recognized as the
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in 1987, and was named the Fuson
Professor of Chemistry in 1991. He served as the president and editor-in-chief of the
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Denmark has published over 400 peer-reviewed articles and 27 book chapters and edited several book volumes including:
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732:"Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates"
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Denmark, S. E.; Harmata, M. A. (September 1, 1982). "Carbanion-accelerated
Claisen rearrangements".
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869:"Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link"
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678:"Frederic Stanley Kipping Award In Silicon Chemistry | Chemical & Engineering News"
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Select chiral Lewis base catalysts developed by Scott
Denmark for asymmetric catalysis
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Denmark, S. E.; Jones, T. K. (May 1, 1982). "Silicon-directed
Nazarov cyclization".
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chemistry, asymmetric allylmetal chemistry, silicon-based cross-coupling reactions,
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838:. Topics in Organometallic Chemistry. Springer Berlin Heidelberg. pp. 55–89.
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as an undergraduate and during his studies he was involved in research with both
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using rapid-injection NMR techniques. Denmark also has research interests in
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and chemoinformatics, organic chemistry, and catalysis with nanoparticles.
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1086:"Scott E. Denmark Elected to the American Academy of Arts and Sciences"
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Beutner, Gregory L.; Denmark, Scott E. (2012). GooĂźen, Lukas J. (ed.).
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book series between 2008 and 2018. In 2017, Denmark was elected to the
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Denmark began his independent academic research career in 1980 at the
297:, where his laboratory's early work focused on investigation of the
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degree from MIT in 1975. His graduate studies were conducted at the
1028:"Special Issue Dedicated to Professor Scott E. Denmark - Laudation"
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Fellows of the
American Association for the Advancement of Science
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University of
Illinois at Urbana-Champaign Department of Chemistry
281:. Denmark received the D.Tech. Sc. degree in 1980 for his thesis
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related cycloaddition reactions, phosphorus-stabilized anions,
250:
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Lewis base catalysis in organic synthesis. Volume 1, 2 and 3
215:. He joined the faculty at UIUC the same year and became an
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Members of the United States National Academy of Sciences
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Vedejs, Edwin; E., Denmark, Scott (October 10, 2016).
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Denmark, Scott E.; Ambrosi, Andrea (August 21, 2015).
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Thomas, Andy A.; Denmark, Scott E. (April 15, 2016).
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Fellows of the American Academy of Arts and Sciences
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556:"Past Eschenmoser Lecturers and Their Laudations"
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560:Department of Chemistry and Applied Biosciences
528:(PhD). ETH ZĂĽrich (Promotionsarbeit Nr. 6665).
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819:: CS1 maint: multiple names: authors list (
211:in 1980, under the supervision of Professor
312:Other interests in Denmark's group include
283:On the Stereochemistry of the S N’ Reaction
736:Organic Process Research & Development
526:On the stereochemistry of the S-N'Reaction
415:United States National Academy of Sciences
295:University of Illinois at Urbana-Champaign
197:University of Illinois at Urbana-Champaign
145:University of Illinois at Urbana–Champaign
31:
20:
1173:Fellows of the Royal Society of Chemistry
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902:
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381:Lewis Base Catalysis in Organic Synthesis
1178:Fellows of the American Chemical Society
643:Journal of the American Chemical Society
608:Journal of the American Chemical Society
349:
305:. This work was later recognized by the
581:Denmark, Scott E. (November 27, 1972).
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207:in 1975 and the D.Sc.Tech. degree from
1084:Yoksoulian, Lois E. (April 13, 2017).
812:
494:
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408:American Academy of Arts and Sciences
231:American Academy of Arts and Sciences
116:American Academy of Arts and Sciences
7:
347:, and have a broad substrate scope.
1128:from the original on June 16, 2023
1110:Notman, Nina (September 9, 2022).
191:is an American chemist who is the
14:
233:. In 2018, he was elected to the
181:http://denmark.scs.illinois.edu/
1117:Chemical & Engineering News
992:Denmark, Scott E., ed. (2004).
1158:21st-century American chemists
195:Professor of Chemistry at the
114:, RSC Pedler Medal, Member of
1:
1112:"2023 National Award winners"
299:Nazarov cyclization reaction
235:National Academy of Sciences
199:(UIUC). Denmark received an
120:National Academy of Sciences
112:Arthur C. Cope Scholar Award
1038:(13): I–II. June 19, 2013.
968:"Topics in Stereochemistry"
383:. He has been an editor of
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587:. ETH Zurich (Switzerland)
524:Denmark, Scott E. (1980).
309:Award to Denmark in 2014.
90:Enantioselective synthesis
1163:American organic chemists
1064:American Chemical Society
500:"May 1 2018 NAS Election"
401:American Chemical Society
371:Topics in Stereochemistry
307:Frederick Stanley Kipping
277:under the supervision of
172:
125:
30:
748:10.1021/acs.oprd.5b00201
534:10.3929/ethz-a-000266394
326:water-gas shift reaction
322:phase-transfer catalysis
241:Early life and education
98:Organometallic chemistry
894:10.1126/science.aad6981
364:computational chemistry
334:Hiyama-Denmark coupling
1090:University of Illinois
1045:10.1055/s-0033-1338502
399:Elected fellow of the
355:
476:Denmark Group website
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303:Claisen rearrangement
249:in 1953. He attended
972:Wiley Online Library
844:10.1007/3418_2012_43
245:Denmark was born in
885:2016Sci...352..329T
836:Inventing Reactions
655:10.1021/ja00382a051
620:10.1021/ja00373a055
542:20.500.11850/137417
422:Arthur C.Cope Award
217:associate professor
1060:"2009 ACS Fellows"
1004:10.1002/0471264180
472:"Scott E. Denmark"
442:"Scott E. Denmark"
356:
279:Albert Eschenmoser
269:. He received his
265:on functionalized
247:Lynbrook, New York
213:Albert Eschenmoser
189:Scott Eric Denmark
157:Albert Eschenmoser
25:Scott Eric Denmark
995:Organic Reactions
879:(6283): 329–332.
649:(18): 4972–4974.
504:www.nasonline.org
420:Recipient of the
394:Awards and honors
386:Organic Reactions
376:Organic Syntheses
226:Organic Reactions
186:
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167:Erick M. Carreira
127:Scientific career
102:Organic Reactions
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163:Notable students
152:Doctoral advisor
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18:American chemist
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255:Richard H. Holm
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94:Suzuki reaction
86:Organocatalysis
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72:(Undergraduate)
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706:"Publications"
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261:analogs and
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203:degree from
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141:Institutions
126:
118:, Member of
46:17 June 1953
15:
1198:1953 births
682:cen.acs.org
314:nitroalkene
267:cyclophanes
1147:Categories
943:"Research"
904:2142/97541
429:References
275:ETH ZĂĽrich
259:ferredoxin
209:ETH Zurich
77:(Graduate)
75:ETH ZĂĽrich
57:Lynbrook,
50:1953-06-17
1095:April 22,
1069:April 22,
1032:Synthesis
952:April 22,
913:0036-8075
815:cite book
807:954732847
756:1083-6160
715:April 22,
663:0002-7863
628:0002-7863
481:April 22,
451:April 22,
345:H-bonding
219:in 1986,
136:Chemistry
1132:June 16,
1126:Archived
921:27081068
774:26478695
687:June 20,
289:Research
59:New York
929:1431914
881:Bibcode
873:Science
765:4608042
177:Website
48: (
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509:May 2,
424:, 2023
417:, 2018
410:, 2017
403:, 2009
379:, and
328:, and
133:Fields
108:Awards
925:S2CID
318:aldol
1134:2023
1097:2019
1071:2019
1008:ISBN
979:2019
954:2019
917:PMID
909:ISSN
848:ISBN
821:link
803:OCLC
793:ISBN
770:PMID
752:ISSN
717:2019
689:2017
659:ISSN
624:ISSN
593:2019
568:2019
511:2018
483:2019
453:2019
301:and
271:S.B.
201:S.B.
43:Born
1122:100
1040:doi
1000:doi
899:hdl
889:doi
877:352
840:doi
760:PMC
744:doi
651:doi
647:104
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538:hdl
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257:on
251:MIT
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Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
