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Volumetric heat capacity

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708:, has nearly 59% more specific heat capacity on a mass basis. In other words; even though an ingot of arsenic is only about 17% larger than an antimony one of the same mass, it absorbs about 59% more heat for a given temperature rise. The heat capacity ratios of the two substances closely follows the ratios of their molar volumes (the ratios of numbers of atoms in the same volume of each substance); the departure from the correlation to simple volumes in this case is due to lighter arsenic atoms being significantly more closely packed than antimony atoms, instead of similar size. In other words, similar-sized atoms would cause a mole of arsenic to be 63% larger than a mole of antimony, with a correspondingly lower density, allowing its volume to more closely mirror its heat capacity behavior. 588:). This fact gives each gas molecule the same effective "volume" in all ideal gases (although this volume/molecule in gases is far larger than molecules occupy on average in solids or liquids). Thus, in the limit of ideal gas behavior (which many gases approximate except at low temperatures and/or extremes of pressure) this property reduces differences in gas volumetric heat capacity to simple differences in the heat capacities of individual molecules. As noted, these differ by a factor depending on the degrees of freedom available to particles within the molecules. 732:. The phenomenon exists because of a body's ability to both store and transport heat relative to its environment. Since the configuration of system components and mix of heat transfer mechanisms (e.g. conduction, convection, radiation, phase change) varies substantially between instances, there is no generally applicable mathematical definition for thermal inertia. The phenomenon occurs in conjunction with a material's or a transport medium's 740: 629:
filled by the atomic volumes of the atoms in the gas. Since the molar volume of gases is very roughly 1000 times that of solids and liquids, this results in a factor of about 1000 loss in volumetric heat capacity for gases, as compared with liquids and solids. Monatomic gas heat capacities per atom (not per molecule) are decreased by a factor of 2 with regard to solids, due to loss of half of the potential
515:) would be constant for all solids. This amounted to a prediction that volumetric heat capacity in solids would be constant. In 1819 they found that volumetric heat capacities were not quite constant, but that the most constant quantity was the heat capacity of solids adjusted by the presumed weight of the atoms of the substance, as defined by Dalton (the 634:
the discussed factor of 2) increase heat capacity per atom in polyatomic gases, as compared with monatomic gases. Volumetric heat capacities in polyatomic gases vary widely, however, since they are dependent largely on the number of atoms per molecule in the gas, which in turn determines the total number of atoms per volume in the gas.
780:. Thermal inertia is less directly comparable to the mass-and-velocity term used in mechanics, where inertia restricts the acceleration of an object. In a similar way, thermal inertia is a measure of the thermal mass and the velocity of the thermal wave which controls the surface temperature of a material. 691:
of solid elements is very roughly constant, and (even more reliably) so also is the molar heat capacity for most solid substances. These two factors determine the volumetric heat capacity, which as a bulk property may be striking in consistency. For example, the element uranium is a metal which has a
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and T is temperature). As noted, the much lower values for gas heat capacity in terms of volume as compared with solids (although more comparable per mole, see below) results mostly from the fact that gases under standard conditions consist of mostly empty space (about 99.9% of volume), which is not
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the same size, molar and volumetric heat capacity would be proportional and differ by only a single constant reflecting ratios of the atomic molar volume of materials (their atomic density). An additional factor for all types of specific heat capacities (including molar specific heats) then further
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This quantity is used almost exclusively for liquids and solids, since for gases it may be confused with the "specific heat capacity at constant volume", which generally has very different values. International standards now recommend that "specific heat capacity" always refer to capacity per unit
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per atom for storing energy in a monatomic gas, as compared with regard to an ideal solid. There is some difference in the heat capacity of monatomic vs. polyatomic gasses, and also gas heat capacity is temperature-dependent in many ranges for polyatomic gases; these factors act to modestly (up to
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system behavior. Steady-state calculations, many of which produce valid estimates of equilibrium heat flows and temperatures without an accounting for thermal inertia, nevertheless yield no information on the pace of changes between equilibrium states. Response times for complex systems can be
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per mole, as noted above), there exists noticeable inverse correlation between a solid's density and its specific heat capacity on a per-mass basis. This is due to a very approximate tendency of atoms of most elements to be about the same size, despite much wider variations in density and atomic
546:) to 3.4 MJ⋅K⋅m (for example iron). This is mostly due to differences in the physical size of atoms. Atoms vary greatly in density, with the heaviest often being more dense, and thus are closer to taking up the same average volume in solids than their mass alone would predict. If all atoms 716:
The volumetric heat capacity of liquids could be measured from the thermal conductivity and thermal diffusivity correlation. The volumetric heat capacity of liquids could be directly obtained during thermal conductivity analysis using thermal conductivity analyzers that use techniques like the
981:, which is always larger due to the pressure–volume work done as a gas expands during heating at constant pressure (thus absorbing heat which is converted to work). The distinctions between constant-volume and constant-pressure heat capacities are also made in various types of 699:
Since the volume-specific corollary of the Dulong–Petit specific heat capacity relationship requires that atoms of all elements take up (on average) the same volume in solids, there are many departures from it, with most of these due to variations in atomic size. For instance,
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Analogies of thermal inertia to the inertial behaviors observed in other disciplines of engineering and physics can sometimes be used with caution. In building design, thermal inertia is also known as the thermal flywheel effect, and a
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are very similar to those of liquids and solids, again differing by less than a factor of two per mole of atoms. This factor of two represents vibrational degrees of freedom available in solids vs. gas molecules of various complexities.
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of any given solid chemical element and its total heat capacity. Another way of stating this, is that the volume-specific heat capacity (volumetric heat capacity) of solid elements is roughly a constant. The
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Since both the heat capacity of an object and its volume may vary with temperature, in unrelated ways, the volumetric heat capacity is usually a function of temperature too. It is equal to the specific heat
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For a semi-infinite rigid body where heat transfer is dominated by the diffusive process of conduction only, the thermal inertia response at a surface can be approximated from the material's
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Eventually it became clear that heat capacities per particle for all substances in all states are the same, to within a factor of two, so long as temperatures are not in the cryogenic range.
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In monatomic gases (like argon) at room temperature and constant volume, volumetric heat capacities are all very close to 0.5 kJ⋅K⋅m, which is the same as the theoretical value of
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For gases at room temperature, the range of volumetric heat capacities per atom (not per molecule) only varies between different gases by a small factor less than two, because every
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The volumetric heat capacity of a substance, especially a gas, may be significantly higher when it is allowed to expand as it is heated (volumetric heat capacity
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U.S. Army Corps of Engineers Technical Manual: Arctic and Subarctic Construction: Calculation Methods for Determination of Depths of Freeze and Thaw in Soils
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A system containing one or more components with large volumetric heat capacity indicates that dynamic, or transient, effects must be considered when
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weight. These two factors (constancy of atomic volume and constancy of mole-specific heat capacity) result in a good correlation between the
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Keshavarz, P.; Taheri, M. (2007). "An improved lumped analysis for transient heat conduction by using the polynomial approximation method".
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Sreekumar, Sreehari.; Ganguly, Abhijit.; Khalil, Sameh.; Chakrabarti, Supriya.; Hewitt, Neil.; Mondol, Jayanta.; Shah, Nikhilkumar. (2023).
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For gases it is necessary to distinguish between volumetric heat capacity at constant volume and volumetric heat capacity at constant
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The volumetric heat capacity of solid materials at room temperatures and above varies widely, from about 1.2 MJ⋅K⋅m (for example
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This quantity may be convenient for materials that are commonly measured by volume rather than mass, as is often the case in
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Large complex gas molecules may have high heat capacities per mole (of molecules), but their heat capacities per mole of
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and other technical disciplines. The volumetric heat capacity often varies with temperature, and is different for each
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at 1.9. This reflects the modest loss of degrees of freedom for particles in liquids as compared with solids.
1014: 585: 1162:"Thermo-optical characterization of novel MXene/Carbon-dot hybrid nanofluid for heat transfer applications" 1440: 999: 982: 813: 757: 101: 62: 822: 753: 516: 805: 654: 551:
reflects degrees of freedom available to the atoms composing the substance, at various temperatures.
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heat flow and temperature which is similar to the delay between current and voltage in an AC-driven
760:. A higher value of volumetric heat capacity generally means a longer time for the system to reach 504: 123: 1134: 1092: 1216: 1064: 1009: 796: 789: 328: 743:
The thermal wave induced by a stepped heat source illustrates the phenomenon of thermal inertia.
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is a term commonly used to describe the observed delays in a body's temperature response during
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Gerald R. North (1988). "Lessons from energy balance models". In Michael E. Schlesinger (ed.).
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predicted in 1818 that the product of solid substance density and specific heat capacity (ρc
1401: 1374: 1313: 1243: 1198: 1173: 748: 736:. A larger thermal storage capacity typically yields a more sluggish temperature response. 97: 883: 111:) than when is heated in a closed vessel that prevents expansion (volumetric heat capacity 1435: 1287: 413: 279: 93: 1392:
Bunn, J.P. (1983). "The thermal response of a homogeneous slab to a constant heat flux".
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of a sample of the substance divided by the volume of the sample. It is the amount of
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Non-SI units of kieffers: Cal⋅cm⋅K⋅s, are also used informally in older references.
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of mass. Therefore, the word "volumetric" should always be used for this quantity.
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of a solid chemical element is strongly related to its molar mass (usually about 3
1332: 1265:(NATO Advanced Study Institute on Physical-Based Modelling ed.). Springer. 1004: 646: 357:
is the amount of heat energy needed to raise the temperature of the sample from
119: 89: 55: 47: 1378: 1247: 777: 662: 658: 524: 82: 577: 804:). It is defined as the square root of the product of the material's bulk 985:(the latter meaning either mass-specific or mole-specific heat capacity). 100:, such as melting or boiling, its volumetric heat capacity is technically 978: 705: 531:(not per unit of volume) which is closest to being a constant in solids. 66: 1263:
Physically-based Modelling and Simulation of Climate and Climatic Change
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For most liquids, the volumetric heat capacity is narrower, for example
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has a very high volumetric heat capacity, at 4.18 MJ⋅K⋅m, and
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When a constant flow of heat is abruptly imposed upon a surface,
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and volumetric heat capacity, where the latter is the product of
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density almost 36 times that of the metal lithium, but uranium's
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of the material in order to cause an increase of one unit in its
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in the sample (as is sometimes done in chemistry), one gets the
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performs nearly the same role in limiting the surfaces initial
406:. This parameter is an intensive property of the substance. 492:. Its SI unit is joule per kelvin per cubic meter (J⋅K⋅m). 935: 638: 519:). This quantity was proportional to the heat capacity per 61:
The volumetric heat capacity can also be expressed as the
54:
unit of volumetric heat capacity is joule per kelvin per
118:
If the amount of substance is taken to be the number of
961:) as the rigid body's usual heat transfer coefficient ( 696:
heat capacity is only about 20% larger than lithium's.
126:(whose SI unit is joule per kelvin per mole, J⋅K⋅mol). 1310:
Handbook of Friction Materials and Their Applications
1058:, TM 5-852-6/AFR 88-19, Volume 6, 1988, Equation 2-1" 908: 886: 864: 825: 478: 449: 416: 383: 363: 331: 311: 282: 143: 752:evaluated with detailed numerical simulation, or a 19:For volumetric heats of particular substances, see 1288:"Mathematical Theory of Thermal Inertia Revisited" 914: 892: 870: 847: 637:The volumetric heat capacity is defined as having 484: 464: 431: 398: 369: 349: 317: 297: 265: 1360:"A New Thermal Inertia Model Based on Effusivity" 1193:Sala-Lizarraga, Jose; Picallo-Perez, Ana (2019). 653:). It can also be described in Imperial units of 1195:Exergy Analysis and Thermoeconomics of Buildings 527:), which suggested that it is the heat capacity 216: 620:RT per kelvin per mole of gas molecules (where 8: 1089:International Bureau of Weights and Measures 1295:46th Lunar and Planetary Science Conference 922:is specific heat capacity, with unit J⋅kg⋅K 305:is the volume of the sample at temperature 134:The volumetric heat capacity is defined as 1177: 907: 885: 863: 832: 824: 477: 448: 415: 382: 362: 330: 310: 281: 234: 219: 194: 159: 142: 1358:van der Maas, J.; Maldonado, E. (1997). 878:is thermal conductivity, with unit W⋅m⋅K 65:(heat capacity per unit of mass, in J⋅K⋅ 1045: 1026: 1286:Veto, M.S.; Christensen, P.R. (2015). 1094:The International System of Units (SI) 704:, which is only 14.5% less dense than 573:is also fairly high: 3.3 MJ⋅K⋅m. 96:. While the substance is undergoing a 1367:International Journal of Solar Energy 973:Constant volume and constant pressure 7: 1331:Carslaw, H.S.; Jaeger, J.C. (1959). 931:multiplied by square root of time: 848:{\displaystyle e={\sqrt {k\rho c}}} 712:Volumetric heat capacity of liquids 472:, both measured at the temperature 38:that must be added, in the form of 1318:10.1016/B978-0-08-100619-1.00009-2 1203:10.1016/B978-0-12-817611-5.00004-7 927:Thermal effusivity has units of a 669:Volumetric heat capacity of solids 390: 332: 254: 237: 220: 14: 965:) plays in determining the final 592:Volumetric heat capacity of gases 21:Table of specific heat capacities 1117:from the original on 2021-06-04 717:transient plane source method. 1312:. Elsevier. pp. 123–134. 1197:. Elsevier. pp. 272–273. 459: 453: 426: 420: 344: 338: 292: 286: 249: 243: 226: 209: 203: 185: 179: 171: 165: 153: 147: 1: 1179:10.1016/j.jclepro.2023.140395 1166:Journal of Cleaner Production 953:"thermal inertia" response ( 1406:10.1016/0360-1323(83)90019-7 1334:Conduction of Heat in Solids 938:units of W⋅m⋅K⋅s or J⋅m⋅K⋅s. 772:can produce a delay between 1337:. Clarendon Press, Oxford. 439:of the substance times its 350:{\displaystyle \Delta Q(T)} 1457: 1308:Dante, Roberto C. (2016). 900:is density, with unit kg⋅m 787: 399:{\displaystyle T+\Delta T} 18: 1379:10.1080/01425919708914334 1248:10.1007/s00231-006-0200-0 929:heat transfer coefficient 1426:Thermodynamic properties 1394:Building and Environment 1033:Coined by the planetary 734:heat transfer properties 465:{\displaystyle \rho (T)} 73:of the substance (in kg/ 28:volumetric heat capacity 1015:Thermodynamic equations 558:at 1.64 MJ⋅K⋅m or 1236:Heat and Mass Transfer 1000:Specific heat capacity 983:specific heat capacity 916: 894: 872: 849: 814:specific heat capacity 758:lumped system analysis 744: 486: 466: 433: 400: 371: 351: 319: 299: 267: 63:specific heat capacity 969:surface temperature. 917: 895: 893:{\displaystyle \rho } 873: 850: 754:thermal time constant 742: 487: 467: 434: 401: 372: 352: 320: 300: 268: 30:of a material is the 906: 884: 862: 823: 806:thermal conductivity 476: 447: 432:{\displaystyle c(T)} 414: 381: 361: 329: 309: 298:{\displaystyle V(T)} 280: 141: 109:at constant pressure 1431:Physical quantities 1133:Based on values in 124:molar heat capacity 1010:Thermal effusivity 912: 890: 868: 845: 797:thermal effusivity 790:Thermal effusivity 784:Thermal effusivity 745: 631:degrees of freedom 482: 462: 443:(mass per volume) 429: 396: 367: 347: 315: 295: 263: 233: 113:at constant volume 1344:978-0-19-853368-9 1272:978-90-277-2789-3 1242:(11): 1151–1156. 915:{\displaystyle c} 871:{\displaystyle k} 843: 756:estimated from a 485:{\displaystyle T} 370:{\displaystyle T} 318:{\displaystyle T} 261: 215: 213: 189: 42:, to one unit of 1448: 1410: 1409: 1389: 1383: 1382: 1373:(1–3): 131–160. 1364: 1355: 1349: 1348: 1328: 1322: 1321: 1305: 1299: 1298: 1292: 1283: 1277: 1276: 1258: 1252: 1251: 1231: 1225: 1224: 1190: 1184: 1183: 1181: 1157: 1151: 1144: 1138: 1131: 1125: 1124: 1123: 1122: 1116: 1100:(8th ed.), 1099: 1085: 1079: 1078: 1076: 1075: 1069: 1063:. Archived from 1062: 1050: 1038: 1037:Hugh H. 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Retrieved 1065:the original 1055: 1048: 1035:geophysicist 1029: 976: 966: 962: 954: 950: 946: 944: 925: 801: 795: 793: 770:thermal mass 766: 746: 725: 724: 715: 698: 693: 689:molar volume 683: 678: 675:bulk density 672: 636: 626:gas constant 621: 603: 597: 595: 582:molar volume 575: 564: 553: 547: 541: 533: 528: 503: 494: 408: 275: 133: 117: 112: 108: 106: 87: 69:) times the 60: 27: 25: 1005:Temperature 762:equilibrium 90:engineering 56:cubic meter 48:temperature 1420:Categories 1135:this table 1121:2021-12-16 1074:2015-05-19 1021:References 778:RC circuit 694:volumetric 673:Since the 525:molar mass 130:Definition 1221:210737476 1148:NIST data 1146:Based on 888:ρ 838:ρ 749:modelling 641:units of 578:ideal gas 565:However, 451:ρ 391:Δ 333:Δ 255:Δ 238:Δ 227:→ 221:Δ 58:, J⋅K⋅m. 1112:archived 1091:(2006), 989:See also 979:pressure 959:≈ e ⋅ t 706:antimony 529:per atom 523:(or per 102:infinite 951:dynamic 810:density 774:diurnal 702:arsenic 624:is the 618:⁠ 606:⁠ 571:ammonia 560:ethanol 544:bismuth 500:History 441:density 71:density 50:. The 1436:Volume 1341:  1269:  1219:  1209:  1104:  967:static 684:volume 556:octane 505:Dulong 325:, and 276:where 44:volume 36:energy 1363:(PDF) 1291:(PDF) 1217:S2CID 1115:(PDF) 1098:(PDF) 1068:(PDF) 1061:(PDF) 598:atoms 567:water 509:Petit 120:moles 77:, or 1339:ISBN 1267:ISBN 1207:ISBN 1102:ISBN 812:and 548:were 507:and 40:heat 26:The 1402:doi 1375:doi 1314:doi 1244:doi 1199:doi 1174:doi 1170:434 957:dyn 665:). 655:BTU 377:to 217:lim 115:). 85:). 1422:: 1398:18 1396:. 1371:19 1369:. 1365:. 1293:. 1240:43 1238:. 1215:. 1205:. 1168:. 1164:. 1110:, 936:SI 816:: 764:. 663:°F 659:ft 657:/( 645:/( 639:SI 83:mL 67:kg 52:SI 1408:. 1404:: 1381:. 1377:: 1347:. 1320:. 1316:: 1297:. 1275:. 1250:. 1246:: 1223:. 1201:: 1182:. 1176:: 1077:. 1054:" 963:U 955:U 947:e 910:c 866:k 841:c 835:k 830:= 827:e 802:e 800:( 679:R 661:⋅ 651:K 649:⋅ 647:m 643:J 622:R 615:2 612:/ 609:3 513:p 480:T 460:) 457:T 454:( 427:) 424:T 421:( 418:c 394:T 388:+ 385:T 365:T 345:) 342:T 339:( 336:Q 313:T 293:) 290:T 287:( 284:V 258:T 250:) 247:T 244:( 241:Q 230:0 224:T 210:) 207:T 204:( 201:V 197:1 192:= 186:) 183:T 180:( 177:V 172:) 169:T 166:( 163:C 157:= 154:) 151:T 148:( 145:s 81:/ 79:g 75:L 23:.

Index

Table of specific heat capacities
heat capacity
energy
heat
volume
temperature
SI
cubic meter
specific heat capacity
kg
density
L
g
mL
engineering
state of matter
phase transition
infinite
moles
molar heat capacity
density
Dulong
Petit
Dulong–Petit law
atomic weight
molar mass
bismuth
octane
ethanol
water

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