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Volhard–Erdmann cyclization

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or other 1,4-difunctional compounds (γ-oxo acids, 1,4-diketones, chloroacetyl-substituted esters) with
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An example is the synthesis of 3-methylthiophene starting from
8: 115:: CS1 maint: multiple names: authors list ( 140:"Synthetische Darstellung von Thiophen" 88:Feldkamp, R. F.; Tullar, B. F. (1954). 80: 108: 7: 178:Sulfur heterocycle forming reactions 25: 138:Volhard, J.; Erdmann, H. (1885). 66: 47:. The reaction is named after 1: 39:by cyclization of disodium 29:Volhard–Erdmann cyclization 18:Volhard-Erdmann cyclization 199: 126:, vol. 4, p. 671 158:10.1002/cber.18850180199 45:phosphorus heptasulfide 90:"3-Methylthiophene" 145:Chemische Berichte 35:of alkyl and aryl 124:Collected Volumes 98:Organic Syntheses 33:organic synthesis 16:(Redirected from 190: 162: 161: 135: 129: 127: 120: 114: 106: 94: 85: 70: 21: 198: 197: 193: 192: 191: 189: 188: 187: 168: 167: 166: 165: 137: 136: 132: 122: 107: 92: 87: 86: 82: 77: 23: 22: 15: 12: 11: 5: 196: 194: 186: 185: 183:Name reactions 180: 170: 169: 164: 163: 152:(1): 454–455. 130: 79: 78: 76: 73: 72: 71: 24: 14: 13: 10: 9: 6: 4: 3: 2: 195: 184: 181: 179: 176: 175: 173: 159: 155: 151: 147: 146: 141: 134: 131: 125: 118: 112: 104: 100: 99: 91: 84: 81: 74: 69: 65: 64: 63: 61: 60:itaconic acid 56: 54: 50: 49:Jacob Volhard 46: 42: 38: 34: 30: 19: 149: 143: 133: 123: 111:cite journal 102: 96: 83: 57: 53:Hugo Erdmann 28: 26: 172:Categories 75:References 37:thiophenes 41:succinate 31:is an 93:(PDF) 117:link 105:: 73 51:and 27:The 154:doi 174:: 150:18 148:. 142:. 121:; 113:}} 109:{{ 103:34 101:. 95:. 62:: 55:. 160:. 156:: 128:. 119:) 20:)

Index

Volhard-Erdmann cyclization
organic synthesis
thiophenes
succinate
phosphorus heptasulfide
Jacob Volhard
Hugo Erdmann
itaconic acid
Volhard-Erdmann cyclization
"3-Methylthiophene"
Organic Syntheses
cite journal
link
"Synthetische Darstellung von Thiophen"
Chemische Berichte
doi
10.1002/cber.18850180199
Categories
Sulfur heterocycle forming reactions
Name reactions

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