93:
1122:
46:
814:
549:
C, which is present in steels. These carbides are more reactive than the interstitial carbides; for example, the carbides of Cr, Mn, Fe, Co and Ni are all hydrolysed by dilute acids and sometimes by water, to give a mixture of hydrogen and hydrocarbons. These compounds share features with both the
164:
C type structure described above, which is only an approximate description of the actual structures. The simple view that the lattice of the pure metal "absorbs" carbon atoms can be seen to be untrue as the packing of the metal atom lattice in the carbides is different from the packing in the pure
1651:
Weiss, Erwin; Corbelin, Siegfried; Cockcroft, Jeremy Karl; Fitch, Andrew
Nicholas (1990). "Über Metallalkyl- und -aryl-Verbindungen, 44 Darstellung und Struktur von Methylnatrium. Strukturbestimmung an NaCD3-Pulvern bei 1.5 und 300 K durch Neutronen- und Synchrotronstrahlenbeugung".
159:
The following table shows structures of the metals and their carbides. (N.B. the body centered cubic structure adopted by vanadium, niobium, tantalum, chromium, molybdenum and tungsten is not a close-packed lattice.) The notation "h/2" refers to the
151:, (hcp), as the octahedral interstices lie directly opposite each other on either side of the layer of metal atoms, filling only one of these with carbon achieves 2:1 stoichiometry with the CdI
2712:
132:
The long-held view is that the carbon atoms fit into octahedral interstices in a close-packed metal lattice when the metal atom radius is greater than approximately 135 pm:
1297:
Kunst, Helmut; Haase, Brigitte; Malloy, James C.; Wittel, Klaus; Nestler, Montia C.; Nicoll, Andrew R.; Erning, Ulrich; Rauscher, Gerhard (2006). "Metals, Surface
Treatment".
2988:
774:
Transition metal carbides are not saline: their reaction with water is very slow and is usually neglected. For example, depending on surface porosity, 5–30 atomic layers of
1299:
1525:
Y. C. Zhou; H. Y. Dong; B. H. Yu (2000). "Development of two-dimensional titanium tin carbide (Ti2SnC) plates based on the electronic structure investigation".
1256:, where gas chlorination of metallic carbides removes metal molecules to form a highly porous, near-pure carbon material capable of high-density energy storage.
2705:
561:, are believed not to form carbides under any circumstances. There exists however a mixed titanium-tin carbide, which is a two-dimensional conductor.
2981:
2698:
785:
Note that methanide in this context is a trivial historical name. According to the IUPAC systematic naming conventions, a compound such as NaCH
1399:
1371:
39:
511:
phases were believed to be disordered with a random filling of the interstices, however short and longer range ordering has been detected.
2974:
1731:
1316:
165:
metal, although it is technically correct that the carbon atoms fit into the octahedral interstices of a close-packed metal lattice.
2909:
1259:
684:
do not. These materials feature isolated carbon centers, often described as "C", in the methanides or methides; two-atom units, "
1229:
713:
1093:
C, on the other hand, has an unusual structure which includes icosahedral boron units linked by carbon atoms. In this respect
2721:
1420:"Anisotropic lattice expansion and enhancement of superconductivity induced by interstitial carbon doping in Rhenium"
1390:
Peter
Ettmayer; Walter Lengauer (1994). "Carbides: transition metal solid state chemistry". In R. Bruce King (ed.).
1081:
are described as "covalent carbides", although virtually all compounds of carbon exhibit some covalent character.
1498:
1253:
105:
The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as
2238:
2060:
2628:
2512:
1724:
1502:
2334:
1980:
1418:
Zhu, Qinqing; Xiao, Guorui; Cui, Yanwei; Yang, Wuzhang; Wu, Siqi; Cao, Guang-Han; Ren, Zhi (2021-10-15).
3212:
2638:
2568:
2552:
2528:
2391:
2114:
2101:
1992:
1240:
1146:
582:
140:, (ccp), then filling all of the octahedral interstices with carbon achieves 1:1 stoichiometry with the
106:
2600:
2520:
2220:
2134:
1916:
1577:
O.O. Kurakevych; T.A. Strobel; D.Y. Kim; G.D. Cody (2013). "Synthesis of Mg2C: A Magnesium
Methanide".
750:
2544:
2536:
2403:
2374:
2317:
2169:
2139:
2068:
2006:
1419:
949:
has been described in terms of La with the extra electron delocalised into the antibonding orbital on
2592:
2576:
2560:
2379:
2365:
2347:
2294:
2258:
2229:
2191:
2048:
1963:
1958:
1891:
1859:
1534:
637:
291:
2584:
2504:
2356:
2263:
2096:
1827:
1709:
1459:"Order and disorder in transition metal carbides and nitrides: experimental and theoretical aspects"
731:
Methanides are a subset of carbides distinguished by their tendency to decompose in water producing
2739:
2616:
2152:
1887:
1203:
886:
141:
2122:
2794:
2690:
2277:
2206:
1779:
1633:
1550:
1480:
508:
1109:. Both materials are important industrially. Boron also forms other covalent carbides, such as B
3294:
2839:
2819:
2643:
2620:
2496:
2196:
2181:
2144:
2110:
1946:
1925:
1875:
1799:
1717:
1669:
1594:
1439:
1395:
1367:
1312:
943:
929:
871:
761:
736:
669:
624:
C), each used in key industrial applications. The naming of ionic carbides is not systematic.
576:
3051:
3058:
2811:
2789:
2773:
2765:
2342:
2330:
2043:
2038:
1970:
1951:
1941:
1904:
1696:
1661:
1625:
1586:
1542:
1470:
1431:
1353:
1304:
890:
775:
609:
589:
126:
122:
96:
50:
35:
3299:
2851:
2827:
2781:
2757:
2744:
2633:
2325:
2201:
2159:
1996:
1937:
1864:
1787:
1082:
1038:
936:
863:
817:
649:
605:
597:
118:
114:
1613:
1538:
789:
would be termed a "methanide", although this compound is often called methylsodium. See
3304:
3000:
2940:
2935:
2799:
2749:
2306:
2284:
2246:
1868:
1816:
1363:
1278:
1173:
970:
851:
719:, prepared from vapour of potassium and graphite, and the alkali metal derivatives of C
31:
3288:
2997:
2945:
1808:
1637:
1554:
1094:
1086:
1011:
843:
148:
137:
1484:
1085:
has two similar crystalline forms, which are both related to the diamond structure.
3181:
3076:
2408:
1763:
1169:
1156:
790:
633:
65:
1435:
1308:
2893:
1357:
1176:
and the early metal halides. A few terminal carbides have been isolated, such as
782:
within 5 minutes at ambient conditions, following by saturation of the reaction.
3028:
2950:
2883:
81:
632:
Salt-like carbides are composed of highly electropositive elements such as the
92:
3166:
3159:
2084:
1687:
Fjellvag H.; Pavel K. (1992). "Crystal
Structure of Magnesium Sesquicarbide".
1235:
1106:
1046:
847:
641:
446:
110:
73:
45:
1673:
1665:
1443:
1225:
In addition to the carbides, other groups of related carbon compounds exist:
569:
Carbides can be generally classified by the chemical bonds type as follows:
3177:
3145:
3124:
3099:
3044:
2966:
2955:
2930:
2914:
2888:
2076:
1475:
1458:
894:
824:
697:
665:
617:
542:
236:
57:
1598:
1590:
877:. Lanthanides also form carbides (sesquicarbides, see below) with formula M
129:, are important industrially and are used to coat metals in cutting tools.
1546:
3272:
3251:
3244:
3219:
3205:
3152:
3128:
3113:
3106:
3092:
3065:
3008:
1852:
1836:
839:
681:
661:
653:
645:
480:
393:
358:
286:
211:
99:
1700:
1246:
metallacarbohedrenes (met-cars) which are cluster compounds containing C
1121:
846:
between the two carbon atoms. Alkali metals, alkaline earth metals, and
117:, being a non-stoichiometric mixture of various carbides arising due to
3258:
3230:
3198:
3138:
3017:
2878:
2873:
1848:
1756:
1629:
779:
732:
673:
657:
323:
261:
17:
3265:
3234:
3037:
2724:
1832:
1266:
1098:
677:
69:
3191:
1243:, where the metal atom is encapsulated within a fullerene molecule
1120:
1078:
813:
812:
91:
44:
1057:, on hydrolysis, which was the first indication that it contains
1504:
The
Metallurgy of Lead, including Desiverization and Cupellation
554:
84:
is the process for producing carbide coatings on a metal piece.
34:. For the metallic compound commonly used in machine tools, see
30:
For the software development tool targeting the
Symbian OS, see
2970:
2694:
1713:
1149:. Most common are carbon-centered octahedral clusters, such as
1612:
A. I. Avgustinik; G. V. Drozdetskaya; S. S. Ordan'yan (1967).
558:
550:
inert interstitials and the more reactive salt-like carbides.
1206:(or "met-cars") are stable clusters with the general formula
885:. Metals from group 11 also tend to form acetylides, such as
924:
The C–C triple bond length ranges from 119.2 pm in CaC
3229:
3176:
3123:
3075:
3027:
3007:
2923:
2902:
2860:
2732:
109:. These carbides have metallic properties and are
1217:where M is a transition metal (Ti, Zr, V, etc.).
909:, are also described as salt-like derivatives of
1105:) and boron carbide are very hard materials and
823:Several carbides are assumed to be salts of the
1300:Ullmann's Encyclopedia of Industrial Chemistry
2982:
2706:
1725:
1567:Shriver and Atkins — Inorganic Chemistry
8:
1348:
1346:
1344:
1342:
1340:
1338:
1336:
1334:
1332:
1330:
1328:
1265:two-dimensional transition metal carbides:
2989:
2975:
2967:
2713:
2699:
2691:
1732:
1718:
1710:
1385:
1383:
1172:) and . Similar species are known for the
1145:Metal complexes containing C are known as
1614:"Reaction of titanium carbide with water"
1474:
928:(similar to ethyne), to 130.3 pm in
838:(also called percarbide, by analogy with
1213:
1209:
1195:
1191:
1187:
1183:
1179:
1163:
1159:
1152:
1136:
1132:
1128:
1033:
1029:
1006:
1002:
995:
991:
766:
755:
745:
741:
723:are not usually classified as carbides.
616:when referring to machine tooling), and
536:
529:
525:
517:
167:
1579:Angewandte Chemie International Edition
1457:C.H. de Novion; J.P. Landesman (1985).
1289:
1769:
1740:Salts and covalent derivatives of the
1101:. Both silicon carbide (also known as
961:, explaining the metallic conduction.
2485:
1413:
1411:
40:Carbide, Wetzel County, West Virginia
38:. For the town in West Virginia, see
7:
1752:
1618:Powder Metallurgy and Metal Ceramics
1392:Encyclopedia of Inorganic Chemistry
628:Salt-like / saline / ionic carbides
565:Chemical classification of carbides
1260:transition metal carbene complexes
714:graphite intercalation compound KC
25:
514:Iron forms a number of carbides,
2910:Graphite intercalation compounds
1230:graphite intercalation compounds
88:Interstitial / Metallic carbides
1507:. London: J. Murray. p. 67
1424:Journal of Alloys and Compounds
1141:, containing a carbon-gold core
793:for more information about the
1527:Materials Research Innovations
850:form acetylides, for example,
1:
1436:10.1016/j.jallcom.2021.160290
1309:10.1002/14356007.a16_403.pub2
1097:is similar to the boron rich
897:, which have stoichiometry MC
1077:The carbides of silicon and
1010:. The ion is linear and is
612:(WC; often called, simply,
3321:
2487:
121:. Some of them, including
113:. Some exhibit a range of
29:
1771:
1749:
1394:. John Wiley & Sons.
1359:Chemistry of the Elements
1356:; Earnshaw, Alan (1984).
1254:tunable nanoporous carbon
1168:(where "Ph" represents a
791:Methyl group#Methyl anion
712:", in the allylides. The
700:; and three-atom units, "
147:When the metal atoms are
136:When the metal atoms are
1666:10.1002/cber.19901230807
1018:. The C–C distance in Mg
778:are hydrolyzed, forming
174:Structure of pure metal
27:Inorganic compound group
1476:10.1351/pac198557101391
1303:. Weinheim: Wiley-VCH.
1147:metal carbido complexes
2722:Inorganic compounds of
1591:10.1002/anie.201303463
1142:
820:
583:interstitial compounds
149:hexagonal close-packed
107:interstitial compounds
102:
53:
1547:10.1007/s100190000065
1241:endohedral fullerenes
1124:
816:
735:. Three examples are
638:alkaline earth metals
553:Some metals, such as
95:
49:Lattice structure of
48:
1354:Greenwood, Norman N.
1204:Metallocarbohedrynes
809:Acetylides/ethynides
668:from group 13 forms
541:. The best known is
507:For a long time the
64:usually describes a
1701:10.1021/ic00041a018
1539:2000MatRI...4...36Z
1366:. pp. 318–22.
984:, sometimes called
935:and 134 pm in
887:copper(I) acetylide
196:metal atom packing
184:metal atom packing
142:rock salt structure
2924:Oxides and related
1654:Chemische Berichte
1630:10.1007/BF00780135
1143:
1117:Molecular carbides
1026:is 133.2 pm.
893:. Carbides of the
821:
577:covalent compounds
573:salt-like (ionic),
509:non-stoichiometric
138:cubic close-packed
103:
54:
3282:
3281:
2964:
2963:
2688:
2687:
2682:
2681:
1585:(34): 8930–8933.
1401:978-0-471-93620-6
1373:978-0-08-022057-4
1221:Related materials
1073:Covalent carbides
942:. The bonding in
895:actinide elements
848:lanthanoid metals
762:beryllium carbide
751:magnesium carbide
737:aluminium carbide
596:Examples include
505:
504:
72:and a metal. In
16:(Redirected from
3312:
3275:
3268:
3261:
3254:
3247:
3222:
3215:
3208:
3201:
3194:
3169:
3162:
3155:
3148:
3141:
3116:
3109:
3102:
3095:
3088:
3068:
3061:
3054:
3047:
3040:
3020:
2991:
2984:
2977:
2968:
2727:and related ions
2715:
2708:
2701:
2692:
1753:
1734:
1727:
1720:
1711:
1705:
1704:
1684:
1678:
1677:
1660:(8): 1629–1634.
1648:
1642:
1641:
1609:
1603:
1602:
1574:
1568:
1565:
1559:
1558:
1522:
1516:
1515:
1513:
1512:
1495:
1489:
1488:
1478:
1454:
1448:
1447:
1415:
1406:
1405:
1387:
1378:
1377:
1350:
1323:
1322:
1294:
1216:
1199:
1167:
1140:
1068:
1067:
1066:
1063:
1036:
1009:
998:
983:
982:
981:
978:
960:
959:
958:
955:
920:
919:
918:
915:
891:silver acetylide
837:
836:
835:
832:
804:
803:
802:
799:
776:titanium carbide
770:
759:
748:
711:
710:
709:
706:
695:
694:
693:
690:
610:tungsten carbide
590:transition metal
540:
532:
521:
168:
127:tungsten carbide
123:titanium carbide
97:Tungsten carbide
51:titanium carbide
36:Tungsten carbide
21:
3320:
3319:
3315:
3314:
3313:
3311:
3310:
3309:
3285:
3284:
3283:
3278:
3271:
3264:
3257:
3250:
3243:
3225:
3218:
3211:
3204:
3197:
3190:
3172:
3165:
3158:
3151:
3144:
3137:
3119:
3112:
3105:
3098:
3091:
3084:
3071:
3064:
3057:
3050:
3043:
3036:
3023:
3016:
3003:
2998:Monatomic anion
2995:
2965:
2960:
2941:Metal carbonyls
2919:
2898:
2856:
2847:
2843:
2835:
2831:
2823:
2815:
2807:
2803:
2785:
2777:
2769:
2761:
2753:
2728:
2719:
2689:
2684:
2683:
2653:
2649:
2645:
2624:
2619:
2604:
2596:
2588:
2580:
2572:
2564:
2556:
2548:
2540:
2532:
2524:
2516:
2508:
2500:
2399:
2395:
2387:
2383:
2369:
2360:
2351:
2338:
2333:
2321:
2310:
2302:
2298:
2283:
2281:
2254:
2250:
2242:
2233:
2224:
2212:
2208:
2185:
2177:
2173:
2158:
2156:
2148:
2126:
2118:
2113:
2105:
2092:
2088:
2083:
2080:
2075:
2072:
2064:
2056:
2052:
2035:
2031:
2027:
2026:
2022:
2018:
2017:
2013:
2009:
2000:
1995:
1988:
1984:
1969:
1967:
1957:
1955:
1940:
1933:
1929:
1920:
1912:
1908:
1895:
1890:
1883:
1879:
1874:
1872:
1867:
1858:
1856:
1851:
1842:
1840:
1835:
1826:
1824:
1820:
1815:
1812:
1803:
1795:
1791:
1786:
1783:
1762:
1760:
1745:
1738:
1708:
1686:
1685:
1681:
1650:
1649:
1645:
1611:
1610:
1606:
1576:
1575:
1571:
1566:
1562:
1524:
1523:
1519:
1510:
1508:
1497:
1496:
1492:
1463:Pure Appl. Chem
1456:
1455:
1451:
1417:
1416:
1409:
1402:
1389:
1388:
1381:
1374:
1352:
1351:
1326:
1319:
1296:
1295:
1291:
1287:
1275:
1249:
1223:
1215:
1211:
1207:
1197:
1193:
1189:
1185:
1181:
1177:
1174:metal carbonyls
1165:
1161:
1154:
1150:
1138:
1134:
1130:
1126:
1119:
1112:
1092:
1083:Silicon carbide
1075:
1064:
1061:
1060:
1058:
1056:
1052:
1044:
1039:methylacetylene
1035:
1031:
1027:
1025:
1021:
1017:
1008:
1004:
1000:
997:
993:
989:
979:
976:
975:
973:
967:
956:
953:
952:
950:
947:
940:
933:
927:
916:
913:
912:
910:
908:
904:
900:
884:
880:
875:
869:
864:calcium carbide
861:
857:
842:), which has a
833:
830:
829:
827:
825:acetylide anion
818:Calcium carbide
811:
800:
797:
796:
794:
788:
768:
764:
757:
753:
747:
743:
739:
729:
722:
717:
707:
704:
703:
701:
691:
688:
687:
685:
630:
623:
606:silicon carbide
603:
598:calcium carbide
588:"intermediate"
567:
548:
538:
534:
531:
527:
523:
519:
515:
475:
471:
441:
437:
433:
429:
425:
423:
419:
415:
388:
384:
353:
349:
318:
314:
206:Other carbides
202:
195:
193:
183:
178:
163:
154:
119:crystal defects
115:stoichiometries
90:
43:
28:
23:
22:
15:
12:
11:
5:
3318:
3316:
3308:
3307:
3302:
3297:
3287:
3286:
3280:
3279:
3277:
3276:
3269:
3262:
3255:
3248:
3240:
3238:
3227:
3226:
3224:
3223:
3216:
3209:
3202:
3195:
3187:
3185:
3174:
3173:
3171:
3170:
3163:
3156:
3149:
3142:
3134:
3132:
3121:
3120:
3118:
3117:
3110:
3103:
3096:
3089:
3081:
3079:
3073:
3072:
3070:
3069:
3062:
3055:
3048:
3041:
3033:
3031:
3025:
3024:
3022:
3021:
3013:
3011:
3005:
3004:
2996:
2994:
2993:
2986:
2979:
2971:
2962:
2961:
2959:
2958:
2953:
2948:
2943:
2938:
2933:
2927:
2925:
2921:
2920:
2918:
2917:
2912:
2906:
2904:
2903:Nanostructures
2900:
2899:
2897:
2896:
2891:
2886:
2881:
2876:
2871:
2864:
2862:
2858:
2857:
2855:
2854:
2849:
2845:
2841:
2837:
2833:
2829:
2825:
2821:
2817:
2813:
2809:
2805:
2801:
2797:
2792:
2787:
2783:
2779:
2775:
2771:
2767:
2763:
2759:
2755:
2751:
2747:
2742:
2736:
2734:
2730:
2729:
2720:
2718:
2717:
2710:
2703:
2695:
2686:
2685:
2680:
2679:
2676:
2673:
2670:
2667:
2664:
2661:
2658:
2655:
2651:
2647:
2641:
2636:
2631:
2626:
2622:
2614:
2611:
2607:
2606:
2602:
2598:
2594:
2590:
2586:
2582:
2578:
2574:
2570:
2566:
2562:
2558:
2554:
2550:
2546:
2542:
2538:
2534:
2530:
2526:
2522:
2518:
2514:
2510:
2506:
2502:
2498:
2494:
2490:
2489:
2486:
2483:
2482:
2479:
2476:
2473:
2470:
2467:
2464:
2461:
2458:
2455:
2452:
2449:
2446:
2443:
2440:
2437:
2434:
2431:
2428:
2424:
2423:
2420:
2417:
2414:
2411:
2406:
2401:
2397:
2393:
2389:
2385:
2381:
2377:
2372:
2367:
2363:
2358:
2354:
2349:
2345:
2340:
2336:
2328:
2323:
2319:
2315:
2312:
2308:
2304:
2300:
2296:
2291:
2290:
2287:
2279:
2275:
2272:
2269:
2266:
2261:
2256:
2252:
2248:
2244:
2240:
2236:
2231:
2227:
2222:
2218:
2215:
2210:
2204:
2199:
2194:
2189:
2187:
2183:
2179:
2175:
2171:
2166:
2165:
2162:
2154:
2150:
2146:
2142:
2137:
2132:
2129:
2124:
2120:
2116:
2108:
2103:
2099:
2094:
2090:
2086:
2078:
2070:
2066:
2062:
2058:
2054:
2050:
2046:
2041:
2036:
2033:
2029:
2024:
2020:
2015:
2011:
2004:
2002:
1998:
1990:
1986:
1982:
1977:
1976:
1973:
1965:
1961:
1953:
1949:
1944:
1935:
1931:
1927:
1923:
1918:
1914:
1910:
1906:
1901:
1900:
1897:
1893:
1885:
1881:
1877:
1870:
1862:
1854:
1846:
1838:
1830:
1822:
1818:
1810:
1806:
1801:
1797:
1793:
1789:
1781:
1776:
1775:
1772:
1770:
1768:
1766:
1758:
1751:
1750:
1747:
1746:
1739:
1737:
1736:
1729:
1722:
1714:
1707:
1706:
1679:
1643:
1624:(6): 470–473.
1604:
1569:
1560:
1517:
1490:
1449:
1407:
1400:
1379:
1372:
1364:Pergamon Press
1324:
1318:978-3527306732
1317:
1288:
1286:
1283:
1282:
1281:
1279:Kappa-carbides
1274:
1271:
1270:
1269:
1263:
1257:
1251:
1247:
1244:
1238:
1232:
1222:
1219:
1118:
1115:
1110:
1090:
1074:
1071:
1054:
1050:
1042:
1023:
1019:
1015:
988:, is found in
971:polyatomic ion
966:
963:
945:
938:
931:
925:
906:
902:
898:
882:
878:
873:
867:
859:
855:
852:sodium carbide
810:
807:
786:
728:
725:
720:
715:
650:group 3 metals
629:
626:
621:
601:
594:
593:
586:
580:
574:
566:
563:
546:
503:
502:
500:
497:
494:
491:
489:
486:
483:
477:
476:
473:
469:
466:
463:
460:
457:
455:
452:
449:
443:
442:
439:
435:
431:
427:
421:
417:
413:
410:
408:
406:
404:
402:
399:
396:
390:
389:
386:
382:
379:
376:
373:
370:
367:
364:
361:
355:
354:
351:
347:
344:
341:
338:
335:
332:
329:
326:
320:
319:
316:
312:
309:
306:
303:
300:
297:
294:
289:
283:
282:
280:
278:
276:
273:
270:
267:
264:
258:
257:
255:
253:
251:
248:
245:
242:
239:
233:
232:
230:
228:
226:
223:
220:
217:
214:
208:
207:
204:
200:
197:
191:
188:
185:
180:
175:
172:
161:
157:
156:
152:
145:
89:
86:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
3317:
3306:
3303:
3301:
3298:
3296:
3293:
3292:
3290:
3274:
3270:
3267:
3263:
3260:
3256:
3253:
3249:
3246:
3242:
3241:
3239:
3236:
3232:
3228:
3221:
3217:
3214:
3210:
3207:
3203:
3200:
3196:
3193:
3189:
3188:
3186:
3183:
3182:Chalcogenides
3179:
3175:
3168:
3164:
3161:
3157:
3154:
3150:
3147:
3143:
3140:
3136:
3135:
3133:
3130:
3126:
3122:
3115:
3111:
3108:
3104:
3101:
3097:
3094:
3090:
3087:
3083:
3082:
3080:
3078:
3074:
3067:
3063:
3060:
3056:
3053:
3049:
3046:
3042:
3039:
3035:
3034:
3032:
3030:
3026:
3019:
3015:
3014:
3012:
3010:
3006:
3002:
2999:
2992:
2987:
2985:
2980:
2978:
2973:
2972:
2969:
2957:
2954:
2952:
2949:
2947:
2946:Carbonic acid
2944:
2942:
2939:
2937:
2934:
2932:
2929:
2928:
2926:
2922:
2916:
2913:
2911:
2908:
2907:
2905:
2901:
2895:
2894:Thiofulminate
2892:
2890:
2887:
2885:
2882:
2880:
2877:
2875:
2872:
2869:
2866:
2865:
2863:
2859:
2853:
2850:
2848:
2838:
2836:
2826:
2824:
2818:
2816:
2810:
2808:
2798:
2796:
2793:
2791:
2788:
2786:
2780:
2778:
2772:
2770:
2764:
2762:
2756:
2754:
2748:
2746:
2743:
2741:
2738:
2737:
2735:
2731:
2726:
2723:
2716:
2711:
2709:
2704:
2702:
2697:
2696:
2693:
2677:
2674:
2671:
2668:
2665:
2662:
2659:
2656:
2654:
2642:
2640:
2637:
2635:
2632:
2630:
2627:
2625:
2618:
2615:
2612:
2609:
2608:
2605:
2599:
2597:
2591:
2589:
2583:
2581:
2575:
2573:
2567:
2565:
2559:
2557:
2551:
2549:
2543:
2541:
2535:
2533:
2527:
2525:
2519:
2517:
2511:
2509:
2503:
2501:
2495:
2492:
2491:
2484:
2480:
2477:
2474:
2471:
2468:
2465:
2462:
2459:
2456:
2453:
2450:
2447:
2444:
2441:
2438:
2435:
2432:
2429:
2426:
2425:
2421:
2418:
2415:
2412:
2410:
2407:
2405:
2402:
2400:
2390:
2388:
2378:
2376:
2373:
2371:
2364:
2362:
2355:
2353:
2346:
2344:
2341:
2339:
2332:
2329:
2327:
2324:
2322:
2316:
2313:
2311:
2305:
2303:
2293:
2292:
2288:
2286:
2282:
2276:
2273:
2270:
2267:
2265:
2262:
2260:
2257:
2255:
2245:
2243:
2237:
2235:
2228:
2226:
2219:
2216:
2214:
2205:
2203:
2200:
2198:
2195:
2193:
2190:
2188:
2186:
2180:
2178:
2168:
2167:
2163:
2161:
2157:
2151:
2149:
2143:
2141:
2138:
2136:
2133:
2130:
2128:
2121:
2119:
2112:
2109:
2107:
2100:
2098:
2095:
2093:
2082:
2074:
2067:
2065:
2059:
2057:
2047:
2045:
2042:
2040:
2037:
2008:
2005:
2003:
2001:
1994:
1991:
1989:
1979:
1978:
1974:
1972:
1968:
1962:
1960:
1956:
1950:
1948:
1945:
1943:
1939:
1936:
1934:
1924:
1922:
1915:
1913:
1903:
1902:
1898:
1896:
1889:
1886:
1884:
1873:
1866:
1863:
1861:
1857:
1850:
1847:
1845:
1841:
1834:
1831:
1829:
1825:
1814:
1807:
1805:
1798:
1796:
1785:
1778:
1777:
1773:
1767:
1765:
1761:
1755:
1754:
1748:
1743:
1735:
1730:
1728:
1723:
1721:
1716:
1715:
1712:
1702:
1698:
1694:
1690:
1683:
1680:
1675:
1671:
1667:
1663:
1659:
1655:
1647:
1644:
1639:
1635:
1631:
1627:
1623:
1619:
1615:
1608:
1605:
1600:
1596:
1592:
1588:
1584:
1580:
1573:
1570:
1564:
1561:
1556:
1552:
1548:
1544:
1540:
1536:
1532:
1528:
1521:
1518:
1506:
1505:
1500:
1494:
1491:
1486:
1482:
1477:
1472:
1468:
1464:
1460:
1453:
1450:
1445:
1441:
1437:
1433:
1429:
1425:
1421:
1414:
1412:
1408:
1403:
1397:
1393:
1386:
1384:
1380:
1375:
1369:
1365:
1361:
1360:
1355:
1349:
1347:
1345:
1343:
1341:
1339:
1337:
1335:
1333:
1331:
1329:
1325:
1320:
1314:
1310:
1306:
1302:
1301:
1293:
1290:
1284:
1280:
1277:
1276:
1272:
1268:
1264:
1261:
1258:
1255:
1252:
1245:
1242:
1239:
1237:
1234:alkali metal
1233:
1231:
1228:
1227:
1226:
1220:
1218:
1205:
1201:
1175:
1171:
1158:
1148:
1123:
1116:
1114:
1108:
1104:
1100:
1096:
1095:boron carbide
1088:
1087:Boron carbide
1084:
1080:
1072:
1070:
1048:
1040:
1013:
1012:isoelectronic
987:
972:
964:
962:
948:
941:
934:
922:
896:
892:
888:
876:
865:
853:
849:
845:
841:
826:
819:
815:
808:
806:
792:
783:
781:
777:
772:
763:
752:
738:
734:
726:
724:
718:
699:
683:
679:
675:
671:
667:
663:
659:
655:
651:
647:
643:
639:
635:
634:alkali metals
627:
625:
619:
615:
611:
607:
599:
591:
587:
584:
581:
578:
575:
572:
571:
570:
564:
562:
560:
556:
551:
544:
512:
510:
501:
498:
495:
492:
490:
487:
484:
482:
479:
478:
467:
464:
461:
458:
456:
453:
450:
448:
445:
444:
411:
409:
407:
405:
403:
400:
397:
395:
392:
391:
380:
377:
374:
371:
368:
365:
362:
360:
357:
356:
345:
342:
339:
336:
333:
330:
327:
325:
322:
321:
310:
307:
304:
301:
298:
295:
293:
290:
288:
285:
284:
281:
279:
277:
274:
271:
268:
265:
263:
260:
259:
256:
254:
252:
249:
246:
243:
240:
238:
235:
234:
231:
229:
227:
224:
221:
218:
215:
213:
210:
209:
205:
198:
189:
187:MC structure
186:
181:
176:
173:
170:
169:
166:
150:
146:
143:
139:
135:
134:
133:
130:
128:
124:
120:
116:
112:
108:
101:
98:
94:
87:
85:
83:
79:
75:
71:
67:
63:
59:
52:
47:
41:
37:
33:
19:
3085:
2951:Bicarbonates
2867:
1843:
1741:
1695:(15): 3260.
1692:
1688:
1682:
1657:
1653:
1646:
1621:
1617:
1607:
1582:
1578:
1572:
1563:
1533:(1): 36–41.
1530:
1526:
1520:
1509:. Retrieved
1503:
1493:
1469:(10): 1391.
1466:
1462:
1452:
1427:
1423:
1391:
1358:
1298:
1292:
1224:
1202:
1170:phenyl group
1144:
1125:The complex
1102:
1076:
985:
968:
923:
822:
784:
773:
730:
631:
613:
595:
568:
552:
513:
506:
203:C structure
179:radius (pm)
158:
131:
104:
77:
68:composed of
61:
55:
2884:Thiocyanate
2861:Carbon ions
1689:Inorg. Chem
1103:carborundum
844:triple bond
642:lanthanides
82:carburizing
32:Carbide.c++
3289:Categories
2956:Carbonates
2915:Fullerides
1511:2013-04-06
1499:John Percy
1430:: 160290.
1362:. Oxford:
1285:References
1236:fullerides
1178:[CRuCl
1107:refractory
1047:propadiene
727:Methanides
698:acetylides
696:", in the
493:hexagonal
459:hexagonal
447:molybdenum
372:rock salt
337:rock salt
302:rock salt
275:rock salt
250:rock salt
225:rock salt
155:structure.
111:refractory
74:metallurgy
3129:Pnictides
3001:compounds
2889:Fulminate
2733:Compounds
1674:0009-2940
1638:134209836
1555:135756713
1444:0925-8388
1045:CCH, and
965:Allylides
666:Aluminium
646:actinides
618:cementite
592:carbides.
543:cementite
237:zirconium
177:Metallic
100:end mills
78:carbiding
58:chemistry
3295:Carbides
3231:Group 17
3178:Group 16
3125:Group 15
3077:Group 14
3029:Group 13
2936:Nitrides
2868:Carbides
1599:23824698
1501:(1870).
1485:59467042
1273:See also
986:allylide
840:peroxide
682:thallium
670:carbides
662:lutetium
654:scandium
481:tungsten
394:chromium
359:tantalum
287:vanadium
212:titanium
66:compound
3235:Halides
3009:Group 1
2879:Cyanate
2874:Cyanide
2488:
1742:carbide
1535:Bibcode
1151:[Au
1127:[Au
1099:borides
1037:yields
1014:with CO
805:anion.
780:methane
733:methane
674:gallium
658:yttrium
614:carbide
608:(SiC),
324:niobium
262:hafnium
62:carbide
18:Methide
3300:Anions
2931:Oxides
2725:carbon
1672:
1636:
1597:
1553:
1483:
1442:
1398:
1370:
1315:
1267:MXenes
1250:units.
870:, and
680:, and
678:indium
672:, but
660:, and
648:, and
171:Metal
70:carbon
3305:Salts
1634:S2CID
1551:S2CID
1481:S2CID
1131:C(PPh
1079:boron
901:and M
585:, and
2870:, ,
2409:?PbC
1853:(CN)
1670:ISSN
1595:PMID
1440:ISSN
1396:ISBN
1368:ISBN
1313:ISBN
1182:{P(C
1049:, CH
1041:, CH
999:and
969:The
889:and
760:and
600:(CaC
557:and
555:lead
545:, Fe
533:and
499:h/2
496:hcp
488:139
485:bcc
465:h/2
462:hcp
454:139
451:bcc
434:, Cr
420:, Cr
401:128
398:bcc
378:h/2
375:hcp
369:ccp
366:146
363:bcc
343:h/2
340:hcp
334:ccp
331:146
328:bcc
308:h/2
305:hcp
299:ccp
296:134
272:ccp
269:159
266:hcp
247:ccp
244:160
241:hcp
222:ccp
219:147
216:hcp
125:and
60:, a
2852:SiC
2820:CSe
2790:COS
2678:No
2675:Md
2672:Fm
2669:Es
2666:Cf
2663:Bk
2660:Cm
2657:Am
2644:PuC
2639:NpC
2629:PaC
2621:ThC
2617:ThC
2613:Ac
2610:**
2601:YbC
2593:TmC
2585:ErC
2577:HoC
2569:DyC
2561:TbC
2553:GdC
2545:EuC
2537:SmC
2529:PmC
2521:NdC
2513:PrC
2505:CeC
2497:LaC
2481:Og
2478:Ts
2475:Lv
2472:Mc
2469:Fl
2466:Nh
2463:Cn
2460:Rg
2457:Ds
2454:Mt
2451:Hs
2448:Bh
2445:Sg
2442:Db
2439:Rf
2436:Lr
2433:**
2430:Ra
2427:Fr
2422:Rn
2419:At
2416:Po
2413:Bi
2404:TlC
2375:PtC
2335:TaC
2331:TaC
2326:HfC
2318:LuC
2307:BaC
2289:Xe
2274:Te
2271:Sb
2268:Sn
2264:InC
2259:CdC
2239:PdC
2217:Tc
2207:MoC
2202:NbC
2197:ZrC
2182:SrC
2164:Kr
2160:+Br
2153:CBr
2145:CSe
2140:+As
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