Knowledge (XXG)

Tributyltin azide

Source 📝

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Aureggi, Valentina; Sedelmeier, Gottfried (2007). "1,3-Dipolar Cycloaddition: Click Chemistry for the Synthesis of 5-Substituted Tetrazoles from Organoaluminum Azides and Nitriles".
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Tributyl tin compounds are highly toxic and have penetrating odors. Tributyltin azide causes skin rashes, itching or blisters.
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Saito, S (1989). "Highly nucleophilic tributyltin azide in oxirane ring cleavage leading to 1,2-azido alcohol".
857: 842: 706: 560: 486: 556: 536: 155: 63:-butylazidotin; Tributyltin azide; Azidotributyltin; Azidotributyltin(iv); Azidotributylstannane; Nsc179738 464: 426: 419: 766: 728:. In some applications, tributyltin azide has been replaced by the less toxic trioctyltin azide and 710: 45: 490: 248: 512: 75: 689:. It is a colorless solid although samples can appear as yellow oils. The compound is used as a 670: 540: 504: 694: 137: 813: 774: 391: 315: 544: 219: 85: 32: 729: 548: 528: 252: 159: 770: 568: 625: 817: 831: 377: 148: 580: 199: 714: 508: 516: 791: 611: 587: 23: 564: 346: 128: 482: 721: 474: 778: 690: 367: 186: 168: 478: 624:
Except where otherwise noted, data are given for materials in their
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InChI=1S/3C4H9.N3.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;;/q;;;-1;+1
576: 383: 552: 236: 642: 592:> 110 °C (230 °F; 383 K) 362:Colorless to light yellow liquid or white solid 198: 84: 382:120 °C (248 °F; 393 K) at 0.2 8: 251: 158: 136: 15: 720:It is a reagent used in the synthesis of 218: 705:Tributyltin azide is synthesized by the 749: 297: 272: 247: 792:Tri-higher alkyl tin azide and its use 149: 724:, which in turn are used to generate 279:Key: JKVRTUCVPZTEQZ-UHFFFAOYSA-N 7: 726:angiotensin II receptor antagonists 189: 14: 632: 440: 435: 430: 425: 333: 327: 31: 22: 794:, United States Patent 5484955 628:(at 25 °C , 100 kPa). 848:Reagents for organic chemistry 321: 1: 818:10.1016/S0040-4039(00)99346-8 600:or concentration (LD, LC): 339: 874: 622: 596: 406: 401: 308: 288: 263: 68: 56: 44: 39: 30: 21: 707:salt metathesis reaction 499:Precautionary statements 701:Synthesis and reactions 618:400 mg/kg (oral, rat) 50:Azidotri(butyl)stannane 779:10.1002/ange.200701045 711:tributyltin chloride 46:Preferred IUPAC name 838:Organotin compounds 806:Tetrahedron Letters 771:2007AngCh.119.8592A 673:with the formula (C 392:Solubility in water 354: g·mol 300:CCCC(CCCC)(CCCC)N== 18: 671:organotin compound 655:Infobox references 17:Tributyltin azide 16: 853:Tin(IV) compounds 812:(31): 4153–4156. 759:Angewandte Chemie 695:organic synthesis 667:Tributyltin azide 663:Chemical compound 661: 660: 465:Hazard statements 232:CompTox Dashboard 110:Interactive image 865: 822: 821: 801: 795: 789: 783: 782: 754: 645: 639: 636: 635: 582: 578: 574: 570: 566: 562: 558: 554: 550: 546: 542: 538: 534: 530: 526: 522: 518: 514: 510: 506: 492: 488: 484: 480: 476: 472: 444: 439: 434: 429: 353: 341: 335: 329: 323: 316:Chemical formula 256: 255: 240: 238: 222: 202: 191: 170: 162: 151: 140: 112: 88: 35: 26: 19: 873: 872: 868: 867: 866: 864: 863: 862: 858:Butyl compounds 843:Azido compounds 828: 827: 826: 825: 803: 802: 798: 790: 786: 756: 755: 751: 746: 738: 730:organoaluminium 703: 688: 684: 680: 676: 664: 657: 652: 651: 650:  ?) 641: 637: 633: 629: 615: 609: 501: 467: 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82: 80: 77: 73: 72: 67: 62: 55: 47: 43: 38: 34: 29: 25: 20: 809: 805: 799: 787: 765:(44): 8592. 762: 758: 752: 739: 719: 715:sodium azide 704: 666: 665: 597: 456: 408: 69:Identifiers 60: 57:Other names 612:median dose 598:Lethal dose 588:Flash point 451:Signal word 372:1.212 g/mL 359:Appearance 309:Properties 156:100.133.218 832:Categories 744:References 722:tetrazoles 420:Pictograms 347:Molar mass 220:H29BF5PHC5 129:ChemSpider 97:3D model ( 86:17846-68-3 76:CAS Number 561:P337+P313 557:P332+P313 529:P302+P352 525:P301+P310 411:labelling 177:605-822-9 169:EC Number 732:azides. 402:Hazards 138:21473438 767:Bibcode 691:reagent 648:what is 646: ( 397:Reacts 368:Density 352:332.079 200:4984872 187:PubChem 736:Safety 669:is an 643:verify 640:  457:Danger 293:SMILES 123:TBSnA 40:Names 268:InChI 99:JSmol 713:and 581:P501 577:P405 573:P391 569:P363 565:P362 553:P330 549:P322 545:P321 541:P314 537:P312 521:P280 517:P273 513:P270 509:P264 505:P260 491:H410 487:H372 483:H319 479:H315 475:H312 471:H301 384:mmHg 211:UNII 59:Tri- 814:doi 775:doi 763:119 709:of 693:in 685:SnN 409:GHS 237:EPA 190:CID 834:: 810:30 808:. 773:. 761:. 717:. 697:. 608:50 606:LD 579:, 575:, 571:, 567:, 563:, 559:, 555:, 551:, 547:, 543:, 539:, 535:, 531:, 527:, 523:, 519:, 515:, 511:, 507:, 489:, 485:, 481:, 477:, 473:, 413:: 340:Sn 331:27 325:12 820:. 816:: 781:. 777:: 769:: 687:3 683:3 681:) 679:9 677:H 675:4 638:Y 614:) 610:( 337:3 334:N 328:H 322:C 239:) 235:( 101:) 61:n

Index

Skeletal formula of butyltin trichloride
Ball-and-stick model of the butyltin trichloride molecule
Preferred IUPAC name
CAS Number
17846-68-3
JSmol
Interactive image
ChemSpider
21473438
ECHA InfoCard
100.133.218
Edit this at Wikidata
EC Number
PubChem
4984872
UNII
H29BF5PHC5
CompTox Dashboard
DTXSID00407252
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Boiling point
mmHg
Solubility in water
GHS labelling
Pictograms

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