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Clarke's equation

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Suppose a radially symmetric hot source is deposited instantaneously in a reacting mixture. When the chemical time is comparable to the acoustic time, diffusion is neglected so that ignition is characterised by heat release by the chemical energy and cooling by the expansion waves. This problem is
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Clarke, J. F. (1981), "Propagation of Gasdynamic Disturbances in an Explosive Atmosphere", in Combustion in Reactive Systems, J.R. Bowen, R.I. Soloukhin, N. Manson, and A.K. Oppenheim (Eds), Progress in Astronautics and Aeronautics, pp.
1039: 1361: 193:{\displaystyle {\frac {\partial ^{2}}{\partial t^{2}}}\left({\frac {\partial \theta }{\partial t}}-\gamma \delta e^{\theta }\right)=\nabla ^{2}\left({\frac {\partial \theta }{\partial t}}-\delta e^{\theta }\right)} 2102:{\displaystyle \left({\frac {\partial ^{2}}{\partial t^{2}}}-\nabla ^{2}\right){\frac {\partial \theta }{\partial t}}=\left(\gamma {\frac {\partial ^{2}}{\partial t^{2}}}-\nabla ^{2}\right)\delta \omega (\theta )} 359:{\displaystyle \left({\frac {\partial ^{2}}{\partial t^{2}}}-\nabla ^{2}\right){\frac {\partial \theta }{\partial t}}=\left(\gamma {\frac {\partial ^{2}}{\partial t^{2}}}-\nabla ^{2}\right)\delta e^{\theta }} 657: 538: 947: 2168:
Clarke, J. F. (1978). "A progress report on the theoretical analysis of the interaction between a shock wave and an explosive gas mixture", College of Aeronautics report. 7801, Cranfield Inst. of Tech.
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Kapila, A. K., and J. W. Dold. "Evolution to detonation in a nonuniformly heated reactive medium." Asymptotic Analysis and the Numerical Solution of Partial Differential Equations 130 (1991).
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Vázquez-Espí, C., & Liñán, A. (2001). Fast, non-diffusive ignition of a gaseous reacting mixture subject to a point energy source. Combustion Theory and Modelling, 5(3), 485.
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Clarke, J. F. (1982). "Non-steady Gas Dynamic Effects in the Induction Domain Behind a Strong Shock Wave", College of Aeronautics report. 8229, Cranfield Inst. of Tech.
1640: 1614: 1258: 756: 680: 437: 387: 1934: 855: 1031: 1011: 991: 967: 875: 1206:{\displaystyle t=0:\,-\theta =r^{2},\quad r=0:\,{\frac {\partial \theta }{\partial r}}=0,\quad r\gg 1:\,-\theta =r^{2}+(j+1){\frac {\gamma -1}{\gamma }}t^{2},} 1266: 2273: 39:
process, including both effects of constant-volume and constant-pressure processes, as well as the effects of adiabatic and isothermal
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Clarke, J. F. (1978). Small amplitude gasdynamic disturbances in an exploding atmosphere. Journal of Fluid Mechanics, 89(2), 343–355.
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be the time, measured in units of acoustic time. In this case, the initial and boundary conditions are given by
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describes the wave propagation at isothermal sound speed. Molecular transports are neglected in the derivation.
2150: 1526: 2278: 1744: 1559: 1260:, respectively, corresponds to the planar, cylindrical and spherical problems. Let us define a new variable 1711: 1678: 1645: 1513:{\displaystyle \varphi =\gamma \delta te^{-r^{2}}+{\frac {1}{2}}(\gamma \delta t)^{2}e^{-2r^{2}}+\cdots } 32: 2115: 440: 2283: 416: 1369: 392: 1619: 1592: 1219: 741: 665: 422: 372: 2227: 1912: 833: 36: 16:
Equation that calculates gas diffusion across membranes in biological and medical contexts
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https://repository.tudelft.nl/view/aereports/uuid%3A9c064b5f-97b4-4527-a97e-a805d5e1abd7
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Example: Fast, non-diffusive ignition by deposition of a radially symmetric hot source
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from its distant values. Then, at small times, the asymptotic solution is given by
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denote the distance from the center, measured in units of initial hot core size and
2209: 970: 1356:{\displaystyle \varphi (r,t)=\theta +r^{2}+(j+1){\frac {\gamma -1}{\gamma }}t^{2}} 40: 20: 2232: 2213: 540:
describes the thermal explosion at constant volume. Similarly, the term
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describes the wave propagation at adiabatic sound speed and the term
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describes the thermal explosion at constant pressure and the term
652:{\displaystyle \gamma \partial ^{2}/\partial t^{2}-\nabla ^{2}} 533:{\displaystyle \partial \theta /\partial t-\gamma e^{\theta }} 942:{\displaystyle \varepsilon T_{m}\equiv RT_{m}^{2}/E\ll T_{m}} 1944:
For generalised form for the reaction term, one may write
1843:{\displaystyle \varphi =-\ln(1-\gamma \delta te^{-r^{2}})} 758:
may also appear in the initial and boundary conditions.
591:{\displaystyle \partial ^{2}/\partial t^{2}-\nabla ^{2}} 1774:, the solution in the first approximation is given by 682:
can be removed from the equation by the transformation
483:{\displaystyle \partial \theta /\partial t-e^{\theta }} 2141:
is arbitrary function representing the reaction term.
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As time progresses, a steady state is approached when
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Biographical Memoirs of Fellows of the Royal Society
823:{\displaystyle \theta =(T_{m}-T)/\varepsilon T_{m}} 2133: 2101: 1928: 1901: 1842: 1766: 1733: 1700: 1667: 1634: 1608: 1581: 1548: 1512: 1393: 1355: 1252: 1205: 1025: 1005: 985: 961: 941: 869: 849: 822: 750: 730: 674: 651: 590: 532: 482: 431: 407: 381: 358: 192: 2214:"John Frederick Clarke 1 May 1927 – 11 June 2013" 389:is the non-dimensional temperature perturbation, 1902:{\displaystyle t=t_{i}\equiv 1/(\gamma \delta )} 1556:and a thermal explosion is found to occur when 1853:which shows that thermal explosion occurs at 993:is the activation energy). Furthermore, let 8: 731:{\displaystyle (x,t)\to (\delta x,\delta t)} 2231: 2117: 2073: 2057: 2043: 2037: 2006: 1995: 1979: 1965: 1959: 1952: 1920: 1914: 1882: 1870: 1858: 1829: 1821: 1782: 1758: 1746: 1719: 1713: 1686: 1680: 1653: 1647: 1621: 1600: 1594: 1573: 1561: 1540: 1528: 1496: 1485: 1475: 1449: 1438: 1430: 1409: 1371: 1347: 1325: 1301: 1268: 1221: 1194: 1172: 1148: 1134: 1092: 1091: 1069: 1055: 1041: 1018: 998: 978: 954: 933: 918: 912: 907: 891: 882: 862: 841: 835: 814: 802: 787: 772: 743: 687: 667: 643: 630: 618: 612: 603: 582: 569: 557: 551: 545: 524: 503: 495: 474: 456: 448: 424: 394: 374: 350: 332: 316: 302: 296: 265: 254: 238: 224: 218: 211: 179: 149: 138: 120: 87: 73: 59: 53: 51: 2245: 2243: 2161: 1616:is the Frank-Kamenetskii parameter; if 1549:{\displaystyle \delta \leq \delta _{c}} 767:governed by the Clarke's equation with 1767:{\displaystyle \delta \gg \delta _{c}} 1582:{\displaystyle \delta >\delta _{c}} 949:is the Frank-Kamenetskii temperature ( 738:, it is, however, retained here since 7: 857:is the maximum initial temperature, 35:in 1978. The equation describes the 1734:{\displaystyle \delta _{c}=0.91448} 1701:{\displaystyle \delta _{c}=0.73583} 1668:{\displaystyle \delta _{c}=0.50340} 2070: 2050: 2040: 2017: 2009: 1992: 1972: 1962: 1103: 1095: 640: 623: 609: 579: 562: 548: 508: 497: 461: 450: 329: 309: 299: 276: 268: 251: 231: 221: 160: 152: 135: 98: 90: 66: 56: 14: 662:It may appear that the parameter 2134:{\displaystyle \omega (\theta )} 1121: 1078: 2274:Partial differential equations 2128: 2122: 2096: 2090: 1896: 1887: 1837: 1799: 1472: 1459: 1388: 1376: 1322: 1310: 1285: 1273: 1247: 1229: 1169: 1157: 799: 780: 725: 707: 704: 701: 689: 1: 29:partial differential equation 1708:in the cylindrical case and 1394:{\displaystyle \theta (r,t)} 408:{\displaystyle \gamma >1} 1741:in the spherical case. For 1635:{\displaystyle \gamma =1.4} 1609:{\displaystyle \delta _{c}} 27:is a third-order nonlinear 2300: 1366:which is the increment of 1253:{\displaystyle j=(0,1,2)} 2151:Frank-Kamenetskii theory 43:. The equation reads as 1936:is the ignition time. 877:is the temperature and 751:{\displaystyle \delta } 675:{\displaystyle \delta } 432:{\displaystyle \delta } 382:{\displaystyle \theta } 2233:10.1098/rsbm.2014.0012 2135: 2103: 1930: 1903: 1844: 1768: 1735: 1702: 1669: 1636: 1610: 1583: 1550: 1514: 1395: 1357: 1254: 1207: 1027: 1007: 987: 963: 943: 871: 851: 824: 752: 732: 676: 653: 592: 534: 484: 433: 409: 383: 360: 194: 2136: 2104: 1931: 1929:{\displaystyle t_{i}} 1904: 1845: 1769: 1736: 1703: 1670: 1637: 1611: 1584: 1551: 1515: 1396: 1358: 1255: 1208: 1028: 1008: 988: 964: 944: 872: 852: 850:{\displaystyle T_{m}} 825: 753: 733: 677: 654: 593: 535: 485: 434: 410: 384: 361: 195: 33:John Frederick Clarke 2212:; Riley, N. (2014). 2116: 1951: 1913: 1857: 1781: 1745: 1712: 1679: 1675:in the planar case, 1646: 1620: 1593: 1560: 1527: 1408: 1370: 1267: 1220: 1040: 1017: 997: 977: 953: 881: 861: 834: 771: 742: 686: 666: 602: 544: 494: 447: 423: 393: 373: 210: 50: 917: 417:specific heat ratio 31:, first derived by 2131: 2099: 1926: 1899: 1840: 1764: 1731: 1698: 1665: 1632: 1606: 1579: 1546: 1510: 1391: 1353: 1250: 1203: 1023: 1003: 983: 959: 939: 903: 867: 847: 820: 748: 728: 672: 649: 588: 530: 480: 429: 405: 379: 356: 203:or, alternatively 190: 2064: 2024: 1986: 1457: 1341: 1188: 1110: 1026:{\displaystyle t} 1006:{\displaystyle r} 986:{\displaystyle E} 962:{\displaystyle R} 870:{\displaystyle T} 323: 283: 245: 167: 105: 80: 37:thermal explosion 25:Clarke's equation 2291: 2259: 2256: 2250: 2247: 2238: 2237: 2235: 2206: 2200: 2194: 2188: 2184: 2178: 2175: 2169: 2166: 2140: 2138: 2137: 2132: 2108: 2106: 2105: 2100: 2083: 2079: 2078: 2077: 2065: 2063: 2062: 2061: 2048: 2047: 2038: 2025: 2023: 2015: 2007: 2005: 2001: 2000: 1999: 1987: 1985: 1984: 1983: 1970: 1969: 1960: 1940:Generalised form 1935: 1933: 1932: 1927: 1925: 1924: 1908: 1906: 1905: 1900: 1886: 1875: 1874: 1849: 1847: 1846: 1841: 1836: 1835: 1834: 1833: 1773: 1771: 1770: 1765: 1763: 1762: 1740: 1738: 1737: 1732: 1724: 1723: 1707: 1705: 1704: 1699: 1691: 1690: 1674: 1672: 1671: 1666: 1658: 1657: 1641: 1639: 1638: 1633: 1615: 1613: 1612: 1607: 1605: 1604: 1588: 1586: 1585: 1580: 1578: 1577: 1555: 1553: 1552: 1547: 1545: 1544: 1519: 1517: 1516: 1511: 1503: 1502: 1501: 1500: 1480: 1479: 1458: 1450: 1445: 1444: 1443: 1442: 1400: 1398: 1397: 1392: 1362: 1360: 1359: 1354: 1352: 1351: 1342: 1337: 1326: 1306: 1305: 1259: 1257: 1256: 1251: 1212: 1210: 1209: 1204: 1199: 1198: 1189: 1184: 1173: 1153: 1152: 1111: 1109: 1101: 1093: 1074: 1073: 1032: 1030: 1029: 1024: 1012: 1010: 1009: 1004: 992: 990: 989: 984: 968: 966: 965: 960: 948: 946: 945: 940: 938: 937: 922: 916: 911: 896: 895: 876: 874: 873: 868: 856: 854: 853: 848: 846: 845: 829: 827: 826: 821: 819: 818: 806: 792: 791: 757: 755: 754: 749: 737: 735: 734: 729: 681: 679: 678: 673: 658: 656: 655: 650: 648: 647: 635: 634: 622: 617: 616: 597: 595: 594: 589: 587: 586: 574: 573: 561: 556: 555: 539: 537: 536: 531: 529: 528: 507: 489: 487: 486: 481: 479: 478: 460: 441:Damköhler number 439:is the relevant 438: 436: 435: 430: 414: 412: 411: 406: 388: 386: 385: 380: 365: 363: 362: 357: 355: 354: 342: 338: 337: 336: 324: 322: 321: 320: 307: 306: 297: 284: 282: 274: 266: 264: 260: 259: 258: 246: 244: 243: 242: 229: 228: 219: 199: 197: 196: 191: 189: 185: 184: 183: 168: 166: 158: 150: 143: 142: 130: 126: 125: 124: 106: 104: 96: 88: 81: 79: 78: 77: 64: 63: 54: 2299: 2298: 2294: 2293: 2292: 2290: 2289: 2288: 2264: 2263: 2262: 2257: 2253: 2248: 2241: 2208: 2207: 2203: 2195: 2191: 2185: 2181: 2176: 2172: 2167: 2163: 2159: 2147: 2114: 2113: 2069: 2053: 2049: 2039: 2033: 2029: 2016: 2008: 1991: 1975: 1971: 1961: 1958: 1954: 1949: 1948: 1942: 1916: 1911: 1910: 1866: 1855: 1854: 1825: 1817: 1779: 1778: 1754: 1743: 1742: 1715: 1710: 1709: 1682: 1677: 1676: 1649: 1644: 1643: 1618: 1617: 1596: 1591: 1590: 1569: 1558: 1557: 1536: 1525: 1524: 1492: 1481: 1471: 1434: 1426: 1406: 1405: 1368: 1367: 1343: 1327: 1297: 1265: 1264: 1218: 1217: 1190: 1174: 1144: 1102: 1094: 1065: 1038: 1037: 1015: 1014: 995: 994: 975: 974: 951: 950: 929: 887: 879: 878: 859: 858: 837: 832: 831: 810: 783: 769: 768: 764: 740: 739: 684: 683: 664: 663: 639: 626: 608: 600: 599: 578: 565: 547: 542: 541: 520: 492: 491: 470: 445: 444: 421: 420: 391: 390: 371: 370: 346: 328: 312: 308: 298: 292: 288: 275: 267: 250: 234: 230: 220: 217: 213: 208: 207: 175: 159: 151: 148: 144: 134: 116: 97: 89: 86: 82: 69: 65: 55: 48: 47: 17: 12: 11: 5: 2297: 2295: 2287: 2286: 2281: 2279:Fluid dynamics 2276: 2266: 2265: 2261: 2260: 2251: 2239: 2210:Bray, K. N. 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The term 2284:Combustion 2268:Categories 2226:: 87–106. 2157:References 21:combustion 2126:θ 2120:ω 2094:θ 2088:ω 2085:δ 2071:∇ 2067:− 2051:∂ 2041:∂ 2035:γ 2018:∂ 2013:θ 2010:∂ 1993:∇ 1989:− 1973:∂ 1963:∂ 1894:δ 1891:γ 1877:≡ 1823:− 1812:δ 1809:γ 1806:− 1797:⁡ 1791:− 1785:φ 1756:δ 1752:≫ 1749:δ 1717:δ 1684:δ 1651:δ 1624:γ 1598:δ 1571:δ 1564:δ 1538:δ 1534:≤ 1531:δ 1508:⋯ 1487:− 1466:δ 1463:γ 1432:− 1421:δ 1418:γ 1412:φ 1374:θ 1339:γ 1332:− 1329:γ 1292:θ 1271:φ 1186:γ 1179:− 1176:γ 1139:θ 1136:− 1126:≫ 1104:∂ 1099:θ 1096:∂ 1060:θ 1057:− 927:≪ 898:≡ 885:ε 808:ε 794:− 775:θ 746:δ 720:δ 711:δ 705:→ 670:δ 641:∇ 637:− 624:∂ 610:∂ 606:γ 580:∇ 576:− 563:∂ 549:∂ 526:θ 518:γ 515:− 509:∂ 501:θ 498:∂ 476:θ 468:− 462:∂ 454:θ 451:∂ 427:δ 397:γ 377:θ 352:θ 344:δ 330:∇ 326:− 310:∂ 300:∂ 294:γ 277:∂ 272:θ 269:∂ 252:∇ 248:− 232:∂ 222:∂ 181:θ 173:δ 170:− 161:∂ 156:θ 153:∂ 136:∇ 122:θ 114:δ 111:γ 108:− 99:∂ 94:θ 91:∂ 67:∂ 57:∂ 2187:383-402. 2145:See also 1909:, where 1589:, where 830:, where 1729:0.91448 1696:0.73583 1663:0.50340 1642:, then 969:is the 415:is the 2112:where 1216:where 369:where 1567:> 973:and 419:and 400:> 2228:doi 1630:1.4 19:In 2270:: 2242:^ 2224:60 2222:. 2216:. 1794:ln 23:, 2236:. 2230:: 2129:) 2123:( 2097:) 2091:( 2081:) 2075:2 2059:2 2055:t 2045:2 2031:( 2027:= 2021:t 2003:) 1997:2 1981:2 1977:t 1967:2 1956:( 1922:i 1918:t 1897:) 1888:( 1884:/ 1880:1 1872:i 1868:t 1864:= 1861:t 1838:) 1831:2 1827:r 1819:e 1815:t 1803:1 1800:( 1788:= 1760:c 1726:= 1721:c 1693:= 1688:c 1660:= 1655:c 1627:= 1602:c 1575:c 1542:c 1505:+ 1498:2 1494:r 1490:2 1483:e 1477:2 1473:) 1469:t 1460:( 1455:2 1452:1 1447:+ 1440:2 1436:r 1428:e 1424:t 1415:= 1389:) 1386:t 1383:, 1380:r 1377:( 1349:2 1345:t 1335:1 1323:) 1320:1 1317:+ 1314:j 1311:( 1308:+ 1303:2 1299:r 1295:+ 1289:= 1286:) 1283:t 1280:, 1277:r 1274:( 1248:) 1245:2 1242:, 1239:1 1236:, 1233:0 1230:( 1227:= 1224:j 1201:, 1196:2 1192:t 1182:1 1170:) 1167:1 1164:+ 1161:j 1158:( 1155:+ 1150:2 1146:r 1142:= 1132:: 1129:1 1123:r 1119:, 1116:0 1113:= 1107:r 1089:: 1086:0 1083:= 1080:r 1076:, 1071:2 1067:r 1063:= 1053:: 1050:0 1047:= 1044:t 1021:t 1001:r 981:E 957:R 935:m 931:T 924:E 920:/ 914:2 909:m 905:T 901:R 893:m 889:T 865:T 843:m 839:T 816:m 812:T 804:/ 800:) 797:T 789:m 785:T 781:( 778:= 726:) 723:t 717:, 714:x 708:( 702:) 699:t 696:, 693:x 690:( 645:2 632:2 628:t 620:/ 614:2 584:2 571:2 567:t 559:/ 553:2 522:e 512:t 505:/ 472:e 465:t 458:/ 403:1 348:e 340:) 334:2 318:2 314:t 304:2 290:( 286:= 280:t 262:) 256:2 240:2 236:t 226:2 215:( 187:) 177:e 164:t 146:( 140:2 132:= 128:) 118:e 102:t 84:( 75:2 71:t 61:2

Index

combustion
partial differential equation
John Frederick Clarke
thermal explosion
sound speeds
specific heat ratio
Damköhler number
gas constant
Frank-Kamenetskii theory
https://repository.tudelft.nl/view/aereports/uuid%3A9c064b5f-97b4-4527-a97e-a805d5e1abd7
Bray, K. N. C.
"John Frederick Clarke 1 May 1927 – 11 June 2013"
Biographical Memoirs of Fellows of the Royal Society
doi
10.1098/rsbm.2014.0012


Categories
Partial differential equations
Fluid dynamics
Combustion

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