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Johan A. Martens, Wim H. Verrelst, Georges M. Mathys, Stephen H. Brown, Pierre A. Jacobs "Tailored
Catalytic Propene Trimerization over Acidic Zeolites with Tubular Pores" Angewandte Chemie International Edition Angewandte Chemie International Edition 2005, Volume 44, Issue 35, pages 5687–5690.
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In this process, two double bonds are lost and one is retained as illustrated by the isomer shown in the figure. The reaction is catalyzed by acids, such as
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G. R. Lappin, L. H. Nemec, J. D. Sauer, J. D. Wagner "Olefins, Higher" in Kirk-Othmer
Encyclopedia of Chemical Technology, 2010.
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https://www.exxonmobilchemical.com/dfsmedia/f743208d804841f6ab89a60202cc3f56/3035-source?extension=pdf/options/download
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CH), which attacks another propylene unit, generating a new carbocation, etc. This kind of process affords mixtures (C
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420:. A variety of catalysts have been explored. The reaction proceeds via the formation of a carbocation ((CH
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4,6-Dimethyl-1-heptene:: InChI=1S/C9H18/c1-5-6-9(4)7-8(2)3/h5,8-9H,1,6-7H2,2-4H3
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Except where otherwise noted, data are given for materials in their
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ExxonMobil
Chemical Product Safety Summary], exxonmobilchemical.com
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459:are produced by alkylation of aromatic substrates.
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285:−93.5 °C (−136.3 °F; 179.7 K)
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518:10.1002/0471238961.1512050612011616.a01.pub2
218:4,6-Dimethyl-1-heptene:: CC(C)CC(C)CC=C
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295:156 °C (313 °F; 429 K)
197:Key: FSWNZCWHTXTQBY-UHFFFAOYSA-N
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322:23 °C (73 °F; 296 K)
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377:, is usually sold as a mixture of
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447:, propylene trimer is used as an
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385:. This mixture is obtained by
332:(at 25 °C , 100 kPa).
125:4,6-Dimethyl-1-heptene::
99:4,6-Dimethyl-1-heptene::
78:4,6-Dimethyl-1-heptene::
53:4,6-Dimethyl-1-heptene::
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257:126.24 g/mol
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535:10.1002/anie.200463045
471:- the linear analogue
558:Trimers (chemistry)
418:polyphosphoric acid
302:Solubility in water
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379:structural isomers
359:Infobox references
265:colourless liquid
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501:Tripropylene MSDS
367:Chemical compound
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150:CompTox Dashboard
81:Interactive image
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449:alkylating agent
375:propylene trimer
373:, also known as
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234:Chemical formula
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371:Tripropylene
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31:Identifiers
453:surfactants
443:Like other
318:Flash point
275:1.022 g/mL
262:Appearance
227:Properties
547:Categories
476:References
457:lubricants
253:Molar mass
92:ChemSpider
67:3D model (
48:13987-01-4
38:CAS Number
307:very low
139:UN number
56:7379-69-3
469:1-Nonene
463:See also
312:Hazards
128:13437467
102:10618997
553:Alkenes
445:alkenes
391:propene
352:what is
350: (
271:Density
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114:PubChem
383:nonene
347:verify
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211:SMILES
405:→ C
186:InChI
143:2057
69:JSmol
455:and
531:doi
514:doi
397:3 C
389:of
381:of
155:EPA
117:CID
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434:6
432:H
430:3
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422:3
409:H
407:9
403:6
401:H
399:3
342:Y
243:H
241:9
239:C
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153:(
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Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
