640:) and the zinc peroxide to the substrate material (wood or wood-like material, i.e. bamboo, paper, cloths, and cellulose products). The metal salt is applied in solution and allowed to dry for up to 30 minutes. Next, zinc peroxide is applied, also in solution. Color change is immediately visible. The two solutions soak into the material, and react, thereby becoming ingrained in the matrix of the substrate. While these stains can produce a variety of colors ranging from a reddish brown to a yellow hue, they are generally used to mimic the look of endangered wood species in cheaper and more commonly available stock.
666:, to create the necessary red/ox reaction. In another modality, a ‘secondary’ explosive is mixed with zinc peroxide. Secondary explosives include nitrocellulose, pentaerythritol tetranitrate (PETN), as well as a variety of compounds, like trinitrobenzene, which provide powerful negative charge balance. These secondary explosives are relatively insensitive to stimuli such as physical impact, heat or charge. The explosive mixture would be comprised, in bulk, of the secondary explosive with a much smaller fraction of zinc peroxide, present to initiate the reaction.
628:
As to the microbicidal function, the Zinc ion itself has been postulated to have antibacterial properties, facilitated by the binding of the Zn ion to the bacterial cell wall, which allows for the exertion of cytotoxic effects. Zinc has been observed to be more effective in the elimination of gram-positive bacteria than gram-negative bacteria. This difference has been attributed to a difference in the protein composition of the respective cell walls, with the gram-positive wall providing a composition more conducive to binding.
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24:
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469:
623:. One aspect of the compound’s microorganism toxicity is the resultant stagnation of microbial populations upon administration. This effect was hypothesized to depend upon the compound’s penchant for oxygen donation. It has been suggested that the increase in oxygen concentration associated with the presence of ZnO
627:
interferes with the replicative processes of anaerobic and micro-aerophillic organisms, both of which require low oxygen environments for their survival. While this mechanism was sufficient to explain the stagnation of microbe populations, it did not account for the active reduction in colony size.
674:
Zinc peroxide is very hazardous in case of skin contact, of eye contact, or inhalation. Harmful if ingested in large quantities. It has been shown to be corrosive to skin. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Skin
675:
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Zinc peroxide is toxic to lungs and mucous membranes. Repeated or prolonged exposure can produce organ damage. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation.
467:
661:
was, as compared to the barium and strontium pyroingredients, that it causes less corrosion in the metallic materials which contain the compounds in the pyrotechnic instrument. In one modality it is necessary for zinc peroxide to act in conjunction with a reducer like
652:
was preferable to the usage of barium compounds, as it was deemed to be less toxic. The zinc compound proves an effective component in explosives because of its oxidizing properties. Many chemical explosives rely on rapid oxidation reactions, for this reason
578:
Zinc hydroxide is reacted with a mixture of hydrochloric acid and hydrogen peroxide and precipitated with sodium hydroxide also containing hydrogen peroxide to ensure a higher yield of zinc peroxide. Unlike in the preparation of
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382:
562:
in explosives and pyrotechnic mixtures. Its properties have been described as a transition between ionic and covalent peroxides. Zinc peroxide can be synthesized through the reaction of
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636:
Recently the compound has found use as a mineral stain for wood and other substances. The mechanism of this action involves the application of a metal salt (such as
241:
991:
727:
603:
was used as a disinfectant in surgical infections. Zinc peroxide was, however, deemed ineffective against certain bacterial strains, such as
492:
216:
599:
The treatment of burrowing ulcers in the abdominal wall with zinc peroxide was first recorded in 1933 and throughout the 1940s ZnO
648:
In the 1980s the discovery of zinc peroxide’s ability to complement pyrotechnical mixtures was discovered. It was noted that ZnO
591:
Since the 1930s zinc peroxide has been applied in a variety of settings, from medicine to aesthetics and even fireworks.
535:
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159:
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854:"The Antiseptic and Detoxifying Actions of Zinc Peroxide on Certain Aerobic, Anaerobic and Micro-aerophilic Bacteria"
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478:
406:
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R.D. Ayengar (1971). "ESR Studies on Zinc
Peroxide and Zinc Oxide Obtained from a Decomposition of Zinc Peroxide".
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554:) appears as a bright yellow powder at room temperature. It was historically used as a surgical
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A.L. Companion (1962). "The diffuse reflectance spectra of zinc oxide and zinc peroxide".
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777:"Synthesis, Thermal Stability and Properties of Zinc Peroxide Nanoparticles"
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S. Atmaca; et al. (1998). "The Effect of Zinc on
Microbial Growth".
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is an ideal candidate for use in pyrotechnics. Another advantage of ZnO
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439:
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Except where otherwise noted, data are given for materials in their
85:
75:
969:
932:
485:
973:
185:
817:
F. Meleney (1941). "Zinc
Peroxide in Surgical Infections".
583:, the zinc ion does not cause the peroxide to decompose.
462:
558:. More recently zinc peroxide has also been used as an
523:
1336:
1053:
1014:
1007:
312:212 °C (414 °F; 485 K) (decomposes)
147:
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61:
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8:
922:Mineral stains for wood and other substrates
1333:
1011:
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694:Journal of Physics and Chemistry of Solids
200:
107:
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877:
167:
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954:"Zinc Peroxide Material Safety Sheet"
228:Key: IPTOGCUGCFHDSS-UHFFFAOYSA-N
7:
138:
933:"Zinc Peroxide Pyrotechnic Patent"
903:Turkish Journal of Medical Science
14:
870:10.1097/00000658-193906000-00001
852:B. Johnson; et al. (1939).
831:10.1097/00000446-194106000-00004
513:
405:
400:
22:
819:The American Journal of Nursing
509:(at 25 °C , 100 kPa).
1:
714:10.1016/0022-3697(62)90205-6
225:InChI=1S/O2.Zn/c1-2;/q-2;+2
1542:
284:97.408 g/mol
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30:
21:
1337:Organozinc(II) compounds
1015:Organozinc(I) compounds
920:US Patent No. 6,905,520
292:white-yellowish powder
605:Streptococcus viridans
473:
609:staphylococcus aureus
472:
455:(fire diamond)
759:10.1021/j100689a009
728:"C&L Inventory"
706:1962JPCS...23.1685C
340:3.8 eV (indirect)
18:
536:Infobox references
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858:Annals of Surgery
796:10.1021/jp808714v
753:(20): 3089–3092.
700:(12): 1685–1688.
638:iron(II) chloride
568:hydrogen peroxide
544:Chemical compound
542:
541:
430:Hazard statements
352:Crystal structure
330:~7 (3% solution)
181:CompTox Dashboard
87:Interactive image
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1001:Zinc compounds
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864:(6): 881–911.
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17:Zinc peroxide
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632:Mineral stain
631:
629:
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621:B. pyocyoneus
618:
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594:
592:
586:
584:
582:
573:
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569:
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564:zinc chloride
561:
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549:
548:Zinc peroxide
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308:Melting point
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99:ECHA InfoCard
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957:. Retrieved
948:
937:. Retrieved
935:. 1982-12-14
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587:Applications
577:
547:
546:
451:
421:
383:
321:
46:Identifiers
40:zinc bioxide
38:zinc dioxide
36:Other names
595:Medical Use
574:Preparation
416:Signal word
364:Space group
289:Appearance
258:Properties
105:100.013.843
1510:Categories
959:2012-05-27
939:2016-07-21
679:References
617:B. proteus
556:antiseptic
395:Pictograms
345:Structure
302:1.57 g/cm
280:Molar mass
169:0I969DVM77
74:3D model (
53:CAS Number
1516:Peroxides
386:labelling
126:215-226-7
118:EC Number
63:1314-22-3
1383:Zn(CH(CH
1061:Zn(acac)
1054:Zinc(II)
888:17857377
839:75606177
804:53965473
452:NFPA 704
377:Hazards
336:Band gap
149:10129902
1399:Zn(C(CH
1008:Zinc(I)
879:1391281
702:Bibcode
613:E. coli
560:oxidant
529:what is
527: (
422:Warning
318:Acidity
298:Density
274:
136:PubChem
1214:Zn(OH)
1191:Zn(ClO
1113:Zn(ClO
1097:Zn(CN)
909:: 595.
886:
876:
837:
802:
670:Safety
619:, and
524:verify
521:
357:Cubic
242:SMILES
31:Names
1451:ZnICH
1371:Zn(CH
1343:Zn(CH
1165:Zn(NO
1157:ZnMoO
1125:ZnCrO
835:S2CID
800:S2CID
780:(PDF)
217:InChI
76:JSmol
1431:Zn(C
1415:Zn(C
1375:COO)
1355:Zn(C
1240:ZnTe
1235:ZnSe
1227:ZnSO
1105:ZnCl
1089:ZnCO
1081:ZnBr
1069:Zn(N
884:PMID
566:and
550:(ZnO
444:H319
440:H315
436:H271
160:UNII
1486:ZnO
1321:(PO
1309:ZnP
1222:ZnS
1182:ZnO
1177:ZnO
1149:ZnI
1141:ZnH
1133:ZnF
1030:(CH
874:PMC
866:doi
862:109
827:doi
792:doi
788:113
755:doi
710:doi
653:ZnO
384:GHS
270:ZnO
186:EPA
139:CID
1512::
1482:46
1473:24
1317:Zn
1297:Zn
1285:Zn
1277:As
1273:Zn
1265:Sb
1261:Zn
1245:Zn
1026:(C
1022:Zn
907:28
905:.
882:.
872:.
860:.
856:.
833:.
823:41
821:.
798:.
786:.
782:.
767:^
751:75
749:.
730:.
708:.
698:23
696:.
615:,
611:,
607:,
570:.
442:,
438:,
388::
369:Pa
327:)
320:(p
1491:4
1477:H
1468:C
1455:I
1453:2
1445:2
1443:)
1441:3
1439:O
1437:5
1435:H
1433:3
1425:2
1423:)
1421:5
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