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Hydroxy group

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161: 38: 356:. The SOFIA Faint Object infrared Camera for the SOFIA Telescope (FORCAST) detected emission bands at a wavelength of 6.1 micrometers that are present in water but not in hydroxyl. The abundance of water on the Moon's surface was inferred to be equivalent to the contents of a 12-ounce bottle of water per cubic meter of lunar soil. 384:
reported measurements of night-side airglow emission in the atmosphere of Venus made with the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on Venus Express. They attributed emission bands in wavelength ranges of 1.40 - 1.49 micrometers and 2.6 - 3.14 micrometers
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probe, which landed on the Moon on 1 December 2020, carried a mineralogical spectrometer that could measure infrared reflectance spectra of lunar rock and regolith. The reflectance spectrum of a rock sample at a wavelength of 2.85 micrometers indicated localized water/hydroxyl concentrations as
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Stevanus K. Nugroho; Hajime Kawahara; Neale P. Gibson; Ernst J. W. de Mooij; Teruyuki Hirano; Takayuki Kotani; Yui Kawashima; Kento Masuda; Matteo Brogi; Jayne L. Birkby; Chris A. Watson; Motohide Tamura; Konstanze Zwintz; Hiroki Harakawa; Tomoyuki Kudo; Masayuki Kuzuhara; Klaus Hodapp; Masato
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Clancy RT, Sandor BJ, García-Muñoz A, Lefèvre F, Smith MD, Wolff MJ, Montmessin F, Murchie SL, Nair H (2013). "First detection of Mars atmospheric hydroxyl: CRISM Near-IR measurement versus LMD GCM simulation of OH Meinel band emission in the Mars polar winter atmosphere".
294:, that is produced by radiative transitions of atoms and molecules. Among the most intense such features observed in the Earth's night sky is a group of infrared transitions at wavelengths between 700 nanometers and 900 nanometers. In 1950, 264:
Hydroxyl radicals are highly reactive and undergo chemical reactions that make them short-lived. When biological systems are exposed to hydroxyl radicals, they can cause damage to cells, including those in humans, where they can react with
538:"Literature review of the role of hydroxyl radicals in chemically-induced mutagenicity and carcinogenicity for the risk assessment of a disinfection system utilizing photolysis of hydrogen peroxide" 879:
Piccioni, G.; Drossart, P.; Zasova, L.; Migliorini, A.; Gérard, J.-C.; Mills, F. P.; Shakun, A.; García Muñoz, A.; Ignatiev, N.; Grassi, D.; Cottini, V.; Taylor, F. W.; Erard, S. (2008-04-01).
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detected an infrared absorption at a wavelength of 3.0 micrometers that only water or hydroxyl—a hydrogen and an oxygen bound together—could have created."
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due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular
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Honniball CI, Lucey PG, Li S, Shenoy S, Orlando TM, Hibbitts CA, Hurley DM, Farrell WM (2020). "Molecular water detected on the sunlit Moon by SOFIA".
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Ishizuka; Shane Jacobson; Mihoko Konishi; Takashi Kurokawa; Jun Nishikawa; Masashi Omiya; Takuma Serizawa; Akitoshi Ueda; Sébastien Vievard (2021).
187:. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by 2047: 504: 183:
increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this
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or other organic moiety, the red and grey spheres represent oxygen and hydrogen atoms respectively, and the rod-like connections between these,
969:"First Detection of Hydroxyl Radical Emission from an Exoplanet Atmosphere: High-dispersion Characterization of {WASP}-33b Using Subaru/{IRD}" 1087: 700: 681: 819:
Lin H, Li S, Xu R, Liu Y, Wu X, Yang W, Wei Y, Lin Y, He Z, Hui H, He K, Hu S, Zhang C, Li C, Lv G, Yuan L, Zou Y, Wang C (2022).
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Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The joining of a
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was found in its emission spectrum at wavelengths between 1 and 2 micrometers. Evidence for OH in the atmosphere of exoplanet
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The hydroxy group is pervasive in chemistry and biochemistry. Many inorganic compounds contain hydroxyl groups, including
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to vibrational transitions of OH. This was the first evidence for OH in the atmosphere of any planet other than Earth's.
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In 2013, OH near-infrared spectra were observed in the night glow in the polar winter atmosphere of Mars by use of the
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Kanno, Taro; Nakamura, Keisuke; Ikai, Hiroyo; Kikuchi, Katsushi; Sasaki, Keiichi; Niwano, Yoshimi (July 2012).
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reported definitive evidence of water on the sunlit surface of the Moon, in the vicinity of the crater
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R. Landman; A. Sánchez-López; P. Mollière; A. Y. Kesseli; A. J. Louca; I. A. G. Snellen (2021).
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and it is likely that any water in their atmospheres is present as dissociated ions.
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This article is about the hydroxy functional group. For the Hydroxyl radical, see
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removes the −OH from the carboxy end of the fatty acid. The joining of two
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each detected evidence of water by evidence of hydroxyl fragments on the
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Ludwig Maximilians Universität München Fakultät für Chemie und Pharmazie
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science data from April 2006 until December 2014. In 2008, Piccioni,
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Reece J, Urry L, Cain M, Wasserman S, Minorsky P, Jackson R (2011).
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In 2021, evidence for OH in the dayside atmosphere of the exoplanet
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showed that these were transitions of the hydroxyl molecule, OH.
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contain one or more hydroxy groups. Both the negatively charged
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The Earth's night sky is illuminated by diffuse light, called
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removes the −OH from the carboxy group of one amino acid.
881:"First detection of hydroxyl in the atmosphere of Venus" 796:"NASA's SOFIA Discovers Water on Sunlit Surface of Moon" 354:
Stratospheric Observatory for Infrared Astronomy (SOFIA)
650:"OH Emission Bands in the Spectrum of the Night Sky. I" 341:
emission spectrum consistent with hydroxyl presence.
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Compact Reconnaissance Imaging Spectrometer for Mars
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National Aeronautics and Space Administration (NASA)
1978: 1898: 1875: 1837: 1814: 1709: 1630: 1500: 1477: 1433: 1376: 1299: 1274: 1139: 1013:"Detection of OH in the ultra-hot Jupiter WASP-76b" 542:Journal of Clinical Biochemistry and Nutrition 230:removes the −OH from the carboxy group at the 1117: 8: 723:"LCROSS Impact Data Indicates Water on Moon" 1497: 1296: 1124: 1110: 1102: 1078:. In Berge S, Golden B, Triglia L (eds.). 1046: 1028: 987: 906: 896: 852: 675: 665: 612: 571: 553: 481: 129:, consist of an unbonded hydroxy group. 461: 7: 794:Chou F, Hawkes A (26 October 2020). 697:"A Whiff of Water Found on the Moon" 45:hydroxy group, where R represents a 144:) only, while the functional group 684:from the original on Oct 24, 2022. 325:. As reported by Richard Kerr, "A 25: 637:from the original on Oct 5, 2023. 703:from the original on Dec 8, 2023 140:refers to the hydroxyl radical ( 364:high as 180 parts per million. 333:also reported in 2009 that the 1: 976:Astrophysical Journal Letters 695:Kerr RA (24 September 2009). 597:"Night airglow phenomenology" 595:Silverman SM (October 1970). 505:"Research Report 2012 – 2013" 413:was subsequently found. Both 953:10.1016/j.icarus.2013.05.035 891:(3). EDP Sciences: L29–L33. 885:Astronomy & Astrophysics 476:. IUPAC. February 24, 2014. 167:contains two hydroxy groups. 1048:10.1051/0004-6361/202141696 898:10.1051/0004-6361:200809761 721:Dino J (13 November 2009). 2097: 1017:Astronomy and Astrophysics 773:10.1038/s41550-020-01222-x 257: 29: 2019: 989:10.3847/2041-8213/abec71 2030:chemical classification 1039:2021A&A...656A.119L 483:10.1351/goldbook.A00204 845:10.1126/sciadv.abl9174 281:Planetary observations 168: 136:definitions, the term 57: 2037:chemical nomenclature 654:Astrophysical Journal 601:Space Science Reviews 163: 41:Representation of an 40: 344:On 26 October 2020, 286:Airglow of the Earth 238:. The creation of a 83:and composed of one 27:Chemical group (–OH) 1493:not C, H or O) 945:2013Icar..226..272T 837:2022SciA....8.9174L 765:2021NatAs...5..121H 667:1950ApJ...111..555M 614:1970SSRv...11..341S 555:10.3164/jcbn.11-105 368:Atmosphere of Venus 302:Surface of the Moon 1935:Hypervalent iodine 648:Meinel AB (1950). 623:10.1007/BF00241526 423:ultra-hot Jupiters 389:Atmosphere of Mars 376:orbiter collected 352:, obtained by the 337:probe revealed an 315:Cassini spacecraft 310:satellite and the 169: 118:, and the neutral 58: 2076:Functional groups 2058: 2057: 1996:Sulfenyl chloride 1974: 1973: 1473: 1472: 1292:(only C, H and O) 1133:Functional groups 1089:978-0-321-55823-7 1076:"Chapter 4&5" 319:Deep Impact probe 306:In 2009, India's 171:Water, alcohols, 97:organic chemistry 89:covalently bonded 16:(Redirected from 2088: 2025: 1930:Trifluoromethoxy 1498: 1494: 1297: 1293: 1146: 1126: 1119: 1112: 1103: 1093: 1080:Campbell Biology 1061: 1060: 1050: 1032: 1008: 1002: 1001: 991: 973: 963: 957: 956: 927: 921: 920: 910: 900: 876: 867: 866: 856: 825:Science Advances 816: 810: 809: 807: 806: 791: 785: 784: 753:Nature Astronomy 748: 742: 741: 739: 738: 729:. Archived from 718: 712: 711: 709: 708: 692: 686: 685: 679: 669: 645: 639: 638: 616: 592: 586: 585: 575: 557: 533: 527: 526: 524: 518:. Archived from 509: 501: 495: 494: 492: 490: 485: 466: 350:Clavius (crater) 260:Hydroxyl radical 254:Hydroxyl radical 185:functional group 181:hydrogen bonding 173:carboxylic acids 147: 143: 127:hydroxyl radical 124: 113: 105:carboxylic acids 82: 78:chemical formula 74:functional group 43:organic compound 32:Hydroxyl radical 21: 2096: 2095: 2091: 2090: 2089: 2087: 2086: 2085: 2061: 2060: 2059: 2054: 2023: 2015: 1970: 1925:Trichloromethyl 1920:Trifluoromethyl 1894: 1871: 1833: 1810: 1705: 1674:Phosphine oxide 1626: 1492: 1490: 1489: 1487: 1485: 1483: 1481: 1479: 1469: 1429: 1372: 1291: 1290: 1285: 1280: 1270: 1144: 1143: 1135: 1130: 1100: 1090: 1073: 1070: 1065: 1064: 1010: 1009: 1005: 971: 965: 964: 960: 929: 928: 924: 878: 877: 870: 831:(1): eabl9174. 818: 817: 813: 804: 802: 793: 792: 788: 750: 749: 745: 736: 734: 720: 719: 715: 706: 704: 694: 693: 689: 647: 646: 642: 594: 593: 589: 535: 534: 530: 525:on Dec 7, 2022. 522: 507: 503: 502: 498: 488: 486: 468: 467: 463: 458: 431: 403: 391: 370: 304: 288: 283: 262: 256: 224:aldehyde sugars 220:triacylglycerol 201: 158: 145: 141: 125:, known as the 122: 111: 80: 35: 28: 23: 22: 15: 12: 11: 5: 2094: 2092: 2084: 2083: 2078: 2073: 2063: 2062: 2056: 2055: 2053: 2052: 2051: 2050: 2045: 2033: 2026: 2020: 2017: 2016: 2014: 2013: 2011:Sulfinylamines 2008: 2003: 1998: 1993: 1991:Phosphoramides 1988: 1986:Isothiocyanate 1982: 1980: 1976: 1975: 1972: 1971: 1969: 1968: 1963: 1962: 1961: 1951: 1950: 1949: 1939: 1938: 1937: 1932: 1927: 1922: 1917: 1906: 1904: 1896: 1895: 1893: 1892: 1887: 1881: 1879: 1873: 1872: 1870: 1869: 1864: 1862:Selenenic acid 1859: 1857:Seleninic acid 1854: 1852:Selenonic acid 1849: 1843: 1841: 1835: 1834: 1832: 1831: 1826: 1820: 1818: 1812: 1811: 1809: 1808: 1803: 1798: 1793: 1788: 1783: 1778: 1773: 1768: 1763: 1758: 1753: 1748: 1743: 1738: 1733: 1732: 1731: 1721: 1715: 1713: 1707: 1706: 1704: 1703: 1698: 1693: 1688: 1687: 1686: 1676: 1671: 1666: 1661: 1660: 1659: 1649: 1648: 1647: 1645:Phosphodiester 1636: 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452: 447: 442: 437: 430: 427: 402: 399: 390: 387: 369: 366: 303: 300: 287: 284: 282: 279: 258:Main article: 255: 252: 200: 197: 157: 154: 70:hydroxyl group 54:chemical bonds 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 2093: 2082: 2079: 2077: 2074: 2072: 2069: 2068: 2066: 2049: 2046: 2044: 2041: 2040: 2039: 2038: 2034: 2032: 2031: 2027: 2022: 2021: 2018: 2012: 2009: 2007: 2004: 2002: 1999: 1997: 1994: 1992: 1989: 1987: 1984: 1983: 1981: 1977: 1967: 1964: 1960: 1957: 1956: 1955: 1952: 1948: 1945: 1944: 1943: 1940: 1936: 1933: 1931: 1928: 1926: 1923: 1921: 1918: 1916: 1913: 1912: 1911: 1908: 1907: 1905: 1903: 1902: 1897: 1891: 1890:Telluroketone 1888: 1886: 1883: 1882: 1880: 1878: 1874: 1868: 1865: 1863: 1860: 1858: 1855: 1853: 1850: 1848: 1845: 1844: 1842: 1840: 1836: 1830: 1827: 1825: 1822: 1821: 1819: 1817: 1813: 1807: 1804: 1802: 1799: 1797: 1794: 1792: 1789: 1787: 1784: 1782: 1779: 1777: 1776:Sulfonic acid 1774: 1772: 1769: 1767: 1766:Sulfinic acid 1764: 1762: 1761:Thiosulfonate 1759: 1757: 1754: 1752: 1751:Thiosulfinate 1749: 1747: 1746:Sulfenic acid 1744: 1742: 1739: 1737: 1734: 1730: 1727: 1726: 1725: 1722: 1720: 1717: 1716: 1714: 1712: 1708: 1702: 1701:Phosphaallene 1699: 1697: 1696:Phosphaalkyne 1694: 1692: 1691:Phosphaalkene 1689: 1685: 1682: 1681: 1680: 1677: 1675: 1672: 1670: 1667: 1665: 1662: 1658: 1655: 1654: 1653: 1650: 1646: 1643: 1642: 1641: 1638: 1637: 1635: 1633: 1629: 1623: 1620: 1618: 1615: 1613: 1610: 1608: 1605: 1603: 1600: 1598: 1595: 1593: 1590: 1588: 1585: 1583: 1580: 1578: 1575: 1573: 1570: 1568: 1565: 1563: 1560: 1558: 1555: 1553: 1550: 1548: 1545: 1543: 1540: 1538: 1535: 1533: 1530: 1528: 1525: 1521: 1518: 1516: 1513: 1512: 1511: 1508: 1507: 1505: 1503: 1499: 1496: 1476: 1464: 1461: 1460: 1459: 1456: 1452: 1449: 1447: 1444: 1443: 1442: 1439: 1438: 1436: 1432: 1426: 1423: 1421: 1418: 1414: 1411: 1410: 1409: 1406: 1402: 1399: 1397: 1394: 1392: 1389: 1388: 1387: 1384: 1383: 1381: 1379: 1375: 1369: 1366: 1364: 1363:Ethylenedioxy 1361: 1357: 1354: 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1141:Hydrocarbons 1079: 1020: 1016: 1006: 979: 975: 961: 936: 932: 925: 888: 884: 828: 824: 814: 803:. 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Science. 660:: 555–564. 548:(1): 9–14. 339:ultraviolet 296:Aden Meinel 244:amino acids 234:end of one 47:hydrocarbon 2081:Hydroxides 2065:Categories 1910:Haloalkane 1781:Thioketone 1736:Persulfide 1632:Phosphorus 1597:Isocyanate 1587:Isonitrile 1488:or oxygen 1486:hydrogen, 1482:not being 1463:Orthoester 1356:Dioxiranes 1334:Enol ether 1222:1-Propenyl 1030:2110.11946 908:1885/35639 805:2020-10-26 737:2009-11-14 707:2016-06-01 470:"Alcohols" 456:References 401:Exoplanets 246:to make a 226:to form a 218:to form a 212:fatty acid 199:Occurrence 193:amino acid 156:Properties 2043:inorganic 1877:Tellurium 1791:Thioester 1756:Sulfoxide 1741:Disulfide 1729:Sulfonium 1679:Phosphine 1657:Phosphite 1640:Phosphate 1572:Carbamate 1547:Hydrazone 1480:element, 1478:Only one 1451:Anhydride 1190:Methylene 1057:239616465 998:232110452 982:(1): L9. 917:0004-6361 781:228954129 631:120677542 564:0912-0009 474:Gold Book 435:Hydronium 397:(CRISM). 361:Chang'e 5 116:hydroxide 114:, called 95:atom. 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Index

Hydroxyl
Hydroxyl radical

organic compound
hydrocarbon
covalent
chemical bonds
chemistry
functional group
chemical formula
oxygen
covalently bonded
hydrogen
organic chemistry
alcohols
carboxylic acids
anion
hydroxide
radical
hydroxyl radical
IUPAC

Sulfuric acid
carboxylic acids
deprotonated
hydrogen bonding
functional group
sugars
amino acid
sulfuric acid

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