Knowledge (XXG)

Metasomatism

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234: 106: 302:, this can happen from the precipitation of new minerals at the same time as the dissolution of existing minerals. The second feature used to identify metasomatism is that it is from the preservation of rocks in its solid state during replacement. The third distinctive feature is from isochemical metamorphism, or the addition or subtraction of major elements other than 1148:
April 1995, p. 909-924. Dickson, F. W., 2000, Chemical emplacement of magma, v. 30, p.475-487. Dickson, F. W., 2005, Role of liquids in irreversible processes in earth and replacement in Papoose Flat pluton, California. In Rhoden, R. H., Steininger, R. C., and Vikre, R.G., eds: Geol. Soc. Nevada Symposium 2005: Window to the World, Reno, Nevada May, 2005, p. 161-178.
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There are two main schemes discussed for the manifestation of metasomatism in nature in granitic systems. Diffusion metasomatism, which was mentioned in the types of metasomatites section, and infiltration metasomatism. Infiltration takes place in cracks or fractures that promote fluid flow in areas
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Dickson, F. W., 1996, Porphyroblasts of barium-zoned K-feldspar and quartz, Papoose Flat California, genesis and exploration implications. In Coyner,A.R., Fahey, P.I., eds. Geology and Ore Deposits of the American Cordillera: Geological Society of Nevada Symposium Proceedings, Reno/Sparks, Nevada,
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These two methods are commonly used for transportation from one region to another. These effected regions can be either enriched or depleted in the components transported relative to the premetasomatic state. Chemical weathering strongly effects the levels and contents of the metasomatic liquid and
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and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and
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Effects of metasomatism in mantle peridotite can be either modal or cryptic. In cryptic metasomatism, mineral compositions are changed, or introduced elements are concentrated on grain boundaries and the peridotite mineralogy appears unchanged. In modal metasomatism, new minerals are formed.
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Taylor, R.D., Hammarstrom, J.M., Piatak, N.M., and Seal II, R.R., 2012, Arc-related porphyry molybdenum deposit model: Chapter D in Mineral deposit models for resource assessment: U.S. Geological Survey Scientific Investigations Report USGS Numbered Series 2010-5070-D,
659:, commonly present in the distal areas of porphyry deposits, is a low-temperature assemblage that converts feldspars and some other minerals into clay minerals such as kaolinite and illite. It can overprint older, higher-temperature alteration assemblages. 337:
In such cases, characterising alteration often requires microscope investigation of the mineral assemblage of the rocks to characterise the minerals, any additional mineral growth, changes in protolith minerals, and so on.
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Boulvais, Philippe; Ruffet, Gilles; Cornichet, Jean; Mermet, Maxime (January 2007). "Cretaceous albitization and dequartzification of Hercynian peraluminous granite in the Salvezines Massif (French Pyrénées)".
443:, sodic pyroxenes or amphiboles and often unusual minerals (such as chevkinite or columbite) comprising ordinarily incompatible elements that do not readily become incorporated into a crystal lattice i.e. 473:
Cryptic metasomatism may be caused as rising or percolating melts interact with surrounding peridotite, and compositions of both melts and peridotite are changed. At high mantle temperatures, solid-state
1090:<0921:uteopm>2.3.co;2 "Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance" 375:
whole-rock replacement in shear zones, resulting in rocks in which the existing mineralogy has been completely recrystallised and replaced by hydrated minerals such as chlorite,
230:. The source region is often largely chemically unaffected compared to the highly hydrated, altered shear zones, but both must have undergone complementary metasomatism. 967:
Engvik, A. K.; Putnis, A.; Fitz Gerald, J. D.; Austrheim, H. (1 December 2008). "Albitization of granitic rocks: The mechanism of replacement of oligoclase by albite".
265:-rich and water-rich fluids, as discussed by Luth (2003). Metasomatism is thought to be particularly important in changing the composition of mantle peridotite below 530:. Rocks altered by infiltration metasomatism will be less altered than rocks altered by diffusion because of the dispersion effects during fluid advection. 686:. Stressed minerals and country rocks of granitic plutons are replaced by porphyroblasts of orthoclase and quartz, in the Papoose Flat quartz monzonites. 188:
components as hydrous minerals break down, with this fluid percolating up into the shallow levels of the crust to chemically change and alter these rocks.
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In some cases, geochemical evidence can be found of metasomatic alteration processes. This is usually in the form of mobile, soluble elements such as
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can also be effective in changing rock compositions over tens of centimeters adjacent to melt conduits: gradients in mineral composition adjacent to
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which is the in-situ mineralogical change of a rock without appreciable change in the chemistry of the rock. Because metamorphism usually requires
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Metasomatism can be similar to other endogenic processes and is separated by 4 main features. The first of these is the ion-by-ion replacement in
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Rarer types of hydrothermal fluids may include highly carbonic fluids, resulting in advanced carbonation reactions of the host rock typical of
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Metasomatism and the Chemical Transformation of Rock: Rock-Mineral-Fluid Interaction in Terrestrial and Extraterrestrial Environments
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Metasomatism and the Chemical Transformation of Rock: Rock-Mineral-Fluid Interaction in Terrestrial and Extraterrestrial Environments
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has been considered strong evidence of metasomatic processes in the mantle. Formation of minerals less common in peridotite, such as
880: 334:, such that the only evidence of alteration is bleaching, change in colour or change in the crystallinity of micaceous minerals. 233: 1167: 526:
of high permeability. Diffusion takes place when fluid is incorporated into the pores of the rock, this is determined by the
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Further, because metasomatism is a mass transfer process, it is not restricted to the rocks which are changed by addition of
1172: 640: 439:, as a variant of metasomatism associated with strongly alkaline or carbonatitic magmatism introducing a variety of 917: 857: 1113: 707: 361:. However, to characterise the alteration properly, it is necessary to compare altered with unaltered samples. 648: 55: 218:
which are the product of focused concentration of fluids derived from many cubic kilometres of dehydrated
631:(adularia) alteration, often quite pervasive and producing distinct salmon-pink alteration vein selvages. 551: 542:
Investigation of altered rocks in hydrothermal ore deposits has highlighted several ubiquitous types of
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mafic dykes, containing grossular-andradite garnet, calcic pyroxene, vesuvianite, epidote and scapolite.
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Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: Web version 01.02.07
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Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: Web version 01.02.07
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This mechanism implies that metasomatism is open system behaviour, which is different from classical
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in order to facilitate metamorphic reactions, metamorphism nearly always occurs with metasomatism.
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into a zone with lower stress and temperature, with metamorphic hydrothermal solutions acting as a
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Metasomatic rocks can be extremely varied. Often, metasomatised rocks are pervasively but weakly
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which form distinct groups of metasomatic alteration effects, textures and mineral assemblages.
210:. In all cases, to produce a metasomatic rock some other rock is also metasomatised, if only by 1117: 1033: 876: 796: 759: 246: 207: 1109: 1070: 1025: 984: 949: 788: 751: 416: 380: 203: 169: 165: 875:(Volume 2 Treatise on Geochemistry ed.). Elsevier-Pergamon, Oxford. pp. 319–361. 816: 291:
melts are often considered to have been responsible for enrichment of mantle peridotite in
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When the process becomes extremely advanced, typical metasomatites can include:
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and metamorphism and form a characteristic pattern of a metasomatic column.
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the major element geochemistry and mineralogy of siliciclastic sediments.
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can be used as a name for specific varieties of metasomatism (for example
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Mantle volatiles - distribution and consequences in The Mantle and Core
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Zharikov V.A.; Pertsev N.N.; Rusinov V.L.; Callegari E.; Fettes D.J.
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Zharikov V.A.; Pertsev N.N.; Rusinov V.L.; Callegari E.; Fettes D.J.
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Metasomatism can occur via the action of hydrothermal fluids from an
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reactions with minimal chemical change. This is best illustrated by
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Roden, Michael F.; Murthy, v. Rama (1985). "Mantle Metasomatism".
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Fedo, Christopher M.; Wayne Nesbitt, H.; Young, Grant M. (1995).
180:. This can be envisaged as the metamorphic rocks within the deep 160:
mass. In the metamorphic environment, metasomatism is driven by
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and deposition occur simultaneously and the rock remains solid.
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and in a disseminated manner; sericite in particular replaces
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Chemical alteration of a rock by hydrothermal and other fluids
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and lode gold deposits, results in production of micaceous,
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10.1130/0091-7613(1995)023<0921:uteopm>2.3.co;2
781:"Fluid-Induced Processes: Metasomatism and Metamorphism" 722: – Obsolete geologic term for magma emitting gasses 667:, and silica-hematite fluids resulting in production of 393:
intrusions and adjacent to reactive lithologies such as
563:-bearing hydrothermal fluids, and typically results in 253:
at high temperatures can be changed by infiltration of
710: – Circulation of water driven by heat exchange 517:, is also attributed to melt or fluid metasomatism. 639:, in which these minerals can be deposited both in 493:, and the presence of these minerals in peridotite 222:into thin, often highly metasomatised and altered 698: – Highly altered granitic rock or pegmatite 1137:http://pubs.er.usgs.gov/publication/sir20105070D 1009:. Academy of Sciences Russia. pp. 131–146. 389:and skarnoid rock types, typically adjacent to 485:Modal metasomatism may result in formation of 8: 482:dikes may preserve evidence of the process. 54:formations are deposited in their place. 779:Putnis, A.; Austrheim, H. (2010-12-23). 245:Metasomatism is more complicated in the 41:"body") is the chemical alteration of a 1005:Zharikov, V. A.; et al. (et al.). 907:"9. Metasomatism and metasomatic rocks" 900: 898: 896: 894: 892: 847:"9. Metasomatism and metasomatic rocks" 738: 623:in iron-rich rocks, muscovite mica or 7: 1020:Harlov, D.E.; Austrheim, H. (2013). 1000: 998: 746:Harlov, D.E.; Austrheim, H. (2013). 1075:10.1146/annurev.ea.13.050185.001413 140:environment, metasomatism produces 1007:Metasomatism and metasomatic rocks 704: – Group of metamorphic rocks 241:in serpentinite Nelson New Zealand 25: 651:and porphyry molybdenum deposits. 636:Quartz-sericite-pyrite alteration 601:, and typically results in weak 647:and biotite. This is common in 821:Merriam-Webster.com Dictionary 453:Albitite, from replacement of 1: 249:, because the composition of 954:10.1016/j.lithos.2006.05.001 184:losing fluids and dissolved 121:alteration of metamorphosed 1030:10.1007/978-3-642-28394-9_1 756:10.1007/978-3-642-28394-9_1 154:contact metamorphic aureole 1189: 793:10.1002/9781444394900.ch18 269:as water is driven out of 969:The Canadian Mineralogist 918:British Geological Survey 858:British Geological Survey 587:Albite-epidote alteration 989:10.3749/canmin.46.6.1401 708:Hydrothermal circulation 593:-bearing fluids rich in 206:and minerals or hydrous 675:and pervasive zones of 575:alteration, often with 785:Frontiers in Geofluids 544:alteration assemblages 538:Alteration assemblages 326:Types of metasomatites 242: 133: 1168:Metamorphic petrology 1055:Earth Planet Sci Lett 627:in felsic rocks, and 552:Propylitic alteration 403:banded iron formation 293:incompatible elements 282:silica-undersaturated 236: 108: 61:Synonyms of the word 33:(from the Greek μετά 1173:Geological processes 1024:. Berlin: Springer. 871:Luth, R. W. (2003). 750:. Berlin: Springer. 521:Metasomatism Schemes 1106:1995Geo....23..921F 1067:1985AREPS..13..269R 981:2008CaMin..46.1401E 946:2007Litho..93...89B 656:Argillic alteration 609:Potassic alteration 429:particularly their 359:rare earth elements 71:metasomatic process 673:manto ore deposits 243: 134: 37:"change" and σῶμα 1039:978-3-642-28393-2 802:978-1-4443-3330-5 765:978-3-642-28393-2 619:minerals such as 216:gold ore deposits 204:chemical elements 164:from a volume of 148:, and may affect 16:(Redirected from 1180: 1149: 1145: 1139: 1132: 1126: 1125: 1085: 1079: 1078: 1050: 1044: 1043: 1017: 1011: 1010: 1002: 993: 992: 975:(6): 1401–1415. 964: 958: 957: 928: 922: 921: 911: 902: 887: 886: 868: 862: 861: 851: 842: 836: 835: 833: 831: 813: 807: 806: 776: 770: 769: 743: 605:-silica-epidote. 411:deposits within 166:metamorphic rock 21: 1188: 1187: 1183: 1182: 1181: 1179: 1178: 1177: 1158: 1157: 1155: 1153: 1152: 1146: 1142: 1133: 1129: 1087: 1086: 1082: 1052: 1051: 1047: 1040: 1019: 1018: 1014: 1004: 1003: 996: 966: 965: 961: 940:(1–2): 89–106. 930: 929: 925: 909: 904: 903: 890: 883: 870: 869: 865: 849: 844: 843: 839: 829: 827: 825:Merriam-Webster 817:"metasomatosis" 815: 814: 810: 803: 778: 777: 773: 766: 745: 744: 740: 735: 692: 679:, typically in 649:porphyry copper 613:porphyry copper 540: 523: 328: 317: 309: 156:adjacent to an 28: 23: 22: 15: 12: 11: 5: 1186: 1184: 1176: 1175: 1170: 1160: 1159: 1151: 1150: 1140: 1127: 1080: 1045: 1038: 1012: 994: 959: 923: 888: 881: 863: 837: 808: 801: 771: 764: 737: 736: 734: 731: 730: 729: 723: 717: 711: 705: 699: 691: 688: 677:silicification 665:calc-silicates 661: 660: 652: 632: 606: 584: 539: 536: 522: 519: 467: 466: 451: 434: 420: 406: 384: 327: 324: 315: 312:carbon dioxide 307: 263:carbon dioxide 247:Earth's mantle 237:Metasomatized 158:intrusive rock 127:Stone Mountain 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 1185: 1174: 1171: 1169: 1166: 1165: 1163: 1156: 1144: 1141: 1138: 1131: 1128: 1123: 1119: 1115: 1111: 1107: 1103: 1099: 1095: 1091: 1084: 1081: 1076: 1072: 1068: 1064: 1060: 1056: 1049: 1046: 1041: 1035: 1031: 1027: 1023: 1016: 1013: 1008: 1001: 999: 995: 990: 986: 982: 978: 974: 970: 963: 960: 955: 951: 947: 943: 939: 935: 927: 924: 919: 915: 908: 901: 899: 897: 895: 893: 889: 884: 882:0-08-043751-6 878: 874: 867: 864: 859: 855: 848: 841: 838: 826: 822: 818: 812: 809: 804: 798: 794: 790: 786: 782: 775: 772: 767: 761: 757: 753: 749: 742: 739: 732: 727: 724: 721: 720:Pneumatolysis 718: 715: 712: 709: 706: 703: 700: 697: 694: 693: 689: 687: 685: 682: 678: 674: 670: 666: 658: 657: 653: 650: 646: 642: 638: 637: 633: 630: 626: 622: 618: 614: 611:, typical of 610: 607: 604: 600: 596: 592: 589:is caused by 588: 585: 582: 578: 574: 570: 566: 562: 558: 555:is caused by 554: 553: 549: 548: 547: 545: 537: 535: 531: 529: 520: 518: 516: 512: 508: 504: 500: 496: 492: 488: 483: 481: 477: 471: 464: 460: 456: 452: 450: 446: 442: 438: 435: 432: 431:serpentinized 428: 424: 421: 418: 414: 410: 407: 404: 400: 396: 392: 388: 385: 382: 378: 374: 370: 367: 366: 365: 362: 360: 356: 352: 348: 344: 339: 335: 333: 325: 323: 321: 313: 305: 301: 296: 294: 290: 286: 283: 279: 275: 272: 268: 264: 261:melts and by 260: 256: 252: 248: 240: 235: 231: 229: 225: 221: 217: 213: 209: 205: 200: 198: 194: 189: 187: 183: 179: 175: 171: 167: 163: 162:mass transfer 159: 155: 151: 147: 143: 139: 132: 128: 124: 120: 116: 112: 107: 103: 101: 97: 92: 90: 89:-metasomatose 88: 83: 82:-metasomatose 81: 76: 72: 68: 67:metasomatosis 64: 59: 57: 53: 48: 44: 40: 36: 32: 19: 1154: 1143: 1130: 1097: 1093: 1083: 1058: 1054: 1048: 1021: 1015: 1006: 972: 968: 962: 937: 933: 926: 913: 872: 866: 853: 840: 828:. Retrieved 820: 811: 784: 774: 747: 741: 662: 654: 634: 608: 586: 550: 543: 541: 532: 524: 484: 472: 468: 463:albitization 462: 415:margins and 363: 340: 336: 331: 329: 297: 244: 211: 201: 193:metamorphism 190: 135: 109:Metasomatic 93: 85: 78: 75:metasomatose 74: 70: 66: 63:metasomatism 62: 60: 47:hydrothermal 38: 34: 31:Metasomatism 30: 29: 1100:(10): 921. 1061:: 269–296. 787:: 254–269. 714:Ore genesis 645:plagioclase 515:armalcolite 455:plagioclase 425:typical of 289:Carbonatite 274:lithosphere 267:island arcs 224:shear zones 212:dehydration 174:temperature 100:metamorphic 73:. The word 56:Dissolution 1162:Categories 669:jasperoids 629:orthoclase 491:phlogopite 480:pyroxenite 427:ophiolites 381:serpentine 278:subduction 251:peridotite 168:at higher 119:tourmaline 115:hornblende 1122:0091-7613 733:Reference 581:magnetite 495:xenoliths 487:amphibole 476:diffusion 449:zirconium 441:feldspars 423:Rodingite 395:limestone 377:muscovite 357:and some 347:strontium 320:magmatism 255:carbonate 208:compounds 102:source. 830:10 April 702:Hornfels 690:See also 681:dolomite 625:sericite 617:potassic 577:hematite 569:chlorite 528:porosity 507:ilmenite 499:dolomite 369:Chlorite 351:rubidium 300:minerals 259:silicate 150:hornfels 18:Potassic 1102:Bibcode 1094:Geology 1063:Bibcode 977:Bibcode 942:Bibcode 696:Greisen 621:biotite 599:calcium 583:facies. 565:epidote 503:calcite 445:niobium 417:cupolas 413:granite 409:Greisen 391:granite 355:calcium 332:altered 310:O) and 276:during 186:mineral 178:solvent 152:in the 146:greisen 138:igneous 136:In the 131:Atlanta 123:granite 96:igneous 52:mineral 1120:  1036:  934:Lithos 879:  799:  762:  684:strata 603:albite 595:sodium 591:silica 573:pyrite 561:sulfur 513:, and 511:rutile 459:albite 437:Fenite 379:, and 343:barium 285:magmas 170:stress 142:skarns 111:albite 910:(PDF) 850:(PDF) 726:Skarn 641:veins 387:Skarn 304:water 271:ocean 228:lodes 220:crust 197:water 182:crust 1118:ISSN 1034:ISBN 877:ISBN 832:2023 797:ISBN 760:ISBN 597:and 579:and 559:and 557:iron 489:and 401:and 399:marl 373:mica 257:and 239:dike 226:and 172:and 84:and 69:and 65:are 50:new 43:rock 39:sôma 35:metá 1110:doi 1071:doi 1026:doi 985:doi 950:doi 789:doi 752:doi 457:by 371:or 314:(CO 98:or 91:). 45:by 1164:: 1116:. 1108:. 1098:23 1096:. 1092:. 1069:. 1059:13 1057:. 1032:. 997:^ 983:. 973:46 971:. 948:. 938:93 936:. 916:. 912:. 891:^ 856:. 852:. 823:. 819:. 795:. 783:. 758:. 671:, 509:, 505:, 501:, 447:, 397:, 353:, 349:, 345:, 306:(H 295:. 287:. 144:, 129:, 125:, 117:+ 113:+ 87:Na 80:Mg 1124:. 1112:: 1104:: 1077:. 1073:: 1065:: 1042:. 1028:: 991:. 987:: 979:: 956:. 952:: 944:: 920:. 885:. 860:. 834:. 805:. 791:: 768:. 754:: 571:- 567:- 465:) 461:( 419:. 405:. 383:. 316:2 308:2 20:)

Index

Potassic
rock
hydrothermal
mineral
Dissolution
Mg
Na
igneous
metamorphic

albite
hornblende
tourmaline
granite
Stone Mountain
Atlanta
igneous
skarns
greisen
hornfels
contact metamorphic aureole
intrusive rock
mass transfer
metamorphic rock
stress
temperature
solvent
crust
mineral
metamorphism

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