1142:
1737:
858:
807:
853:
683:
504:
1157:
1543:
1152:
790:
1538:
884:
1957:
509:
1732:
1162:
1861:
448:
499:
696:
104:
1015:
109:
453:
725:
443:
2038:
1962:
1851:
165:
1580:
678:
738:
377:
160:
2028:
2164:
1147:
1942:
1856:
215:
1005:
170:
2033:
1727:
1322:
751:
384:
1952:
1846:
1327:
1947:
1010:
1332:
55:
Greenwood & Earnshaw, p. 207: instructive to compare B-N compounds with their C-C counterparts, since they are isoelectronic and have similar sizes and electronegativities (ish)
396:
1141:
1736:
906:
RB≡NR′ (R, R′ = long alkyl chains) polymerise at 25 °C to colourless waxy materials - they may be polymers, but are poorly characterised
465:
857:
432:, is in reversible equilibrium between monomer and dimer in the gas phase, and can cyclotrimerise to cyclotriborazane in the solid state.
987:
852:
682:
806:
503:
1156:
1542:
1151:
1478:
Crystal structure shows Si non-planar, but slightly pyramidal, due to appreciable π-σ* mixing, which is not seen in alkenes:
1537:
883:
1956:
508:
1731:
1161:
789:
1860:
1311:
447:
498:
695:
25:
1014:
1982:
1662:
871:
tBu-B≡N-tBu reacts with at 25 °C to form the complex , in which the iminoborane bonds to niobium side-on:
724:
452:
442:
39:"Chemistry of the Main Group Elements, Part 2: Rings, Chains and Macromolecules, Based on Main Group Elements"
21:
2037:
1961:
1295:
643:
103:
1850:
1831:
1346:
108:
1827:
1631:
164:
1080:
1074:
1050:
1799:
1704:
1579:
677:
2027:
1043:
737:
376:
159:
1875:
1823:
1374:
1291:
922:
591:
2163:
1883:
1146:
994:
and not thermodynamically stable with respect to HCl or water addition - Housecroft 3rd edn. p. 355)
2058:
1819:
1815:
1528:
774:
471:
1941:
1303:
1998:
1351:
1206:
1855:
1030:
214:
1569:
1096:
2054:
2032:
1682:
1651:
1004:
169:
17:
1715:, formally a trimer of the hypothetical molecule phosphonitrile dichloride (1832-07-1), N≡PCl
464:
Dehydrocoupling amine-borane adducts to cyclic aminoboranes and borazines at 25 °C with
1726:
43:
1321:
1227:) - many structures, either discrete anions or anionic chains and rings - contain planar BO
184:
The bonding in B-N compounds can be confusing. Amine-borane adducts can be represented as R
1951:
1920:
1916:
1903:
1845:
1811:
1751:
1307:
1270:
750:
383:
1993:
196:, the charges are meant to be relative to the charges in the separate neutral fragments R
91:
1946:
1326:
897:
Iminoboranes can undergo addition across their BN groups — e.g. RB≡NR′ + HCl → RClB=NHR′
1976:
1896:
1835:
1299:
1220:
1009:
825:
147:
572:
1912:
1765:
1694:
1360:
647:
79:
1892:
1426:
1407:
1243:
1239:
1517:
2010:
1607:
1595:
1417:(review, including π-σ* mixing MO diagram accounting for pyramidalization of Si)
1364:
1176:
1641:
G&E p. 536: Produced industrially by R. Schenk and G. Römer's 1924 method:
1369:
1356:
1331:
1066:
763:
562:
532:
1558:
1401:, thermally stable yellow or orange crystalline solids if R groups are bulky
622:
611:
193:
1490:
1186:- reluctant to crystallise, consists of 3D network with trigonal planar BO
762:
Tert-butyl(tert-butylimino)borane, tBu-B≡N-tBu, B-N distance 1.26 Å,
1554:
1479:
1386:
1287:
1283:
1251:
932:
83:
1589:
1120:
1108:
1058:
971:
655:
536:
521:
87:
483:
1398:
1278:
1216:
976:
but significant ΔEN means electron density more localised on nitrogen
714:
366:
130:
125:
69:
230:
N has a large δ−, which is reduced to a small δ− upon formation of R
1224:
1210:
251:
has a large δ+, which decreases to a small δ+ upon formation of R
238:. The negative charge on N decreases, but is still negative.
424:
ring compounds are known. For example, aminoborane itself, H
259:. The positive charge on B decreases, but is still positive.
1926:
S-O polymers pretty useless because they all hydrolyse to H
1610:: compounds with PN multiple bonds (at least formally)
399:), aminoboranes tend to cyclise and readily hydrolyse
267:
Calculated partial charges (Spartan, MP2, 6–311+G**)
990:
characteristic of benzene (although benzene is only
416:
rings due to steric hindrance, but some 6-membered B
1508:
Recent calculated structures of disilene itself, Si
1461:(cyclotrisilane) → (UV radiation, −60 °C) (R
1238:Many molecular B-O species, e.g. hydrolysis of
8:
408:Aminoboranes usually cyclise to 4-membered B
42:If you like this sort of thing, you'll like
1590:the first carbon substituted disilyne: 2008
982:tends to undergo addition (e.g. of HCl or H
520:Other catalysts include colloidal rhodium (
395:Without bulky substituents (i.e. without
967:— formally a trimer of iminoborane, HBNH
265:
2132:forms adducts with Lewis acids, e.g. S
1425:First disilene, tetramesityldisilene:
7:
979:only weak delocalisation/aromaticity
988:electrophilic aromatic substitution
986:O across BN bonds) rather than the
32:
2162:
2036:
2031:
2026:
1960:
1955:
1950:
1945:
1940:
1859:
1854:
1849:
1844:
1735:
1730:
1725:
1578:
1541:
1536:
1330:
1325:
1320:
1160:
1155:
1150:
1145:
1140:
1013:
1008:
1003:
882:
856:
851:
805:
788:
749:
736:
723:
694:
681:
676:
507:
502:
497:
451:
446:
441:
382:
375:
213:
168:
163:
158:
107:
102:
1427:R. West, M. J. Fink, J. Michl,
1029:Phosphine-borane adducts, e.g.
204:, but this is still misleading.
1:
1909:(monomer, trimer and polymer)
1776:(n = 3, 4) → (250 °C) → (NPCl
1602:Phosphorus–nitrogen chemistry
139:nice, stable compounds e.g. H
1359:, sigma delocalisation c.f.
1806:Phosphorus–oxygen chemistry
1341:Catenated silicon chemistry
1312:ring-opening polymerization
2183:
1024:Boron–phosphorus chemistry
824:BN) cyclodimerises to the
2114:, 25 °C, slow → (SN)
2096:, heat over Ag wool → 2 S
1971:Sulfur–nitrogen chemistry
1784:(n = lots) → (Nu) → (NPNu
1697:solvent, 120–150 °C)
970:has six π electrons like
339:
325:
311:
297:
289:
283:
273:
1265:Silicon–oxygen chemistry
50:Boron–nitrogen chemistry
1870:Sulfur–oxygen chemistry
1832:sodium tripolyphosphate
1397:, silicon analogues of
1347:Organosilicon chemistry
1260:linear B-O polymers yet
1042:Phosphinoboranes, e.g.
78:Two main polymorphs of
1828:tripolyphosphoric acid
1171:Boron–oxygen chemistry
1098:Angew. Chem., Int. Ed.
773:(Shelf 20 in library,
1800:Living polymerization
1705:Hexachlorophosphazene
1409:Adv. Organomet. Chem.
1296:Rochow-Müller process
820:tBu-B≡N-tBu (i.e. tBu
624:Angew. Chem. Int. Ed.
613:Angew. Chem. Int. Ed.
610:at 25 °C :
397:kinetic stabilisation
86:-like) and cubic BN (
1878:: Cyclooctasulfur, S
1824:phosphorus pentoxide
1764:+ Cl → (120-150 °C,
1081:Polyphosphinoboranes
644:Brookhart's catalyst
118:Amine-borane adducts
2059:disulfur dichloride
1820:phosphorus trioxide
1816:pyrophosphoric acid
1615:Cyclic phosphazenes
1231:triangles and/or BO
1051:Boraphosphabenzenes
931:parent compound is
590:Dehydrogenation to
574:J. Organomet. Chem.
268:
1352:Hexamethyldisilane
1310:, thermal anionic
1207:borosilicate glass
354:
266:
247:Similarly, B in BR
2055:ammonium chloride
2047:Synthesis of (SN)
1519:Chem. Phys. Lett.
1418:
1110:J. Am. Chem. Soc.
580:, 2849–2853
538:J. Am. Chem. Soc.
523:J. Am. Chem. Soc.
353:
352:
264:
92:explore with Jmol
68:, c.f. elemental
56:
18:User:Benjah-bmm27
2174:
2166:
2040:
2035:
2030:
1964:
1959:
1954:
1949:
1944:
1876:Catenated sulfur
1863:
1858:
1853:
1848:
1768:solvent) → (NPCl
1752:polyphosphazenes
1746:Polyphosphazenes
1739:
1734:
1729:
1582:
1545:
1540:
1406:
1375:Polycarbosilanes
1334:
1329:
1324:
1164:
1159:
1154:
1149:
1144:
1017:
1012:
1007:
947:or equivalently
886:
860:
855:
809:
792:
753:
740:
727:
698:
685:
680:
592:polyaminoboranes
559:Polyaminoboranes
553:Polyaminoboranes
511:
506:
501:
455:
450:
445:
386:
379:
269:
217:
172:
167:
162:
111:
106:
82:, hexagonal BN (
54:
35:Main group 2, IM
2182:
2181:
2177:
2176:
2175:
2173:
2172:
2171:
2155:
2151:
2147:
2143:
2139:
2135:
2131:
2127:
2119:
2113:
2109:
2103:
2099:
2095:
2091:
2085:
2081:
2077:
2073:
2069:
2052:
2016:
2006:
2002:
1990:
1986:
1977:Sulfur nitrides
1973:
1933:
1929:
1921:disulfuric acid
1917:sulfur oxoacids
1907:
1900:
1889:
1881:
1872:
1836:polynucleotides
1812:Phosphoric acid
1808:
1791:
1787:
1783:
1779:
1775:
1771:
1763:
1748:
1718:
1714:
1710:
1677:
1671:
1666:
1655:
1629:
1623:
1617:
1604:
1551:
1515:
1511:
1492:Heteroat. Chem.
1481:Organometallics
1468:
1464:
1460:
1456:
1452:
1448:
1396:
1392:
1383:
1343:
1308:silicone rubber
1271:Silicon dioxide
1267:
1259:
1249:
1234:
1230:
1221:borate minerals
1204:
1200:
1196:
1189:
1184:
1180:
1173:
1093:Manners et al:
1090:
1086:
1083:, e.g. (PHPh-BH
1072:
1064:
1046:
1038:
1034:
1026:
985:
966:
958:
954:
946:
942:
938:
915:
839:
835:
831:
823:
707:
657:Organometallics
653:
609:
605:
601:
597:
555:
479:
475:
468:
431:
427:
423:
419:
415:
411:
359:
293:
287:
281:
277:
258:
254:
250:
237:
233:
229:
203:
199:
191:
187:
178:
146:
142:
120:
62:
52:
37:
30:
29:
28:
12:
11:
5:
2180:
2178:
2170:
2169:
2168:
2167:
2157:
2156:
2153:
2149:
2145:
2141:
2137:
2133:
2129:
2125:
2121:
2120:
2115:
2111:
2107:
2104:
2101:
2097:
2093:
2089:
2086:
2083:
2079:
2075:
2071:
2067:
2063:
2062:
2048:
2044:
2043:
2042:
2041:
2021:
2020:
2019:
2018:
2012:
2008:
2004:
2000:
1996:
1988:
1984:
1972:
1969:
1968:
1967:
1966:
1965:
1935:
1934:
1931:
1927:
1924:
1910:
1905:
1898:
1890:
1887:
1884:plastic sulfur
1879:
1871:
1868:
1867:
1866:
1865:
1864:
1839:
1838:
1807:
1804:
1803:
1802:
1796:
1795:
1794:
1793:
1789:
1785:
1781:
1777:
1773:
1769:
1761:
1755:
1754:
1747:
1744:
1743:
1742:
1741:
1740:
1720:
1719:
1716:
1712:
1708:
1701:
1700:
1699:
1698:
1688:
1687:
1686:
1685:
1673:
1669:
1664:
1653:
1643:
1642:
1639:
1625:
1621:
1616:
1613:
1612:
1611:
1603:
1600:
1599:
1598:
1586:
1585:
1584:
1583:
1573:
1572:
1570:view with Jmol
1550:
1547:
1534:
1533:
1532:
1531:
1529:Jmol structure
1513:
1509:
1503:
1502:
1501:
1500:
1473:
1472:
1471:
1470:
1466:
1462:
1458:
1454:
1450:
1446:
1440:
1439:
1438:
1437:
1420:
1419:
1403:
1402:
1394:
1390:
1382:
1379:
1378:
1377:
1372:
1367:
1354:
1349:
1342:
1339:
1338:
1337:
1336:
1335:
1315:
1314:
1300:Direct process
1281:
1266:
1263:
1262:
1261:
1257:
1254:
1247:
1236:
1232:
1228:
1214:
1202:
1198:
1194:
1191:
1187:
1182:
1178:
1172:
1169:
1168:
1167:
1166:
1165:
1135:
1134:
1133:
1132:
1131:
1130:
1122:Macromolecules
1118:
1106:
1088:
1084:
1078:
1075:view with Jmol
1070:
1062:
1048:
1044:
1040:
1036:
1032:
1025:
1022:
1021:
1020:
1019:
1018:
998:
997:
996:
995:
983:
980:
977:
974:
968:
964:
956:
952:
944:
940:
936:
926:
925:
914:
911:
910:
909:
908:
907:
901:
900:
899:
898:
892:
891:
890:
889:
888:
887:
875:
874:
873:
872:
866:
865:
864:
863:
862:
861:
844:
843:
842:
841:
837:
833:
829:
826:cyclobutadiene
821:
815:
814:
813:
812:
811:
810:
798:
797:
796:
795:
794:
793:
781:
780:
779:
778:
757:
756:
755:
754:
744:
743:
742:
741:
731:
730:
729:
728:
718:
717:
706:
703:
702:
701:
700:
699:
689:
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687:
686:
671:
670:
669:
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666:
651:
635:
634:
633:
632:
607:
603:
599:
595:
585:
584:
583:
582:
566:
565:
554:
551:
550:
549:
548:
547:
515:
514:
513:
512:
492:
491:
490:
489:
487:(2001) 962-963
477:
473:
466:
459:
458:
457:
456:
436:
435:
434:
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429:
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421:
417:
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409:
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401:
400:
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370:
369:
358:
355:
351:
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344:
341:
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336:
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327:
323:
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302:
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241:
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218:
208:
207:
206:
205:
201:
197:
189:
185:
176:
175:
174:
173:
153:
152:
151:
150:
148:ammonia borane
144:
140:
134:
133:
119:
116:
115:
114:
113:
112:
97:
96:
95:
94:
73:
72:
61:
58:
51:
48:
36:
33:
31:
15:
14:
13:
10:
9:
6:
4:
3:
2:
2179:
2165:
2161:
2160:
2159:
2158:
2123:
2122:
2118:
2105:
2087:
2065:
2064:
2060:
2056:
2051:
2046:
2045:
2039:
2034:
2029:
2025:
2024:
2023:
2022:
2017:
2015:
2009:
2007:
1997:
1995:
1991:
1981:
1980:
1978:
1975:
1974:
1970:
1963:
1958:
1953:
1948:
1943:
1939:
1938:
1937:
1936:
1925:
1922:
1918:
1914:
1913:Sulfuric acid
1911:
1908:
1901:
1894:
1893:Sulfur oxides
1891:
1885:
1877:
1874:
1873:
1869:
1862:
1857:
1852:
1847:
1843:
1842:
1841:
1840:
1837:
1833:
1829:
1825:
1821:
1817:
1813:
1810:
1809:
1805:
1801:
1798:
1797:
1767:
1759:
1758:
1757:
1756:
1753:
1750:
1749:
1745:
1738:
1733:
1728:
1724:
1723:
1722:
1721:
1706:
1703:
1702:
1696:
1692:
1691:
1690:
1689:
1684:
1681:
1676:
1667:
1661:
1657:
1650:
1647:
1646:
1645:
1644:
1640:
1637:
1633:
1628:
1619:
1618:
1614:
1609:
1606:
1605:
1601:
1597:
1594:
1593:
1592:
1591:
1581:
1577:
1576:
1575:
1574:
1571:
1567:
1565:
1561:
1556:
1553:
1552:
1548:
1546:
1544:
1539:
1530:
1526:
1524:
1520:
1507:
1506:
1505:
1504:
1499:
1497:
1493:
1488:
1486:
1482:
1477:
1476:
1475:
1474:
1444:
1443:
1442:
1441:
1436:
1434:
1430:
1424:
1423:
1422:
1421:
1416:
1414:
1410:
1405:
1404:
1400:
1388:
1385:
1384:
1380:
1376:
1373:
1371:
1368:
1366:
1362:
1361:polyacetylene
1358:
1355:
1353:
1350:
1348:
1345:
1344:
1340:
1333:
1328:
1323:
1319:
1318:
1317:
1316:
1313:
1309:
1305:
1301:
1297:
1293:
1289:
1288:polysiloxanes
1285:
1282:
1280:
1276:
1272:
1269:
1268:
1264:
1255:
1253:
1245:
1244:boronic acids
1241:
1240:chlorosilanes
1237:
1226:
1222:
1218:
1215:
1212:
1208:
1192:
1185:
1175:
1174:
1170:
1163:
1158:
1153:
1148:
1143:
1139:
1138:
1137:
1136:
1129:
1127:
1123:
1119:
1117:
1115:
1111:
1107:
1105:
1103:
1099:
1095:
1094:
1092:
1091:
1082:
1079:
1076:
1068:
1060:
1056:
1052:
1049:
1047:
1041:
1039:
1028:
1027:
1023:
1016:
1011:
1006:
1002:
1001:
1000:
999:
993:
989:
981:
978:
975:
973:
969:
962:
950:
934:
930:
929:
928:
927:
924:
920:
917:
916:
912:
905:
904:
903:
902:
896:
895:
894:
893:
885:
881:
880:
879:
878:
877:
876:
870:
869:
868:
867:
859:
854:
850:
849:
848:
847:
846:
845:
827:
819:
818:
817:
816:
808:
804:
803:
802:
801:
800:
799:
791:
787:
786:
785:
784:
783:
782:
776:
772:
770:
766:
761:
760:
759:
758:
752:
748:
747:
746:
745:
739:
735:
734:
733:
732:
726:
722:
721:
720:
719:
716:
712:
709:
708:
704:
697:
693:
692:
691:
690:
684:
679:
675:
674:
673:
672:
664:
662:
658:
649:
648:pincer ligand
645:
641:
640:
639:
638:
637:
636:
631:
629:
625:
620:
618:
614:
593:
589:
588:
587:
586:
581:
579:
575:
571:Nice review:
570:
569:
568:
567:
564:
560:
557:
556:
552:
545:
543:
539:
534:
530:
528:
524:
519:
518:
517:
516:
510:
505:
500:
496:
495:
494:
493:
488:
486:
485:Chem. Commun.
481:
469:
463:
462:
461:
460:
454:
449:
444:
440:
439:
438:
437:
407:
406:
405:
404:
398:
394:
393:
392:
391:
385:
381:
378:
374:
373:
372:
371:
368:
364:
361:
360:
356:
348:
345:
342:
338:
334:
331:
328:
324:
320:
317:
314:
310:
306:
303:
300:
296:
271:
270:
246:
245:
244:
243:
225:
224:
223:
222:
216:
212:
211:
210:
209:
195:
183:
182:
181:
180:
179:
171:
166:
161:
157:
156:
155:
154:
149:
138:
137:
136:
135:
132:
128:
127:
124:Amine-borane
122:
121:
117:
110:
105:
101:
100:
99:
98:
93:
89:
85:
81:
80:boron nitride
77:
76:
75:
74:
71:
67:
66:Boron nitride
64:
63:
60:Boron nitride
59:
57:
49:
47:
45:
40:
34:
27:
23:
19:
2116:
2082:+ 16 HCl + S
2049:
2013:
1679:
1674:
1659:
1648:
1635:
1626:
1608:Phosphazenes
1596:Silabenzenes
1587:
1563:
1559:
1535:
1522:
1518:
1495:
1491:
1484:
1480:
1432:
1428:
1412:
1408:
1304:silicone gum
1274:
1125:
1121:
1113:
1109:
1101:
1097:
1054:
991:
960:
948:
918:
828:analogue tBu
768:
764:
711:Iminoboranes
710:
705:Iminoboranes
660:
656:
627:
623:
616:
612:
577:
573:
558:
541:
537:
526:
522:
484:
363:Aminoboranes
362:
357:Aminoboranes
177:
123:
65:
53:
44:this article
41:
38:
1792:(n > 10)
1566:, 1755-1757
1435:, 1343-1344
1370:Polysilynes
1365:lithography
1357:Polysilanes
1242:leading to
1116:, 6669–6678
1104:, 3321-3323
992:kinetically
771:, 1089-1102
663:, 1766-1776
630:, 9600-9602
619:, 6212-6215
602:→ (-NHMe-BH
594:, e.g. MeNH
563:polyolefins
544:, 9582–9583
533:titanocenes
529:, 9776–9785
482:catalysts:
2066:4 Cl + 6 S
1915:and other
1638:= 3, 4, 5)
1469:(disilene)
1235:tetrahedra
765:Chem. Ber.
192:. In this
1555:Disilynes
1549:Disilynes
1487:, 793–800
1453:+ Li → (R
1387:Disilenes
1381:Disilenes
1284:Siloxanes
1256:No high-M
1252:boroxines
1128:, 291–297
919:Borazines
913:Borazines
654:complex:
194:formalism
90:-like) -
1588:Update:
1415:, 73-148
933:borazine
200:N and BR
84:graphite
24: |
20: |
1707:, (NPCl
1668:→ (NPCl
1562:(2004)
1560:Science
1525:, 11-15
1521:(2008)
1494:(1990)
1483:(1984)
1431:(1981)
1429:Science
1411:(2006)
1399:alkenes
1290:, e.g.
1217:Borates
1124:(2003)
1112:(2000)
1100:(1999)
1053:, e.g.
972:benzene
963:-(HBNH)
921:, c.f.
767:(1984)
715:alkynes
713:, c.f.
659:(2004)
642:(using
626:(2008)
615:(2008)
576:(2007)
561:, c.f.
540:(2006)
525:(2004)
367:alkenes
365:, c.f.
349:−0.113
343:−0.122
335:+0.338
329:−0.058
318:−0.998
315:−0.412
304:+0.335
301:+0.279
131:alkanes
129:, c.f.
126:adducts
88:diamond
1393:Si=SiR
1279:quartz
1250:, and
1246:RB(OH)
1223:(e.g.
923:arenes
531:) and
226:N in R
70:carbon
22:degree
2053:from
1620:(NPCl
1498:, 1-7
1225:borax
1211:Pyrex
1201:+ SiO
1190:units
1055:cyclo
1035:P→BCl
961:cyclo
951:-(BH)
949:cyclo
16:<
2140:+ BF
2057:and
2011:(SN)
1994:Jmol
1882:and
1766:PhCl
1695:PhCl
1632:Jmol
1449:SiCl
1292:PDMS
1286:and
1219:and
955:(NH)
775:Jmol
650:-IrH
646:, a
472:RhCl
470:and
278:N–BH
255:N→BR
234:N→BR
188:N-BR
143:N→BH
2152:·BF
2144:→ S
2074:→ S
1886:, S
1760:PCl
1683:HCl
1678:+ 4
1663:PCl
1564:305
1523:466
1465:Si)
1457:Si)
1433:214
1389:: R
1302:),
1114:122
1059:Mes
1057:-(B
959:or
935:, B
769:117
598:·BH
578:692
542:128
527:126
476:.3H
428:NBH
340:BH
298:NH
2070:Cl
1992::
1979::
1930:SO
1919::
1904:SO
1902:,
1897:SO
1895::
1834:,
1830:,
1826:,
1822:,
1818:,
1814:,
1658:+
1656:Cl
1652:NH
1630::
1568:,
1557::
1527:,
1516::
1489:,
1413:54
1363:,
1306:,
1294:,
1273:–
1205:→
1126:36
1102:38
1067:Cy
1065:(P
1031:Ph
661:23
628:47
621:,
617:47
606:-)
346:—
332:—
326:B
321:—
312:N
307:—
290:BH
284:NH
46:.
2154:3
2150:4
2148:N
2146:4
2142:3
2138:4
2136:N
2134:4
2130:4
2128:N
2126:4
2124:S
2117:x
2112:2
2110:N
2108:2
2106:S
2102:2
2100:N
2098:2
2094:4
2092:N
2090:4
2088:S
2084:8
2080:4
2078:N
2076:4
2072:2
2068:2
2061::
2050:x
2014:x
2005:2
2003:N
2001:2
1999:S
1989:4
1987:N
1985:4
1983:S
1932:4
1928:2
1923:\
1906:3
1899:2
1888:n
1880:8
1790:n
1788:)
1786:2
1782:n
1780:)
1778:2
1774:n
1772:)
1770:2
1762:5
1717:2
1713:3
1711:)
1709:2
1693:(
1680:n
1675:n
1672:)
1670:2
1665:5
1660:n
1654:4
1649:n
1636:n
1634:(
1627:n
1624:)
1622:2
1514:4
1512:H
1510:2
1496:1
1485:3
1467:2
1463:2
1459:3
1455:2
1451:2
1447:2
1445:R
1395:2
1391:2
1298:(
1277:-
1275:α
1258:w
1248:2
1233:4
1229:3
1213:)
1209:(
1203:2
1199:3
1197:O
1195:2
1193:B
1188:3
1183:3
1181:O
1179:2
1177:B
1089:n
1087:)
1085:2
1077:)
1073:(
1071:3
1069:)
1063:3
1061:)
1045:4
1037:3
1033:3
984:2
965:3
957:3
953:3
945:6
943:H
941:3
939:N
937:3
840::
838:2
836:N
834:2
832:B
830:4
822:2
777:)
665:)
652:2
608:n
604:2
600:3
596:2
546:)
535:(
480:O
478:2
474:3
467:2
430:2
426:2
422:3
420:N
418:3
414:2
412:N
410:2
292:3
286:3
280:3
276:3
274:H
257:3
253:3
249:3
236:3
232:3
228:3
202:3
198:3
190:3
186:3
145:3
141:3
26:2
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