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Vanadium(IV) oxide

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2474: 2377: 262: 177: 463: 1115: 554: 982: 776: 42: 688: 964:. The thermal conductivity that could be attributed to electron movement was 10% of the amount predicted by the Wiedemann–Franz law. The reason for this appears to be the fluidic way that the electrons move through the material, reducing the typical random electron motion. Thermal conductivity ~ 0.2 W/m⋅K, electrical conductivity ~ 8.0 ×10^5 S/m. 847:. In the monoclinic phase, the V ions form pairs along the c axis, leading to alternate short and long V-V distances of 2.65 Å and 3.12 Å. In comparison, in the rutile phase the V ions are separated by a fixed distance of 2.96 Å. As a result, the number of V ions in the crystallographic unit cell doubles from the rutile to the monoclinic phase. 559: 862:
particles is acicular, laterally confined by (110) surfaces, which are the most stable termination planes. The surface tends to be oxidized with respect to the stoichiometric composition, with the oxygen adsorbed on the (110) surface forming vanadyl species. The presence of V ions at the surface of
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A thin film of vanadium oxide on a highly reflecting substrate (for specific infrared wavelengths) such as sapphire is either absorbing or reflecting, dependent on temperature. Its emissivity varies considerably with temperature. When the vanadium oxide transitions with increased temperature, the
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structure with shorter distances between pairs of V atoms indicating metal-metal bonding. Above 68 Â°C (341 K), the structure changes to an undistorted rutile structure and the metal-metal bonds are broken causing an increase in electrical conductivity and magnetic susceptibility as the
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surfaces without additional energy input. Temperature-based switching can be essential to mitigate potential "overcooling" effects of radiative cooling devices in urban environments, especially those with hot summers and cool winters, making it possible for radiative coolers to also function as
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transmission and reduce the loss of building interior heat through windows. Varying the amount of tungsten allows regulating the phase transition temperature at a rate of 20 Â°C (20 K) per 1 atomic percent of tungsten. The coating has a slight yellow-green color. The performance of
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has a phase transition very close to room temperature (~68 Â°C (341 K)). Electrical resistivity, opacity, etc, can change up several orders. Owing to these properties, it has been used in surface coating, sensors, and imaging. Potential applications include use in memory devices,
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expresses temperature-dependent reflective properties. When heated from room temperature to 80 Â°C (353 K), the material's thermal radiation rises normally until 74 Â°C (347 K), before suddenly appearing to drop to around 20 Â°C (293 K). At room temperature,
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Tang, Kechao; Dong, Kaichen; Li, Jiachen; Gordon, Madeleine P.; Reichertz, Finnegan G.; Kim, Hyungjin; Rho, Yoonsoo; Wang, Qingjun; Lin, Chang-Yu; Grigoropoulos, Costas P.; Javey, Ali; Urban, Jeffrey J.; Yao, Jie; Levinson, Ronnen; Wu, Junqiao (17 December 2021).
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Other potential applications of its thermal properties include passive camouflage, thermal beacons, communication, or to deliberately speed up or slow down cooling. These applications could be useful for a variety of structures from homes to satellites.
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In 2022, a to date unique and unknown feature of the material was reported – it can "remember" previous external stimuli (via structural rather than electronic states), with potential for e.g. data storage and processing, potentially including in
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Varying the substrate materials (e.g., to indium tin oxide), as well as modifying the vanadium oxide coating using doping, straining, or other processes, alters the wavelengths and temperature ranges at which the thermal effects are observed.
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Kats, M. A.; Blanchard, R.; Zhang, S.; Genevet, P.; Ko, C.; Ramanathan, S.; Capasso, F. (2013). "Vanadium Dioxide as a Natural Disordered Metamaterial: Perfect Thermal Emission and Large Broadband Negative Differential Thermal Emittance".
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Xie, Rongguo; Bui, Cong Tinh; Varghese, Binni; Zhang, Qingxin; Sow, Chorng Haur; Li, Baowen; Thong, John T. L. (2011-05-10). "An Electrically Tuned Solid-State Thermal Memory Based on Metal–Insulator Transition of Single-Crystalline
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Shin, S.; Suga, S.; Taniguchi, M.; Fujisawa, M.; Kanzaki, H.; Fujimori, A.; Daimon, H.; Ueda, Y.; Kosuge, K. (1990). "Vacuum-ultraviolet reflectance and photoemission study of the metal-insulator phase transitions in
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Manning, Troy D.; Parkin, Ivan P.; Pemble, Martyn E.; Sheel, David; Vernardou, Dimitra (2004). "Intelligent Window Coatings: Atmospheric Pressure Chemical Vapor Deposition of Tungsten-Doped Vanadium Dioxide".
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Samizadeh Nikoo, Mohammad; Soleimanzadeh, Reza; Krammer, Anna; Migliato Marega, Guilherme; Park, Yunkyu; Son, Junwoo; Schueler, Andreas; Kis, Andras; Moll, Philip J. W.; Matioli, Elison (22 August 2022).
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Potential applications include converting waste heat from engines and appliances into electricity, and windows or window coverings that keep buildings cool. Thermal conductivity varied when VO
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structure. Vanadium atoms are purple and oxygen atoms are pink. The V–V dimers are highlighted by violet lines in (a). The distances between adjacent vanadium atoms are equal in (b).
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Wang, Shancheng; Jiang, Tengyao; Meng, Yun; Yang, Ronggui; Tan, Gang; Long, Yi (17 December 2021). "Scalable thermochromic smart windows with passive radiative cooling regulation".
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is almost transparent to infrared light. As its temperature rises it gradually changes to reflective. At intermediate temperatures it behaves as a highly absorbing dielectric.
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Hu, Bin; Ding, Yong; Chen, Wen; Kulkarni, Dhaval; Shen, Yue; Tsukruk, Vladimir V.; Wang, Zhong Lin (2010-12-01). "External-Strain Induced Insulating Phase Transition in VO
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Crunteanu, Aurelian; Givernaud, Julien; Leroy, Jonathan; Mardivirin, David; Champeaux, Corinne; Orlianges, Jean-Christophe; Catherinot, Alain; Blondy, Pierre (2010).
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between the transparent semiconductive and reflective conductive phase, occurring at 68 Â°C (341 K), can happen in times as short as 100 femtoseconds.
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Nanoscale structures that appear naturally in the materials' transition region can suppress thermal radiation as the temperature rises. Doping the coating with
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can be manipulated at the nanoscale using a biased conducting atomic force microscope tip, suggesting applications in computing and information storage.
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Driscoll, T.; Palit, S.; Qazilbash, M. M.; et al. (2008). "Dynamic tuning of an infrared hybrid-metamaterial resonance using vanadium dioxide".
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Lee, Sangwook; Hippalgaonkar, Kedar; Yang, Fan; Hong, Jiawang; Ko, Changhyun; Suh, Joonki; Liu, Kai; Wang, Kevin; Urban, Jeffrey J. (2017-01-27).
582: 2978: 2964: 2429:"Vanadium Dioxide as a Natural Disordered Metamaterial: Perfect Thermal Emission and Large Broadband Negative Differential Thermal Emittance" 1354: 1205:
energy-saving smart windows can be enhanced by combining VO2 with antireflection layers. The technology of low-temperature preparation of V
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bonding electrons are "released". The origin of this insulator to metal transition remains controversial and is of interest both for
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Rezek, Jiƙí; Szelwicka, Jolanta; Vlček, Jaroslav; ČerstvĂœ, RadomĂ­r; HouĆĄka, Jiƙí; Fahland, Matthias; Fahlteich, John (July 2022).
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was mixed with other materials. At a low temperature it could act as an insulator, while conducting heat at a higher temperature.
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applications, such as smart windows and roofs, that cool or warm depending on temperature, aerospace communication systems and
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composite films with enhanced infrared light regulation performance, solar modulation capability, and superhydrophobicity"
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Gurvitch, M.; Luryi, S.; Polyakov, A.; Shabalov, A. (2009-11-15). "Nonhysteretic behavior inside the hysteresis loop of VO
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and practical applications, such as electrical switches, tunable electrical filters, power limiters, nano-oscillators,
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transition in its electronic structure: the rutile phase is metallic while the monoclinic phase is semiconducting. The
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nanorods that combine thermochromic and photocatalytic properties for application as energy-saving smart coatings"
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structure undergoes a sudden decrease in emissivity – looking colder to infrared cameras than it really is.
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Vanadium dioxide is essential to achieving temperature-based 'switchable' cooling and heating effects for
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Undoped and tungsten-doped vanadium dioxide films can act as "spectrally-selective" coatings to block
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Morin, F. J. (1959). "Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature".
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Goodenough, John B. (1971-11-01). "The two components of the crystallographic transition in VO
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Jeehoon Kim; Ko, Changhyun; Frenzel, Alex; Ramanathan, Shriram; Hoffman, Jennifer E. (2010).
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Mellan, Thomas A.; Grau-Crespo, Ricardo (2012). "Density functional theory study of rutile VO
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Pattanayak, Milinda; Hoque, Md Nadim F.; Fan, Zhaoyang; Bernussi, Ayrton A. (2018).
1914: 1723:"Temperature-adaptive radiative coating for all-season household thermal regulation" 1643: 1601: 5853: 5516: 5502: 5386: 4945: 4303: 4297: 4253: 4036: 3989: 3963: 3715: 2785: 2427:
Kats, Mikhail A.; Blanchard, Romain; Zhang, Shuyan; et al. (21 October 2013).
2330:"Electrical oscillation generation with current-induced resistivity switching in VO 1561: 1408:
Li, Yamei; Ji, Shidong; Gao, Yanfeng; Luo, Hongjie; Kanehira, Minoru (2013-04-02).
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Wang, Chao; Zhao, Li; Liang, Zihui; Dong, Binghai; Wan, Li; Wang, Shimin (2017).
1340: 6252: 5219: 4690: 4588: 961: 817: 744: 594: 17: 2890: 2873: 2657:"Intelligent Window Coatings that Allow Light In but Keep Heat Out - News Item" 2003: 1635: 981: 533: 6247: 6117: 5929: 5836: 5600: 4962: 4928: 4741: 4673: 4410: 4277: 3419: 2549: 2465: 2428: 2160:"Anomalously low electronic thermal conductivity in metallic vanadium dioxide" 1698: 1093: 900:
At the rutile to monoclinic transition temperature (67 Â°C (340 K)),
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Chen, Meijie; Pang, Dan; Chen, Xingyu; Yan, Hongjie; Yang, Yuan (2022).
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film. Mild heating results in significant absorption of infrared light.
357: 215: 185: 28: 2937: 2728: 2413: 2368: 2141:"Physicists Have Found a Metal That Conducts Electricity but Not Heat" 1942: 1898: 1754: 1553: 1441: 491: 6159: 5985: 5586: 5446: 5348: 5303: 5261: 5247: 5233: 4911: 4809: 4707: 4639: 4605: 4347: 4337: 4307: 4247: 4197: 4140: 4130: 4100: 4040: 3993: 3967: 3889: 3850: 3824: 3732: 3698: 3613: 3562: 2992: 2255:
New studies explain insulator-to-metal transition of vanadium dioxide
833: 410: 405: 2705:"Design and reactive magnetron sputtering of thermochromic coatings" 2217:"Scientists discover material that conducts electricity but no heat" 678:
Except where otherwise noted, data are given for materials in their
1837:"A revolutionary material for aerospace and neuromorphic computing" 1619: 6187: 6041: 4554: 3545: 3510: 2532: 2447: 1881: 1657: 1113: 980: 957: 774: 656: 125: 113: 103: 575: 5390: 4826: 4775: 4414: 4207: 4187: 3664: 3647: 2269:"Voltage- and current-activated metal–insulator transition in VO 1217:-based multilayers has been scaled up to industrial dimensions. 940:
that holds that the ratio of the electronic contribution of the
3483: 2996: 1957:"Researchers discover a material that can learn like the brain" 5656: 4374: 634: 611: 2907:"Nanoscale imaging and control of resistance switching in VO 1236:
systems, cameras, data storage, and other applications. The
245: 747:, and in alkali to give the brown ion, or at high pH . VO 2273:-based electrical switches: A lifetime operation analysis" 3479: 1477:
Nanobeam and Its Application as Flexible Strain Sensor".
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in the low-temperature monoclinic phase is about 0.7 eV.
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lowers the effect's thermal range to room temperature.
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Wang, Zhaochen; Kim, Sun-Kyung; Hu, Run (March 2022).
2679:"Intelligent Window Coating Reflects Heat, Not Light" 743:, dissolving in non-oxidising acids to give the blue 6215: 6134: 6055: 5904: 5740: 5166: 4424: 4019: 3800: 3517: 3438: 3339: 3316: 3287: 3227: 3198: 3110: 3049: 3030: 1532:and its possible application in infrared imaging". 1985: 227: 2497:"Natural metamaterial looks cooler when heated" 556: 89: 2245:, 2nd Ed. Academic Press. NY. Vol. 1. p. 1267. 3495: 3008: 8: 2592:Science and Technology of Advanced Materials 2338:Science and Technology of Advanced Materials 2277:Science and Technology of Advanced Materials 2644:Vanadium dioxide as infrared active coating 2243:Handbook of Preparative Inorganic Chemistry 1368: 1366: 1331: 1329: 1224:Vanadium dioxide can act as extremely fast 3502: 3488: 3480: 3435: 3284: 3195: 3015: 3001: 2993: 2491: 2489: 2487: 2485: 2483: 1264:The insulator-metal phase transition in VO 413:(>70 Â°C (343 K), tetragonal) 260: 175: 153: 33: 2889: 2848: 2818:"Timing nature's fastest optical shutter" 2793: 2736: 2619: 2531: 2464: 2446: 2367: 2357: 2304: 1880: 1697: 1679: 1677: 1449: 408:(<70 Â°C (343 K), monoclinic) 1962:Ecole Polytechnique Federale de Lausanne 1618:Zhou, You; Ramanathan, S. (2015-08-01). 1256:passive heating devices when necessary. 1289: 306: 281: 256: 1620:"Mott Memory and Neuromorphic Devices" 166: 2966:CRC Handbook of Chemistry and Physics 2573: 2571: 2569: 2567: 2134: 2132: 1613: 1611: 850:The equilibrium morphology of rutile 288:Key: GRUMUEUJTSXQOI-UHFFFAOYSA-N 133: 7: 2580:"New intelligent multifunctional SiO 2874:"Self-switchable radiative cooling" 1684:Miller, Brittney J. (8 June 2022). 218: 991:Following the method described by 25: 2677:Espinasse, Phillip (2009-11-03). 1260:Phase change computing and memory 1253:passive daytime radiative cooling 2963:Haynes, William M., ed. (2011). 2472: 2375: 2039:Journal of Solid State Chemistry 1835:Barraud, Emmanuel (2018-02-05). 985:Nanostars of vanadium(IV) oxide. 877:X-ray photoelectron spectroscopy 686: 461: 40: 2774:Surface and Coatings Technology 2139:MacDonald, Fiona (2017-01-28). 1869:The Journal of Chemical Physics 1686:"How smart windows save energy" 682:(at 25 Â°C , 100 kPa). 2786:10.1016/j.surfcoat.2022.128273 2499:. physicsworld.com. 2013-10-25 824:/c) crystal structure. Above T 425:Occupational safety and health 344:82.94 g/mol 1: 3199:Organovanadium(III) compounds 2681:. oe magazine. Archived from 2612:10.1080/14686996.2017.1360752 2359:10.1080/14686996.2018.1521249 2297:10.1088/1468-6996/11/6/065002 1582:Advanced Functional Materials 1196:Infrared radiation management 374:1,967 Â°C (2,240 K) 364:4.653 g/cm (tetragonal) 3288:Organovanadium(IV) compounds 2059:10.1016/0022-4596(71)90091-0 875:films has been confirmed by 362:4.571 g/cm (monoclinic) 2703:Houska, Jiri (2022-03-21). 1662:Phase-Change Switch Project 1118:Transmittance spectra of a 800:= 340 K (67 Â°C), 735:. It is a dark blue solid. 6309: 3712:Praseodymium(III,IV) oxide 2891:10.1016/j.matt.2022.01.018 2820:. Physorg.com. 2005-04-07. 2709:Journal of Applied Physics 2257:, PhysOrg. April 11, 2015. 2004:10.1038/s41928-022-00812-z 1636:10.1109/JPROC.2015.2431914 1534:Journal of Applied Physics 26: 6261: 2550:10.1103/PhysRevX.3.041004 2466:10.1103/PhysRevX.3.041004 1699:10.1146/knowable-060822-3 1342:Chemistry of the Elements 1339:; Earnshaw, Alan (1984). 1247:Passive radiative cooling 912:also exhibits a metal to 754:passive radiative cooling 676: 603: 442: 422: 417: 391: 317: 297: 272: 73: 63: 53: 48: 39: 2115:10.1103/physrevb.41.4993 1540:(10): 104504–104504–15. 1395:10.1103/PhysRevLett.3.34 1320:pubchem.ncbi.nlm.nih.gov 1098:field-effect transistors 1090:condensed matter physics 504:Precautionary statements 27:Not to be confused with 6293:Transition metal oxides 4942:Praseodymium(III) oxide 3678:Manganese(II,III) oxide 2918:Applied Physics Letters 2393:Applied Physics Letters 2187:10.1126/science.aag0410 1806:10.1126/science.abg0291 1747:10.1126/science.abf7136 1624:Proceedings of the IEEE 1375:Physical Review Letters 975:Synthesis and structure 960:is proportional to the 950:electrical conductivity 796:At temperatures below T 752:phase-change switches, 381:Magnetic susceptibility 6288:Vanadium(IV) compounds 5513:Protactinium(IV) oxide 5499:Praseodymium(IV) oxide 4687:Einsteinium(III) oxide 4585:Californium(III) oxide 4003:Water (hydrogen oxide) 3518:Mixed oxidation states 2659:. Azom.com. 2004-08-12 2334:micro-channel devices" 2241:Brauer, G. ed. (1963) 1931:Chemistry of Materials 1594:10.1002/adfm.201002436 1499:10.1002/adma.201002868 1278:Vanadium redox battery 1143: 1079:At room temperature VO 986: 890:neuromorphic computing 791: 758:neuromorphic computing 563: 6263:Oxides are sorted by 6114:Technetium(VII) oxide 5850:Protactinium(V) oxide 4959:Promethium(III) oxide 4738:Gadolinium(III) oxide 4670:Dysprosium(III) oxide 4294:Protactinium monoxide 3746:Terbium(III,IV) oxide 3317:Vanadyl(IV) compounds 1117: 984: 778: 562: 6063:Dichlorine heptoxide 5833:Phosphorus pentoxide 5799:Dinitrogen pentoxide 5597:Technetium(IV) oxide 5314:Dinitrogen tetroxide 5129:Ytterbium(III) oxide 4891:Neodymium(III) oxide 4874:Manganese(III) oxide 4517:Berkelium(III) oxide 4466:Americium(III) oxide 3627:Dichlorine pentoxide 3610:Cobalt(II,III) oxide 3576:Chlorine perchlorate 3439:Vanadyl(V) compounds 2911:at room temperature" 1349:. pp. 1144–45. 1337:Greenwood, Norman N. 1108:Infrared reflectance 942:thermal conductivity 626:Vanadium ditelluride 545:(fire diamond) 68:Divanadium tetroxide 6170:Ruthenium tetroxide 6080:Manganese heptoxide 5926:Molybdenum trioxide 5541:Ruthenium(IV) oxide 5471:Plutonium(IV) oxide 5415:Neptunium(IV) oxide 5216:Californium dioxide 5188:Berkelium(IV) oxide 5112:Vanadium(III) oxide 5095:Tungsten(III) oxide 5078:Titanium(III) oxide 5044:Thallium(III) oxide 4993:Samarium(III) oxide 4925:Phosphorus trioxide 4857:Lutetium(III) oxide 4721:Europium(III) oxide 4653:Dinitrogen trioxide 4619:Chromium(III) oxide 4568:Caesium sesquioxide 4432:Actinium(III) oxide 4274:Phosphorus monoxide 4264:Palladium(II) oxide 4224:Manganese(II) oxide 4027:Aluminium(II) oxide 3860:Dichlorine monoxide 3780:Triuranium octoxide 3763:Tribromine octoxide 3729:Silver(I,III) oxide 3593:Chloryl perchlorate 2930:2010ApPhL..96u3106K 2721:2022JAP...131k0901H 2604:2017STAdM..18..563W 2542:2013PhRvX...3d1004K 2457:2013PhRvX...3d1004K 2406:2008ApPhL..93b4101D 2350:2018STAdM..19..693P 2289:2010STAdM..11f5002C 2179:2017Sci...355..371L 2107:1990PhRvB..41.4993S 2051:1971JSSCh...3..490G 1891:2012JChPh.137o4706M 1798:2021Sci...374.1501W 1792:(6574): 1501–1504. 1739:2021Sci...374.1504T 1733:(6574): 1504–1509. 1546:2009JAP...106j4504G 1491:2010AdM....22.5134H 1434:2013NatSR...3E1370L 1387:1959PhRvL...3...34M 1013:vanadium(III) oxide 938:Wiedemann–Franz law 828:, the structure is 731:with the formula VO 667:Vanadium(III) oxide 622:Vanadium diselenide 36: 35:Vanadium(IV) oxide 6135:+8 oxidation state 6097:Rhenium(VII) oxide 6056:+7 oxidation state 5996:Tellurium trioxide 5905:+6 oxidation state 5867:Tantalum pentoxide 5748:Antimony pentoxide 5741:+5 oxidation state 5709:Vanadium(IV) oxide 5681:Tungsten(IV) oxide 5286:Chromium(IV) oxide 5167:+4 oxidation state 5146:Yttrium(III) oxide 5061:Thulium(III) oxide 5027:Terbium(III) oxide 4976:Rhodium(III) oxide 4789:Holmium(III) oxide 4755:Gallium(III) oxide 4534:Bismuth(III) oxide 4425:+3 oxidation state 4391:Vanadium(II) oxide 4381:Titanium(II) oxide 4174:Germanium monoxide 4164:Europium(II) oxide 4147:Dinitrogen dioxide 4117:Chromium(II) oxide 4047:Berkelium monoxide 4020:+2 oxidation state 3808:Aluminium(I) oxide 3801:+1 oxidation state 3695:Mellitic anhydride 3644:Iron(II,III) oxide 3525:Antimony tetroxide 3024:Vanadium compounds 2850:10.1002/eom2.12153 2221:The Indian Express 1992:Nature Electronics 1479:Advanced Materials 1422:Scientific Reports 1316:"Vanadium dioxide" 1226:optical modulators 1144: 1009:comproportionation 987: 792: 729:inorganic compound 721:Vanadium(IV) oxide 709:Infobox references 663:Vanadium(II) oxide 645:Tantalum(IV) oxide 618:Vanadium disulfide 604:Related compounds 564: 352:Blue-black powder 58:Vanadium(IV) oxide 34: 6275: 6274: 6198:Hassium tetroxide 6142:Iridium tetroxide 6010:Tungsten trioxide 5968:Selenium trioxide 5940:Polonium trioxide 5912:Chromium trioxide 5884:Vanadium(V) oxide 5816:Niobium pentoxide 5782:Bismuth pentoxide 5765:Arsenic pentoxide 5723:Zirconium dioxide 5625:Terbium(IV) oxide 5611:Tellurium dioxide 5527:Rhodium(IV) oxide 5401:Manganese dioxide 5373:Hafnium(IV) oxide 5331:Germanium dioxide 5174:Americium dioxide 4908:Nickel(III) oxide 4806:Indium(III) oxide 4704:Erbium(III) oxide 4636:Cobalt(III) oxide 4602:Cerium(III) oxide 4483:Antimony trioxide 4401:Yttrium(II) oxide 4284:Polonium monoxide 4234:Mercury(II) oxide 4107:Chlorine monoxide 3977:Thallium(I) oxide 3847:Dicarbon monoxide 3661:Lead(II,IV) oxide 3477: 3476: 3473: 3472: 3335: 3334: 3223: 3222: 2980:978-1-4398-5511-9 2969:(92nd ed.). 2938:10.1063/1.3435466 2729:10.1063/5.0084792 2520:Physical Review X 2434:Physical Review X 2414:10.1063/1.2956675 2223:. 29 January 2017 2173:(6323): 371–374. 2095:Physical Review B 1943:10.1021/cm034905y 1899:10.1063/1.4758319 1690:Knowable Magazine 1554:10.1063/1.3243286 1485:(45): 5134–5139. 1442:10.1038/srep01370 1356:978-0-08-022057-4 1017:vanadium(V) oxide 717:Chemical compound 715: 714: 671:Vanadium(V) oxide 641:Niobium(IV) oxide 486:Hazard statements 399:Crystal structure 241:CompTox Dashboard 115:Interactive image 16:(Redirected from 6300: 6156:Osmium tetroxide 6024:Uranium trioxide 5954:Rhenium trioxide 5667:Titanium dioxide 5555:Selenium dioxide 5485:Polonium dioxide 5457:Platinum dioxide 5429:Nitrogen dioxide 5300:Curium(IV) oxide 5272:Chlorine dioxide 5258:Cerium(IV) oxide 4500:Arsenic trioxide 4361:Thorium monoxide 4344:Disulfur dioxide 4314:Silicon monoxide 4244:Nickel(II) oxide 4137:Copper(II) oxide 4127:Cobalt(II) oxide 4067:Bromine monoxide 3912:Mercury(I) oxide 3873:Gallium(I) oxide 3834:Caesium monoxide 3504: 3497: 3490: 3481: 3436: 3430: 3429: 3428: 3425: 3285: 3196: 3017: 3010: 3003: 2994: 2984: 2950: 2949: 2915: 2902: 2896: 2895: 2893: 2869: 2863: 2862: 2852: 2828: 2822: 2821: 2814: 2808: 2807: 2797: 2765: 2759: 2758: 2740: 2700: 2694: 2693: 2691: 2690: 2674: 2668: 2667: 2665: 2664: 2653: 2647: 2640: 2634: 2633: 2623: 2575: 2562: 2561: 2535: 2514: 2508: 2507: 2505: 2504: 2493: 2478: 2477: 2476: 2470: 2468: 2450: 2424: 2418: 2417: 2387: 2381: 2380: 2379: 2373: 2371: 2361: 2325: 2319: 2318: 2308: 2264: 2258: 2252: 2246: 2239: 2233: 2232: 2230: 2228: 2213: 2207: 2206: 2164: 2155: 2149: 2148: 2136: 2127: 2126: 2101:(8): 4993–5009. 2069: 2063: 2062: 2030: 2024: 2023: 1989: 1980: 1974: 1973: 1971: 1969: 1953: 1947: 1946: 1925: 1919: 1918: 1884: 1860: 1851: 1850: 1848: 1847: 1832: 1826: 1825: 1781: 1775: 1774: 1717: 1711: 1710: 1708: 1706: 1701: 1681: 1672: 1671: 1669: 1668: 1654: 1648: 1647: 1630:(8): 1289–1310. 1615: 1606: 1605: 1588:(9): 1602–1607. 1572: 1566: 1565: 1525: 1519: 1518: 1470: 1464: 1463: 1453: 1405: 1399: 1398: 1370: 1361: 1360: 1333: 1324: 1323: 1312: 1306: 1305:Haynes, p. 4.136 1303: 1297: 1294: 1241:phase transition 1234:missile guidance 1171: 1170: 1169: 1158: 1157: 1156: 1141: 1140: 1139: 1129: 1128: 1127: 1083:has a distorted 1075: 1074: 1073: 1063: 1062: 1061: 1053: 1052: 1042: 1041: 1040: 1032: 1031: 1006: 1005: 1004: 936:contradicts the 918:optical band gap 911: 910: 909: 874: 873: 872: 861: 860: 859: 846: 845: 844: 811: 810: 809: 789: 788: 787: 739:(IV) dioxide is 725:vanadium dioxide 699: 693: 690: 689: 584: 577: 570: 555: 535: 531: 527: 523: 519: 515: 511: 497: 493: 465: 387:+99.0·10 cm/mol 325:Chemical formula 265: 264: 249: 247: 231: 220: 204:Gmelin Reference 187: 179: 168: 157: 137: 117: 93: 66:Vanadium dioxide 44: 37: 21: 18:Vanadium dioxide 6308: 6307: 6303: 6302: 6301: 6299: 6298: 6297: 6278: 6277: 6276: 6271: 6269:Category:Oxides 6265:oxidation state 6257: 6211: 6207: 6193: 6184:Xenon tetroxide 6179: 6165: 6151: 6130: 6126: 6122: 6109: 6105: 6092: 6088: 6075: 6071: 6051: 6047: 6033: 6019: 6005: 5991: 5982:Sulfur trioxide 5977: 5963: 5949: 5935: 5921: 5900: 5896: 5892: 5879: 5875: 5862: 5858: 5845: 5841: 5828: 5824: 5811: 5807: 5794: 5790: 5777: 5773: 5760: 5756: 5736: 5732: 5718: 5704: 5695:Uranium dioxide 5690: 5676: 5662: 5648: 5639:Thorium dioxide 5634: 5620: 5606: 5592: 5578: 5569:Silicon dioxide 5564: 5550: 5536: 5522: 5508: 5494: 5480: 5466: 5452: 5438: 5424: 5410: 5396: 5382: 5368: 5359:Iridium dioxide 5354: 5340: 5326: 5322: 5309: 5295: 5281: 5267: 5253: 5244:Carbon trioxide 5239: 5225: 5211: 5202:Bromine dioxide 5197: 5183: 5162: 5158: 5154: 5141: 5137: 5124: 5120: 5107: 5103: 5090: 5086: 5073: 5069: 5056: 5052: 5039: 5035: 5022: 5018: 5005: 5001: 4988: 4984: 4971: 4967: 4954: 4950: 4937: 4933: 4920: 4916: 4903: 4899: 4886: 4882: 4869: 4865: 4852: 4848: 4840:Lanthanum oxide 4835: 4831: 4823:Iron(III) oxide 4818: 4814: 4801: 4797: 4784: 4780: 4772:Gold(III) oxide 4767: 4763: 4750: 4746: 4733: 4729: 4716: 4712: 4699: 4695: 4682: 4678: 4665: 4661: 4648: 4644: 4631: 4627: 4614: 4610: 4597: 4593: 4580: 4576: 4563: 4559: 4546: 4542: 4529: 4525: 4512: 4508: 4495: 4491: 4478: 4474: 4461: 4457: 4449:Aluminium oxide 4444: 4440: 4420: 4356: 4352: 4334:Sulfur monoxide 4324:Strontium oxide 4214:Magnesium oxide 4194:Iodine monoxide 4159: 4155: 4097:Carbon monoxide 4057:Beryllium oxide 4015: 4011: 3998: 3985: 3972: 3959: 3946: 3938:Potassium oxide 3933: 3920: 3907: 3894: 3886:Iodine(I) oxide 3881: 3868: 3855: 3842: 3829: 3821:Copper(I) oxide 3816: 3796: 3792: 3788: 3775: 3771: 3758: 3754: 3741: 3737: 3724: 3720: 3707: 3703: 3690: 3686: 3673: 3669: 3656: 3652: 3639: 3635: 3622: 3618: 3605: 3601: 3588: 3584: 3571: 3567: 3559:Carbon suboxide 3554: 3550: 3537: 3533: 3513: 3508: 3478: 3469: 3465: 3461: 3453: 3449: 3434: 3426: 3423: 3422: 3420: 3415: 3407: 3403: 3395: 3387: 3378: 3370: 3362: 3354: 3350: 3331: 3327: 3312: 3309: 3305: 3301: 3297: 3283: 3279: 3271: 3263: 3259: 3251: 3243: 3219: 3216: 3212: 3208: 3194: 3190: 3186: 3178: 3174: 3170: 3162: 3158: 3145: 3137: 3129: 3121: 3106: 3102: 3084: 3076: 3068: 3060: 3045: 3041: 3026: 3021: 2991: 2981: 2962: 2959: 2954: 2953: 2913: 2910: 2904: 2903: 2899: 2871: 2870: 2866: 2830: 2829: 2825: 2816: 2815: 2811: 2767: 2766: 2762: 2702: 2701: 2697: 2688: 2686: 2676: 2675: 2671: 2662: 2660: 2655: 2654: 2650: 2641: 2637: 2587: 2583: 2577: 2576: 2565: 2516: 2515: 2511: 2502: 2500: 2495: 2494: 2481: 2471: 2426: 2425: 2421: 2389: 2388: 2384: 2374: 2333: 2327: 2326: 2322: 2272: 2266: 2265: 2261: 2253: 2249: 2240: 2236: 2226: 2224: 2215: 2214: 2210: 2162: 2157: 2156: 2152: 2138: 2137: 2130: 2092: 2088: 2084: 2080: 2076: 2071: 2070: 2066: 2036: 2032: 2031: 2027: 1982: 1981: 1977: 1967: 1965: 1955: 1954: 1950: 1927: 1926: 1922: 1866: 1862: 1861: 1854: 1845: 1843: 1834: 1833: 1829: 1783: 1782: 1778: 1719: 1718: 1714: 1704: 1702: 1683: 1682: 1675: 1666: 1664: 1656: 1655: 1651: 1617: 1616: 1609: 1579: 1574: 1573: 1569: 1531: 1527: 1526: 1522: 1476: 1472: 1471: 1467: 1417: 1413: 1407: 1406: 1402: 1372: 1371: 1364: 1357: 1335: 1334: 1327: 1314: 1313: 1309: 1304: 1300: 1296:Haynes, p. 4.98 1295: 1291: 1286: 1274: 1267: 1262: 1249: 1232:modulators for 1216: 1212: 1208: 1198: 1193: 1168: 1165: 1164: 1163: 1161: 1155: 1152: 1151: 1150: 1148: 1146: 1145: 1138: 1135: 1134: 1133: 1131: 1126: 1123: 1122: 1121: 1119: 1110: 1082: 1072: 1069: 1068: 1067: 1065: 1060: 1057: 1056: 1055: 1051: 1048: 1047: 1046: 1044: 1039: 1036: 1035: 1034: 1030: 1027: 1026: 1025: 1023: 1007:is prepared by 1003: 1000: 999: 998: 996: 989: 988: 977: 970: 935: 930: 923: 908: 905: 904: 903: 901: 898: 885: 871: 868: 867: 866: 864: 858: 855: 854: 853: 851: 843: 840: 839: 838: 836: 827: 823: 808: 805: 804: 803: 801: 799: 794: 793: 786: 783: 782: 781: 779: 771: 766: 750: 734: 718: 711: 706: 705: 704:  ?) 695: 691: 687: 683: 669: 665: 659: 643: 637: 624: 620: 614: 589: 588: 587: 586: 579: 572: 565: 561: 553: 506: 488: 474: 458: 435: 409: 401: 384: 363: 333: 327: 313: 310: 305: 304: 293: 290: 289: 286: 280: 279: 268: 250: 243: 234: 221: 206: 197: 160: 140: 120: 107: 96: 83: 69: 67: 59: 32: 23: 22: 15: 12: 11: 5: 6306: 6304: 6296: 6295: 6290: 6280: 6279: 6273: 6272: 6262: 6259: 6258: 6256: 6255: 6250: 6245: 6240: 6235: 6230: 6225: 6219: 6217: 6213: 6212: 6210: 6209: 6205: 6195: 6191: 6181: 6177: 6167: 6163: 6153: 6149: 6138: 6136: 6132: 6131: 6129: 6128: 6124: 6120: 6111: 6107: 6103: 6094: 6090: 6086: 6077: 6073: 6069: 6059: 6057: 6053: 6052: 6050: 6049: 6045: 6038:Xenon trioxide 6035: 6031: 6021: 6017: 6007: 6003: 5993: 5989: 5979: 5975: 5965: 5961: 5951: 5947: 5937: 5933: 5923: 5919: 5908: 5906: 5902: 5901: 5899: 5898: 5894: 5890: 5881: 5877: 5873: 5864: 5860: 5856: 5847: 5843: 5839: 5830: 5826: 5822: 5813: 5809: 5805: 5796: 5792: 5788: 5779: 5775: 5771: 5762: 5758: 5754: 5744: 5742: 5738: 5737: 5735: 5734: 5730: 5720: 5716: 5706: 5702: 5692: 5688: 5678: 5674: 5664: 5660: 5650: 5646: 5636: 5632: 5622: 5618: 5608: 5604: 5594: 5590: 5583:Sulfur dioxide 5580: 5576: 5566: 5562: 5552: 5548: 5538: 5534: 5524: 5520: 5510: 5506: 5496: 5492: 5482: 5478: 5468: 5464: 5454: 5450: 5443:Osmium dioxide 5440: 5436: 5426: 5422: 5412: 5408: 5398: 5394: 5384: 5380: 5370: 5366: 5356: 5352: 5345:Iodine dioxide 5342: 5338: 5328: 5324: 5320: 5311: 5307: 5297: 5293: 5283: 5279: 5269: 5265: 5255: 5251: 5241: 5237: 5230:Carbon dioxide 5227: 5223: 5213: 5209: 5199: 5195: 5185: 5181: 5170: 5168: 5164: 5163: 5161: 5160: 5156: 5152: 5143: 5139: 5135: 5126: 5122: 5118: 5109: 5105: 5101: 5092: 5088: 5084: 5075: 5071: 5067: 5058: 5054: 5050: 5041: 5037: 5033: 5024: 5020: 5016: 5010:Scandium oxide 5007: 5003: 4999: 4990: 4986: 4982: 4973: 4969: 4965: 4956: 4952: 4948: 4939: 4935: 4931: 4922: 4918: 4914: 4905: 4901: 4897: 4888: 4884: 4880: 4871: 4867: 4863: 4854: 4850: 4846: 4837: 4833: 4829: 4820: 4816: 4812: 4803: 4799: 4795: 4786: 4782: 4778: 4769: 4765: 4761: 4752: 4748: 4744: 4735: 4731: 4727: 4718: 4714: 4710: 4701: 4697: 4693: 4684: 4680: 4676: 4667: 4663: 4659: 4650: 4646: 4642: 4633: 4629: 4625: 4616: 4612: 4608: 4599: 4595: 4591: 4582: 4578: 4574: 4565: 4561: 4557: 4551:Boron trioxide 4548: 4544: 4540: 4531: 4527: 4523: 4514: 4510: 4506: 4497: 4493: 4489: 4480: 4476: 4472: 4463: 4459: 4455: 4446: 4442: 4438: 4428: 4426: 4422: 4421: 4419: 4418: 4408: 4398: 4388: 4378: 4368: 4358: 4354: 4350: 4341: 4331: 4321: 4311: 4301: 4291: 4281: 4271: 4261: 4251: 4241: 4231: 4221: 4211: 4204:Lead(II) oxide 4201: 4191: 4184:Iron(II) oxide 4181: 4171: 4161: 4157: 4153: 4144: 4134: 4124: 4114: 4104: 4094: 4084: 4074: 4064: 4054: 4044: 4034: 4023: 4021: 4017: 4016: 4014: 4013: 4009: 4000: 3996: 3987: 3983: 3974: 3970: 3961: 3957: 3951:Rubidium oxide 3948: 3944: 3935: 3931: 3922: 3918: 3909: 3905: 3896: 3892: 3883: 3879: 3870: 3866: 3857: 3853: 3844: 3840: 3831: 3827: 3818: 3814: 3804: 3802: 3798: 3797: 3795: 3794: 3790: 3786: 3777: 3773: 3769: 3760: 3756: 3752: 3743: 3739: 3735: 3726: 3722: 3718: 3709: 3705: 3701: 3692: 3688: 3684: 3675: 3671: 3667: 3658: 3654: 3650: 3641: 3637: 3633: 3624: 3620: 3616: 3607: 3603: 3599: 3590: 3586: 3582: 3573: 3569: 3565: 3556: 3552: 3548: 3542:Boron suboxide 3539: 3535: 3531: 3521: 3519: 3515: 3514: 3509: 3507: 3506: 3499: 3492: 3484: 3475: 3474: 3471: 3470: 3468: 3467: 3463: 3459: 3455: 3451: 3447: 3442: 3440: 3433: 3432: 3417: 3413: 3409: 3405: 3401: 3397: 3393: 3389: 3385: 3381: 3376: 3372: 3368: 3364: 3360: 3356: 3352: 3348: 3343: 3341: 3337: 3336: 3333: 3332: 3330: 3329: 3325: 3320: 3318: 3314: 3313: 3311: 3307: 3303: 3299: 3295: 3291: 3289: 3282: 3281: 3277: 3273: 3269: 3265: 3261: 3257: 3253: 3249: 3245: 3241: 3237: 3231: 3229: 3225: 3224: 3221: 3220: 3218: 3214: 3210: 3206: 3202: 3200: 3193: 3192: 3188: 3184: 3180: 3176: 3172: 3168: 3164: 3160: 3156: 3152: 3147: 3143: 3139: 3135: 3131: 3127: 3123: 3119: 3114: 3112: 3108: 3107: 3105: 3104: 3100: 3096: 3091: 3086: 3082: 3078: 3074: 3070: 3066: 3062: 3058: 3053: 3051: 3047: 3046: 3044: 3043: 3039: 3034: 3032: 3028: 3027: 3022: 3020: 3019: 3012: 3005: 2997: 2990: 2989:External links 2987: 2986: 2985: 2979: 2958: 2955: 2952: 2951: 2924:(21): 213106. 2908: 2897: 2884:(3): 780–782. 2864: 2823: 2809: 2760: 2715:(11): 110901. 2695: 2669: 2648: 2635: 2598:(1): 563–573. 2585: 2581: 2563: 2509: 2479: 2419: 2382: 2344:(1): 693–701. 2331: 2320: 2270: 2259: 2247: 2234: 2208: 2150: 2128: 2090: 2086: 2082: 2078: 2074: 2064: 2045:(4): 490–500. 2034: 2025: 1998:(9): 596–603. 1975: 1948: 1937:(4): 744–749. 1920: 1875:(15): 154706. 1864: 1852: 1827: 1776: 1712: 1673: 1649: 1607: 1577: 1567: 1529: 1520: 1474: 1465: 1415: 1411: 1410:"Core-shell VO 1400: 1362: 1355: 1347:Pergamon Press 1325: 1307: 1298: 1288: 1287: 1285: 1282: 1281: 1280: 1273: 1270: 1265: 1261: 1258: 1248: 1245: 1214: 1210: 1206: 1197: 1194: 1192: 1189: 1166: 1153: 1136: 1124: 1112: 1111: 1109: 1106: 1080: 1077: 1076: 1070: 1058: 1049: 1037: 1028: 1001: 979: 978: 976: 973: 968: 933: 929: 926: 921: 906: 897: 894: 884: 881: 869: 856: 841: 825: 821: 806: 797: 784: 773: 772: 770: 767: 765: 762: 748: 732: 716: 713: 712: 707: 685: 684: 680:standard state 677: 674: 673: 660: 651: 648: 647: 638: 632: 629: 628: 615: 609: 606: 605: 601: 600: 599:Non-flammable 597: 591: 590: 580: 573: 566: 551: 550: 549: 548: 546: 537: 536: 522:P305+P351+P338 507: 502: 499: 498: 489: 484: 481: 480: 475: 470: 467: 466: 459: 454: 451: 450: 440: 439: 436: 433: 430: 429: 420: 419: 415: 414: 402: 397: 394: 393: 389: 388: 385: 379: 376: 375: 372: 366: 365: 360: 354: 353: 350: 346: 345: 342: 336: 335: 331: 328: 323: 320: 319: 315: 314: 312: 311: 308: 300: 299: 298: 295: 294: 292: 291: 287: 284: 283: 275: 274: 273: 270: 269: 267: 266: 253: 251: 239: 236: 235: 233: 232: 224: 222: 214: 211: 210: 207: 202: 199: 198: 196: 195: 191: 189: 181: 180: 170: 162: 161: 159: 158: 150: 148: 142: 141: 139: 138: 130: 128: 122: 121: 119: 118: 110: 108: 101: 98: 97: 95: 94: 86: 84: 79: 76: 75: 71: 70: 65: 61: 60: 57: 51: 50: 46: 45: 24: 14: 13: 10: 9: 6: 4: 3: 2: 6305: 6294: 6291: 6289: 6286: 6285: 6283: 6270: 6266: 6260: 6254: 6251: 6249: 6246: 6244: 6241: 6239: 6236: 6234: 6231: 6229: 6226: 6224: 6221: 6220: 6218: 6214: 6203: 6199: 6196: 6189: 6185: 6182: 6175: 6171: 6168: 6161: 6157: 6154: 6147: 6143: 6140: 6139: 6137: 6133: 6119: 6115: 6112: 6102: 6098: 6095: 6085: 6081: 6078: 6068: 6064: 6061: 6060: 6058: 6054: 6043: 6039: 6036: 6029: 6025: 6022: 6015: 6011: 6008: 6001: 5997: 5994: 5987: 5983: 5980: 5973: 5969: 5966: 5959: 5955: 5952: 5945: 5941: 5938: 5931: 5927: 5924: 5917: 5913: 5910: 5909: 5907: 5903: 5889: 5885: 5882: 5872: 5868: 5865: 5855: 5851: 5848: 5838: 5834: 5831: 5821: 5817: 5814: 5804: 5800: 5797: 5787: 5783: 5780: 5770: 5766: 5763: 5753: 5749: 5746: 5745: 5743: 5739: 5728: 5724: 5721: 5714: 5710: 5707: 5700: 5696: 5693: 5686: 5682: 5679: 5672: 5668: 5665: 5658: 5654: 5651: 5644: 5640: 5637: 5630: 5626: 5623: 5616: 5612: 5609: 5602: 5598: 5595: 5588: 5584: 5581: 5574: 5570: 5567: 5560: 5556: 5553: 5546: 5542: 5539: 5532: 5528: 5525: 5518: 5514: 5511: 5504: 5500: 5497: 5490: 5486: 5483: 5476: 5472: 5469: 5462: 5458: 5455: 5448: 5444: 5441: 5434: 5430: 5427: 5420: 5416: 5413: 5406: 5402: 5399: 5392: 5388: 5385: 5378: 5374: 5371: 5364: 5360: 5357: 5350: 5346: 5343: 5336: 5332: 5329: 5319: 5315: 5312: 5305: 5301: 5298: 5291: 5287: 5284: 5277: 5273: 5270: 5263: 5259: 5256: 5249: 5245: 5242: 5235: 5231: 5228: 5221: 5217: 5214: 5207: 5203: 5200: 5193: 5189: 5186: 5179: 5175: 5172: 5171: 5169: 5165: 5151: 5147: 5144: 5134: 5130: 5127: 5117: 5113: 5110: 5100: 5096: 5093: 5083: 5079: 5076: 5066: 5062: 5059: 5049: 5045: 5042: 5032: 5028: 5025: 5015: 5011: 5008: 4998: 4994: 4991: 4981: 4977: 4974: 4964: 4960: 4957: 4947: 4943: 4940: 4930: 4926: 4923: 4913: 4909: 4906: 4896: 4892: 4889: 4879: 4875: 4872: 4862: 4858: 4855: 4845: 4841: 4838: 4828: 4824: 4821: 4811: 4807: 4804: 4794: 4790: 4787: 4777: 4773: 4770: 4760: 4756: 4753: 4743: 4739: 4736: 4726: 4722: 4719: 4709: 4705: 4702: 4692: 4688: 4685: 4675: 4671: 4668: 4658: 4654: 4651: 4641: 4637: 4634: 4624: 4620: 4617: 4607: 4603: 4600: 4590: 4586: 4583: 4573: 4569: 4566: 4556: 4552: 4549: 4539: 4535: 4532: 4522: 4518: 4515: 4505: 4501: 4498: 4488: 4484: 4481: 4471: 4467: 4464: 4454: 4450: 4447: 4437: 4433: 4430: 4429: 4427: 4423: 4416: 4412: 4409: 4406: 4402: 4399: 4396: 4392: 4389: 4386: 4382: 4379: 4376: 4372: 4371:Tin(II) oxide 4369: 4366: 4362: 4359: 4349: 4345: 4342: 4339: 4335: 4332: 4329: 4325: 4322: 4319: 4315: 4312: 4309: 4305: 4302: 4299: 4295: 4292: 4289: 4285: 4282: 4279: 4275: 4272: 4269: 4265: 4262: 4259: 4255: 4252: 4249: 4245: 4242: 4239: 4235: 4232: 4229: 4225: 4222: 4219: 4215: 4212: 4209: 4205: 4202: 4199: 4195: 4192: 4189: 4185: 4182: 4179: 4175: 4172: 4169: 4165: 4162: 4152: 4148: 4145: 4142: 4138: 4135: 4132: 4128: 4125: 4122: 4118: 4115: 4112: 4108: 4105: 4102: 4098: 4095: 4092: 4088: 4087:Calcium oxide 4085: 4082: 4078: 4077:Cadmium oxide 4075: 4072: 4068: 4065: 4062: 4058: 4055: 4052: 4048: 4045: 4042: 4038: 4035: 4032: 4028: 4025: 4024: 4022: 4018: 4008: 4004: 4001: 3995: 3991: 3988: 3982: 3978: 3975: 3969: 3965: 3962: 3956: 3952: 3949: 3943: 3939: 3936: 3930: 3926: 3925:Nitrous oxide 3923: 3917: 3913: 3910: 3904: 3900: 3899:Lithium oxide 3897: 3891: 3887: 3884: 3878: 3874: 3871: 3865: 3861: 3858: 3852: 3848: 3845: 3839: 3835: 3832: 3826: 3822: 3819: 3813: 3809: 3806: 3805: 3803: 3799: 3785: 3781: 3778: 3768: 3764: 3761: 3751: 3747: 3744: 3734: 3730: 3727: 3717: 3713: 3710: 3700: 3696: 3693: 3683: 3679: 3676: 3666: 3662: 3659: 3649: 3645: 3642: 3632: 3628: 3625: 3615: 3611: 3608: 3598: 3594: 3591: 3581: 3577: 3574: 3564: 3560: 3557: 3547: 3543: 3540: 3530: 3526: 3523: 3522: 3520: 3516: 3512: 3505: 3500: 3498: 3493: 3491: 3486: 3485: 3482: 3466: 3456: 3454: 3444: 3443: 3441: 3437: 3431: 3418: 3416: 3410: 3408: 3398: 3396: 3390: 3388: 3382: 3380: 3373: 3371: 3365: 3363: 3357: 3355: 3345: 3344: 3342: 3338: 3328: 3322: 3321: 3319: 3315: 3310: 3292: 3290: 3286: 3280: 3274: 3272: 3266: 3264: 3254: 3252: 3246: 3244: 3238: 3236: 3233: 3232: 3230: 3226: 3217: 3203: 3201: 3197: 3191: 3181: 3179: 3165: 3163: 3153: 3151: 3148: 3146: 3140: 3138: 3132: 3130: 3124: 3122: 3116: 3115: 3113: 3111:Vanadium(III) 3109: 3103: 3097: 3095: 3092: 3090: 3087: 3085: 3079: 3077: 3071: 3069: 3063: 3061: 3055: 3054: 3052: 3048: 3042: 3036: 3035: 3033: 3029: 3025: 3018: 3013: 3011: 3006: 3004: 2999: 2998: 2995: 2988: 2982: 2976: 2972: 2968: 2967: 2961: 2960: 2956: 2947: 2943: 2939: 2935: 2931: 2927: 2923: 2919: 2912: 2901: 2898: 2892: 2887: 2883: 2879: 2875: 2868: 2865: 2860: 2856: 2851: 2846: 2842: 2838: 2834: 2827: 2824: 2819: 2813: 2810: 2805: 2801: 2796: 2791: 2787: 2783: 2779: 2775: 2771: 2764: 2761: 2756: 2752: 2748: 2744: 2739: 2734: 2730: 2726: 2722: 2718: 2714: 2710: 2706: 2699: 2696: 2685:on 2005-05-24 2684: 2680: 2673: 2670: 2658: 2652: 2649: 2645: 2639: 2636: 2631: 2627: 2622: 2617: 2613: 2609: 2605: 2601: 2597: 2593: 2589: 2574: 2572: 2570: 2568: 2564: 2559: 2555: 2551: 2547: 2543: 2539: 2534: 2529: 2526:(4): 041004. 2525: 2521: 2513: 2510: 2498: 2492: 2490: 2488: 2486: 2484: 2480: 2475: 2467: 2462: 2458: 2454: 2449: 2444: 2441:(4): 041004. 2440: 2436: 2435: 2430: 2423: 2420: 2415: 2411: 2407: 2403: 2400:(2): 024101. 2399: 2395: 2394: 2386: 2383: 2378: 2370: 2365: 2360: 2355: 2351: 2347: 2343: 2339: 2335: 2324: 2321: 2316: 2312: 2307: 2302: 2298: 2294: 2290: 2286: 2283:(6): 065002. 2282: 2278: 2274: 2263: 2260: 2256: 2251: 2248: 2244: 2238: 2235: 2222: 2218: 2212: 2209: 2204: 2200: 2196: 2192: 2188: 2184: 2180: 2176: 2172: 2168: 2161: 2154: 2151: 2146: 2142: 2135: 2133: 2129: 2124: 2120: 2116: 2112: 2108: 2104: 2100: 2096: 2068: 2065: 2060: 2056: 2052: 2048: 2044: 2040: 2029: 2026: 2021: 2017: 2013: 2009: 2005: 2001: 1997: 1993: 1988: 1979: 1976: 1964: 1963: 1958: 1952: 1949: 1944: 1940: 1936: 1932: 1924: 1921: 1916: 1912: 1908: 1904: 1900: 1896: 1892: 1888: 1883: 1878: 1874: 1870: 1859: 1857: 1853: 1842: 1838: 1831: 1828: 1823: 1819: 1815: 1811: 1807: 1803: 1799: 1795: 1791: 1787: 1780: 1777: 1772: 1768: 1764: 1760: 1756: 1752: 1748: 1744: 1740: 1736: 1732: 1728: 1724: 1716: 1713: 1700: 1695: 1691: 1687: 1680: 1678: 1674: 1663: 1659: 1653: 1650: 1645: 1641: 1637: 1633: 1629: 1625: 1621: 1614: 1612: 1608: 1603: 1599: 1595: 1591: 1587: 1583: 1571: 1568: 1563: 1559: 1555: 1551: 1547: 1543: 1539: 1535: 1524: 1521: 1516: 1512: 1508: 1504: 1500: 1496: 1492: 1488: 1484: 1480: 1469: 1466: 1461: 1457: 1452: 1447: 1443: 1439: 1435: 1431: 1427: 1423: 1419: 1404: 1401: 1396: 1392: 1388: 1384: 1380: 1376: 1369: 1367: 1363: 1358: 1352: 1348: 1344: 1343: 1338: 1332: 1330: 1326: 1321: 1317: 1311: 1308: 1302: 1299: 1293: 1290: 1283: 1279: 1276: 1275: 1271: 1269: 1259: 1257: 1254: 1246: 1244: 1242: 1239: 1238:thermochromic 1235: 1231: 1227: 1222: 1218: 1203: 1195: 1190: 1188: 1186: 1181: 1177: 1173: 1116: 1107: 1105: 1103: 1102:metamaterials 1099: 1095: 1091: 1086: 1022: 1021: 1020: 1018: 1014: 1010: 994: 983: 974: 972: 965: 963: 959: 955: 951: 947: 943: 939: 927: 925: 919: 915: 914:semiconductor 895: 893: 891: 883:Memory effect 882: 880: 878: 848: 835: 831: 819: 815: 777: 768: 763: 761: 759: 755: 746: 742: 738: 730: 726: 722: 710: 703: 698: 681: 675: 672: 668: 664: 661: 658: 655: 650: 649: 646: 642: 639: 636: 631: 630: 627: 623: 619: 616: 613: 608: 607: 602: 598: 596: 593: 592: 585: 578: 571: 547: 544: 543: 539: 538: 508: 505: 501: 500: 490: 487: 483: 482: 479: 476: 473: 469: 468: 464: 460: 457: 453: 452: 448: 446: 441: 437: 432: 431: 427: 426: 421: 416: 412: 407: 403: 400: 396: 395: 390: 386: 382: 378: 377: 373: 371: 370:Melting point 368: 367: 361: 359: 356: 355: 351: 348: 347: 343: 341: 338: 337: 329: 326: 322: 321: 316: 307: 303: 296: 285:InChI=1S/2O.V 282: 278: 271: 263: 259: 258:DTXSID5065194 255: 254: 252: 242: 238: 237: 230: 226: 225: 223: 217: 213: 212: 208: 205: 201: 200: 193: 192: 190: 188: 183: 182: 178: 174: 171: 169: 167:ECHA InfoCard 164: 163: 156: 152: 151: 149: 147: 144: 143: 136: 132: 131: 129: 127: 124: 123: 116: 112: 111: 109: 105: 100: 99: 92: 88: 87: 85: 82: 78: 77: 72: 62: 56: 52: 47: 43: 38: 30: 19: 5708: 5387:Lead dioxide 4304:Radium oxide 4254:Nitric oxide 4037:Barium oxide 3990:Sodium oxide 3964:Silver oxide 3239: 3228:Vanadium(IV) 3050:Vanadium(II) 2965: 2957:Bibliography 2921: 2917: 2900: 2881: 2877: 2867: 2840: 2836: 2826: 2812: 2777: 2773: 2763: 2712: 2708: 2698: 2687:. Retrieved 2683:the original 2672: 2661:. Retrieved 2651: 2646:. solgel.com 2638: 2595: 2591: 2523: 2519: 2512: 2501:. Retrieved 2438: 2432: 2422: 2397: 2391: 2385: 2341: 2337: 2323: 2280: 2276: 2262: 2250: 2242: 2237: 2225:. Retrieved 2220: 2211: 2170: 2166: 2153: 2145:ScienceAlert 2144: 2098: 2094: 2067: 2042: 2038: 2028: 1995: 1991: 1978: 1968:15 September 1966:. Retrieved 1960: 1951: 1934: 1930: 1923: 1872: 1868: 1844:. Retrieved 1840: 1830: 1789: 1785: 1779: 1730: 1726: 1715: 1703:. Retrieved 1689: 1665:. Retrieved 1661: 1652: 1627: 1623: 1585: 1581: 1580:Nanobeams". 1570: 1537: 1533: 1523: 1482: 1478: 1468: 1425: 1421: 1403: 1381:(1): 34–36. 1378: 1374: 1341: 1319: 1310: 1301: 1292: 1263: 1250: 1223: 1219: 1199: 1182: 1178: 1174: 1147: 1078: 990: 966: 953: 945: 931: 899: 886: 849: 795: 724: 720: 719: 541: 477: 444: 434:Main hazards 423: 74:Identifiers 64:Other names 6253:Oxypnictide 5653:Tin dioxide 3340:Vanadium(V) 3031:Vanadium(0) 2795:11025/49623 2738:11025/47644 2642:Guzman, G. 1867:surfaces". 962:temperature 932:Metallic VO 818:space group 745:vanadyl ion 595:Flash point 472:Signal word 428:(OHS/OSH): 349:Appearance 318:Properties 173:100.031.661 135:CHEBI:30047 6282:Categories 6248:Superoxide 4411:Zinc oxide 2780:: 128273. 2689:2012-09-12 2663:2012-09-12 2503:2014-01-01 2369:2346/95263 1846:2018-05-05 1667:2018-05-05 1345:. Oxford: 1284:References 1094:memristors 896:Electronic 830:tetragonal 814:monoclinic 764:Properties 741:amphoteric 456:Pictograms 404:Distorted 392:Structure 340:Molar mass 146:ChemSpider 102:3D model ( 91:12036-21-4 81:CAS Number 55:IUPAC name 6223:Oxocarbon 2971:CRC Press 2946:122696544 2859:240331557 2804:247121490 2755:247568375 2747:0021-8979 2533:1305.0033 2448:1305.0033 2203:206650639 2020:251759964 2012:2520-1131 1882:1209.6177 1841:EPFL News 1822:245262692 1771:245263196 1515:205238368 993:Berzelius 948:) to the 769:Structure 530:P337+P313 526:P332+P313 518:P302+P352 447:labelling 194:234-841-1 186:EC Number 6243:Peroxide 6233:Oxyanion 6228:Suboxide 2630:28970866 2558:53496680 2315:27877369 2195:28126811 1915:29006673 1907:23083183 1814:34914526 1763:34914515 1644:11347598 1602:95830675 1507:20842663 1460:23546301 1428:: 1370. 1272:See also 1230:infrared 1202:infrared 1185:tungsten 737:Vanadium 654:vanadium 652:Related 542:NFPA 704 418:Hazards 383:(χ) 6238:Ozonide 6216:Related 2926:Bibcode 2717:Bibcode 2621:5613921 2600:Bibcode 2538:Bibcode 2453:Bibcode 2402:Bibcode 2346:Bibcode 2306:5090451 2285:Bibcode 2227:29 July 2175:Bibcode 2167:Science 2123:9994356 2103:Bibcode 2085:, and V 2047:Bibcode 1887:Bibcode 1794:Bibcode 1786:Science 1755:1875448 1735:Bibcode 1727:Science 1705:15 July 1562:7107273 1542:Bibcode 1487:Bibcode 1451:3613806 1430:Bibcode 1383:Bibcode 1064:→ 4 956:) of a 928:Thermal 832:, like 702:what is 700: ( 635:cations 478:Warning 358:Density 334: 216:PubChem 209:873472 29:VO2 max 3511:Oxides 3446:VO(ClO 2977:  2944:  2878:Matter 2857:  2837:EcoMat 2802:  2753:  2745:  2628:  2618:  2556:  2313:  2303:  2201:  2193:  2121:  2018:  2010:  1913:  1905:  1820:  1812:  1769:  1761:  1753:  1642:  1600:  1560:  1513:  1505:  1458:  1448:  1353:  1085:rutile 834:rutile 812:has a 727:is an 697:verify 694:  657:oxides 633:Other 612:anions 610:Other 438:toxic 411:Rutile 406:rutile 302:SMILES 49:Names 3458:VO(NO 3038:V(CO) 2942:S2CID 2914:(PDF) 2855:S2CID 2800:S2CID 2751:S2CID 2554:S2CID 2528:arXiv 2443:arXiv 2199:S2CID 2163:(PDF) 2016:S2CID 1911:S2CID 1877:arXiv 1818:S2CID 1767:S2CID 1640:S2CID 1598:S2CID 1558:S2CID 1511:S2CID 958:metal 920:of VO 277:InChI 229:82849 155:74761 126:ChEBI 104:JSmol 3412:VOPO 3359:VOCl 3324:VOSO 3294:VO(C 3248:VOCl 2975:ISBN 2743:ISSN 2626:PMID 2311:PMID 2229:2022 2191:PMID 2119:PMID 2008:ISSN 1970:2022 1903:PMID 1810:PMID 1759:PMID 1751:OSTI 1707:2022 1503:PMID 1456:PMID 1414:@TiO 1351:ISBN 1191:Uses 1100:and 1015:and 534:P362 514:P280 510:P264 496:H319 492:H315 309:O==O 3392:VCl 3367:VOF 3268:VCl 3256:V(S 3205:V(C 3171:(SO 3126:VCl 3118:VBr 3099:VSO 3073:VCl 3065:VBr 2934:doi 2886:doi 2845:doi 2790:hdl 2782:doi 2778:442 2733:hdl 2725:doi 2713:131 2616:PMC 2608:doi 2584:/VO 2546:doi 2461:doi 2410:doi 2364:hdl 2354:doi 2301:PMC 2293:doi 2183:doi 2171:355 2111:doi 2093:". 2077:, V 2055:doi 2037:". 2000:doi 1939:doi 1895:doi 1873:137 1802:doi 1790:374 1743:doi 1731:374 1694:doi 1632:doi 1628:103 1590:doi 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Index

Vanadium dioxide
VO2 max

IUPAC name
CAS Number
12036-21-4
JSmol
Interactive image
ChEBI
CHEBI:30047
ChemSpider
74761
ECHA InfoCard
100.031.661
Edit this at Wikidata
EC Number
Gmelin Reference
PubChem
82849
CompTox Dashboard
DTXSID5065194
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Magnetic susceptibility
Crystal structure

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