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Polycrystalline silicon

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1586:. Timminco. Retrieved on 2011-04-02. Note regarding Timminco: On May 14, 2009, Timminco Limited, Photon Consulting LLC, Rogol Energy Consulting LLC, Michael Rogol, Dr. Heinz Schimmelbusch, Robert Dietrich, René Boisvert, Arthur R. Spector, Jack L. Messman, John C. Fox, Michael D. Winfield, Mickey P. Yakisch and John P. Walsh were named as defendants in a lawsuit. The claim was for $ 500 million plus punitive damages. The Superior Court of Justice decision in favor of the defendants is available here: https://www.canlii.org/en/on/onsc/doc/2016/2016onsc3124/2016onsc3124.html An appeal to the Ontario Superior Court is available at the following link. The Court again found in favor of the defendants and awarded costs accordingly. https://www.canlii.org/en/on/onca/doc/2017/2017onca369/2017onca369.html An appeal to the Canadian Supreme Court was made. The final decision by the Canadian Supreme Court fully vindicating the defendants' position with partial costs awarded to the defendants. The final decision is available here: https://scc-csc.lexum.com/scc-csc/scc-l-csc-a/en/16947/1/document.do A summary of this case is available here: https://www.canadianunderwriter.ca/insurance/court-shuts-door-case-may-muddied-water-limitation-periods-1004126598/ 580:) for polysilicon deposition is about 1.7 eV. Based on this equation, the rate of polysilicon deposition increases as the deposition temperature increases. There will be a minimum temperature, however, wherein the rate of deposition becomes faster than the rate at which unreacted silane arrives at the surface. Beyond this temperature, the deposition rate can no longer increase with temperature, since it is now being hampered by lack of silane from which the polysilicon will be generated. Such a reaction is then said to be "mass-transport-limited". When a polysilicon deposition process becomes mass-transport-limited, the reaction rate becomes dependent primarily on reactant concentration, reactor geometry, and gas flow. 1050:
polysilicon. Buyers will accept down payment and long-term agreements to acquire a large enough volume of polysilicon. On the contrary, spot prices will be below contract prices once the solar PV installation is in a down trend. In late 2010, booming installation brought up the spot prices of polysilicon. In the first half of 2011, prices of polysilicon kept strong owing to the FIT policies of Italy. The solar PV price survey and market research firm, PVinsights, reported that the prices of polysilicon might be dragged down by lack of installation in the second half of 2011. As recently as 2008 prices were over $ 400/kg spiking from levels around $ 200/kg, while seen falling to $ 15/kg in 2013.
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are attractive because of a low cost of production even with reduced efficiency. Higher efficiency devices yield modules that occupy less space and are more compact; however, the 5–10% efficiency of typical CSG devices still makes them attractive for installation in large central-service stations, such as a power station. The issue of efficiency versus cost is a value decision of whether one requires an "energy dense" solar cell or sufficient area is available for the installation of less expensive alternatives. For instance, a solar cell used for power generation in a remote location might require a more highly efficient solar cell than one used for low-power applications, such as solar
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inside a low-pressure reactor either by changing the pumping speed or changing the inlet gas flow into the reactor. If the inlet gas is composed of both silane and nitrogen, the inlet gas flow, and hence the reactor pressure, may be varied either by changing the nitrogen flow at constant silane flow, or changing both the nitrogen and silane flow to change the total gas flow while keeping the gas ratio constant. Recent investigations have shown that e-beam evaporation, followed by SPC (if needed) can be a cost-effective and faster alternative for producing solar-grade poly-Si thin films. Modules produced by such method are shown to have a photovoltaic efficiency of ~6%.
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the Siemens process. GT Solar claims a new Siemens process can produce at $ 27/kg and may reach $ 20/kg in 5 years. GCL-Poly expects production costs to be $ 20/kg by end of 2011. Elkem Solar estimates their UMG costs to be $ 25/kg, with a capacity of 6,000 tonnes by the end of 2010. Calisolar expects UMG technology to produce at $ 12/kg in 5 years with boron at 0.3 ppm and phosphorus at 0.6 ppm. At $ 50/kg and 7.5 g/W, module manufacturers spend $ 0.37/W for the polysilicon. For comparison, if a CdTe manufacturer pays spot price for tellurium ($ 420/kg in April 2010) and has a 3 
702:; however, it has potential for large-scale photovoltaic devices. The abundance, stability, and low toxicity of silicon, combined with the low cost of polysilicon relative to single crystals makes this variety of material attractive for photovoltaic production. Grain size has been shown to have an effect on the efficiency of polycrystalline solar cells. Solar cell efficiency increases with grain size. This effect is due to reduced recombination in the solar cell. Recombination, which is a limiting factor for current in a solar cell, occurs more prevalently at grain boundaries, see figure 1. 254:. Polycrystalline silicon (or semi-crystalline silicon, polysilicon, poly-Si, or simply "poly") is a material consisting of multiple small silicon crystals. Polycrystalline cells can be recognized by a visible grain, a "metal flake effect". Semiconductor grade (also solar grade) polycrystalline silicon is converted to single-crystal silicon – meaning that the randomly associated crystallites of silicon in polycrystalline silicon are converted to a large single crystal. Single-crystal silicon is used to manufacture most Si-based 214: 1042: 737: 36: 669:. UMG-Si greatly reduces impurities in a variety of ways that require less equipment and energy than the Siemens process. It is about 99% pure which is three or more orders of magnitude less pure and about 10 times less expensive than polysilicon ($ 1.70 to $ 3.20 per kg from 2005 to 2008 compared to $ 40 to $ 400 per kg for polysilicon). It has the potential to provide nearly-as-good solar cell efficiency at 1/5 the capital expenditure, half the energy requirements, and less than $ 15/kg. 616: 3377: 412: 289: 67: 350: 3389: 147:(ppb), while polycrystalline solar grade silicon (SoG-Si) is generally less pure. In the 2010's, production shifted toward China, with China-based companies accounting for seven of the top ten producers and around 90% of total worldwide production capacity of approximately 1,400,000 MT. German, US and South Korea companies account for the remainder. 564:
thickness uniformities of ±5%. Critical process variables for polysilicon deposition include temperature, pressure, silane concentration, and dopant concentration. Wafer spacing and load size have been shown to have only minor effects on the deposition process. The rate of polysilicon deposition increases rapidly with temperature, since it follows
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depend on the polycrystalline grain size, which is a physical parameter that the material scientist can manipulate. Through the methods of crystallization to form polycrystalline silicon, an engineer can control the size of the polycrystalline grains which will vary the physical properties of the material.
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processes must be surface-reaction-limited because they result in excellent thickness uniformity and step coverage. A plot of the logarithm of the deposition rate against the reciprocal of the absolute temperature in the surface-reaction-limited region results in a straight line whose slope is equal to –qE
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But as established producers (mentioned below) expand their capacities, additional newcomers – many from Asia – are moving into the market. Even long-time players in the field have recently had difficulties expanding plant production. It is yet unclear which companies will be able to produce at costs
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A primary concern in the photovoltaics industry is cell efficiency. However, sufficient cost savings from cell manufacturing can be suitable to offset reduced efficiency in the field, such as the use of larger solar cell arrays compared with more compact/higher efficiency designs. Designs such as CSG
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manufacturing. One of its primary uses is as gate electrode material for MOS devices. A polysilicon gate's electrical conductivity may be increased by depositing a metal (such as tungsten) or a metal silicide (such as tungsten silicide) over the gate. Polysilicon may also be employed as a resistor, a
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The resistivity, mobility, and free-carrier concentration in monocrystalline silicon vary with doping concentration of the single crystal silicon. Whereas the doping of polycrystalline silicon does have an effect on the resistivity, mobility, and free-carrier concentration, these properties strongly
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A picture of grain boundaries for polysilicon. Each grain is crystalline over the width of the grain. The grain boundary separates the grains where the adjoining grain is at a different orientation from its neighbor. The grain boundary separates regions of different crystal structure thus serving as
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In 2008 several companies were touting the potential of UMG-Si, but in 2010 the credit crisis greatly lowered the cost of polysilicon and several UMG-Si producers put plans on hold. The Siemens process will remain the dominant form of production for years to come due to more efficiently implementing
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Polysilicon doping, if needed, is also done during the deposition process, usually by adding phosphine, arsine, or diborane. Adding phosphine or arsine results in slower deposition, while adding diborane increases the deposition rate. The deposition thickness uniformity usually degrades when dopants
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When the rate at which polysilicon deposition occurs is slower than the rate at which unreacted silane arrives, then it is said to be surface-reaction-limited. A deposition process that is surface-reaction-limited is primarily dependent on reactant concentration and reaction temperature. Deposition
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The deposition of polycrystalline silicon on plastic substrates is motivated by the desire to be able to manufacture digital displays on flexible screens. Therefore, a relatively new technique called laser crystallization has been devised to crystallize a precursor amorphous silicon (a-Si) material
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Prices of polysilicon are often divided into two categories, contract and spot prices, and higher purity commands higher prices. While in booming installation times, price rally occurs in polysilicon. Not only spot prices surpass contract prices in the market; but it is also hard to acquire enough
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in supply of polysilicon feedstock and was forced to idle about a quarter of its cell and module manufacturing capacity in 2007. Only twelve factories were known to produce solar-grade polysilicon in 2008; however, by 2013 the number increased to over 100 manufacturers. Monocrystalline silicon is
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At reduced pressure levels for VLSI manufacturing, polysilicon deposition rate below 575 °C is too slow to be practical. Above 650 °C, poor deposition uniformity and excessive roughness will be encountered due to unwanted gas-phase reactions and silane depletion. Pressure can be varied
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Asia predicts 328,000 tons production with only 196,000 tons of demand, with spot prices expected to fall 56%. While good for renewable energy prospects, the subsequent drop in price could be brutal for manufacturers. As of late 2012, SolarIndustryMag reports a capacity of 385,000 tons will be
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The use of polycrystalline silicon in the production of solar cells requires less material and therefore provides higher profits and increased manufacturing throughput. Polycrystalline silicon does not need to be deposited on a silicon wafer to form a solar cell, rather it can be deposited on
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Polysilicon layers can be deposited using 100% silane at a pressure of 25–130 Pa (0.19–0.98 Torr) or with 20–30% silane (diluted in nitrogen) at the same total pressure. Both of these processes can deposit polysilicon on 10–200 wafers per run, at a rate of 10–20 nm/min and with
823:, in July 2011, the total polysilicon production in 2010 was 209,000 tons. First-tier suppliers account for 64% of the market while China-based polysilicon firms have 30% of market share. The total production is likely to increase 37.4% to 281,000 tons by end of 2011. For 2012, 680:
Q-Cells, Canadian Solar, and Calisolar have used Timminco UMG. Timminco is able to produce UMG-Si with 0.5 ppm boron for $ 21/kg but were sued by shareholders because they had expected $ 10/kg. RSI and Dow Corning have also been in litigation over UMG-Si technology.
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other-cheaper materials, thus reducing the cost. Not requiring a silicon wafer alleviates the silicon shortages occasionally faced by the microelectronics industry. An example of not using a silicon wafer is crystalline silicon on glass (CSG) materials
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Méndez, Laura; Forniés, Eduardo; Garrain, Daniel; Pérez Vázquez, Antonio; Souto, Alejandro; Vlasenko, Timur (1 October 2021). "Upgraded metallurgical grade silicon and polysilicon for solar electricity production: A comparative life cycle assessment".
143:. The photovoltaic industry also produces upgraded metallurgical-grade silicon (UMG-Si), using metallurgical instead of chemical purification processes. When produced for the electronics industry, polysilicon contains impurity levels of less than one 427:
The molten silicon will then crystallize as it cools. By precisely controlling the temperature gradients, researchers have been able to grow very large grains, of up to hundreds of micrometers in size in the extreme case, although grain sizes of 10
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are also common. In order to create devices on polysilicon over large-areas, however, a crystal grain size smaller than the device feature size is needed for homogeneity of the devices. Another method to produce poly-Si at low temperatures is
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Wacker's projected its total hyperpure-polysilicon production capacity to increase to 67,000 metric tons by 2014, due to its new polysilicon-production facility in Cleveland, Tennessee (US) with an annual capacity of 15,000 metric tons.
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characteristics. When polysilicon and a-Si devices are used in the same process, this is called hybrid processing. A complete polysilicon active layer process is also used in some cases where a small pixel size is required, such as in
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in certain processing regimes, these processes still require relatively high temperatures of at least 300 °C. These temperatures make deposition of polysilicon possible for glass substrates but not for plastic substrates.
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industry, starting from poly rods that are two to three meters in length. In the microelectronics industry (semiconductor industry), poly is used at both the macro and micro scales. Single crystals are grown using the
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The Siemens process is the most commonly used method of polysilicon production, especially for electronics, with close to 75% of the world's production using this process as of 2005.
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and light-induced stress. This allows more complex, high-speed circuitry to be created on the glass substrate along with the a-Si devices, which are still needed for their low-
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a center for recombination. 'd' here is a characteristic grain size, which should be maximized for maximum solar cell efficiency. Typical values of d are about 1 micrometre.
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The polysilicon feedstock – large rods, usually broken into chunks of specific sizes and packaged in clean rooms before shipment – is directly cast into multicrystalline
225:, the crystalline framework is homogeneous, which can be recognized by an even external colouring. The entire sample is one single, continuous and unbroken crystal as 2226: 2012: 3282: 2959: 499:. For the first time, in 2006, over half of the world's supply of polysilicon was being used by PV manufacturers. The solar industry was severely hindered by a 1987: 2764: 677:
thickness, their cost would be 10 times less, $ 0.037/Watt. At 0.1 g/W and $ 31/ozt for silver, polysilicon solar producers spend $ 0.10/W on silver.
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where an amorphous-Si thin film can be crystallized at temperatures as low as 150 °C if annealed while in contact of another metal film such as
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higher priced and a more efficient semiconductor than polycrystalline as it has undergone additional recrystallization via the Czochralski method.
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Polycrystalline silicon is the key feedstock in the crystalline silicon based photovoltaic industry and used for the production of conventional
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conductor, or as an ohmic contact for shallow junctions, with the desired electrical conductivity attained by doping the polysilicon material.
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Ghosh, Amal K.; Fishman, Charles & Feng, Tom (1980), "Theory of the electrical and photovoltaic properties of polycrystalline silicon",
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Due to the rapid growth in manufacturing in China and the lack of regulatory controls, there have been reports of the dumping of waste
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Polysilicon deposition, or the process of depositing a layer of polycrystalline silicon on a semiconductor wafer, is achieved by the
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of as much as 57 percent on polysilicon shipped from these two countries in order to stop the product from being sold below cost.
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C.Becker, Microstructure and photovoltaic performance of polycrystalline silicon thin films on temperature-stable ZnO:Al layers.
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pulses are used to heat the deposited a-Si material to above the melting point of silicon, without melting the entire substrate.
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Polysilicon production by country in 2013 (company head-quarter, not location of facility). World total of 227,000 tonnes.
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and consume most of the worldwide produced polysilicon. About 5 tons of polysilicon is required to manufacture one 1
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Is Upgraded Metallurgical Grade Silicon The Only Hope For Manufacturers of Photovoltaic Solar Cells? – GLG News
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processing technologies. For these technologies it is deposited using low-pressure chemical-vapour deposition (
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Kolic, Y (1995). "Electron powder ribbon polycrystalline silicon plates used for porous layer fabrication".
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Currently, polysilicon is commonly used for the conducting gate materials in semiconductor devices such as
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of the polysilicon can be orders of magnitude larger and the material also shows greater stability under
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Price cut of solar PV supply chain spreads and the price of poly-silicon might be dragged down by others
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devices. Polycrystalline silicon can be as much as 99.9999% pure. Ultra-pure poly is used in the
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http://www.bernreuter.com/fileadmin/user_upload/samples/SWE_6-2010_Solar_Silicon_Conference.pdf
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At the component level, polysilicon has long been used as the conducting gate material in
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into silicon at high temperatures. An emerging, alternative process of refinement uses a
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Please help update this article to reflect recent events or newly available information.
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Please help update this article to reflect recent events or newly available information.
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Advances in Solar Energy: An Annual Review of Research and Development, Volume 1 · 1982
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on a plastic substrate without melting or damaging the plastic. Short, high-intensity
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low enough to be profitable after the steep drop in spot-prices of the last months.
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are rare in nature and can also be difficult to produce in the laboratory (see also
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One major difference between polysilicon and a-Si is that the mobility of the
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is being produced as a low cost alternative to polysilicon created by the
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Market Realist cites World production capacity at 300,000 tons in 2013.
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Comparing polycrystalline (left) to monocrystalline (right) solar cells
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The polysilicon manufacturing market is growing rapidly. According to
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Proceedings of the 21st European Photovoltaic Solar Energy Conference
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or submitted to a recrystallization process to grow single crystal
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More recently, intrinsic and doped polysilicon is being used in
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Largest polysilicon producers in 2013 (market-share in %)
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Commerzbank Equity Research, Robert Schramm, Lauren Licuanan:
730: 282: 29: 1772:. Bloomberg New Energy Finance. 16 April 2014. pp. 2–3. 369:) reactors at high temperatures and is usually heavily doped 2238: 1250: 1248: 1574:. GUNTHER Portfolio (2010-04-29). Retrieved on 2011-04-02. 1562:. GUNTHER Portfolio (2010-04-29). Retrieved on 2011-04-02. 1499:
High-Efficient Low-Cost Photovoltaics: Recent Developments
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BNEF estimated actual production for 2013 at 227,000 tons
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impurities. The process is relatively expensive and slow.
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Solarserver | Das Internetportal für erneuerbare Energien
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Solarserver | Das Internetportal für erneuerbare Energien
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Solarserver | Das Internetportal für erneuerbare Energien
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or pocket calculators, or near established power grids.
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phases are composed of a number of smaller crystals or
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Dow Corning stopped UMG Solar Grade Silicon Production
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Dow Corning stopped UMG Solar Grade Silicon Production
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Schematic diagram of the traditional Siemens and the
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Gulf Times Ras Laffan to get $ 1bn polysilicon plant
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Solar Grade Litigation: Dow Corning vs. RSI Silicon
524:) at high temperatures of 580 to 650 °C. This 1058:The Chinese government accused United States and 815:Chemical processing at a P.S.T. polysilicon plant 415:Polycrystalline silicon (used to produce silicon 2333:"Solar Energy Firms Leave Waste Behind in China" 1419:An Introduction To Semiconductor Microtechnology 634:and then to silicon in a reactor, thus removing 158:. The boules are then sliced into thin silicon 127:by a chemical purification process, called the 1032:, announced an 8 t facility for start in 2013. 3283:List of countries by photovoltaics production 2960:Solar-Powered Aircraft Developments Solar One 2389: 1660:. GUNTHER Portfolio. Retrieved on 2011-04-02. 1256:"China: The new silicon valley – Polysilicon" 572:/kT) where q is electron charge and k is the 568:behavior, that is deposition rate = A·exp(–qE 8: 1670:Streetman, B. G. & Banerjee, S. (2000), 978:(2010: 8 kt, Jan 2013: 18 kt) USA. 606:Chemical vapor deposition § Polysilicon 2765:Photovoltaic thermal hybrid solar collector 2278:"Login to DIGITIMES archive & research" 1896:WACKER TENNESSEE Frequently Asked Questions 1792:"Login to DIGITIMES archive & research" 1674:(5th ed.), New Jersey: Prentice Hall, 1464: 1462: 1460: 1020:Beijing Lier High-temperature Materials Co. 317:. Unsourced material may be challenged and 81:: polysilicon rod (top) and chunks (bottom) 3272: 3087: 2791: 2638:Copper indium gallium selenide solar cells 2585: 2415: 2396: 2382: 2374: 1737: 1735: 1733: 1731: 1646:The Who's Who of Solar Silicon Production 1524:"Polysilicon Production: Siemens Process" 1175: 337:Learn how and when to remove this message 221:In single-crystal silicon, also known as 135:of volatile silicon compounds, and their 3100:Grid-connected photovoltaic power system 1696: 1694: 1692: 1690: 843: 353:A rod of semiconductor-grade polysilicon 3067:Victorian Model Solar Vehicle Challenge 3062:Hunt-Winston School Solar Car Challenge 1879:Citigroup Global Markets, Timothy Lam: 1153: 1070:. As a consequence, in 2013 it imposed 984:(2011: 3.2 kt, 2013: 14.5 kt) 2145:. Arizona State University. Nov 2010. 2074: 2042:: CS1 maint: archived copy as title ( 2035: 1951: 1868:Feedback form Solar Silicon Conference 112:, used as a raw material by the solar 2152:from the original on January 24, 2023 992:, (2011: 5 kt, Jan 2011), Russia 661:(UMG) silicon (also known as UMG-Si) 456:Polysilicon has many applications in 384:as the active and/or doped layers in 7: 3388: 653:Upgraded metallurgical-grade silicon 315:adding citations to reliable sources 3105:List of photovoltaic power stations 630:The process converts MG Si to SiHCl 3121:Rooftop photovoltaic power station 2524:Polycrystalline silicon (multi-Si) 2473:Third-generation photovoltaic cell 1779:from the original on 30 June 2014. 1045:History of polysilicon spot prices 388:. Although it can be deposited by 185:, giving the material its typical 25: 3126:Building-integrated photovoltaics 2623:Carbon nanotubes in photovoltaics 2529:Monocrystalline silicon (mono-Si) 2175:"Polysilicon - Solar Value Chain" 1417:Morgan, D. V.; Board, K. (1991). 1258:. 2 February 2015. Archived from 3387: 3376: 3375: 2498:Polarizing organic photovoltaics 1496:Vesselinka Petrova-Koch (2009). 1469:Karl W. Boer (6 December 2012). 1347:"Photovoltaics: Getting Cheaper" 1164:Science of the Total Environment 735: 287: 77:made of polycrystalline silicon 34: 2633:Cadmium telluride photovoltaics 2514:List of semiconductor materials 2361:Alan Joch (November 10, 2006). 1194:10.1016/j.scitotenv.2021.147969 162:and used for the production of 2745:Incremental conductance method 2539:Copper indium gallium selenide 2488:Thermodynamic efficiency limit 2309:. 18 July 2013. Archived from 2276:DIGITIMES (23 November 2012). 1672:Solid State Electronic Devices 177:Polysilicon consists of small 1: 3052:South African Solar Challenge 596:are added during deposition. 439:metal-induced crystallization 123:Polysilicon is produced from 2699:Photovoltaic mounting system 1333:10.1016/0040-6090(94)05644-S 926: 910: 894: 878: 862: 2704:Maximum power point tracker 1378:A Shortage Hits Solar Power 1224:"POLYSILICON MANUFACTURERS" 1107:Metallurgical grade silicon 1005:Osaka Titanium Technologies 528:process releases hydrogen. 125:metallurgical grade silicon 27:High purity form of silicon 3447: 2955:Solar panels on spacecraft 2802:Solar-powered refrigerator 2760:Concentrated photovoltaics 2740:Perturb and observe method 2519:Crystalline silicon (c-Si) 1881:Asia Solar View – May 2010 1790:DIGITIMES (19 July 2011). 1703:Journal of Applied Physics 603: 576:. The activation energy (E 488: 209:Vs monocrystalline silicon 3371: 2653:Heterojunction solar cell 2628:Dye-sensitized solar cell 2468:Multi-junction solar cell 2458:Nominal power (Watt-peak) 2084:Cite uses generic title ( 1961:Cite uses generic title ( 1376:The Wall Street Journal, 954:(2010: 15 kt) China. 931: 846: 828:reached by yearend 2012. 793: South Korea (11.4%) 744:This section needs to be 647:chemical vapor deposition 485:Feedstock for PV industry 43:This article needs to be 3136:Strasskirchen Solar Park 3027:American Solar Challenge 2873:Solar-powered flashlight 2860:Solar-powered calculator 2855:Solar cell phone charger 2544:Amorphous silicon (a-Si) 2179:www.greenrhinoenergy.com 1026:Qatar Solar Technologies 131:. This process involves 90:multicrystalline silicon 3416:Group IV semiconductors 3042:Frisian Solar Challenge 3012:List of solar car teams 2770:Space-based solar power 2750:Constant voltage method 2679:Solar charge controller 2565:Timeline of solar cells 2560:Growth of photovoltaics 1112:Nanocrystalline silicon 223:monocrystalline silicon 199:monocrystalline silicon 86:Polycrystalline silicon 3032:Formula Sun Grand Prix 2864:Solar-powered fountain 2807:Solar air conditioning 2608:Quantum dot solar cell 2598:Nanocrystal solar cell 2493:Sun-free photovoltaics 2104:www.chemicalonline.com 1742:Basore, P. A. (2006), 1046: 997:Mitsubishi Polysilicon 816: 695: 685:Potential applications 624: 610:Siemens–Martin process 514:chemical decomposition 424: 382:large-area electronics 354: 218: 191:fast-growing PV market 82: 3431:Allotropes of silicon 3022:World Solar Challenge 2845:Photovoltaic keyboard 2775:PV system performance 2648:Perovskite solar cell 2446:Solar cell efficiency 1893:http://www.wacker.com 1447:DOI:10.1063/1.3240343 1084:silicon tetrachloride 1044: 901:Hemlock Semiconductor 814: 799: Germany (21.6%) 692: 621:fluidized bed reactor 618: 414: 386:thin-film transistors 352: 216: 172:semiconductor devices 141:fluidized bed reactor 69: 3292:Individual producers 3000:Solar vehicle racing 2689:Solar micro-inverter 2618:Plasmonic solar cell 2463:Thin-film solar cell 2431:Photoelectric effect 1846:solarindustrymag.com 1445:106, 084506 (2009), 1137:Thin-film solar cell 959:Tokuyama Corporation 623:purification process 311:improve this section 273:Bridgman–Stockbarger 244:Polycrystalline and 118:electronics industry 104:, is a high purity, 3426:Silicon solar cells 2888:Solar traffic light 2868:Solar-powered radio 2835:Solar-powered watch 2643:Printed solar panel 2478:Solar cell research 1715:1980JAP....51..446G 1528:Bernreuter Research 1325:1995TSF...255..159K 1228:BernReuter Research 1186:2021ScTEn.78947969M 1142:Wafer (electronics) 1117:Photovoltaic module 1008:(2008: 4.2 kt) 1000:(2008: 4.3 kt) 944:Other manufacturers 781: China (36.1%) 659:metallurgical-grade 491:Crystalline silicon 479:projection displays 421:Czochralski process 168:integrated circuits 2924:The Quiet Achiever 2883:Solar street light 2830:Solar-powered pump 2603:Organic solar cell 2483:Thermophotovoltaic 2451:Quantum efficiency 2243:www.pvinsights.com 1292:on 25 January 2009 1047: 817: 805: Japan (4.9%) 696: 625: 574:Boltzmann constant 508:Deposition methods 425: 355: 219: 187:metal flake effect 83: 3403: 3402: 3367: 3366: 3262: 3261: 3075: 3074: 2950:Mauro Solar Riser 2945:Electric aircraft 2878:Solar-powered fan 2783: 2782: 2674:Balance of system 2662:System components 2613:Hybrid solar cell 2573: 2572: 2534:Cadmium telluride 2282:www.digitimes.com 1796:www.digitimes.com 1509:978-3-540-79358-8 1482:978-1-4684-8992-7 1380:. April 29, 2006. 1357:on 2 January 2015 1102:Cadmium telluride 1097:Amorphous silicon 1064:predatory pricing 1062:manufacturers of 1022:(2012: 5 kt) 941: 940: 836:Leading producers 787: USA (25.9%) 765: 764: 394:amorphous silicon 347: 346: 339: 239:recrystallisation 203:amorphous silicon 64: 63: 16:(Redirected from 3438: 3391: 3390: 3379: 3378: 3273: 3114:Building-mounted 3092:PV power station 3088: 3017:Solar challenges 3007:Solar car racing 2975:Solar Challenger 2965:Gossamer Penguin 2792: 2586: 2436:Solar irradiance 2416: 2398: 2391: 2384: 2375: 2370: 2349: 2348: 2346: 2344: 2329: 2323: 2322: 2320: 2318: 2299: 2293: 2292: 2290: 2288: 2273: 2267: 2260: 2254: 2253: 2251: 2249: 2235: 2229: 2224: 2218: 2217: 2206: 2200: 2196: 2190: 2189: 2187: 2185: 2171: 2162: 2161: 2159: 2157: 2151: 2140: 2132: 2126: 2121: 2115: 2114: 2112: 2110: 2096: 2090: 2089: 2082: 2080: 2072: 2070: 2068: 2054: 2048: 2047: 2041: 2033: 2031: 2030: 2024: 2018:. Archived from 2017: 2009: 2003: 2002: 2000: 1999: 1990:. Archived from 1984: 1978: 1973: 1967: 1966: 1959: 1957: 1949: 1947: 1945: 1939:www.ldksolar.com 1931: 1925: 1924: 1922: 1920: 1905: 1899: 1890: 1884: 1877: 1871: 1870:. 28. April 2010 1864: 1858: 1857: 1855: 1853: 1848:. 2 October 2012 1838: 1832: 1831: 1829: 1827: 1813: 1807: 1806: 1804: 1802: 1787: 1781: 1780: 1778: 1771: 1763: 1754: 1753: 1748: 1739: 1726: 1725: 1723:10.1063/1.327342 1698: 1685: 1684: 1667: 1661: 1655: 1649: 1643: 1637: 1636: 1634: 1632: 1623: 1615: 1609: 1604: 1598: 1593: 1587: 1581: 1575: 1569: 1563: 1557: 1551: 1545: 1539: 1538: 1536: 1535: 1520: 1514: 1513: 1493: 1487: 1486: 1466: 1455: 1449: 1439: 1433: 1432: 1414: 1408: 1407: 1405: 1403: 1397:www.enfsolar.com 1388: 1382: 1373: 1367: 1366: 1364: 1362: 1353:. Archived from 1343: 1337: 1336: 1313:Thin Solid Films 1308: 1302: 1301: 1299: 1297: 1288:. Archived from 1278: 1272: 1271: 1269: 1267: 1262:on 25 April 2015 1252: 1243: 1242: 1240: 1239: 1230:. Archived from 1220: 1214: 1213: 1179: 1158: 844: 804: 798: 792: 786: 780: 760: 757: 751: 739: 738: 731: 645:It is a type of 636:transition metal 554: 553: 552: 543:(g) → Si(s) + 2 542: 541: 540: 342: 335: 331: 328: 322: 291: 283: 231:grain boundaries 181:, also known as 145:part per billion 59: 56: 50: 38: 37: 30: 21: 3446: 3445: 3441: 3440: 3439: 3437: 3436: 3435: 3406: 3405: 3404: 3399: 3363: 3287: 3258: 3140: 3109: 3082: 3071: 2995: 2984:Water transport 2979: 2933: 2919:Solar golf cart 2892: 2850:Solar road stud 2779: 2733:System concepts 2728: 2657: 2580: 2569: 2548: 2502: 2407: 2402: 2367:Plenty Magazine 2360: 2357: 2352: 2342: 2340: 2337:Washington Post 2331: 2330: 2326: 2316: 2314: 2301: 2300: 2296: 2286: 2284: 2275: 2274: 2270: 2261: 2257: 2247: 2245: 2237: 2236: 2232: 2225: 2221: 2208: 2207: 2203: 2197: 2193: 2183: 2181: 2173: 2172: 2165: 2155: 2153: 2149: 2138: 2134: 2133: 2129: 2122: 2118: 2108: 2106: 2098: 2097: 2093: 2083: 2073: 2066: 2064: 2056: 2055: 2051: 2034: 2028: 2026: 2022: 2015: 2013:"Archived copy" 2011: 2010: 2006: 1997: 1995: 1986: 1985: 1981: 1974: 1970: 1960: 1950: 1943: 1941: 1935:"404 Not Found" 1933: 1932: 1928: 1918: 1916: 1915:. 21 April 2010 1913:presseportal.de 1907: 1906: 1902: 1891: 1887: 1878: 1874: 1865: 1861: 1851: 1849: 1840: 1839: 1835: 1825: 1823: 1821:www.eetasia.com 1815: 1814: 1810: 1800: 1798: 1789: 1788: 1784: 1776: 1769: 1765: 1764: 1757: 1746: 1741: 1740: 1729: 1700: 1699: 1688: 1682: 1669: 1668: 1664: 1656: 1652: 1644: 1640: 1630: 1628: 1621: 1617: 1616: 1612: 1605: 1601: 1594: 1590: 1582: 1578: 1570: 1566: 1558: 1554: 1546: 1542: 1533: 1531: 1522: 1521: 1517: 1510: 1495: 1494: 1490: 1483: 1468: 1467: 1458: 1452: 1440: 1436: 1429: 1416: 1415: 1411: 1401: 1399: 1390: 1389: 1385: 1374: 1370: 1360: 1358: 1351:nyecospaces.com 1345: 1344: 1340: 1310: 1309: 1305: 1295: 1293: 1280: 1279: 1275: 1265: 1263: 1254: 1253: 1246: 1237: 1235: 1222: 1221: 1217: 1160: 1159: 1155: 1151: 1146: 1092: 1080: 1056: 1039: 1013:Daqo New Energy 982:Hankook Silicon 936: 853:GCL-Poly Energy 838: 809: 808: 807: 806: 802: 800: 796: 794: 790: 788: 784: 782: 778: 770: 761: 755: 752: 749: 740: 736: 729: 721:accent lighting 712: 687: 667:Siemens process 655: 633: 613: 602: 600:Siemens process 587: 579: 571: 551: 548: 547: 546: 544: 539: 536: 535: 534: 532: 523: 510: 493: 487: 466:charge carriers 343: 332: 326: 323: 308: 292: 281: 256:microelectronic 246:paracrystalline 235:single crystals 211: 129:Siemens process 106:polycrystalline 60: 54: 51: 48: 39: 35: 28: 23: 22: 18:Siemens process 15: 12: 11: 5: 3444: 3442: 3434: 3433: 3428: 3423: 3418: 3408: 3407: 3401: 3400: 3398: 3397: 3385: 3372: 3369: 3368: 3365: 3364: 3362: 3361: 3356: 3351: 3346: 3341: 3336: 3331: 3329:Solar Frontier 3326: 3321: 3316: 3311: 3306: 3304:Hanwha Q CELLS 3301: 3295: 3293: 3289: 3288: 3286: 3285: 3279: 3277: 3270: 3264: 3263: 3260: 3259: 3257: 3256: 3251: 3249:United Kingdom 3246: 3241: 3236: 3231: 3226: 3221: 3216: 3211: 3206: 3201: 3196: 3191: 3186: 3184:Czech Republic 3181: 3176: 3171: 3166: 3161: 3156: 3150: 3148: 3142: 3141: 3139: 3138: 3133: 3128: 3123: 3117: 3115: 3111: 3110: 3108: 3107: 3102: 3096: 3094: 3085: 3077: 3076: 3073: 3072: 3070: 3069: 3064: 3059: 3054: 3049: 3044: 3039: 3034: 3029: 3024: 3019: 3014: 3009: 3003: 3001: 2997: 2996: 2994: 2993: 2987: 2985: 2981: 2980: 2978: 2977: 2972: 2970:Qinetiq Zephyr 2967: 2962: 2957: 2952: 2947: 2941: 2939: 2935: 2934: 2932: 2931: 2926: 2921: 2916: 2911: 2906: 2900: 2898: 2897:Land transport 2894: 2893: 2891: 2890: 2885: 2880: 2875: 2870: 2865: 2862: 2857: 2852: 2847: 2842: 2837: 2832: 2827: 2824: 2822:Solar backpack 2819: 2814: 2809: 2804: 2798: 2796: 2789: 2785: 2784: 2781: 2780: 2778: 2777: 2772: 2767: 2762: 2757: 2752: 2747: 2742: 2736: 2734: 2730: 2729: 2727: 2726: 2724:Synchronverter 2721: 2716: 2714:Solar shingles 2711: 2706: 2701: 2696: 2691: 2686: 2684:Solar inverter 2681: 2676: 2671: 2665: 2663: 2659: 2658: 2656: 2655: 2650: 2645: 2640: 2635: 2630: 2625: 2620: 2615: 2610: 2605: 2600: 2594: 2592: 2583: 2575: 2574: 2571: 2570: 2568: 2567: 2562: 2556: 2554: 2550: 2549: 2547: 2546: 2541: 2536: 2531: 2526: 2521: 2516: 2510: 2508: 2504: 2503: 2501: 2500: 2495: 2490: 2485: 2480: 2475: 2470: 2465: 2460: 2455: 2454: 2453: 2443: 2441:Solar constant 2438: 2433: 2428: 2422: 2420: 2413: 2409: 2408: 2403: 2401: 2400: 2393: 2386: 2378: 2372: 2371: 2356: 2355:External links 2353: 2351: 2350: 2339:. 9 March 2008 2324: 2294: 2268: 2255: 2230: 2219: 2201: 2191: 2163: 2127: 2116: 2091: 2049: 2004: 1979: 1968: 1926: 1900: 1885: 1872: 1859: 1833: 1808: 1782: 1755: 1727: 1686: 1680: 1662: 1650: 1638: 1610: 1599: 1588: 1576: 1564: 1552: 1540: 1515: 1508: 1488: 1481: 1456: 1450: 1443:J. Appl. Phys. 1434: 1427: 1409: 1383: 1368: 1338: 1303: 1273: 1244: 1215: 1152: 1150: 1147: 1145: 1144: 1139: 1134: 1129: 1124: 1119: 1114: 1109: 1104: 1099: 1093: 1091: 1088: 1079: 1076: 1072:import tariffs 1055: 1052: 1038: 1035: 1034: 1033: 1023: 1017: 1009: 1001: 993: 985: 979: 967: 955: 946: 945: 939: 938: 929: 928: 925: 922: 919: 913: 912: 909: 906: 903: 897: 896: 893: 890: 887: 881: 880: 877: 874: 871: 865: 864: 861: 858: 855: 849: 848: 837: 834: 801: 795: 789: 783: 777: 773: 772: 771: 769: 766: 763: 762: 743: 741: 734: 728: 725: 711: 708: 686: 683: 654: 651: 631: 601: 598: 585: 577: 569: 561: 560: 549: 537: 521: 509: 506: 489:Main article: 486: 483: 470:electric field 345: 344: 295: 293: 286: 280: 277: 210: 207: 92:, also called 62: 61: 42: 40: 33: 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 3443: 3432: 3429: 3427: 3424: 3422: 3419: 3417: 3414: 3413: 3411: 3396: 3395: 3386: 3384: 3383: 3374: 3373: 3370: 3360: 3357: 3355: 3352: 3350: 3347: 3345: 3342: 3340: 3337: 3335: 3332: 3330: 3327: 3325: 3322: 3320: 3317: 3315: 3312: 3310: 3307: 3305: 3302: 3300: 3297: 3296: 3294: 3290: 3284: 3281: 3280: 3278: 3274: 3271: 3269: 3265: 3255: 3252: 3250: 3247: 3245: 3242: 3240: 3237: 3235: 3232: 3230: 3227: 3225: 3222: 3220: 3217: 3215: 3212: 3210: 3207: 3205: 3202: 3200: 3197: 3195: 3192: 3190: 3187: 3185: 3182: 3180: 3177: 3175: 3172: 3170: 3167: 3165: 3162: 3160: 3157: 3155: 3152: 3151: 3149: 3147: 3143: 3137: 3134: 3132: 3129: 3127: 3124: 3122: 3119: 3118: 3116: 3112: 3106: 3103: 3101: 3098: 3097: 3095: 3093: 3089: 3086: 3084: 3078: 3068: 3065: 3063: 3060: 3058: 3055: 3053: 3050: 3048: 3045: 3043: 3040: 3038: 3035: 3033: 3030: 3028: 3025: 3023: 3020: 3018: 3015: 3013: 3010: 3008: 3005: 3004: 3002: 2998: 2992: 2989: 2988: 2986: 2982: 2976: 2973: 2971: 2968: 2966: 2963: 2961: 2958: 2956: 2953: 2951: 2948: 2946: 2943: 2942: 2940: 2938:Air transport 2936: 2930: 2927: 2925: 2922: 2920: 2917: 2915: 2914:Solar roadway 2912: 2910: 2907: 2905: 2904:Solar vehicle 2902: 2901: 2899: 2895: 2889: 2886: 2884: 2881: 2879: 2876: 2874: 2871: 2869: 2866: 2863: 2861: 2858: 2856: 2853: 2851: 2848: 2846: 2843: 2841: 2838: 2836: 2833: 2831: 2828: 2825: 2823: 2820: 2818: 2817:Solar charger 2815: 2813: 2810: 2808: 2805: 2803: 2800: 2799: 2797: 2793: 2790: 2786: 2776: 2773: 2771: 2768: 2766: 2763: 2761: 2758: 2756: 2753: 2751: 2748: 2746: 2743: 2741: 2738: 2737: 2735: 2731: 2725: 2722: 2720: 2717: 2715: 2712: 2710: 2709:Solar tracker 2707: 2705: 2702: 2700: 2697: 2695: 2692: 2690: 2687: 2685: 2682: 2680: 2677: 2675: 2672: 2670: 2667: 2666: 2664: 2660: 2654: 2651: 2649: 2646: 2644: 2641: 2639: 2636: 2634: 2631: 2629: 2626: 2624: 2621: 2619: 2616: 2614: 2611: 2609: 2606: 2604: 2601: 2599: 2596: 2595: 2593: 2591: 2587: 2584: 2582: 2576: 2566: 2563: 2561: 2558: 2557: 2555: 2551: 2545: 2542: 2540: 2537: 2535: 2532: 2530: 2527: 2525: 2522: 2520: 2517: 2515: 2512: 2511: 2509: 2505: 2499: 2496: 2494: 2491: 2489: 2486: 2484: 2481: 2479: 2476: 2474: 2471: 2469: 2466: 2464: 2461: 2459: 2456: 2452: 2449: 2448: 2447: 2444: 2442: 2439: 2437: 2434: 2432: 2429: 2427: 2426:Photovoltaics 2424: 2423: 2421: 2417: 2414: 2410: 2406: 2405:Photovoltaics 2399: 2394: 2392: 2387: 2385: 2380: 2379: 2376: 2368: 2364: 2359: 2358: 2354: 2338: 2334: 2328: 2325: 2313:on 2017-03-14 2312: 2308: 2304: 2298: 2295: 2283: 2279: 2272: 2269: 2266: 2265: 2259: 2256: 2244: 2240: 2234: 2231: 2228: 2223: 2220: 2216:. 2011-07-12. 2215: 2211: 2205: 2202: 2199: 2195: 2192: 2180: 2176: 2170: 2168: 2164: 2148: 2144: 2137: 2136:"Nitol Solar" 2131: 2128: 2125: 2120: 2117: 2105: 2101: 2095: 2092: 2087: 2078: 2063: 2059: 2053: 2050: 2045: 2039: 2025:on 2010-12-15 2021: 2014: 2008: 2005: 1994:on 2011-04-06 1993: 1989: 1983: 1980: 1977: 1972: 1969: 1964: 1955: 1940: 1936: 1930: 1927: 1914: 1910: 1904: 1901: 1897: 1894: 1889: 1886: 1883:, 3. May 2010 1882: 1876: 1873: 1869: 1863: 1860: 1847: 1843: 1837: 1834: 1822: 1818: 1812: 1809: 1797: 1793: 1786: 1783: 1775: 1768: 1762: 1760: 1756: 1752: 1745: 1738: 1736: 1734: 1732: 1728: 1724: 1720: 1716: 1712: 1708: 1704: 1697: 1695: 1693: 1691: 1687: 1683: 1681:0-13-025538-6 1677: 1673: 1666: 1663: 1659: 1654: 1651: 1647: 1642: 1639: 1627: 1620: 1614: 1611: 1608: 1603: 1600: 1597: 1592: 1589: 1585: 1584:Press Release 1580: 1577: 1573: 1568: 1565: 1561: 1556: 1553: 1549: 1544: 1541: 1529: 1525: 1519: 1516: 1511: 1505: 1501: 1500: 1492: 1489: 1484: 1478: 1474: 1473: 1465: 1463: 1461: 1457: 1454: 1451: 1448: 1444: 1438: 1435: 1430: 1424: 1420: 1413: 1410: 1398: 1394: 1387: 1384: 1381: 1379: 1372: 1369: 1356: 1352: 1348: 1342: 1339: 1334: 1330: 1326: 1322: 1318: 1314: 1307: 1304: 1291: 1287: 1286:solarworld.de 1283: 1277: 1274: 1261: 1257: 1251: 1249: 1245: 1234:on 2024-05-29 1233: 1229: 1225: 1219: 1216: 1211: 1207: 1203: 1199: 1195: 1191: 1187: 1183: 1178: 1173: 1169: 1165: 1157: 1154: 1148: 1143: 1140: 1138: 1135: 1133: 1130: 1128: 1125: 1123: 1122:Photovoltaics 1120: 1118: 1115: 1113: 1110: 1108: 1105: 1103: 1100: 1098: 1095: 1094: 1089: 1087: 1085: 1077: 1075: 1073: 1069: 1065: 1061: 1053: 1051: 1043: 1036: 1031: 1027: 1024: 1021: 1018: 1015: 1014: 1010: 1007: 1006: 1002: 999: 998: 994: 991: 990: 986: 983: 980: 977: 976: 972: 968: 965: 961: 960: 956: 953: 952: 948: 947: 943: 942: 934: 930: 923: 920: 918: 915: 914: 907: 904: 902: 899: 898: 891: 888: 886: 883: 882: 875: 872: 870: 869:Wacker Chemie 867: 866: 859: 856: 854: 851: 850: 845: 842: 835: 833: 829: 826: 822: 813: 776: 767: 759: 747: 742: 733: 732: 727:Manufacturers 726: 724: 722: 716: 709: 707: 703: 701: 691: 684: 682: 678: 676: 670: 668: 664: 660: 652: 650: 648: 643: 641: 637: 628: 622: 617: 611: 607: 599: 597: 593: 589: 581: 575: 567: 558: 531: 530: 529: 527: 519: 515: 507: 505: 502: 498: 492: 484: 482: 480: 475: 471: 467: 462: 459: 454: 452: 448: 444: 440: 435: 431: 422: 418: 413: 409: 407: 404: 398: 395: 391: 387: 383: 378: 376: 372: 368: 364: 360: 351: 341: 338: 330: 320: 316: 312: 306: 305: 301: 296:This section 294: 290: 285: 284: 278: 276: 274: 270: 266: 261: 260:semiconductor 257: 253: 252: 247: 242: 240: 236: 232: 228: 227:its structure 224: 215: 208: 206: 204: 200: 196: 192: 188: 184: 180: 175: 173: 169: 165: 161: 157: 153: 148: 146: 142: 138: 137:decomposition 134: 130: 126: 121: 119: 115: 111: 107: 103: 99: 95: 91: 87: 80: 76: 72: 68: 58: 46: 41: 32: 31: 19: 3393: 3380: 3359:Yingli Solar 3339:Sungen Solar 3314:Motech Solar 3268:PV companies 3229:South Africa 3047:Solar Splash 2788:Applications 2719:Solar mirror 2579:Photovoltaic 2523: 2366: 2341:. Retrieved 2336: 2327: 2315:. Retrieved 2311:the original 2306: 2297: 2285:. Retrieved 2281: 2271: 2263: 2258: 2246:. Retrieved 2242: 2239:"PVinsights" 2233: 2222: 2213: 2204: 2194: 2182:. Retrieved 2178: 2154:. Retrieved 2142: 2130: 2119: 2107:. Retrieved 2103: 2094: 2065:. Retrieved 2062:www.memc.com 2061: 2052: 2027:. Retrieved 2020:the original 2007: 1996:. Retrieved 1992:the original 1982: 1971: 1942:. Retrieved 1938: 1929: 1917:. Retrieved 1912: 1903: 1888: 1880: 1875: 1867: 1862: 1850:. Retrieved 1845: 1836: 1824:. Retrieved 1820: 1811: 1799:. Retrieved 1795: 1785: 1750: 1706: 1702: 1671: 1665: 1653: 1641: 1629:. Retrieved 1625: 1613: 1602: 1591: 1579: 1567: 1555: 1543: 1532:. Retrieved 1530:. 2020-06-29 1527: 1518: 1498: 1491: 1471: 1453: 1442: 1437: 1418: 1412: 1400:. Retrieved 1396: 1386: 1377: 1371: 1359:. Retrieved 1355:the original 1350: 1341: 1319:(1–2): 159. 1316: 1312: 1306: 1294:. Retrieved 1290:the original 1285: 1276: 1264:. Retrieved 1260:the original 1236:. 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Index

Siemens process

solar cells
polycrystalline
silicon
photovoltaic
electronics industry
metallurgical grade silicon
Siemens process
distillation
decomposition
fluidized bed reactor
part per billion
ingots
boules
wafers
solar cells
integrated circuits
semiconductor devices
crystals
crystallites
metal flake effect
fast-growing PV market
megawatt
monocrystalline silicon
amorphous silicon

monocrystalline silicon
its structure
grain boundaries

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