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Adduct

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of the copper atoms within the structure. This reaction can also be considered a reaction between a base and a Lewis acid with the copper atom in the electron-receiving role and the
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is formed from a precursor ion and contains all of the constituent atoms of that ion as well as additional atoms or molecules. Adduct ions are often formed in a
81:. It can be considered as a single product resulting from the direct combination of different molecules which comprises all atoms of the reactant molecules. 434: 377: 218: 138:. Many Lewis acids and Lewis bases reacting in the gas phase or in non-aqueous solvents to form adducts have been examined in the 509: 277:. Upon formation of the adduct, a new extended phase is formed in which the gas molecules are incorporated (inserted) as 162:
on the tin and the ethyl groups on oxygen. But when the Lewis base is tetrahydrofuran, steric repulsion is reduced. The
504: 514: 185: 158:. For example: trimethyltin chloride, when reacting with diethyl ether, exhibits steric repulsion between the 151: 255: 248: 147: 402: 200: 364:
Housecroft, Catherine E.; Sharpe, Alan G. (2008). "Acids, bases and ions in aqueous solution".
451: 373: 369: 298: 274: 54: 432:(M = Al and Ga) upon Small-Molecule Binding and the Competitive Binding of CO and Ethylene". 482: 443: 410: 348: 244: 70: 66: 62: 53: 'drawn toward'; alternatively, a contraction of "addition product") is a product of a 428:
Capracotta, M. D.; Sullivan, R. M.; Martin, J. D. (2006). "Sorptive Reconstruction of CuMCl
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This article is about the chemical term. For the anatomical term of motion, see
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containing all atoms of all components. The resultant is considered a distinct
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Adducts are not necessarily molecular in nature. A good example from
225: 206: 93: 92:. A good example is the formation of adducts between the Lewis acid 294: 243:
Compounds or mixtures that cannot form an adduct because of
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are examples of Lewis acids that form adducts which exhibit
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Product of direct addition of two or more distinct molecules
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Ball and stick diagram of the Lewis adduct between BH
393:Vogel G. C.; Drago, R. S. (1996). "The ECW Model". 285:of the gas molecule in the electron-donating role. 166:can provide a measure of these steric effects. 8: 168: 273:. The latter is a solid with an extended 435:Journal of the American Chemical Society 269: 152:bis(hexafluoroacetylacetonato)copper(II) 134: 130: 126: 122: 111: 107: 103: 96:and the oxygen atom in the Lewis bases, 327: 181: 7: 69:. Examples include the addition of 474:Compendium of Chemical Terminology 340:Compendium of Chemical Terminology 25: 479:adduct ion (in mass spectrometry) 217: 199: 184: 368:(3rd ed.). Harlow, Essex: 1: 395:Journal of Chemical Education 84:Adducts often form between 531: 29: 61:, resulting in a single 57:of two or more distinct 487:10.1351/goldbook.A00139 353:10.1351/goldbook.A00138 249:frustrated Lewis pairs 510:Solid-state chemistry 256:solid-state chemistry 224:Lewis adduct between 148:trimethyltin chloride 442:(41): 13463–13473. 407:1996JChEd..73..701V 366:Inorganic Chemistry 177: 505:Chemical reactions 258:is the adducts of 169: 515:General chemistry 448:10.1021/ja063172q 415:10.1021/ed073p701 379:978-0-13-175553-6 370:Pearson Education 299:mass spectrometer 275:lattice structure 241: 240: 67:molecular species 16:(Redirected from 522: 489: 466: 460: 459: 425: 419: 418: 390: 384: 383: 361: 355: 332: 272: 245:steric hindrance 221: 203: 188: 178: 137: 114: 71:sodium bisulfite 63:reaction product 21: 530: 529: 525: 524: 523: 521: 520: 519: 495: 494: 493: 492: 467: 463: 431: 427: 426: 422: 392: 391: 387: 380: 372:. p. 199. 363: 362: 358: 333: 329: 324: 307: 291: 271: 267: 264:carbon monoxide 235: 229: 222: 213: 210: 204: 195: 189: 174: 144:Trimethylborane 136: 132: 128: 124: 120: 113: 109: 105: 101: 98:tetrahydrofuran 55:direct addition 35: 28: 23: 22: 15: 12: 11: 5: 528: 526: 518: 517: 512: 507: 497: 496: 491: 490: 461: 429: 420: 401:(8): 701–707. 385: 378: 356: 326: 325: 323: 320: 319: 318: 313: 306: 303: 290: 287: 239: 238: 237: 236: 227: 223: 216: 214: 208: 205: 198: 196: 190: 183: 172: 156:steric effects 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 527: 516: 513: 511: 508: 506: 503: 502: 500: 488: 484: 480: 476: 475: 470: 465: 462: 457: 453: 449: 445: 441: 437: 436: 424: 421: 416: 412: 408: 404: 400: 396: 389: 386: 381: 375: 371: 367: 360: 357: 354: 350: 346: 342: 341: 336: 331: 328: 321: 317: 314: 312: 309: 308: 304: 302: 300: 296: 288: 286: 284: 280: 276: 265: 261: 257: 252: 250: 246: 234: 230: 220: 215: 211: 202: 197: 193: 187: 182: 180: 179: 176: 167: 165: 161: 160:methyl groups 157: 153: 149: 145: 141: 118: 117:diethyl ether 99: 95: 91: 87: 82: 80: 76: 72: 68: 64: 60: 56: 52: 48: 44: 40: 33: 19: 472: 464: 439: 433: 423: 398: 394: 388: 365: 359: 338: 330: 301:ion source. 292: 283:pi electrons 253: 242: 170: 83: 50: 42: 36: 311:Adductomics 289:Adduct ions 247:are called 90:Lewis bases 86:Lewis acids 499:Categories 322:References 316:DNA adduct 293:An adduct 125:·O(CH 106:·O(CH 77:to give a 45:(from 164:ECW model 140:ECW model 79:sulfonate 59:molecules 39:chemistry 32:adduction 456:17031959 305:See also 260:ethylene 212:molecule 194:molecule 75:aldehyde 51:adductus 403:Bibcode 279:ligands 175:and THF 100:(THF): 18:Adducts 454:  376:  345:adduct 268:CuAlCl 94:borane 73:to an 43:adduct 469:IUPAC 335:IUPAC 49: 47:Latin 41:, an 452:PMID 374:ISBN 231:and 150:and 88:and 483:doi 481:". 444:doi 440:128 411:doi 349:doi 347:". 295:ion 266:of 262:or 233:THF 192:THF 115:or 37:In 501:: 471:, 450:. 438:. 409:. 399:73 397:. 337:, 251:. 226:BH 207:BH 146:, 142:. 129:CH 121:BH 119:: 102:BH 485:: 458:. 446:: 430:4 417:. 413:: 405:: 382:. 351:: 270:4 228:3 209:3 173:3 135:2 133:) 131:2 127:3 123:3 112:4 110:) 108:2 104:3 34:. 20:)

Index

Adducts
adduction
chemistry
Latin
direct addition
molecules
reaction product
molecular species
sodium bisulfite
aldehyde
sulfonate
Lewis acids
Lewis bases
borane
tetrahydrofuran
diethyl ether
ECW model
Trimethylborane
trimethyltin chloride
bis(hexafluoroacetylacetonato)copper(II)
steric effects
methyl groups
ECW model
THF molecule
THF
BH3 molecule
BH3
Lewis adduct between BH3 and THF
BH3
THF

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