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24:
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D.G. Golovanov, K.A. Lyssenko, M.Yu. Antipin, Ya.S. Vygodskii, E.I. Lozinskaya, A.S. Shaplov. ”Long-awaited polymorphic modification of triphenyl phosphite“, Cryst. Eng. Comm., 2005, v. 7, no. 77, P.465 – 468.
824:
Gerlach, D. H.; Peet, W. G.; Muetterties, E. L. (1972). "Stereochemically
Nonrigid Six-Coordinate Molecules. II. Preparations and Reactions of Tetrakis(organophosphorus)metal Dihydride Complexes".
702:
in organic compounds, namely it exists in two different amorphous forms at temperatures about 200 K. One polymorphic modification of triphenyl phosphite was obtained by means of crystallization in
442:
264:
808:
748:
229:
399:
97:
851:
Ha, Alice; Cohen, Itai; Zhao, Xiaolin; Lee, Michelle; Kivelson, Daniel (1996). "Supercooled
Liquids and Polyamorphism†".
172:
193:
449:
902:
635:
465:
381:
32:
135:
897:
627:
493:
791:
Ittel, Steven D. (1977). "Olefin, Acetylene, Phosphine, Isocyanide, and
Diazene Complexes of Nickel(0)".
667:
45:
732:
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210:
63:
538:
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860:
833:
796:
773:
736:
469:
359:
287:
238:
InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
181:
248:
InChI=1/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
117:
73:
214:
139:
671:
634:(M = Ni, Pd, Pt). The nickel complex can be prepared by displacement of the diene from
420:
891:
699:
590:
541:, it serves as a source of P that is less electrophilic than phosphorus trichloride:
348:
338:
128:
703:
161:
800:
740:
370:
310:
108:
777:
764:
H. N. Rydon (1971). "Alkyl
Iodides: Neopentyl Iodide and Iodocyclohexane".
837:
723:
Leutkens, M. L. Jr.; Sattelberger, A. P.; Murray, H. H.; Basil, J. D.;
679:
328:
148:
879:
864:
678:. It also forms a variety of Fe(0) and Fe(II) complexes such as the di
675:
623:
497:
419:
Except where otherwise noted, data are given for materials in their
23:
96:
86:
198:
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343:
22 to 24 °C (72 to 75 °F; 295 to 297 K)
160:
500:in the presence of a catalytic amount of base:
72:
630:. It forms zero-valent complexes of the type M
8:
698:Triphenylphosphite is a notable example of
213:
138:
116:
15:
180:
826:Journal of the American Chemical Society
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269:
234:
209:
353:360 °C (680 °F; 633 K)
129:
589:Triphenylphosphite is quaternized by
537:Triphenylphosphite is a precursor to
484:. It is a colourless viscous liquid.
241:Key: HVLLSGMXQDNUAL-UHFFFAOYSA-N
7:
795:. Vol. XVII. pp. 117–124.
492:Triphenylphosphite is prepared from
251:Key: HVLLSGMXQDNUAL-UHFFFAOYAF
151:
735:. Vol. 28. pp. 305–310.
14:
853:The Journal of Physical Chemistry
427:
272:O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3
31:
22:
622:Triphenylphosphite is a common
423:(at 25 °C , 100 kPa).
727:(1990). "Trimethylphosphine".
400:Occupational safety and health
1:
919:
801:10.1002/9780470132487.ch34
741:10.1002/9780470132593.ch76
315:310.28 g/mol
636:bis(cyclooctadiene)nickel
466:organophosphorus compound
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397:
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260:
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56:
44:
39:
30:
21:
778:10.15227/orgsyn.051.0044
382:Magnetic susceptibility
666:Related complexes are
628:coordination chemistry
618:Coordination complexes
494:phosphorus trichloride
880:doi: 10.1039/b505052a
668:homogeneous catalysts
46:Preferred IUPAC name
17:Triphenyl phosphite
838:10.1021/ja00768a022
793:Inorganic Syntheses
733:Inorganic Syntheses
729:Inorganic Syntheses
462:Triphenyl phosphite
360:Solubility in water
50:Triphenyl phosphite
18:
725:Fackler, J. P. Jr.
539:trimethylphosphine
450:Infobox references
323:colourless liquid
16:
865:10.1021/jp9530820
810:978-0-470-13248-7
766:Organic Syntheses
750:978-0-470-13259-3
458:Chemical compound
456:
455:
388:-183.7·10 cm/mol
375:organic solvents
194:CompTox Dashboard
98:Interactive image
910:
903:Organophosphites
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288:Chemical formula
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704:ionic liquids
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700:polyamorphism
694:Polyamorphism
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591:methyl iodide
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130:ECHA InfoCard
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832:(13): 4545.
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697:
665:
621:
588:
565:MgBr → P(CH
536:
491:
461:
460:
409:Main hazards
398:
57:Identifiers
488:Preparation
403:(OHS/OSH):
333:1.184 g/mL
320:Appearance
281:Properties
136:100.002.645
892:Categories
710:References
413:flammable
371:Solubility
311:Molar mass
182:9P45GRD24X
109:ChemSpider
85:3D model (
64:CAS Number
533:Reactions
468:with the
670:for the
646:+ 4 P(OC
393:Hazards
384:(χ)
305:P
74:101-02-0
859:: 1–4.
680:hydride
676:alkenes
662:+ 2 COD
642:Ni(COD)
577:"MgBrOC
557:P + 3
528:+ 3 HCl
516:→ P(OC
508:+ 3 HOC
470:formula
464:is the
443:what is
441: (
329:Density
149:PubChem
807:
772:: 44.
747:
624:ligand
609:P + CH
575:
559:
498:phenol
438:verify
435:
265:SMILES
40:Names
613:I → I
230:InChI
87:JSmol
805:ISBN
745:ISBN
658:→ Ni
496:and
472:P(OC
365:low
173:UNII
162:7540
118:7259
861:doi
857:100
834:doi
797:doi
774:doi
737:doi
674:of
626:in
573:+ 3
504:PCl
199:EPA
152:CID
894::
855:.
830:94
828:.
803:.
770:51
768:.
743:.
731:.
706:.
690:.
686:Fe
638::
605:O)
597:(C
593::
561:CH
553:O)
545:(C
299:15
295:18
867:.
863::
840:.
836::
813:.
799::
780:.
776::
753:.
739::
688:4
684:2
682:H
660:4
656:3
654:)
652:5
650:H
648:6
644:2
632:4
611:3
607:3
603:5
601:H
599:6
585:"
583:5
581:H
579:6
571:3
569:)
567:3
563:3
555:3
551:5
549:H
547:6
526:3
524:)
522:5
520:H
518:6
514:5
512:H
510:6
506:3
482:3
480:)
478:5
476:H
474:6
433:N
303:3
301:O
297:H
293:C
201:)
197:(
89:)
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