Knowledge (XXG)

Capped octahedral molecular geometry

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Roald. Hoffmann; Barbara F. Beier; Earl L. Muetterties; Angelo R. Rossi (1977). "Seven-coordination. A molecular orbital exploration of structure, stereochemistry, and reaction dynamics".
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describes the shape of compounds where seven atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a
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Zhenyang Lin; Ian Bytheway (1996). "Stereochemistry of Seven-Coordinate Main Group and d0 Transition Metal Molecules".
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and is one of the three common shapes for heptacoordinate transition metal complexes, along with the
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Examples of the capped octahedral molecular geometry are the heptafluoromolybdate (
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Kaupp, Martin (2001). ""Non-VSEPR" Structures and Bonding in d(0) Systems".
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10.1002/1521-3773(20011001)40:19<3534::AID-ANIE3534>3.0.CO;2-#
184: 268: 278: 282: 577: 511: 485: 459: 433: 407: 381: 355: 334: 63: 50: 32: 18: 597: 294: 8: 604: 590: 301: 287: 279: 24: 201:5th edition Oxford Science Publications 161: 15: 7: 558: 556: 81:capped octahedral molecular geometry 19:Capped octahedral molecular geometry 576:. You can help Knowledge (XXG) by 14: 560: 537: 536: 117:) and the heptafluorotungstate ( 85:gyroelongated triangular pyramid 199:Structural Inorganic Chemistry 1: 134:distorted octahedral geometry 519:Tricapped trigonal prismatic 524:Capped square antiprismatic 503:Bicapped trigonal prismatic 649: 555: 532: 477:Capped trigonal prismatic 316: 23: 467:Pentagonal bipyramidal 220:Angew Chem Int Ed Engl 136:" exhibited by some AX 633:Stereochemistry stubs 512:Coordination number 9 486:Coordination number 8 460:Coordination number 7 434:Coordination number 6 408:Coordination number 5 382:Coordination number 4 356:Coordination number 3 335:Coordination number 2 100:capped trigonal prism 493:Square antiprismatic 451:Pentagonal pyramidal 415:Trigonal bipyramidal 96:pentagonal bipyramid 326:Coordination number 256:Inorganic Chemistry 185:10.1021/ic50169a002 172:Inorganic Chemistry 65:Coordination number 628:Molecular geometry 446:Trigonal prismatic 368:Trigonal pyramidal 310:Molecular geometry 197:Wells A.F. (1984) 146:xenon hexafluoride 144:molecules such as 87:. This shape has C 585: 584: 550: 549: 472:Capped octahedral 425:Pentagonal planar 269:10.1021/ic950271o 73: 72: 640: 606: 599: 592: 564: 557: 540: 539: 420:Square pyramidal 303: 296: 289: 280: 273: 272: 250: 244: 243: 226:(1): 3534–3565. 215: 209: 195: 189: 188: 166: 128: 127: 126: 116: 115: 114: 46: 45: 44: 28: 16: 648: 647: 643: 642: 641: 639: 638: 637: 623:Stereochemistry 613: 612: 611: 610: 570:stereochemistry 553: 551: 546: 528: 507: 481: 455: 429: 403: 377: 363:Trigonal planar 351: 330: 312: 307: 277: 276: 252: 251: 247: 217: 216: 212: 196: 192: 168: 167: 163: 158: 151: 143: 139: 125: 122: 121: 120: 118: 113: 110: 109: 108: 106: 90: 59: 43: 40: 39: 38: 36: 12: 11: 5: 646: 644: 636: 635: 630: 625: 615: 614: 609: 608: 601: 594: 586: 583: 582: 565: 548: 547: 545: 544: 533: 530: 529: 527: 526: 521: 515: 513: 509: 508: 506: 505: 500: 495: 489: 487: 483: 482: 480: 479: 474: 469: 463: 461: 457: 456: 454: 453: 448: 443: 437: 435: 431: 430: 428: 427: 422: 417: 411: 409: 405: 404: 402: 401: 396: 391: 385: 383: 379: 378: 376: 375: 370: 365: 359: 357: 353: 352: 350: 349: 344: 338: 336: 332: 331: 329: 328: 323: 317: 314: 313: 308: 306: 305: 298: 291: 283: 275: 274: 263:(3): 594–603. 245: 210: 190: 179:(3): 511–522. 160: 159: 157: 154: 149: 141: 137: 123: 111: 88: 71: 70: 67: 61: 60: 57: 54: 48: 47: 41: 34: 30: 29: 21: 20: 13: 10: 9: 6: 4: 3: 2: 645: 634: 631: 629: 626: 624: 621: 620: 618: 607: 602: 600: 595: 593: 588: 587: 581: 579: 575: 572:article is a 571: 566: 563: 559: 554: 543: 535: 534: 531: 525: 522: 520: 517: 516: 514: 510: 504: 501: 499: 496: 494: 491: 490: 488: 484: 478: 475: 473: 470: 468: 465: 464: 462: 458: 452: 449: 447: 444: 442: 439: 438: 436: 432: 426: 423: 421: 418: 416: 413: 412: 410: 406: 400: 399:Square planar 397: 395: 392: 390: 387: 386: 384: 380: 374: 371: 369: 366: 364: 361: 360: 358: 354: 348: 345: 343: 340: 339: 337: 333: 327: 324: 322: 319: 318: 315: 311: 304: 299: 297: 292: 290: 285: 284: 281: 270: 266: 262: 258: 257: 249: 246: 241: 237: 233: 229: 225: 221: 214: 211: 208: 207:0-19-855370-6 204: 200: 194: 191: 186: 182: 178: 174: 173: 165: 162: 155: 153: 147: 135: 130: 103: 101: 97: 93: 86: 82: 78: 68: 66: 62: 55: 53: 49: 35: 31: 27: 22: 17: 578:expanding it 567: 552: 498:Dodecahedral 471: 321:VSEPR theory 260: 254: 248: 223: 219: 213: 198: 193: 176: 170: 164: 131: 104: 80: 74: 389:Tetrahedral 52:Point group 617:Categories 441:Octahedral 156:References 77:chemistry 542:Category 373:T-shaped 240:11592184 129:) ions. 98:and the 92:symmetry 33:Examples 394:Seesaw 342:Linear 238:  205:  79:, the 568:This 132:The " 574:stub 347:Bent 236:PMID 203:ISBN 148:(XeF 265:doi 228:doi 181:doi 107:MoF 75:In 37:MoF 619:: 261:35 259:. 234:. 224:40 222:. 177:16 175:. 119:WF 102:. 89:3v 58:3v 605:e 598:t 591:v 580:. 302:e 295:t 288:v 271:. 267:: 242:. 230:: 187:. 183:: 150:6 142:1 140:E 138:6 124:7 112:7 69:7 56:C 42:7

Index


Point group
Coordination number
chemistry
gyroelongated triangular pyramid
symmetry
pentagonal bipyramid
capped trigonal prism
distorted octahedral geometry
xenon hexafluoride
Inorganic Chemistry
doi
10.1021/ic50169a002
ISBN
0-19-855370-6
doi
10.1002/1521-3773(20011001)40:19<3534::AID-ANIE3534>3.0.CO;2-#
PMID
11592184
Inorganic Chemistry
doi
10.1021/ic950271o
v
t
e
Molecular geometry
VSEPR theory
Coordination number
Linear
Bent

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