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294:. Treatment of the complex with electrophilic alkenes results in elimination of ethylene, giving alkene complexes.
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Göttker-Schnetmann, Inigo; Mecking, Stefan (2020). "A Practical
Synthesis of (tmeda)Ni(CH
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Kaschube, Wilfried; Pörschke, Klaus R.; Wilke, Günther (1988). "Tmeda-Nickel-Komplexe".
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267:). This yellow-brown, air-sensitive compound is popular precursor to diverse
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InChI=1S/C6H16N2.2CH3.Ni/c1-7(2)5-6-8(3)4;;;/h5-6H2,1-4H3;2*1H3;/q;2*-1;
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Except where otherwise noted, data are given for materials in their
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The tmeda ligand is easily displaced by bases such as
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Tetramethylethylenediamine(dimethyl)nickel(II)
326:, and Neutral Chelated-Nickel Methyl Complexes".
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231:Tetramethylethylenediamine(dimethyl)nickel(II)
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122:Key: YAZPWQVRDILILI-UHFFFAOYSA-N
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366:Journal of Organometallic Chemistry
318:, Isotopically Labeled (tmeda)Ni(CH
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215:(at 25 °C , 100 kPa).
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1:
340:10.1021/acs.organomet.0c00500
378:10.1016/0022-328X(88)89050-8
271:. It is prepared from the
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277:nickel(II) acetylacetonate
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397:Organonickel compounds
269:organonickel complexes
235:organonickel complex
205:yellow-brown solid
197: g·mol
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219:Infobox references
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334:(18): 3433–3440.
279:by reaction with
237:with the formula
227:Chemical compound
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72:Interactive image
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372:(1–3): 525–532.
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159:Chemical formula
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328:Organometallics
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281:methyl lithium
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31:Identifiers
202:Appearance
152:Properties
48:122905-76-4
298:References
288:bipyridine
275:adduct of
190:Molar mass
59:3D model (
38:CAS Number
348:224930545
391:Category
97:59048650
233:is the
195:204.971
84:PubChem
346:
260:(Me =
136:SMILES
344:S2CID
273:tmeda
255:)NiMe
111:InChI
61:JSmol
290:and
374:doi
370:355
336:doi
251:NMe
243:NCH
239:(Me
87:CID
393::
368:.
356:^
342:.
332:39
330:.
283:.
262:CH
247:CH
183:Ni
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380:.
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350:.
338::
324:2
322:)
320:3
316:2
314:)
312:3
264:3
257:2
253:2
249:2
245:2
241:2
180:2
177:N
171:H
168:8
165:C
63:)
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