33:
265:
160:
418:
423:
770:
24:
431:
398:
533:
525:
304:
990:
Pospiech, S.; Bolte, M.; Lerner, H.-W.; Wagner, M. (2014). "Insertion
Reactions into the Boron–Boron Bonds of Barrelene-Type 1,2-Diaminodiboranes(4)".
529:
477:
920:
739:
is 132°. Being a relatively compact phosphine, several can bind to a single transition metal, as illustrated by the existence of Pt(PEt
890:
279:
1028:
865:
Annette Schier and Hubert
Schmidbaur "P-Donor Ligands" in Encyclopedia of Inorganic Chemistry 2006, Wiley-VCH, Weinheim.
513:
580:
1023:
471:
222:
711:
reacts with strong acids to give salts X. This reaction is reversible. Similarly, it is also easily alkylated to give
243:
32:
615:. It is a colorless liquid with an unpleasant odor characteristic of alkylphosphines. The compound is a common
596:
167:
829:
620:
521:
493:
417:
517:
422:
155:
501:
445:
410:
948:
838:
732:
537:
45:
799:
260:
63:
489:
972:
748:
553:
505:
97:
964:
916:
886:
803:
736:
999:
956:
908:
866:
846:
795:
549:
459:
327:
747:. As a phosphine ligand, triethylphosphine gained acceptance earlier than did the simpler
541:
231:
137:
752:
264:
186:
159:
73:
952:
842:
545:
117:
903:
Yoshida, T.; Matsuda, T.; Otsuka, S. (1990). "Tetrakis(Triethylphosphine)Platinum(0)".
574:
463:
1017:
451:
383:
148:
976:
565:
936:
509:
455:
211:
960:
712:
649:
912:
851:
824:
485:
481:
352:
128:
870:
636:
624:
497:
968:
561:
373:
198:
168:
1003:
728:
616:
573:
Except where otherwise noted, data are given for materials in their
769:
768:
108:
96:
86:
557:
23:
825:"Trimethylphosphine and Triethylphosphine in the Solid State"
248:
719:
is easily oxidised to the phosphine oxide with oxygen.
735:
with many metals. As a ligand, triethylphosphine's
388:127–128 °C (261–262 °F; 400–401 K)
210:
72:
659:is usually prepared using Grignard reagents:
8:
885:, 3rd Ed, Pearson/Prentice Hall publisher,
751:, as illustrated by the preparation of the
288:InChI=1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
263:
158:
136:
15:
850:
794:is toxic. It converts to a low toxicity
230:
815:
309:
284:
259:
149:
291:Key: RXJKFRMDXUJTEX-UHFFFAOYSA-N
116:
7:
727:Triethylphosphine is a highly basic
201:
823:Bruckmann, J.; Krüger, C. (1995).
345:
14:
421:
416:
339:
31:
22:
577:(at 25 °C , 100 kPa).
881:G. L. Miessler and D. A. Tarr
631:Structure and simple reactions
333:
1:
939:(1968). "Hydride Complexes".
907:. Vol. 28. p. 122.
611:, commonly abbreviated as PEt
961:10.1126/science.160.3829.723
1045:
913:10.1002/9780470132593.ch32
639:molecule with approximate
852:10.1107/S0108270194014368
597:organophosphorus compound
571:
397:
392:
320:
300:
275:
56:
44:
39:
30:
21:
871:10.1002/0470862106.ia177
621:organometallic chemistry
472:Precautionary statements
1029:Foul-smelling chemicals
782:
733:coordination complexes
723:Coordination chemistry
772:
599:with the formula P(CH
798:upon treatment with
46:Preferred IUPAC name
1024:Tertiary phosphines
953:1968Sci...160..723C
905:Inorganic Syntheses
883:Inorganic Chemistry
843:1995AcCrC..51.1155B
830:Acta Crystallogr. C
800:sodium hypochlorite
773:Structure of Pt(PEt
360: g·mol
18:
783:
749:trimethylphosphine
581:Infobox references
17:Triethylphosphine
16:
1004:10.1021/om501087u
998:(23): 6967–6974.
947:(3829): 723–729.
922:978-0-470-13259-3
804:hydrogen peroxide
737:Tolman cone angle
593:Triethylphosphine
589:Chemical compound
587:
586:
446:Hazard statements
368:colorless liquid
244:CompTox Dashboard
98:Interactive image
50:Triethylphosphane
1036:
1008:
1007:
987:
981:
980:
933:
927:
926:
900:
894:
879:
873:
863:
857:
856:
854:
837:(6): 1155–1158.
820:
715:derivatives. PEt
567:
563:
559:
555:
551:
547:
543:
539:
535:
531:
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465:
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425:
420:
359:
347:
341:
335:
328:Chemical formula
268:
267:
252:
250:
234:
214:
203:
187:Gmelin Reference
170:
162:
151:
140:
120:
100:
76:
35:
26:
19:
1044:
1043:
1039:
1038:
1037:
1035:
1034:
1033:
1014:
1013:
1012:
1011:
992:Organometallics
989:
988:
984:
935:
934:
930:
923:
902:
901:
897:
880:
876:
864:
860:
822:
821:
817:
812:
796:phosphine oxide
793:
788:
780:
776:
765:
761:
753:hydride complex
746:
742:
725:
718:
710:
702:
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686:
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670:
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633:
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590:
583:
578:
474:
448:
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413:
357:
344:
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330:
316:
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308:
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189:
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143:
123:
103:
90:
79:
66:
52:
51:
12:
11:
5:
1042:
1040:
1032:
1031:
1026:
1016:
1015:
1010:
1009:
982:
928:
921:
895:
874:
858:
814:
813:
811:
808:
791:
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778:
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763:
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724:
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688:
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668:
664:
656:
643:
632:
629:
612:
608:
604:
600:
588:
585:
584:
579:
575:standard state
572:
569:
568:
534:P305+P351+P338
526:P303+P361+P353
518:P301+P330+P331
475:
470:
467:
466:
449:
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153:
145:
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133:
131:
125:
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121:
113:
111:
105:
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101:
93:
91:
84:
81:
80:
78:
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69:
67:
62:
59:
58:
54:
53:
49:
48:
42:
41:
37:
36:
28:
27:
13:
10:
9:
6:
4:
3:
2:
1041:
1030:
1027:
1025:
1022:
1021:
1019:
1005:
1001:
997:
993:
986:
983:
978:
974:
970:
966:
962:
958:
954:
950:
946:
942:
938:
932:
929:
924:
918:
914:
910:
906:
899:
896:
892:
891:0-13-035471-6
888:
884:
878:
875:
872:
868:
862:
859:
853:
848:
844:
840:
836:
832:
831:
826:
819:
816:
809:
807:
805:
801:
797:
785:
771:
767:
757:
754:
750:
738:
734:
730:
722:
720:
714:
662:
661:
660:
653:
651:
647:
642:
638:
630:
628:
626:
623:, such as in
622:
618:
598:
594:
582:
576:
570:
476:
473:
469:
468:
450:
447:
443:
442:
439:
436:
433:
429:
428:
424:
419:
415:
412:
408:
407:
403:
401:
396:
391:
387:
385:
384:Boiling point
382:
381:
377:
375:
372:
371:
367:
364:
363:
356:
354:
351:
350:
332:
329:
325:
324:
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310:
306:
299:
285:
281:
274:
266:
262:
261:DTXSID3060293
258:
257:
255:
245:
241:
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233:
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213:
209:
208:
206:
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196:
195:
191:
188:
184:
183:
176:
175:
173:
171:
166:
165:
161:
157:
154:
152:
150:ECHA InfoCard
147:
146:
139:
135:
134:
132:
130:
127:
126:
119:
115:
114:
112:
110:
107:
106:
99:
95:
94:
92:
88:
83:
82:
75:
71:
70:
68:
65:
61:
60:
55:
47:
43:
38:
34:
29:
25:
20:
995:
991:
985:
944:
940:
937:Joseph Chatt
931:
904:
898:
882:
877:
861:
834:
828:
818:
789:
755:
726:
706:
671:MgCl + P(OC
654:
645:
640:
634:
592:
591:
437:
399:
57:Identifiers
731:that forms
713:phosphonium
432:Signal word
378:0.802 g/cm
365:Appearance
321:Properties
156:100.008.245
118:CHEBI:39971
1018:Categories
810:References
758:-PtHCl(PEt
411:Pictograms
353:Molar mass
232:5W435D16PM
129:ChemSpider
85:3D model (
64:CAS Number
637:pyramidal
625:auranofin
554:P403+P235
550:P370+P378
530:P304+P340
522:P302+P334
402:labelling
312:CCP(CC)CC
177:209-068-8
169:EC Number
977:22350909
969:17784306
650:symmetry
635:It is a
393:Hazards
74:554-70-1
949:Bibcode
941:Science
839:Bibcode
683:→ P(CH
595:is the
374:Density
358:118.160
199:PubChem
975:
967:
919:
889:
786:Safety
729:ligand
695:+ 3 C
617:ligand
438:Danger
305:SMILES
40:Names
973:S2CID
756:trans
703:OMgCl
280:InChI
212:27365
192:2485
138:25463
109:ChEBI
87:JSmol
965:PMID
917:ISBN
887:ISBN
663:3 CH
566:P501
562:P422
558:P405
546:P363
542:P321
538:P310
514:P280
510:P264
506:P260
502:P243
498:P242
494:P241
490:P240
486:P233
482:P222
478:P210
464:H314
460:H250
456:H225
452:H224
223:UNII
1000:doi
957:doi
945:160
909:doi
867:doi
847:doi
802:or
790:PEt
707:PEt
655:PEt
619:in
400:GHS
249:EPA
202:CID
1020::
996:33
994:.
971:.
963:.
955:.
943:.
915:.
845:.
835:51
833:.
827:.
806:.
766:.
687:CH
667:CH
652:.
627:.
603:CH
564:,
560:,
556:,
552:,
548:,
544:,
540:,
536:,
532:,
528:,
524:,
520:,
516:,
512:,
508:,
504:,
500:,
496:,
492:,
488:,
484:,
480:,
462:,
458:,
454:,
404::
343:15
1006:.
1002::
979:.
959::
951::
925:.
911::
893:.
869::
855:.
849::
841::
792:3
781:.
779:4
777:)
775:3
764:2
762:)
760:3
745:4
743:)
741:3
717:3
709:3
701:5
699:H
697:6
693:3
691:)
689:3
685:2
681:3
679:)
677:5
675:H
673:6
669:2
665:3
657:3
646:v
644:3
641:C
613:3
609:3
607:)
605:3
601:2
346:P
340:H
337:6
334:C
251:)
247:(
89:)
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