Knowledge (XXG)

Calorimeter

Source 📝

329: 2060:°C and account for heat loss through the walls of the reaction vessel to the environment, hence, semi-adiabatic. The reaction vessel is a dewar flask which is immersed in a constant temperature bath. This provides a constant heat leak rate that can be corrected through the software. The heat capacity of the reactants (and the vessel) are measured by introducing a known amount of heat using a heater element (voltage and current) and measuring the temperature change. 2442: 50: 412: 147: 2454:
flatter temperature profiles. Thus, the selectivity of not well-defined reactions can be affected. This can lead to the formation of by-products or consecutive products which alter the measured heat of reaction, since other bonds are formed. The amount of by-product or secondary product can be found by calculating the yield of the desired product.
441:
ignited. Energy is released by the combustion and heat flow from this crosses the stainless steel wall, thus raising the temperature of the steel bomb, its contents, and the surrounding water jacket. The temperature change in the water is then accurately measured with a thermometer. This reading, along with a bomb factor (which is dependent on the
2450:
Reaction Calorimeter an axial temperature profile along the tube reactor can be recorded and the specific heat of reaction can be determined by means of heat balances and segmental dynamic parameters. The system must consist of a tubular reactor, dosing systems, preheaters, temperature sensors and flow meters.
320:
burning. Lavoisier dubbed this apparatus the calorimeter, based on both Greek and Latin roots. One of the first ice calorimeters was used in the winter of 1782 by Lavoisier and Pierre-Simon Laplace, which relied on the heat required to melt ice to water to measure the heat released from chemical reactions.
2052:
The measurement of heat using a simple calorimeter, like the coffee cup calorimeter, is an example of constant-pressure calorimetry, since the pressure (atmospheric pressure) remains constant during the process. Constant-pressure calorimetry is used in determining the changes in enthalpy occurring in
445:
of the metal bomb parts), is used to calculate the energy given out by the sample burn. A small correction is made to account for the electrical energy input, the burning fuse, and acid production (by titration of the residual liquid). After the temperature rise has been measured, the excess pressure
2538:
Antoine Laurent Lavoisier, Elements of Chemistry: In a New Systematic Order; Containing All the Modern Discoveries, 1789: "I acknowledge the name of Calorimeter, which I have given it, as derived partly from Greek and partly from Latin, is in some degree open to criticism; but in matters of science,
2449:
The Continuous Reaction Calorimeter is especially suitable to obtain thermodynamic information for a scale-up of continuous processes in tubular reactors. This is useful because the released heat can strongly depend on the reaction control, especially for non-selective reactions. With the Continuous
1793:
surrounds the experimental space within the calorimetric block. The radial arrangement of the thermopiles guarantees an almost complete integration of the heat. This is verified by the calculation of the efficiency ratio that indicates that an average value of 94% ± 1% of heat is transmitted through
367:
is initiated within a closed insulated container. Reaction heats are measured and the total heat is obtained by integrating heatflow versus time. This is the standard used in industry to measure heats since industrial processes are engineered to run at constant temperatures. Reaction calorimetry can
319:
In 1761 Joseph Black introduced the idea of latent heat which led to the creation of the first ice calorimeters. In 1780, Antoine Lavoisier used the heat from the guinea pig's respiration to melt snow surrounding his apparatus, showing that respiratory gas exchange is combustion, similar to a candle
2063:
Adiabatic calorimeters most commonly used in materials science research to study reactions that occur at a constant pressure and volume. They are particularly useful for determining the heat capacity of substances, measuring the enthalpy changes of chemical reactions, and studying the thermodynamic
424:
is used to ignite the fuel; as the fuel is burning, it will heat up the surrounding air, which expands and escapes through a tube that leads the air out of the calorimeter. When the air is escaping through the copper tube it will also heat up the water outside the tube. The change in temperature of
210:
calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry,
440:
in calculations), is submerged under a known volume of water (ca. 2000 ml) before the charge is electrically ignited. The bomb, with the known mass of the sample and oxygen, form a closed system — no gases escape during the reaction. The weighed reactant put inside the steel container is then
2368:
This has a number of advantages. It facilitates the direct measurement of the heat capacity in one measurement, even in (quasi-)isothermal conditions. It permits the simultaneous measurement of heat effects that respond to a changing heating rate (reversing) and that don't respond to the changing
449:
At its core, a bomb calorimeter consists of a small cup to contain the sample, oxygen, a stainless steel bomb, water, a stirrer, a thermometer, the dewar or insulating container (to prevent heat flow from the calorimeter to the surroundings) and an ignition circuit connected to the bomb. By using
2453:
In traditional heat flow calorimeters, one reactant is added continuously in small amounts, similar to a semi-batch process, in order to obtain a complete conversion of the reaction. In contrast to the tubular reactor, this leads to longer residence times, different substance concentrations and
1637:
in the bomb system can render combustible some compounds that are not normally flammable. Some substances do not combust completely, making the calculations harder as the remaining mass has to be taken into consideration, making the possible error considerably larger and compromising the data.
2457:
If the heat of reaction measured in the HFC (Heat flow calorimetry) and PFR calorimeter differ, most probably some side reactions have occurred. They could for example be caused by different temperatures and residence times. The totally measured Qr is composed of partially overlapped reaction
1437: 376:
The cooling/heating jacket controls either the temperature of the process or the temperature of the jacket. Heat is measured by monitoring the temperature difference between heat transfer fluid and the process fluid. In addition, fill volumes (i.e. wetted area), specific heat, heat transfer
2466:
Calorimeters can be used to measure the efficiency of geothermal energy conversion processes. Through measuring the heat input and output of the process, engineers can determine how effective the plant is at converting geothermal energy into usable electricity or other forms of energy.
1857:
cups, providing insulation from the surroundings, and a lid with two holes, allowing insertion of a thermometer and a stirring rod. The inner cup holds a known amount of a solvent, usually water, that absorbs the heat from the reaction. When the reaction occurs, the outer cup provides
344:
No adiabatic calorimeter is fully adiabatic - some heat will be lost by the sample to the sample holder. A mathematical correction factor, known as the phi-factor, can be used to adjust the calorimetric result to account for these heat losses. The phi-factor is the ratio of the
432:(typically at 30 standard atmospheres (3,000 kPa)) and containing a weighed mass of a sample (typically 1–1.5 g) and a small fixed amount of water (to saturate the internal atmosphere, thus ensuring that all water produced is liquid, and removing the need to include 2396:, it is necessary to deduct about 75–100 °C from the initial start of the observed exotherm to suggest a maximum temperature for the material. A much more accurate data set can be obtained from an adiabatic calorimeter, but such a test may take 2–3 days from 1533: 823: 340:
calorimeter is a calorimeter used to examine a runaway reaction. Since the calorimeter runs in an adiabatic environment, any heat generated by the material sample under test causes the sample to increase in temperature, thus fueling the reaction.
2539:
a slight deviation from strict etymology, for the sake of giving distinctness of idea, is excusable; and I could not derive the name entirely from Greek without approaching too near to the names of known instruments employed for other purposes."
2470:
Calorimeters can also monitor the quality of the steam extracted from the geothermal resource. By analyzing the heat content of the steam, engineers can ensure that the resource meets the required specifications for efficient energy production.
2369:
heating rate (non-reversing). It allows for the optimization of both sensitivity and resolution in a single test by allowing for a slow average heating rate (optimizing resolution) and a fast changing heating rate (optimizing sensitivity).
579: 419:
A bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of a particular reaction. Bomb calorimeters have to withstand the large pressure within the calorimeter as the reaction is being measured.
1641:
When working with compounds that are not as flammable (that might not combust completely) one solution would be to mix the compound with some flammable compounds with a known heat of combustion and make a pallet with the mixture. Once the
651: 393:
Power compensation uses a heater placed within the vessel to maintain a constant temperature. The energy supplied to this heater can be varied as reactions require and the calorimetry signal is purely derived from this electrical power.
2638:
Bech, N., Jensen, P. A., & Dam-Johansen, K. (2009). Determining the elemental composition of fuels by bomb calorimetry and the inverse correlation of HHV with elemental composition. Biomass & Bioenergy, 33(3), 534-537.
1299: 1007: 943: 368:
also be used to determine maximum heat release rate for chemical process engineering and for tracking the global kinetics of reactions. There are four main methods for measuring the heat in reaction calorimeter:
402:
Constant flux calorimetry (or COFLUX as it is often termed) is derived from heat balance calorimetry and uses specialized control mechanisms to maintain a constant heat flow (or flux) across the vessel wall.
2217: 1227: 1919: 1289: 1089: 1615: 2342: 1805:
or electrical calibration, has been developed to overcome all the problems encountered by a calibration done with standard materials. The main advantages of this type of calibration are as follows:
4153:
Bech, Niels; Jensen, Peter Arendt; Dam-Johansen, Kim (2009). "Determining the elemental composition of fuels by bomb calorimetry and the inverse correlation of HHV with elemental composition".
1171: 1133: 2392:
of a substance to heat. However, due to a combination of relatively poor sensitivity, slower than normal scan rates (typically 2–3 °C per min) due to much heavier crucible, and unknown
1798:. The main advantage of the setup is the increase of the experimental vessel's size and consequently the size of the sample, without affecting the accuracy of the calorimetric measurement. 1443: 2100:, both pans sit on a small slab of material with a known (calibrated) heat resistance K. The temperature of the calorimeter is raised linearly with time (scanned), i.e., the heating rate 1794:
the sensor on the full range of temperature of the Calvet-type calorimeter. In this setup, the sensitivity of the calorimeter is not affected by the crucible, the type of purgegas, or the
505: 296: 1242:
g) of benzoic acid, or p-methyl benzoic acid is weighed. A length of nickel fuse wire (~10 cm) is weighed both before and after the combustion process. Mass of fuse wire burned
755: 2118:
is kept constant. This time linearity requires good design and good (computerized) temperature control. Of course, controlled cooling and isothermal experiments are also possible.
878: 851: 684: 377:
coefficient have to be determined to arrive at a correct value. It is possible with this type of calorimeter to do reactions at reflux, although it is very less accurate.
1952: 1669: 1563: 1037: 747: 717: 1801:
The calibration of the calorimetric detectors is a key parameter and has to be performed very carefully. For Calvet-type calorimeters, a specific calibration, so called
1812:
The use of standard materials for calibration is not necessary. The calibration can be performed at a constant temperature, in the heating mode and in the cooling mode.
328: 2002: 1977: 516: 585: 2817: 2046: 2024: 1231:
A small factor contributes to the correction of the total heat of combustion is the fuse wire. Nickel fuse wire is often used and has heat of combustion: 981.2
4046: 4025: 2705: 1432:{\displaystyle \Delta H_{c}=\Delta H_{\ce {c(benzoic\ acid)}}m_{\ce {benzoic\ acid}}+\Delta H_{\ce {c(Ni\ fuse\ wire)}}\Delta m_{\ce {Ni\ fuse\ wire}}} 385:
The cooling/heating jacket controls the temperature of the process. Heat is measured by monitoring the heat gained or lost by the heat transfer fluid.
311:
is the heat capacity of the calorimeter which is a value associated with each individual apparatus in units of energy per temperature (joules/kelvin).
4135: 2629:
Bozzelli, J. (2010). Heat of Combustion via Calorimetry: Detailed Procedures. Chem 339-Physical Chemistry Lab for Chemical Engineers –Lab Manual.
949: 234:
given off or absorbed during the reaction. Dividing the energy change by how many moles of A were present gives its enthalpy change of reaction.
2759: 3661: 885: 2614: 222:
of a substance A in a reaction between two substances A and B, the substances are separately added to a calorimeter and the initial and final
2772: 2763: 2674: 2810: 2372:
A DSC may also be used as an initial safety screening tool. In this mode the sample will be housed in a non-reactive crucible (often
3722: 2073: 133: 2789:
Reaction Calorimetry in continuous flow mode. A new approach for the thermal characterization of high energetic and fast reactions
2153: 2056:
Commercial calorimeters operate in a similar way. The semi-adiabatic (isoperibol) calorimeters measure temperature changes up to 10
1183: 3699: 2409: 1868: 1245: 239: 2719:
Schröder, Elisabeth (2015). "Design and Test of a New Flow Calorimeter for Online Detection of Geothermal Water Heat Capacity".
1042: 1571: 4193: 2510: 2273: 71: 31: 453:
Since there is no heat exchange between the calorimeter and surroundings (Q = 0) (adiabatic), no work is performed (W = 0)
4198: 3990: 3879: 3220: 2803: 2422:) (N) of a reaction as well as its enthalpy (delta H), entropy (delta S) and of primary concern the binding affinity (Ka) 226:(before the reaction has started and after it has finished) are noted. Multiplying the temperature change by the mass and 114: 3694: 2418:
calorimeter, the heat of reaction is used to follow a titration experiment. This permits determination of the midpoint (
2267:
When suddenly heat is absorbed by the sample (e.g., when the sample melts), the signal will respond and exhibit a peak.
86: 67: 1528:{\displaystyle \Delta H_{\text{c}}=C_{\text{v}}\Delta T\ \rightarrow C_{\text{v}}={\Delta H_{\text{c}} \over \Delta T}} 1138: 1100: 3770: 3739: 3651: 462: 93: 60: 3894: 3225: 818:{\displaystyle C_{\text{v(calorimeter)}}=m_{\text{water}}C_{\text{v(water)}}+m_{\text{steel}}C_{\text{v(steel)}}} 722:
Before the bomb can be used to determine heat of combustion of any compound, it must be calibrated. The value of
3296: 2529:
Chisholm, Hugh, ed. (1911). "Black, Joseph". Encyclopædia Britannica. 4 (11th ed.). Cambridge University Press.
1565:
value of the bomb is determined, the bomb is ready to use to calculate heat of combustion of any compounds by
2899: 1822:
An example of Calvet-type calorimeter is the C80 Calorimeter (reaction, isothermal and scanning calorimeter).
100: 3729: 3646: 3110: 2783:
Continuous milli‑scale reaction calorimeter for direct scale‑up of flow chemistry Journal of Flow Chemistry
2649: 2090:
capsule or 'pan'—is measured differentially, i.e., by comparing it to the flow into an empty reference pan.
38: 2433:. The technique is commonly used in the pharmaceutical industry to characterize potential drug candidates. 3332: 3080: 3049: 2223: 227: 2365:(MTDSC) is a type of DSC in which a small oscillation is imposed upon the otherwise linear heating rate. 3322: 3200: 2912: 358: 82: 2121:
Heat flows into the two pans by conduction. The flow of heat into the sample is larger because of its
856: 829: 4203: 4162: 3618: 3278: 3120: 2728: 2505: 2500: 1847: 1839: 1795: 1790: 658: 159: 2351:
of this peak the enthalpy of melting can be determined, and from its onset the melting temperature.
3306: 3115: 3030: 2967: 2611: 2397: 1930: 1647: 1541: 1015: 725: 695: 3833: 3816: 3755: 3656: 3580: 3516: 3511: 3429: 3250: 2495: 2389: 1859: 574:{\displaystyle \Delta E_{\text{total}}=\Delta E_{\text{system}}+\Delta E_{\text{surroundings}}=0} 2441: 4101: 4091: 3899: 3889: 3666: 3470: 3460: 3455: 3301: 3215: 3210: 2962: 2699: 2572: 2393: 1984: 1959: 646:{\displaystyle \Delta E_{\text{system}}=-\Delta E_{\text{surroundings}}=-C_{\text{v}}\Delta T} 421: 364: 337: 195: 155: 4170: 3439: 3404: 3394: 3386: 3361: 3345: 3255: 3162: 3065: 2957: 2778: 2736: 2681: 2562: 2458:
enthalpies (ΔHr) of main and side reactions, depending on their degrees of conversion (U).
2354:
Differential scanning calorimetry is a workhorse technique in many fields, particularly in
4116: 3843: 3709: 3491: 3465: 3240: 3135: 2618: 199: 179: 167: 107: 4166: 2732: 4111: 4061: 3951: 3925: 3869: 3826: 3821: 3760: 3419: 3409: 3070: 2952: 2917: 2879: 2864: 2031: 2009: 2740: 450:
stainless steel for the bomb, the reaction will occur with no volume change observed.
4187: 4056: 3935: 3765: 3434: 3371: 3035: 2869: 2419: 2122: 1802: 442: 203: 302:
is the amount of heat according to the change in temperature measured in joules and
4174: 4096: 3884: 3848: 3775: 3671: 3641: 3636: 3564: 3399: 3185: 3140: 3057: 3025: 3008: 2987: 2977: 2907: 2889: 2426: 2144: 1782: 1094: 437: 346: 171: 2227: 2550: 428:
In more recent calorimeter designs, the whole bomb, pressurized with excess pure
4010: 3838: 3798: 3734: 3590: 3559: 3544: 3539: 3501: 3376: 3340: 3190: 2992: 2947: 223: 219: 191: 175: 49: 17: 411: 4015: 4005: 3956: 3874: 3686: 3531: 3506: 3366: 3245: 3205: 3175: 3130: 3125: 3105: 3075: 2972: 2874: 2826: 2768: 2385: 2381: 1786: 146: 2784: 2567: 1853:
An example is a coffee-cup calorimeter, which is constructed from two nested
4106: 3904: 3554: 3167: 2982: 2942: 2884: 2415: 2095: 2087: 2083: 1854: 1843: 1778: 207: 2790: 2576: 1002:{\displaystyle C_{\text{v(steel)}}=0.1{\text{ cal g}}^{-1}{\text{ K}}^{-1}} 2596:
Bozzeli, J. W. "Heat of Combustion via Calorimetry: Detailed Procedures".
30:
This article is about heat measuring devices. For particle detectors, see
4051: 3930: 3920: 3676: 3585: 3549: 3230: 3180: 2480: 2377: 2348: 2053:
solution. Under these conditions the change in enthalpy equals the heat.
1835: 1039:
is determined by running a compound with known heat of combustion value:
938:{\displaystyle C_{\text{v(water)}}=1{\text{ cal g}}^{-1}{\text{ K}}^{-1}} 433: 349:
of the sample and sample holder to the thermal mass of the sample alone.
215: 1673:
of the bomb is known, the heat of combustion of the flammable compound (
4071: 4066: 3864: 3521: 3496: 3486: 3414: 3235: 3195: 2795: 2490: 2355: 3424: 2430: 2147:. The heat capacity can in principle be determined from this signal: 429: 231: 206:. Differential scanning calorimeters, isothermal micro calorimeters, 2425:
The technique is gaining in importance particularly in the field of
1842:
during which the no heat exchange with the surroundings is allowed (
4041: 4020: 2440: 410: 327: 145: 2653: 2143:
across the slab. This temperature difference is measured using a
3595: 2894: 2612:
http://www.chem.hope.edu/~polik/Chem345-2000/bombcalorimetry.htm
2485: 2373: 163: 3977: 3796: 3616: 3276: 2837: 2799: 2429:, because it facilitates determination of substrate binding to 425:
the water allows for calculating calorie content of the fuel.
43: 2376:, or gold-plated steel), and which will be able to withstand 2212:{\displaystyle \Delta T=K{dq \over dt}=KC_{\text{p}}\,\beta } 1781:
sensor. The fluxmeter element consists of a ring of several
1222:{\displaystyle \Delta T=T_{\text{final}}-T_{\text{initial}}} 1914:{\displaystyle C_{\text{p}}={\frac {W\Delta H}{M\Delta T}}} 1284:{\displaystyle \Delta m=m_{\text{before}}-m_{\text{after}}} 1713:), the heat of combustion of the less flammable compound ( 1084:{\displaystyle C_{\text{v}}={H_{\text{c}} \over \Delta T}} 1610:{\displaystyle \Delta H_{\text{c}}=C_{\text{v}}\Delta T} 1293:
The combustion of sample (benzoic acid) inside the bomb
2363:
modulated temperature differential scanning calorimeter
2337:{\displaystyle {dq \over dt}=C_{\text{p}}\beta +f(t,T)} 2598:
Chem 339-Physical Chemistry Lab for Chemical Engineers
2610:
Polik, W. (1997). Bomb Calorimetery. Retrieved from
2276: 2156: 2034: 2012: 1987: 1962: 1933: 1871: 1650: 1574: 1544: 1446: 1302: 1248: 1186: 1141: 1103: 1045: 1018: 952: 888: 859: 832: 758: 728: 698: 661: 588: 519: 465: 242: 1815:
It can be applied to any experimental vessel volume.
4084: 4034: 3988: 3944: 3913: 3857: 3809: 3748: 3708: 3685: 3629: 3573: 3530: 3479: 3448: 3385: 3354: 3331: 3315: 3289: 3155: 3089: 3001: 2926: 2848: 1238:
In order to calibrate the bomb, a small amount (~ 1
363:A reaction calorimeter is a calorimeter in which a 74:. Unsourced material may be challenged and removed. 2336: 2211: 2040: 2018: 1996: 1971: 1946: 1913: 1663: 1609: 1557: 1527: 1431: 1283: 1221: 1165: 1127: 1083: 1031: 1001: 937: 872: 845: 817: 741: 711: 678: 645: 573: 499: 290: 2400:at a rate of 3 °C increment per half hour. 1166:{\displaystyle H_{\text{c}}=6957{\text{ cal/g}}} 1128:{\displaystyle H_{\text{c}}=6318{\text{ cal/g}}} 2549:Buchholz, Andrea C; Schoeller, Dale A. (2004). 1834:, adiabatic calorimeters measure the change in 332:The Calorimeter of Lavoisier and La Place, 1801 2650:"C80 Calorimeter from Setaram Instrumentation" 1777:The detection is based on a three-dimensional 2811: 500:{\displaystyle \Delta E_{\text{total}}=Q+W=0} 8: 178:. These experiments mark the foundation of 3771:Nuclear magnetic resonance (NMR) instrument 2769:Fact Sheet: Isothermal Battery Calorimeters 2086:into a sample—usually contained in a small 291:{\displaystyle q=C_{\text{v}}(T_{f}-T_{i})} 3998: 3985: 3974: 3806: 3793: 3626: 3613: 3286: 3273: 2845: 2834: 2818: 2804: 2796: 2785:https://doi.org/10.1007/s41981-021-00204-y 194:, or the process of measuring the heat of 2566: 2304: 2277: 2275: 2205: 2199: 2169: 2155: 2033: 2011: 1986: 1961: 1938: 1932: 1885: 1876: 1870: 1655: 1649: 1625:The higher pressure and concentration of 1595: 1582: 1573: 1549: 1543: 1508: 1498: 1489: 1467: 1454: 1445: 1411: 1379: 1375: 1353: 1330: 1326: 1310: 1301: 1275: 1262: 1247: 1213: 1200: 1185: 1158: 1146: 1140: 1120: 1108: 1102: 1065: 1059: 1050: 1044: 1023: 1017: 990: 985: 975: 970: 957: 951: 926: 921: 911: 906: 893: 887: 864: 858: 837: 831: 809: 799: 786: 776: 763: 757: 733: 727: 703: 697: 662: 660: 631: 615: 596: 587: 559: 543: 527: 518: 473: 464: 279: 266: 253: 241: 134:Learn how and when to remove this message 4136:Instruments used in medical laboratories 2791:https://doi.org/10.1021/acs.oprd.0c00117 2226:) is analogous to, and much older than, 2139:induces a small temperature difference Δ 230:of the substances gives a value for the 4155:Biomass & Bioenergy, 33(3), 534-537 4145: 3652:Inductively coupled plasma (ICP) device 2522: 456:Thus, the total internal energy change 3700:Transmission electron microscope (TEM) 2779:Fluitec Contiplant Continuous Reactors 2704:: CS1 maint: archived copy as title ( 2697: 2555:American Journal of Clinical Nutrition 2222:Note that this formula (equivalent to 2388:event can then be used to assess the 1826:Adiabatic and Isoperibol calorimeters 7: 2773:National Renewable Energy Laboratory 2764:National Renewable Energy Laboratory 1954:, Specific heat at constant pressure 154:, used in the winter of 1782–83, by 72:adding citations to reliable sources 510:Also, total internal energy change 170:; calculations which were based on 3695:Scanning electron microscope (SEM) 2462:Calorimetry in Geothermal Reactors 2157: 1988: 1963: 1902: 1891: 1818:It is a very accurate calibration. 1601: 1575: 1516: 1501: 1473: 1447: 1404: 1368: 1319: 1303: 1249: 1187: 1072: 663: 637: 608: 589: 552: 536: 520: 466: 25: 2741:10.1016/j.geothermics.2014.06.001 2080:differential scanning calorimeter 2074:Differential scanning calorimetry 2068:Differential scanning calorimeter 3740:Thermogravimetric analyzer (TGA) 3550:Nuclear magnetic resonance (NMR) 2410:Isothermal titration calorimetry 2404:Isothermal titration calorimeter 1709:), and the temperature change (Δ 873:{\displaystyle m_{\text{steel}}} 846:{\displaystyle m_{\text{water}}} 48: 2760:Isothermal Battery Calorimeters 2445:Continuous reaction calorimeter 2437:Continuous Reaction Calorimeter 1180:) is recorded every minute and 679:{\displaystyle \mathrm {d} V=0} 59:needs additional citations for 4175:10.1016/j.biombioe.2008.08.015 2639:10.1016/j.biombioe.2008.08.015 2511:Calorimeter (particle physics) 2331: 2319: 1832:constant-pressure calorimeters 1809:It is an absolute calibration. 1482: 1398: 1380: 1343: 1331: 285: 259: 32:Calorimeter (particle physics) 1: 1785:in series. The corresponding 719:is heat capacity of the bomb 27:Instrument for measuring heat 1947:{\displaystyle C_{\text{p}}} 1664:{\displaystyle C_{\text{v}}} 1621:Combustion of non-flammables 1558:{\displaystyle C_{\text{v}}} 1135:) or p-methyl benzoic acid ( 1032:{\displaystyle C_{\text{v}}} 742:{\displaystyle C_{\text{v}}} 712:{\displaystyle C_{\text{v}}} 2048:, molecular mass of solvent 1838:of a reaction occurring in 4220: 2407: 2071: 1722:) can be calculated with: 356: 36: 29: 4133: 4001: 3984: 3973: 3895:Time-domain reflectometer 3805: 3792: 3662:Liquid chromatograph (LC) 3625: 3612: 3285: 3272: 2844: 2833: 2551:"Is a Calorie a Calorie?" 2224:Newton's law of heat flow 2131:. The difference in flow 2064:properties of materials. 1830:Sometimes referred to as 446:in the bomb is released. 1997:{\displaystyle \Delta T} 1972:{\displaystyle \Delta H} 1773:Calvet-type calorimeters 381:Heat balance calorimeter 228:specific heat capacities 37:Not to be confused with 3730:Melting-point apparatus 3111:Cryogenic storage dewar 2004:, Change in temperature 39:Colorimeter (chemistry) 3667:Mass spectrometer (MS) 3657:Gas chromatograph (GC) 2568:10.1093/ajcn/79.5.899S 2446: 2384:). The presence of an 2338: 2213: 2042: 2020: 1998: 1979:, Enthalpy of solution 1973: 1948: 1915: 1665: 1611: 1559: 1529: 1433: 1285: 1223: 1167: 1129: 1085: 1033: 1003: 939: 874: 847: 819: 743: 713: 680: 647: 575: 501: 416: 333: 324:Adiabatic calorimeters 292: 183: 174:'s prior discovery of 4194:Measuring instruments 4042:Acid-resistant gloves 3723:differential scanning 2444: 2380:(typically up to 100 2339: 2214: 2043: 2021: 1999: 1974: 1949: 1916: 1666: 1612: 1560: 1530: 1434: 1286: 1224: 1168: 1130: 1093:Common compounds are 1086: 1034: 1004: 940: 875: 848: 820: 744: 714: 681: 648: 576: 502: 414: 372:Heat flow calorimeter 359:Reaction calorimeters 353:Reaction calorimeters 331: 293: 190:is a device used for 149: 4199:Laboratory equipment 3619:Analytical chemistry 3121:Laminar flow cabinet 2827:Laboratory equipment 2506:Reaction calorimeter 2501:Calorimeter constant 2274: 2154: 2032: 2010: 1985: 1960: 1931: 1869: 1848:atmospheric pressure 1791:thermal conductivity 1648: 1572: 1542: 1444: 1300: 1246: 1184: 1139: 1101: 1043: 1016: 950: 886: 857: 830: 756: 749:can be estimated by 726: 696: 659: 586: 517: 463: 240: 166:involved in various 160:Pierre-Simon Laplace 68:improve this article 4167:2009BmBe...33..534B 3991:Personal protective 2900:Meker–Fisher burner 2733:2015Geoth..53..202S 1012:In the laboratory, 162:, to determine the 3834:Function generator 3817:Bench power supply 3756:Analytical balance 3517:Ostwald viscometer 3512:Graduated cylinder 3251:Inoculation needle 2617:2015-10-06 at the 2496:Heat of combustion 2447: 2358:characterization. 2334: 2230:of electric flow: 2209: 2038: 2016: 1994: 1969: 1944: 1911: 1850:remains constant. 1691:) and the masses ( 1661: 1607: 1555: 1525: 1429: 1281: 1219: 1163: 1125: 1081: 1029: 999: 935: 870: 843: 815: 739: 709: 676: 643: 571: 497: 417: 389:Power compensation 334: 288: 211:and biochemistry. 196:chemical reactions 184: 150:The world's first 4142: 4141: 4129: 4128: 4125: 4124: 4102:Fire extinguisher 4092:Biosafety cabinet 4080: 4079: 3969: 3968: 3965: 3964: 3900:Transistor tester 3890:Spectrum analyzer 3788: 3787: 3784: 3783: 3608: 3607: 3604: 3603: 3480:Measuring devices 3302:Soxhlet extractor 3268: 3267: 3264: 3263: 3216:Spectrophotometer 3211:Pipeclay triangle 2963:Mortar and pestle 2414:In an isothermal 2394:activation energy 2307: 2295: 2202: 2187: 2041:{\displaystyle M} 2026:, mass of solvent 2019:{\displaystyle W} 1941: 1909: 1879: 1658: 1598: 1585: 1552: 1523: 1511: 1492: 1481: 1470: 1457: 1426: 1423: 1420: 1417: 1414: 1397: 1394: 1391: 1388: 1385: 1378: 1362: 1359: 1356: 1342: 1339: 1336: 1329: 1278: 1265: 1216: 1203: 1161: 1149: 1123: 1111: 1079: 1068: 1053: 1026: 988: 973: 960: 924: 909: 896: 867: 840: 812: 802: 789: 779: 766: 736: 706: 655:(constant volume 634: 618: 599: 562: 546: 530: 476: 422:Electrical energy 407:Bomb calorimeters 365:chemical reaction 256: 156:Antoine Lavoisier 144: 143: 136: 118: 16:(Redirected from 4211: 4179: 4178: 4150: 3999: 3986: 3975: 3880:Network analyzer 3807: 3794: 3627: 3614: 3287: 3274: 3256:Inoculation loop 3126:Microtiter plate 3066:Test tube holder 2958:Magnetic stirrer 2846: 2835: 2820: 2813: 2806: 2797: 2745: 2744: 2716: 2710: 2709: 2703: 2695: 2693: 2692: 2686: 2680:. Archived from 2679: 2671: 2665: 2664: 2662: 2661: 2652:. Archived from 2646: 2640: 2636: 2630: 2627: 2621: 2608: 2602: 2601: 2593: 2587: 2586: 2584: 2583: 2570: 2561:(5): 899S–906S. 2546: 2540: 2536: 2530: 2527: 2343: 2341: 2340: 2335: 2309: 2308: 2305: 2296: 2294: 2286: 2278: 2262: 2256: 2254: 2253: 2250: 2247: 2218: 2216: 2215: 2210: 2204: 2203: 2200: 2188: 2186: 2178: 2170: 2059: 2047: 2045: 2044: 2039: 2025: 2023: 2022: 2017: 2003: 2001: 2000: 1995: 1978: 1976: 1975: 1970: 1953: 1951: 1950: 1945: 1943: 1942: 1939: 1920: 1918: 1917: 1912: 1910: 1908: 1897: 1886: 1881: 1880: 1877: 1721: 1708: 1699: 1690: 1682:), of the wire ( 1681: 1672: 1670: 1668: 1667: 1662: 1660: 1659: 1656: 1636: 1635: 1634: 1616: 1614: 1613: 1608: 1600: 1599: 1596: 1587: 1586: 1583: 1564: 1562: 1561: 1556: 1554: 1553: 1550: 1534: 1532: 1531: 1526: 1524: 1522: 1514: 1513: 1512: 1509: 1499: 1494: 1493: 1490: 1479: 1472: 1471: 1468: 1459: 1458: 1455: 1438: 1436: 1435: 1430: 1428: 1427: 1424: 1421: 1418: 1415: 1412: 1403: 1402: 1401: 1395: 1392: 1389: 1386: 1383: 1376: 1364: 1363: 1360: 1357: 1354: 1348: 1347: 1346: 1340: 1337: 1334: 1327: 1315: 1314: 1290: 1288: 1287: 1282: 1280: 1279: 1276: 1267: 1266: 1263: 1241: 1234: 1228: 1226: 1225: 1220: 1218: 1217: 1214: 1205: 1204: 1201: 1179: 1172: 1170: 1169: 1164: 1162: 1159: 1151: 1150: 1147: 1134: 1132: 1131: 1126: 1124: 1121: 1113: 1112: 1109: 1090: 1088: 1087: 1082: 1080: 1078: 1070: 1069: 1066: 1060: 1055: 1054: 1051: 1038: 1036: 1035: 1030: 1028: 1027: 1024: 1008: 1006: 1005: 1000: 998: 997: 989: 986: 983: 982: 974: 971: 962: 961: 958: 944: 942: 941: 936: 934: 933: 925: 922: 919: 918: 910: 907: 898: 897: 894: 880:can be measured; 879: 877: 876: 871: 869: 868: 865: 852: 850: 849: 844: 842: 841: 838: 824: 822: 821: 816: 814: 813: 810: 804: 803: 800: 791: 790: 787: 781: 780: 777: 768: 767: 764: 748: 746: 745: 740: 738: 737: 734: 718: 716: 715: 710: 708: 707: 704: 685: 683: 682: 677: 666: 652: 650: 649: 644: 636: 635: 632: 620: 619: 616: 601: 600: 597: 580: 578: 577: 572: 564: 563: 560: 548: 547: 544: 532: 531: 528: 506: 504: 503: 498: 478: 477: 474: 415:Bomb calorimeter 310: 301: 297: 295: 294: 289: 284: 283: 271: 270: 258: 257: 254: 200:physical changes 168:chemical changes 139: 132: 128: 125: 119: 117: 76: 52: 44: 21: 18:Bomb calorimeter 4219: 4218: 4214: 4213: 4212: 4210: 4209: 4208: 4184: 4183: 4182: 4152: 4151: 4147: 4143: 4138: 4121: 4117:Solvent cabinet 4076: 4047:Eyewash station 4030: 3995: 3993:equipment (PPE) 3992: 3980: 3961: 3940: 3909: 3853: 3844:Pulse generator 3810:Control devices 3801: 3780: 3744: 3710:Thermochemistry 3704: 3681: 3621: 3600: 3569: 3526: 3492:Conical measure 3475: 3444: 3381: 3350: 3327: 3311: 3281: 3260: 3241:Test tube brush 3151: 3136:Picotiter plate 3099: 3085: 3081:Lab drying rack 3040:Extension clamp 3016: 2997: 2936: 2922: 2858: 2840: 2829: 2824: 2756: 2749: 2748: 2718: 2717: 2713: 2696: 2690: 2688: 2684: 2677: 2675:"Archived copy" 2673: 2672: 2668: 2659: 2657: 2648: 2647: 2643: 2637: 2633: 2628: 2624: 2619:Wayback Machine 2609: 2605: 2595: 2594: 2590: 2581: 2579: 2548: 2547: 2543: 2537: 2533: 2528: 2524: 2519: 2477: 2464: 2439: 2412: 2406: 2300: 2287: 2279: 2272: 2271: 2251: 2248: 2245: 2244: 2242: 2234: 2195: 2179: 2171: 2152: 2151: 2130: 2076: 2070: 2057: 2030: 2029: 2008: 2007: 1983: 1982: 1958: 1957: 1934: 1929: 1928: 1898: 1887: 1872: 1867: 1866: 1828: 1775: 1768: 1762: 1755: 1749: 1738: 1731: 1720: 1714: 1707: 1701: 1698: 1692: 1689: 1683: 1680: 1674: 1651: 1646: 1645: 1643: 1633: 1630: 1629: 1628: 1626: 1623: 1591: 1578: 1570: 1569: 1545: 1540: 1539: 1515: 1504: 1500: 1485: 1463: 1450: 1442: 1441: 1407: 1371: 1349: 1322: 1306: 1298: 1297: 1271: 1258: 1244: 1243: 1239: 1232: 1209: 1196: 1182: 1181: 1177: 1142: 1137: 1136: 1104: 1099: 1098: 1071: 1061: 1046: 1041: 1040: 1019: 1014: 1013: 984: 969: 953: 948: 947: 920: 905: 889: 884: 883: 860: 855: 854: 833: 828: 827: 805: 795: 782: 772: 759: 754: 753: 729: 724: 723: 699: 694: 693: 657: 656: 627: 611: 592: 584: 583: 555: 539: 523: 515: 514: 469: 461: 460: 409: 400: 391: 383: 374: 361: 355: 326: 317: 309: 303: 299: 275: 262: 249: 238: 237: 180:thermochemistry 152:ice-calorimeter 140: 129: 123: 120: 77: 75: 65: 53: 42: 35: 28: 23: 22: 15: 12: 11: 5: 4217: 4215: 4207: 4206: 4201: 4196: 4186: 4185: 4181: 4180: 4144: 4140: 4139: 4134: 4131: 4130: 4127: 4126: 4123: 4122: 4120: 4119: 4114: 4112:Safety cabinet 4109: 4104: 4099: 4094: 4088: 4086: 4082: 4081: 4078: 4077: 4075: 4074: 4072:Safety goggles 4069: 4067:Safety glasses 4064: 4062:Nitrile gloves 4059: 4057:Medical gloves 4054: 4049: 4044: 4038: 4036: 4032: 4031: 4029: 4028: 4023: 4018: 4013: 4008: 4002: 3996: 3989: 3982: 3981: 3978: 3971: 3970: 3967: 3966: 3963: 3962: 3960: 3959: 3954: 3952:Alligator clip 3948: 3946: 3942: 3941: 3939: 3938: 3933: 3928: 3926:Soldering iron 3923: 3917: 3915: 3911: 3910: 3908: 3907: 3902: 3897: 3892: 3887: 3882: 3877: 3872: 3870:Logic analyzer 3867: 3861: 3859: 3855: 3854: 3852: 3851: 3846: 3841: 3836: 3831: 3830: 3829: 3827:Voltage source 3824: 3822:Current source 3813: 3811: 3803: 3802: 3797: 3790: 3789: 3786: 3785: 3782: 3781: 3779: 3778: 3773: 3768: 3763: 3761:Colony counter 3758: 3752: 3750: 3746: 3745: 3743: 3742: 3737: 3732: 3727: 3726: 3725: 3714: 3712: 3706: 3705: 3703: 3702: 3697: 3691: 3689: 3683: 3682: 3680: 3679: 3674: 3669: 3664: 3659: 3654: 3649: 3644: 3639: 3633: 3631: 3623: 3622: 3617: 3610: 3609: 3606: 3605: 3602: 3601: 3599: 3598: 3593: 3588: 3583: 3577: 3575: 3571: 3570: 3568: 3567: 3562: 3557: 3552: 3547: 3542: 3536: 3534: 3528: 3527: 3525: 3524: 3519: 3514: 3509: 3504: 3499: 3494: 3489: 3483: 3481: 3477: 3476: 3474: 3473: 3468: 3463: 3458: 3452: 3450: 3446: 3445: 3443: 3442: 3437: 3432: 3427: 3422: 3417: 3412: 3407: 3402: 3400:Vacuum (Dewar) 3397: 3391: 3389: 3383: 3382: 3380: 3379: 3374: 3369: 3364: 3358: 3356: 3352: 3351: 3349: 3348: 3343: 3337: 3335: 3329: 3328: 3326: 3325: 3319: 3317: 3313: 3312: 3310: 3309: 3304: 3299: 3293: 3291: 3283: 3282: 3277: 3270: 3269: 3266: 3265: 3262: 3261: 3259: 3258: 3253: 3248: 3243: 3238: 3233: 3228: 3223: 3218: 3213: 3208: 3203: 3198: 3193: 3188: 3183: 3178: 3173: 3170: 3165: 3159: 3157: 3153: 3152: 3150: 3149: 3146: 3143: 3138: 3133: 3128: 3123: 3118: 3113: 3108: 3102: 3100: 3098: 3097: 3094: 3090: 3087: 3086: 3084: 3083: 3078: 3073: 3071:Test tube rack 3068: 3063: 3060: 3055: 3052: 3047: 3046:Funnel support 3044: 3041: 3038: 3033: 3028: 3023: 3019: 3017: 3015: 3014: 3011: 3006: 3002: 2999: 2998: 2996: 2995: 2990: 2985: 2980: 2975: 2970: 2965: 2960: 2955: 2953:Liquid whistle 2950: 2945: 2939: 2937: 2935: 2934: 2931: 2927: 2924: 2923: 2921: 2920: 2918:Vacuum dry box 2915: 2910: 2905: 2902: 2897: 2892: 2887: 2882: 2880:Heating mantle 2877: 2872: 2867: 2865:Alcohol burner 2861: 2859: 2857: 2856: 2853: 2849: 2842: 2841: 2838: 2831: 2830: 2825: 2823: 2822: 2815: 2808: 2800: 2794: 2793: 2787: 2781: 2776: 2766: 2755: 2754:External links 2752: 2747: 2746: 2711: 2666: 2641: 2631: 2622: 2603: 2588: 2541: 2531: 2521: 2520: 2518: 2515: 2514: 2513: 2508: 2503: 2498: 2493: 2488: 2483: 2476: 2473: 2463: 2460: 2438: 2435: 2408:Main article: 2405: 2402: 2345: 2344: 2333: 2330: 2327: 2324: 2321: 2318: 2315: 2312: 2303: 2299: 2293: 2290: 2285: 2282: 2265: 2264: 2220: 2219: 2208: 2198: 2194: 2191: 2185: 2182: 2177: 2174: 2168: 2165: 2162: 2159: 2128: 2116: 2115: 2072:Main article: 2069: 2066: 2050: 2049: 2037: 2027: 2015: 2005: 1993: 1990: 1980: 1968: 1965: 1955: 1937: 1922: 1921: 1907: 1904: 1901: 1896: 1893: 1890: 1884: 1875: 1827: 1824: 1820: 1819: 1816: 1813: 1810: 1774: 1771: 1770: 1769: 1766: 1760: 1753: 1747: 1736: 1729: 1716: 1703: 1694: 1685: 1676: 1654: 1631: 1622: 1619: 1618: 1617: 1606: 1603: 1594: 1590: 1581: 1577: 1548: 1536: 1535: 1521: 1518: 1507: 1503: 1497: 1488: 1484: 1478: 1475: 1466: 1462: 1453: 1449: 1439: 1410: 1406: 1400: 1382: 1374: 1370: 1367: 1352: 1345: 1333: 1325: 1321: 1318: 1313: 1309: 1305: 1274: 1270: 1261: 1257: 1254: 1251: 1212: 1208: 1199: 1195: 1192: 1189: 1157: 1154: 1145: 1119: 1116: 1107: 1077: 1074: 1064: 1058: 1049: 1022: 1010: 1009: 996: 993: 981: 978: 968: 965: 956: 945: 932: 929: 917: 914: 904: 901: 892: 881: 863: 836: 825: 808: 798: 794: 785: 775: 771: 765:v(calorimeter) 762: 732: 702: 690: 689: 688: 687: 675: 672: 669: 665: 642: 639: 630: 626: 623: 614: 610: 607: 604: 595: 591: 581: 570: 567: 558: 554: 551: 542: 538: 535: 526: 522: 508: 507: 496: 493: 490: 487: 484: 481: 472: 468: 408: 405: 399: 396: 390: 387: 382: 379: 373: 370: 357:Main article: 354: 351: 325: 322: 316: 313: 307: 287: 282: 278: 274: 269: 265: 261: 252: 248: 245: 142: 141: 56: 54: 47: 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 4216: 4205: 4202: 4200: 4197: 4195: 4192: 4191: 4189: 4176: 4172: 4168: 4164: 4160: 4156: 4149: 4146: 4137: 4132: 4118: 4115: 4113: 4110: 4108: 4105: 4103: 4100: 4098: 4095: 4093: 4090: 4089: 4087: 4083: 4073: 4070: 4068: 4065: 4063: 4060: 4058: 4055: 4053: 4050: 4048: 4045: 4043: 4040: 4039: 4037: 4033: 4027: 4026:Safety shower 4024: 4022: 4019: 4017: 4014: 4012: 4009: 4007: 4004: 4003: 4000: 3997: 3994: 3987: 3983: 3976: 3972: 3958: 3955: 3953: 3950: 3949: 3947: 3943: 3937: 3936:Wire stripper 3934: 3932: 3929: 3927: 3924: 3922: 3919: 3918: 3916: 3912: 3906: 3903: 3901: 3898: 3896: 3893: 3891: 3888: 3886: 3883: 3881: 3878: 3876: 3873: 3871: 3868: 3866: 3863: 3862: 3860: 3856: 3850: 3847: 3845: 3842: 3840: 3837: 3835: 3832: 3828: 3825: 3823: 3820: 3819: 3818: 3815: 3814: 3812: 3808: 3804: 3800: 3795: 3791: 3777: 3774: 3772: 3769: 3767: 3766:Spiral plater 3764: 3762: 3759: 3757: 3754: 3753: 3751: 3747: 3741: 3738: 3736: 3733: 3731: 3728: 3724: 3721: 3720: 3719: 3716: 3715: 3713: 3711: 3707: 3701: 3698: 3696: 3693: 3692: 3690: 3688: 3684: 3678: 3675: 3673: 3670: 3668: 3665: 3663: 3660: 3658: 3655: 3653: 3650: 3648: 3645: 3643: 3640: 3638: 3635: 3634: 3632: 3630:Compositional 3628: 3624: 3620: 3615: 3611: 3597: 3594: 3592: 3589: 3587: 3584: 3582: 3579: 3578: 3576: 3572: 3566: 3563: 3561: 3558: 3556: 3553: 3551: 3548: 3546: 3543: 3541: 3538: 3537: 3535: 3533: 3529: 3523: 3520: 3518: 3515: 3513: 3510: 3508: 3505: 3503: 3500: 3498: 3495: 3493: 3490: 3488: 3485: 3484: 3482: 3478: 3472: 3469: 3467: 3464: 3462: 3459: 3457: 3454: 3453: 3451: 3447: 3441: 3438: 3436: 3433: 3431: 3428: 3426: 3423: 3421: 3418: 3416: 3413: 3411: 3408: 3406: 3403: 3401: 3398: 3396: 3393: 3392: 3390: 3388: 3384: 3378: 3375: 3373: 3370: 3368: 3365: 3363: 3360: 3359: 3357: 3353: 3347: 3344: 3342: 3339: 3338: 3336: 3334: 3330: 3324: 3321: 3320: 3318: 3314: 3308: 3305: 3303: 3300: 3298: 3295: 3294: 3292: 3288: 3284: 3280: 3275: 3271: 3257: 3254: 3252: 3249: 3247: 3244: 3242: 3239: 3237: 3234: 3232: 3229: 3227: 3224: 3222: 3219: 3217: 3214: 3212: 3209: 3207: 3204: 3202: 3199: 3197: 3194: 3192: 3189: 3187: 3184: 3182: 3179: 3177: 3174: 3172:Balance brush 3171: 3169: 3166: 3164: 3161: 3160: 3158: 3154: 3148:Weighing dish 3147: 3145:Weighing boat 3144: 3142: 3139: 3137: 3134: 3132: 3129: 3127: 3124: 3122: 3119: 3117: 3114: 3112: 3109: 3107: 3104: 3103: 3101: 3095: 3092: 3091: 3088: 3082: 3079: 3077: 3074: 3072: 3069: 3067: 3064: 3061: 3059: 3056: 3053: 3051: 3048: 3045: 3042: 3039: 3037: 3036:Burette clamp 3034: 3032: 3029: 3027: 3024: 3021: 3020: 3018: 3012: 3010: 3007: 3004: 3003: 3000: 2994: 2991: 2989: 2986: 2984: 2981: 2979: 2976: 2974: 2971: 2969: 2966: 2964: 2961: 2959: 2956: 2954: 2951: 2949: 2946: 2944: 2941: 2940: 2938: 2932: 2929: 2928: 2925: 2919: 2916: 2914: 2911: 2909: 2906: 2903: 2901: 2898: 2896: 2893: 2891: 2888: 2886: 2883: 2881: 2878: 2876: 2873: 2871: 2870:Bunsen burner 2868: 2866: 2863: 2862: 2860: 2854: 2851: 2850: 2847: 2843: 2836: 2832: 2828: 2821: 2816: 2814: 2809: 2807: 2802: 2801: 2798: 2792: 2788: 2786: 2782: 2780: 2777: 2774: 2770: 2767: 2765: 2761: 2758: 2757: 2753: 2751: 2742: 2738: 2734: 2730: 2726: 2722: 2715: 2712: 2707: 2701: 2687:on 2014-07-29 2683: 2676: 2670: 2667: 2656:on 2010-05-31 2655: 2651: 2645: 2642: 2635: 2632: 2626: 2623: 2620: 2616: 2613: 2607: 2604: 2599: 2592: 2589: 2578: 2574: 2569: 2564: 2560: 2556: 2552: 2545: 2542: 2535: 2532: 2526: 2523: 2516: 2512: 2509: 2507: 2504: 2502: 2499: 2497: 2494: 2492: 2489: 2487: 2484: 2482: 2479: 2478: 2474: 2472: 2468: 2461: 2459: 2455: 2451: 2443: 2436: 2434: 2432: 2428: 2423: 2421: 2420:stoichiometry 2417: 2411: 2403: 2401: 2399: 2395: 2391: 2387: 2383: 2379: 2375: 2370: 2366: 2364: 2359: 2357: 2352: 2350: 2328: 2325: 2322: 2316: 2313: 2310: 2301: 2297: 2291: 2288: 2283: 2280: 2270: 2269: 2268: 2261: 2257: 2238: 2233: 2232: 2231: 2229: 2225: 2206: 2196: 2192: 2189: 2183: 2180: 2175: 2172: 2166: 2163: 2160: 2150: 2149: 2148: 2146: 2142: 2138: 2134: 2127: 2124: 2123:heat capacity 2119: 2114: 2110: 2106: 2103: 2102: 2101: 2099: 2097: 2091: 2089: 2085: 2081: 2075: 2067: 2065: 2061: 2054: 2035: 2028: 2013: 2006: 1991: 1981: 1966: 1956: 1935: 1927: 1926: 1925: 1905: 1899: 1894: 1888: 1882: 1873: 1865: 1864: 1863: 1861: 1856: 1851: 1849: 1845: 1841: 1837: 1833: 1825: 1823: 1817: 1814: 1811: 1808: 1807: 1806: 1804: 1799: 1797: 1792: 1788: 1784: 1783:thermocouples 1780: 1772: 1765: 1759: 1752: 1746: 1742: 1735: 1728: 1725: 1724: 1723: 1719: 1712: 1706: 1697: 1688: 1679: 1652: 1639: 1620: 1604: 1592: 1588: 1579: 1568: 1567: 1566: 1546: 1519: 1505: 1495: 1486: 1476: 1464: 1460: 1451: 1440: 1408: 1372: 1365: 1350: 1323: 1316: 1311: 1307: 1296: 1295: 1294: 1291: 1272: 1268: 1259: 1255: 1252: 1236: 1229: 1210: 1206: 1197: 1193: 1190: 1176:Temperature ( 1174: 1155: 1152: 1143: 1117: 1114: 1105: 1096: 1091: 1075: 1062: 1056: 1047: 1020: 994: 991: 979: 976: 966: 963: 954: 946: 930: 927: 915: 912: 902: 899: 890: 882: 861: 834: 826: 806: 796: 792: 783: 773: 769: 760: 752: 751: 750: 730: 720: 700: 673: 670: 667: 654: 653: 640: 628: 624: 621: 612: 605: 602: 593: 582: 568: 565: 556: 549: 540: 533: 524: 513: 512: 511: 494: 491: 488: 485: 482: 479: 470: 459: 458: 457: 454: 451: 447: 444: 443:heat capacity 439: 435: 431: 426: 423: 413: 406: 404: 398:Constant flux 397: 395: 388: 386: 380: 378: 371: 369: 366: 360: 352: 350: 348: 342: 339: 330: 323: 321: 314: 312: 306: 280: 276: 272: 267: 263: 250: 246: 243: 235: 233: 229: 225: 221: 217: 212: 209: 205: 204:heat capacity 201: 197: 193: 189: 181: 177: 173: 169: 165: 161: 157: 153: 148: 138: 135: 127: 124:November 2017 116: 113: 109: 106: 102: 99: 95: 92: 88: 85: –  84: 83:"Calorimeter" 80: 79:Find sources: 73: 69: 63: 62: 57:This article 55: 51: 46: 45: 40: 33: 19: 4158: 4154: 4148: 4097:Fire blanket 4035:Eye and hand 4021:Rubber apron 3885:Oscilloscope 3849:Potentiostat 3776:Plate reader 3717: 3672:pH indicator 3642:CHN analyzer 3637:AutoAnalyzer 3430:Round-bottom 3323:Boston round 3186:Filter paper 3141:Refrigerator 3058:Retort stand 3026:Clamp holder 3022:Beaker clamp 2988:Vortex mixer 2983:Stirring rod 2978:Static mixer 2908:Teclu burner 2775:, March 2015 2750: 2724: 2720: 2714: 2689:. Retrieved 2682:the original 2669: 2658:. Retrieved 2654:the original 2644: 2634: 2625: 2606: 2597: 2591: 2580:. Retrieved 2558: 2554: 2544: 2534: 2525: 2469: 2465: 2456: 2452: 2448: 2427:biochemistry 2424: 2413: 2371: 2367: 2362: 2360: 2353: 2346: 2266: 2259: 2240: 2236: 2221: 2145:thermocouple 2140: 2136: 2132: 2125: 2120: 2117: 2112: 2108: 2104: 2094: 2092: 2079: 2077: 2062: 2055: 2051: 1923: 1852: 1831: 1829: 1821: 1803:Joule effect 1800: 1776: 1763: 1757: 1750: 1744: 1740: 1733: 1726: 1717: 1710: 1704: 1695: 1686: 1677: 1640: 1624: 1537: 1292: 1237: 1230: 1175: 1095:benzoic acid 1092: 1011: 721: 691: 617:surroundings 561:surroundings 509: 455: 452: 448: 438:vaporization 427: 418: 401: 392: 384: 375: 362: 347:thermal mass 343: 335: 318: 304: 236: 224:temperatures 214:To find the 213: 187: 185: 172:Joseph Black 151: 130: 121: 111: 104: 97: 90: 78: 66:Please help 61:verification 58: 4204:Calorimetry 4085:Other items 4011:Face shield 3858:Measurement 3839:Galvanostat 3799:Electronics 3749:Other items 3735:Thermometer 3718:Calorimeter 3647:Colorimeter 3591:Gas syringe 3574:Other items 3502:Eye dropper 3377:Watch glass 3362:Evaporating 3341:Cold finger 3156:Other items 3062:Screw clamp 3054:Pinch clamp 3043:Flask clamp 2993:Wash bottle 2948:Homogenizer 2721:Geothermics 1160: cal/g 1122: cal/g 972: cal g 908: cal g 218:change per 202:as well as 192:calorimetry 188:calorimeter 176:latent heat 4188:Categories 4161:(3): 534. 4016:Respirator 3957:Test probe 3875:Multimeter 3687:Microscopy 3507:Eudiometer 3471:Separatory 3440:Volumetric 3405:Erlenmeyer 3333:Condensers 3297:Dean–Stark 3246:Wire brush 3206:Microscope 3201:Centrifuge 3176:Cork borer 3131:Petri dish 3106:Agar plate 3093:Containers 3076:Wire gauze 2913:Water bath 2875:Desiccator 2727:: 12–202. 2691:2014-07-25 2660:2010-07-12 2582:2007-03-12 2517:References 2386:exothermic 1860:insulation 1846:) and the 1787:thermopile 94:newspapers 4107:Fume hood 4052:Glove box 3905:Voltmeter 3290:Apparatus 3279:Glassware 3168:Autoclave 3163:Aspirator 3116:Incubator 3050:Iron ring 2973:Sonicator 2943:Chemostat 2885:Hot plate 2416:titration 2390:stability 2347:From the 2311:β 2228:Ohm's law 2207:β 2158:Δ 2096:heat flux 2088:aluminium 2084:heat flow 1989:Δ 1964:Δ 1903:Δ 1892:Δ 1855:Styrofoam 1844:adiabatic 1796:flow rate 1779:fluxmeter 1602:Δ 1576:Δ 1517:Δ 1502:Δ 1483:→ 1474:Δ 1448:Δ 1405:Δ 1369:Δ 1320:Δ 1304:Δ 1269:− 1250:Δ 1207:− 1188:Δ 1073:Δ 992:− 977:− 928:− 913:− 638:Δ 625:− 609:Δ 606:− 590:Δ 553:Δ 537:Δ 521:Δ 467:Δ 338:adiabatic 273:− 208:titration 4006:Lab coat 3931:Tweezers 3921:Heat gun 3677:pH meter 3586:Bell jar 3466:Dropping 3420:Florence 3410:Fernbach 3372:Syracuse 3231:Scoopula 3181:Crucible 2890:Lab oven 2700:cite web 2615:Archived 2577:15113737 2481:Enthalpy 2475:See also 2378:pressure 2349:integral 1840:solution 1836:enthalpy 1789:of high 959:v(steel) 895:v(water) 811:v(steel) 788:v(water) 434:enthalpy 216:enthalpy 4163:Bibcode 3945:General 3865:Ammeter 3565:Thistle 3522:Pipette 3497:Cuvette 3487:Burette 3456:Büchner 3449:Funnels 3435:Schlenk 3415:Fleaker 3395:Büchner 3316:Bottles 3236:Spatula 3226:Stopper 3196:Forceps 3096:Storage 3013:Holders 2933:Shakers 2904:Striker 2852:Heaters 2839:General 2729:Bibcode 2491:Calorie 2431:enzymes 2398:ambient 2356:polymer 2255:⁠ 2243:⁠ 2082:(DSC), 1862:. Then 1671:⁠ 1644:⁠ 1355:benzoic 1335:benzoic 1235:cal/g. 1215:initial 987: K 923: K 315:History 108:scholar 3979:Safety 3581:Beaker 3560:Thiele 3545:Cragie 3540:Drying 3461:Hirsch 3425:Retort 3387:Flasks 3355:Dishes 3346:Liebig 3307:Kipp's 3221:Splint 3031:Tripod 3009:Clamps 3005:Stands 2968:Shaker 2930:Mixers 2855:Dryers 2575:  2058:  1924:where 1480:  1422:  1416:  1393:  1387:  1358:  1338:  1264:before 1240:  1233:  692:where 598:system 545:system 430:oxygen 298:where 232:energy 110:  103:  96:  89:  81:  3914:Tools 3532:Tubes 3367:Petri 2685:(PDF) 2678:(PDF) 2093:In a 2078:In a 1538:Once 1277:after 1202:final 866:steel 839:water 801:steel 778:water 529:total 475:total 115:JSTOR 101:books 3596:Vial 3555:Test 3191:File 2895:Kiln 2706:link 2573:PMID 2486:Heat 2374:gold 1700:and 1425:wire 1419:fuse 1396:wire 1390:fuse 1361:acid 1341:acid 1156:6957 1118:6318 853:and 220:mole 164:heat 158:and 87:news 4171:doi 2737:doi 2563:doi 2382:bar 2098:DSC 1730:LFC 1718:LFC 1173:). 967:0.1 436:of 336:An 198:or 70:by 4190:: 4169:. 4159:33 4157:. 2771:, 2762:- 2735:. 2725:53 2723:. 2702:}} 2698:{{ 2571:. 2559:79 2557:. 2553:. 2361:A 2260:RI 2258:= 2252:dt 2246:dQ 2239:= 2137:dt 2133:dq 2111:= 2109:dt 2105:dT 1756:− 1754:FC 1748:FC 1743:− 1732:= 1696:FC 1678:FC 1413:Ni 1384:Ni 186:A 4177:. 4173:: 4165:: 2819:e 2812:t 2805:v 2743:. 2739:: 2731:: 2708:) 2694:. 2663:. 2600:. 2585:. 2565:: 2332:) 2329:T 2326:, 2323:t 2320:( 2317:f 2314:+ 2306:p 2302:C 2298:= 2292:t 2289:d 2284:q 2281:d 2263:. 2249:/ 2241:R 2237:V 2235:Δ 2201:p 2197:C 2193:K 2190:= 2184:t 2181:d 2176:q 2173:d 2167:K 2164:= 2161:T 2141:T 2135:/ 2129:p 2126:C 2113:β 2107:/ 2036:M 2014:W 1992:T 1967:H 1940:p 1936:C 1906:T 1900:M 1895:H 1889:W 1883:= 1878:p 1874:C 1767:W 1764:m 1761:W 1758:C 1751:m 1745:C 1741:T 1739:Δ 1737:v 1734:C 1727:C 1715:C 1711:T 1705:W 1702:m 1693:m 1687:W 1684:C 1675:C 1657:v 1653:C 1632:2 1627:O 1605:T 1597:v 1593:C 1589:= 1584:c 1580:H 1551:v 1547:C 1520:T 1510:c 1506:H 1496:= 1491:v 1487:C 1477:T 1469:v 1465:C 1461:= 1456:c 1452:H 1409:m 1399:) 1381:( 1377:c 1373:H 1366:+ 1351:m 1344:) 1332:( 1328:c 1324:H 1317:= 1312:c 1308:H 1273:m 1260:m 1256:= 1253:m 1211:T 1198:T 1194:= 1191:T 1178:T 1153:= 1148:c 1144:H 1115:= 1110:c 1106:H 1097:( 1076:T 1067:c 1063:H 1057:= 1052:v 1048:C 1025:v 1021:C 995:1 980:1 964:= 955:C 931:1 916:1 903:1 900:= 891:C 862:m 835:m 807:C 797:m 793:+ 784:C 774:m 770:= 761:C 735:v 731:C 705:v 701:C 686:) 674:0 671:= 668:V 664:d 641:T 633:v 629:C 622:= 613:E 603:= 594:E 569:0 566:= 557:E 550:+ 541:E 534:= 525:E 495:0 492:= 489:W 486:+ 483:Q 480:= 471:E 308:v 305:C 300:q 286:) 281:i 277:T 268:f 264:T 260:( 255:v 251:C 247:= 244:q 182:. 137:) 131:( 126:) 122:( 112:· 105:· 98:· 91:· 64:. 41:. 34:. 20:)

Index

Bomb calorimeter
Calorimeter (particle physics)
Colorimeter (chemistry)

verification
improve this article
adding citations to reliable sources
"Calorimeter"
news
newspapers
books
scholar
JSTOR
Learn how and when to remove this message

Antoine Lavoisier
Pierre-Simon Laplace
heat
chemical changes
Joseph Black
latent heat
thermochemistry
calorimetry
chemical reactions
physical changes
heat capacity
titration
enthalpy
mole
temperatures

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.